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21 pages, 4665 KiB  
Article
Hydrochemical Characteristics and Indicative Significance of Terminal Tributaries in Karst Water Systems: A Case Study of the Zhongdu River Basin in Southwest China
by Jun Zhang, Chi Chen, Jianwei Bu, Xing Xiong, Chunshan Xiao, Chenzhou Yang and Yinhe Huang
Water 2025, 17(6), 822; https://doi.org/10.3390/w17060822 (registering DOI) - 12 Mar 2025
Abstract
The terminal tributaries of karst rivers are often under-researched, with low investigation coverage and incomplete surveys. These areas face significant human activity disturbances, fragile soil and water environments, and insufficient research on water quality conditions. Residents in their basins are confronted with urgent [...] Read more.
The terminal tributaries of karst rivers are often under-researched, with low investigation coverage and incomplete surveys. These areas face significant human activity disturbances, fragile soil and water environments, and insufficient research on water quality conditions. Residents in their basins are confronted with urgent issues of water scarcity and deteriorating water quality. This study focused on the Zhongdu River Basin, a terminal tributary in the Pearl River system in Southwest China. By measuring the conventional hydrochemical parameters and stable isotope ratios (e.g., δ18O and δ2H), this study employed methods such as hydrological and geochemical approaches, as well as classical statistical analyses, to reveal the hydrochemical characteristics, regulatory mechanisms, and water health status in the basin. Data show that the water in the Zhongdu River Basin is generally weakly alkaline, with a pH range between 6.46 and 8.28. The highest values for electrical conductivity (EC) and total dissolved solids (TDSs) are found upstream, reaching 497 μS/cm and 324.5 mg/L, respectively. The average dissolved oxygen (DO) value is 71.3 mg/L. The hydrochemical type is primarily HCO3-Ca2⁺, with Ca2⁺ and HCO3⁻ as the dominant ions. The surface water in the middle and lower reaches of the basin is strongly influenced by evaporation, with atmospheric precipitation as the main recharge source. Rock weathering is the primary influencing factor in the basin, with most minerals in a dissolved state. Agricultural activities are the primary pollution source in the basin, with domestic pollution having a minimal effect on water quality. Water quality was assessed using the entropy-weighted water quality index (EWQI) based on 11 parameters, indicating overall good water quality, classified as Grade I. The findings indicate that human activities have a minimal impact on the water quality in the region, and the basin is expected to maintain its healthy condition for an extended period. Full article
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Figure 1
<p>Map of study area and sampling sites.</p>
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<p>Relationship diagram of TDS-TH in study area.</p>
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<p>Durov diagram of water samples in study area.</p>
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<p>Piper trilinear diagram of hydrochemistry.</p>
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<p>Cluster analysis of hydrochemical parameters.</p>
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<p>Study area hydrochemical parameter correlation heatmap.</p>
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<p>Study area δ2H−δ18O relationship diagram.</p>
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<p>Gibbs plot of water samples in the study area.</p>
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<p>Ion relationship diagram of water samples in the study area.</p>
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<p>Ion relationship diagram of water samples in the study area.</p>
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<p>Statistical data of CAI in the study area.</p>
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<p>Relationship between TDS and δ18O in the study area.</p>
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<p>Relationship between NO<sub>3</sub><sup>−</sup>/Cl<sup>−</sup> and K<sup>+</sup>/NO<sub>3</sub><sup>−</sup> in the study area.</p>
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16 pages, 11907 KiB  
Article
Impact of Climate, Phenology, and Soil Factors on Net Ecosystem Productivity in Zoigê Alpine Grassland
by Rui Qu, Zhengwei He, Li He, Joseph Awange, Yongze Song, Bing Wang, Bo Wen and Jiao Hu
Agronomy 2025, 15(3), 685; https://doi.org/10.3390/agronomy15030685 (registering DOI) - 12 Mar 2025
Abstract
Net ecosystem productivity (NEP) is a crucial metric for quantifying carbon storage, exchange, and cycling across global atmospheric and terrestrial ecosystems. This study examines the spatiotemporal patterns of NEP in China’s Zoigê alpine grassland and its response to climate variability, phenological changes, and [...] Read more.
Net ecosystem productivity (NEP) is a crucial metric for quantifying carbon storage, exchange, and cycling across global atmospheric and terrestrial ecosystems. This study examines the spatiotemporal patterns of NEP in China’s Zoigê alpine grassland and its response to climate variability, phenological changes, and soil conditions from 2000 to 2020. The results show a statistically significant increase in the annual NEP of the Zoigê Plateau, with an average rate of 3.18 g C/m2/year. Spatially, NEP displays strong heterogeneity, with higher values in the southwestern and northeastern marginal areas (>80 g C/m2) and lower values in the central region (<0 g C/m2). In alpine meadows (standardized total effect coefficient [STEC] = 0.52) and alpine steppes (STEC = 0.43), NEP is primarily regulated by soil moisture modulation, influenced by both water and temperature factors. This study accurately assesses NEP by incorporating regional soil characteristics, providing a more precise evaluation of changes in vegetation carbon sink sources in high-altitude areas. Full article
(This article belongs to the Special Issue Advances in Grassland Productivity and Sustainability — 2nd Edition)
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Figure 1
<p>Location of the study area: (<b>a</b>) the location of the Gansu and Sichuan Provinces in China; (<b>b</b>) the location of the Zoigê Plateau in Sichuan and Gansu; and (<b>c</b>) the Zoigê Plateau.</p>
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<p>Scatterplot of net ecosystem productivity (NEP) generated by the 2005, 2010, 2015, and 2020 models versus the validation product before NEP.</p>
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<p>Characteristics of interannual variations in the mean values of (<b>a</b>) net ecosystem productivity (NEP), (<b>b</b>) aridity index (AI), and (<b>c</b>) length Of the growing season (LOS). Note: The blue, yellow, and green lines in the figure represent the interannual variation of the predicted values, and the gray boundary represents the range of fluctuation of the predicted values; (<b>d</b>) Time–frequency distribution of LOS. Temporal variation of NEP (<b>e</b>), AI (<b>f</b>), and LOS (<b>g</b>) in (A) Alpine Meadow and (B) Alpine Steppe. Note: The left <span class="html-italic">y</span>-axis represents the mean values of NEP, AI, and LOS, respectively; the right <span class="html-italic">y</span>-axis represents the temporal trends of NEP, AI, and LOS, respectively.</p>
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<p>(<b>a</b>,<b>d</b>,<b>g</b>) Spatial distribution of aridity index (AI), net ecosystem productivity (NEP g C/m<sup>2</sup>), and LOS (day); (<b>b</b>,<b>e</b>,<b>h</b>) standard deviation; (<b>c</b>,<b>f</b>,<b>i</b>) temporal changes.</p>
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<p>Net ecosystem productivity (NEP) of alpine meadow systems in relation to climate, soil and phenological factors. (<b>a</b>) Precipitation (mm), (<b>b</b>) Temperature (°C), (<b>c</b>) AI, (<b>d</b>) LOS (day), (<b>e</b>) SM (m<sup>3</sup>/m<sup>3</sup>), (<b>f</b>) ST (°C), (<b>g</b>) AP (mg/kg), (<b>h</b>) TN (g/100 g), (<b>i</b>) SOM (g/100 g).</p>
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<p>Net ecosystem productivity (NEP) of alpine steppe systems in relation to climate, soil and phenological factors. (<b>a</b>) Precipitation (mm), (<b>b</b>) Temperature (°C), (<b>c</b>) AI, (<b>d</b>) LOS (day), (<b>e</b>) SM (m<sup>3</sup>/m<sup>3</sup>), (<b>f</b>) ST (°C), (<b>g</b>) AP (mg/kg), (<b>h</b>) TN (g/100 g), (<b>i</b>) SOM (g/100 g).</p>
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<p>Relationships among NEP, AI, and LOS for (<b>a</b>) alpine meadows, (<b>d</b>) alpine steppe, (<b>b</b>) alpine meadows, (<b>e</b>) alpine steppe, and the aridity index (AI); (<b>c</b>) alpine meadows, (<b>f</b>) alpine steppe, and the relationship between annual mean precipitation (AMP) and annual mean temperature (AMT).</p>
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<p>Mechanisms affecting NEP distribution in (<b>a</b>) alpine meadows and (<b>b</b>) alpine steppe were analyzed using SEM to evaluate the overall impacts of the variables. Red and black solid lines represent negative and positive standardized SEM coefficients, respectively, with line thickness representing the magnitude of these coefficients for different vegetation types. SM = soil moisture, ST = soil temperature, AP = available phosphorus, SOM = soil organic matter, TN = total nitrogen. Note: standardized total effect coefficients &lt; 0.20 are not indicated in the figure.</p>
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15 pages, 1514 KiB  
Article
Influence of Land-Use Type on Black Soil Features in Indonesia Based on Soil Survey Data
by Yiyi Sulaeman, Eni Maftuáh, Sukarman Sukarman, Risma Neswati, Nurdin Nurdin, Tony Basuki, Ahmad Suriadi and Ivan Vasenev
Land 2025, 14(3), 599; https://doi.org/10.3390/land14030599 (registering DOI) - 12 Mar 2025
Abstract
Black soils refer to soils with black, thick upper layers containing 0.6% or more soil organic carbon in the tropical region. This high organic carbon content makes these soils essential for climate change control and food production. In Indonesia, black soils are found [...] Read more.
Black soils refer to soils with black, thick upper layers containing 0.6% or more soil organic carbon in the tropical region. This high organic carbon content makes these soils essential for climate change control and food production. In Indonesia, black soils are found under forests, shrublands, and grasslands in tropical monsoon and savannah climates. Land clearing for agricultural uses will change black soil properties; however, knowledge of change (level, direction, and sensitivity) is limited. Meanwhile, soil surveying records land-use types and collects soil samples, resulting in voluminous legacy soil data. This study aimed to compare the mean difference in soil properties between two land-cover/use types. We used 142 black soil datasets containing legacy data on particle size distribution (sand, silt, clay), pH, soil organic carbon (SOC), total nitrogen (TN), available P2O5 (AP), and exchangeable cations (Ca, Mg, K, Na). We calculated the Hedges’s g-index for effect size assessment and performed a Welch’s t-test for significant differences. The results show that, compared to the forest, the agricultural dryland and monoculture home gardens have a large effect size and trigger changes in many soil properties. In contrast, mixed home gardens and paddy fields have a small effect size. In decreasing order, the black soil properties sensitive to change are TN > SOC = exchangeable K > exchangeable Mg = available phosphorus = pH = exchangeable Na > sand = silt = clay > exchangeable Ca. The results suggest that a combination of home gardens and paddy fields better supports food security and mitigates climate change in black soils. In addition, the legacy soil data can be used to monitor soil property changes. Full article
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<p>Distribution of 291 black soil profiles (red dots) from 1994 to 2017. As many as 54 profiles in the dataset have no coordinate location. From 345 soil profiles, only 142 profiles were sampled for soil laboratory analysis. Source: Sulaeman et al. [<a href="#B11-land-14-00599" class="html-bibr">11</a>], with modifications.</p>
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<p>Boxplots of stable black soil properties by land-cover and land-use types. Note: HT = forests; KB = home gardens, monocropping; KC = home gardens, mixed cropping; SB = shrublands; SW = paddy fields; TG = agriculture dryland. Data source: Sulaeman et al. [<a href="#B11-land-14-00599" class="html-bibr">11</a>].</p>
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<p>Boxplots of regulated black soil properties by land-cover and land-use types. Data source: Sulaeman et al. [<a href="#B11-land-14-00599" class="html-bibr">11</a>].</p>
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18 pages, 4817 KiB  
Article
Implementing Best Management Practices in Complex Agricultural Watersheds: Insights from High-Resolution Nitrogen Load Dynamics Analysis
by Wanqi Shen, Ruidong Chen, Xingchen Zhao, Xiaoming Lu, Hao Yan and Lachun Wang
Water 2025, 17(6), 821; https://doi.org/10.3390/w17060821 (registering DOI) - 12 Mar 2025
Abstract
Agricultural activities such as fertilization and cultivation constitute a substantial source of non-point source (NPS) nitrogen (N) in aquatic ecosystems. Precise quantification of fluxes across diverse land uses and identification of critical source areas are essential for effectively mitigating nitrogen loads. In this [...] Read more.
Agricultural activities such as fertilization and cultivation constitute a substantial source of non-point source (NPS) nitrogen (N) in aquatic ecosystems. Precise quantification of fluxes across diverse land uses and identification of critical source areas are essential for effectively mitigating nitrogen loads. In this study, the Soil Water Assessment Tool (SWAT) was employed to accurately model the watershed hydrology and total nitrogen (TN) transport in the Zhongtian River Basin, i.e., an agricultural watershed characterized by low mountainous terrain. The simulation results indicated that the average TN load intensity within the watershed was 21.34 kg ha−1 yr−1, and that TN load intensities for paddy fields and tea plantation were 34.96 and 33.04 kg ha−1 yr−1, respectively. Agricultural land, which covered 32.06% of the area, disproportionately contributed 52.88% of the N output in the watershed. Pearson and redundancy analysis (RDA) underscored land use as the primary driver of nitrogen emissions, with a contribution exceeding 50%. Building on a high-precision simulation analysis, a suite of best management practices (BMPs) was established. These findings highlight the superior performance of engineered BMPs over agricultural BMPs, with TN load reduction rates of 12.23 and 27.07% for filter strips and grassed waterways, respectively. Among three agricultural BMPs, the effect of fertilizer reduction was the most pronounced, achieving reductions of 6.44% for TN and 21.26% for nitrate. These results suggest that optimizing fertilizer management and implementing engineered BMPs could significantly reduce nitrogen pollution in agricultural watersheds, providing valuable insights for sustainable agricultural practices and water quality management. Full article
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Figure 1
<p>(<b>a</b>) Location, land use, and sampling points of the Zhongtian River Basin. Digital elevation model (DEM) of (<b>b</b>) sub-basins and (<b>c</b>) monitoring stations of the watershed. The numbers in (<b>c</b>) represent different sub-basins.</p>
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<p>Comparison of average monthly simulated and observed (<b>a</b>) runoff and (<b>b</b>) total nitrogen (TN) load at the hydrological station during the calibration and validation periods. NSE—Nash–Sutcliffe efficiency; PBIAS—percentage bias.</p>
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<p>(<b>a</b>) Comparison of multi-year average monthly observed precipitation, flow, and total nitrogen (TN) load in the watershed. Linear regression analysis between monthly observed precipitation and (<b>b</b>) flow and (<b>c</b>) TN load.</p>
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<p>Spatial distribution of total nitrogen (TN) load intensity at the sub-basin scale for the annual average (<b>a</b>), wet season (<b>b</b>), and dry season (<b>c</b>). Spatial distribution of TN load intensity and at hydrologic response unit (HRU) scales for the annual average (<b>d</b>), wet season (<b>e</b>), and dry season (<b>f</b>).</p>
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<p>(<b>a</b>) TN load intensity and (<b>b</b>) nitrate load intensity of different land use types.</p>
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<p>Correlation analysis between nitrogen load and multiple environmental factors at the HRU scale: (<b>a</b>) annual average, (<b>b</b>) wet season, and (<b>c</b>) dry season. Redundancy analysis (RDA) between nitrogen load and multiple environmental factors: (<b>d</b>) annual average, (<b>e</b>) wet season, and (<b>f</b>) dry season. Abbreviations are as follows: sediment yield (SYLD), water yield contribution by surface runoff (SURQ), water yield contribution by lateral flow (LATQ), and water yield contribution by groundwater (GW_Q).</p>
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24 pages, 6846 KiB  
Article
A Two-Step Reconstruction Approach for High-Resolution Soil Moisture Estimates from Multi-Source Data
by Yueyuan Zhang, Yangbo Chen and Lingfang Chen
Water 2025, 17(6), 819; https://doi.org/10.3390/w17060819 - 12 Mar 2025
Abstract
Accurate soil moisture (SM) estimates with high spatial resolution are highly desirable for agricultural, hydrological, and environmental applications. This study developed a two-step reconstruction approach to obtain a high-quality and high-spatial-resolution (0.05°) SM dataset from microwave and model-based SM products, combining Bayesian three-cornered [...] Read more.
Accurate soil moisture (SM) estimates with high spatial resolution are highly desirable for agricultural, hydrological, and environmental applications. This study developed a two-step reconstruction approach to obtain a high-quality and high-spatial-resolution (0.05°) SM dataset from microwave and model-based SM products, combining Bayesian three-cornered hat (BTCH) merging and machine/deep learning downscaling algorithms. Firstly, a three-cornered hat (TCH) method was used to analyze the uncertainty of seven SM products on four main land cover types in the Pearl River Basin (PRB). On this basis, the SM products with low uncertainty were merged using the BTCH method. Secondly, two machine/deep learning algorithms (random forest, RF, and long short-term memory, LSTM) were applied to downscale the merged SM data from 0.25° to 0.05° based on the relationship between SM and auxiliary variables. The overall performance of RF and LSTM downscaling models with/without antecedent precipitation were compared. The merged and downscaled SM results were validated against in situ observations and the China Meteorological Administration (CMA) Land Data Assimilation System (CLDAS) SM data. The results indicated the following: (1) The BTCH-based SM estimate outperformed the parent products and the AVE-based SM estimate (the arithmetic average), indicating that BTCH is a fusion approach that can effectively reduce data uncertainties and optimize weights. (2) The optimal time scale for the cumulative effect of precipitation on SM was 35 days during 2015–2020 in the PRB. SM estimations using RF and LSTM downscaling algorithms both had substantial improvement by considering the antecedent precipitation variable, both at the 0.25° and 0.05° spatial scales. Feature importance assessment also revealed the most important role of antecedent precipitation (30.01%). Moreover, the LSTM model with antecedent precipitation performed slightly better than the RF model with antecedent precipitation. (3) The downscaled SM results all mitigated the overestimation inherent in the original SM data, though they were inevitably limited by the performance of the original SM data and difficult to surpass. The developed two-step reconstruction approach was effective in generating an accurate SM dataset at a finer spatial scale for wide regional applications. Full article
15 pages, 1262 KiB  
Review
The Impact of the Soil Environment and Surface Mulching on N2O Emissions from Farmland
by Qian Chen, Lei Chang, Khuram Shehzad Khan, Shouxi Chai, Yuwei Chai and Fanxiang Han
Sustainability 2025, 17(6), 2502; https://doi.org/10.3390/su17062502 - 12 Mar 2025
Abstract
A reduction in emissions of nitrous oxide (N2O), one of the three major greenhouse gases, is important for achieving environmental sustainability and carbon neutrality goals. Agricultural fields are the primary source of N2O emissions, and their management measures influence [...] Read more.
A reduction in emissions of nitrous oxide (N2O), one of the three major greenhouse gases, is important for achieving environmental sustainability and carbon neutrality goals. Agricultural fields are the primary source of N2O emissions, and their management measures influence greenhouse gas emission reductions and the greening of agriculture. Among these practices, cover cropping plays a key role in promoting sustainable agricultural production as a major cropping technique for efficient water use and increasing crop yields in water-scarce regions worldwide. The present paper systematically reviews the influence of various soil environmental factors, such as soil temperature, moisture, pH, carbon, and nitrogen contents, as well as nitrogen cycle-related enzymes, microorganisms and mulching practices, including general mulching and straw mulching, on N2O emissions from agricultural fields. This review suggests that future research should explore the long-term effects of different mulching materials and their application rates and durations on soil N2O emissions. Furthermore, a networked mathematical model for causal analysis should be employed in future research to elucidate the relationships among soil environmental factors, nitrogen cycle microorganisms, and soil N2O production and consumption. These future studies will help to deepen our understanding of nitrogen cycling processes in agroecosystems with the aim of developing environmentally friendly agricultural technologies and promoting green and sustainable agricultural development. Full article
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Figure 1
<p>Process and mechanism of nitrous oxide production and emission in farmland. Note: AMO, ammonia monooxygenase; HAD, hydroxylamine dehydrogenase; NiR, nitrite reductase; Nor, NO reductase; NR, nitrate reductase; N<sub>2</sub>OR, N<sub>2</sub>O reductase; AOA, ammonia-oxidizing archaebacteria; AOB, ammonia-oxidizing bacteria; NOB, nitrite-oxidizing bacteria; NN, nitrification by nitrifying bacteria; ND, denitrification by nitrifying bacteria; NCD, denitrification coupled to nitrification reactions; HD, heterotrophic denitrification.</p>
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<p>Effect of soil environmental factors on N<sub>2</sub>O emissions. Note: NN, nitrification by nitrifying bacteria; ND, denitrification by nitrifying bacteria; NCD, denitrification coupled to nitrification reactions; HD, heterotrophic denitrification.</p>
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28 pages, 3050 KiB  
Review
Harnessing Nitrogen-Fixing Cyanobacteria for Sustainable Agriculture: Opportunities, Challenges, and Implications for Food Security
by Taufiq Nawaz, Shah Fahad, Liping Gu, Lan Xu and Ruanbao Zhou
Nitrogen 2025, 6(1), 16; https://doi.org/10.3390/nitrogen6010016 - 12 Mar 2025
Abstract
Nitrogen, an essential element for plant growth and food production, presents significant challenges in agriculture due to the environmental consequences of synthetic nitrogen fertilizers. This review explores the potential of nitrogen-fixing cyanobacteria as a sustainable alternative for agricultural nitrogen fertilization. The molecular mechanisms [...] Read more.
Nitrogen, an essential element for plant growth and food production, presents significant challenges in agriculture due to the environmental consequences of synthetic nitrogen fertilizers. This review explores the potential of nitrogen-fixing cyanobacteria as a sustainable alternative for agricultural nitrogen fertilization. The molecular mechanisms underlying nitrogen fixation in cyanobacteria, including key genes such as nif and related biochemical pathways, are examined in detail. Biotechnological approaches for utilizing nitrogen-fixing cyanobacteria as biofertilizers are discussed, alongside strategies for genetic engineering to improve nitrogen fixation efficiency. The review further evaluates the impact of cyanobacteria on soil health and environmental sustainability, emphasizing their role in mitigating the detrimental effects of synthetic fertilizers. While promising, challenges such as oxygen sensitivity during nitrogen fixation and competition with native microorganisms are critically analyzed. Finally, future directions are proposed, including advancements in synthetic biology, integration with conventional agricultural practices, and scalable implementation strategies. This review underscores the transformative potential of nitrogen-fixing cyanobacteria in promoting sustainable agriculture and enhancing global food security. Full article
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Figure 1
<p>The nitrogenase complex, comprising the Fe protein and MoFe protein with the FeMo-cofactor, facilitates electron transfer and catalyzes the reduction of atmospheric N<sub>2</sub> to NH<sub>3</sub>, providing a plant-usable nitrogen form essential for the nitrogen cycle.</p>
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<p>This diagram illustrates the nif gene cluster (nifH, nifD, nifK) encoding the nitrogenase complex, which catalyzes nitrogen (N<sub>2</sub>) reduction to ammonia (NH<sub>3</sub>).</p>
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<p>The diagram synthesizes the biotechnological advancements and practical applications of nitrogen-fixing cyanobacteria, offering a concise and scientifically structured visualization to facilitate a comprehensive understanding of the subject.</p>
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<p>The figure highlights the role of nitrogen-fixing cyanobacteria in enhancing soil health by enriching microbial diversity, fostering nutrient cycling, and reducing reliance on synthetic fertilizers. It illustrates their influence on microbial interactions, soil fertility, and sustainable agricultural practices, while also emphasizing associated environmental benefits.</p>
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<p>Illustration of the role of nitrogen-fixing cyanobacteria in enhancing soil structure and water retention. Cyanobacteria produce extracellular polymeric substances (EPSs), which bind soil particles into stable aggregates, preventing erosion and increasing porosity. These improvements facilitate root penetration, promote microbial diversity, and enhance water retention, contributing to soil health, drought resilience, and sustainable agricultural productivity.</p>
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19 pages, 1396 KiB  
Article
Impact of Freeze–Thaw Action on Soil Erodibility in the Permafrost Regions of the Sanjiangyuan Area Affected by Thermokarst Landslides
by Bihui Wang, Yidong Gu, Kexin Zhou, Shengnan Li, Ce Zheng and Yudong Lu
Water 2025, 17(6), 818; https://doi.org/10.3390/w17060818 - 12 Mar 2025
Abstract
The Sanjiangyuan region, known as the “Chinese Water Tower”, serves as a crucial ecological zone that is highly sensitive to climate change. In recent years, rising temperatures and increased precipitation have led to permafrost melt and frequent occurrences of thermokarst landslides, exacerbating soil [...] Read more.
The Sanjiangyuan region, known as the “Chinese Water Tower”, serves as a crucial ecological zone that is highly sensitive to climate change. In recent years, rising temperatures and increased precipitation have led to permafrost melt and frequent occurrences of thermokarst landslides, exacerbating soil erosion issues. Although studies have explored the impact of freeze–thaw action (FTA) on soil properties, research on this phenomenon within the unique geomorphological unit of thermokarst landslides, formed from degrading permafrost, remains sparse. This study, set against the backdrop of temperature-induced soil landslides, combines field investigations and controlled laboratory experiments on typical thermokarst landslide bodies within the permafrost region of Sanjiangyuan to systematically investigate the effects of FTA on the properties of soils within thermokarst landslides. Furthermore, this study employs the EPIC model to establish an empirical formula for the soil erodibility (SE) factor before and after freeze–thaw cycles (FTCs). The results indicate that: (1) FTCs significantly alter soil particle composition, reducing the content of clay particles in the surface soil while increasing the content of sand particles and the median particle size, thus compromising soil structure and enhancing erodibility. (2) FTA initially significantly increases soil organic matter content (OMC); however, as the number of FTCs increases, the magnitude of these changes diminishes. The initial moisture content of the soil significantly influences the effects of FTA, with more pronounced changes in particle composition and OMC in soils with higher moisture content. (3) With an increasing number of FTCs, the SE K-value first significantly increases and then tends to stabilize, showing significant differences across the cycles (1 to 15) (p < 0.05). This study reveals that FTCs, by altering the physicochemical properties of the soil, significantly increase SE, providing a scientific basis for soil erosion control and ecological environmental protection in the Sanjiangyuan area. Full article
37 pages, 882 KiB  
Article
Soil-Specific Effects of the Bio-Growth Regulator Supporter on Seed Potato Yield and Quality Across Varieties: Unlocking Sustainable Potential in Diverse Environments
by Piotr Barbaś, Piotr Pszczółkowski, Barbara Krochmal-Marczak, Talal Saeed Hameed and Barbara Sawicka
Land 2025, 14(3), 595; https://doi.org/10.3390/land14030595 - 12 Mar 2025
Abstract
The growing demand for sustainable agricultural practices requires the search for innovative solutions to improve crop yield and quality. This study investigated the soil-specific effects of the bio-growth regulator Supporter on seed potato yield and quality in different potato varieties, with the aim [...] Read more.
The growing demand for sustainable agricultural practices requires the search for innovative solutions to improve crop yield and quality. This study investigated the soil-specific effects of the bio-growth regulator Supporter on seed potato yield and quality in different potato varieties, with the aim of unlocking its sustainable potential under different environmental conditions. Field trials were conducted on several soil types using the bio-growth stimulator Supporter at a rate of 300 mL per hectare. Standardized agronomic practices, including continuous fertilization, weed control, and pest control, were applied at all test sites to ensure comparability. The results showed that the use of the bio-growth stimulator Supporter significantly increased tuber yield and quality, especially in soils with moderate fertility levels. In the treatments, with the Supporter biostimulator, there was better tuber size uniformity and a higher fraction and number of seed potato. A higher average seed potato mass and higher multiplication coefficient were observed. The effectiveness of the Supporter varied across study locations and soil types, with sandy and sandy loam soils showing the most pronounced benefits, while clay soils showed more limited responses. The results underscore the potential of the Supporter as a sustainable tool for increasing potato seed production, while also emphasizing the need for soil-specific recommendations. This study highlights the importance of integrating growth regulators into precision agriculture to optimize crop performance and support global food security goals. Therefore, further research is needed on the use of biostimulants, which will allow us to understand the purpose of their action, which is important in agricultural practice. Full article
20 pages, 6389 KiB  
Article
Evaluation of Data Acquisition Areas in Geotechnical Seismic Tests: Insights from Field Applications
by Gunwoong Kim
Sensors 2025, 25(6), 1757; https://doi.org/10.3390/s25061757 - 12 Mar 2025
Abstract
Geotechnical field testing evaluates soil, rock, and groundwater conditions in their natural states, offering critical information about subsurface properties such as the density, strength, permeability, and groundwater flow. These tests are essential in ensuring the safety, reliability, and performance of civil engineering projects [...] Read more.
Geotechnical field testing evaluates soil, rock, and groundwater conditions in their natural states, offering critical information about subsurface properties such as the density, strength, permeability, and groundwater flow. These tests are essential in ensuring the safety, reliability, and performance of civil engineering projects and are increasingly used for 3D geographical visualization and subsurface modeling. While point-based tests like the cone penetration test (CPT) and standard penetration test (SPT) are widely used, area-based methods such as the spectral analysis of surface waves (SASW) and electrical resistivity testing significantly enhance the accuracy of such models by providing broader coverage. Furthermore, these non-destructive techniques are particularly effective in identifying subsurface defects. This study focuses on analyzing the data acquisition areas of various field seismic tests, including SASW, downhole, crosshole, and suspension logging (PS logging). While other tests clearly define data acquisition areas based on their array paths, the SASW test posed challenges due to the complexity of data reconstruction. To address this, 69 datasets from four different sites were analyzed to predict the data acquisition areas for SASW as a function of depth. Moreover, a case study demonstrates the practical application of the SASW method in detecting cavities near a dam spillway. The findings of this research improve the understanding and interpretation of geotechnical seismic test data, enabling more precise geotechnical investigations and advancing the detection of subsurface defects using non-destructive methods. Full article
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<p>Conceptual architecture of proposed MLP-based 3D geotechnical layer classification model [<a href="#B1-sensors-25-01757" class="html-bibr">1</a>].</p>
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<p>SASW testing configuration and surface waves with different wavelengths (<b><span class="html-italic">λ</span></b><b>1</b> and <b><span class="html-italic">λ</span></b><b>2</b>) when sampling a layered system.</p>
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<p>SASW data analysis procedure: (<b>a</b>) experimental (field) and compacted dispersion curves; (<b>b</b>) comparison of the compacted and theoretical dispersion curves with the resulting Vs profile.</p>
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<p>Generalized field setup for downhole seismic measurements.</p>
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<p>Downhole P waveforms generated with the source.</p>
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<p>Crosshole testing setup using two boreholes.</p>
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<p>Suspension logging test setup.</p>
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<p>Comparison of Vs profiles from (<b>a</b>) SASW, crosshole, and downhole testing at a uniform site [<a href="#B38-sensors-25-01757" class="html-bibr">38</a>] and (<b>b</b>) SASW, PS logging, and downhole testing at a partially uniform site [<a href="#B39-sensors-25-01757" class="html-bibr">39</a>].</p>
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<p>Maximum and minimum depth data for 69 SASW data normalized by the length of receiver spacing.</p>
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<p>The areas of data collected using the improved SASW method (3.6 m depth profiling).</p>
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<p>The areas of data collected using downhole testing (3.6 m depth profiling).</p>
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<p>The areas of data collected using crosshole testing with 3 boreholes (3.6 m depth pro-filing).</p>
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<p>The areas of data collected using PS logging testing (3.6 m depth profiling).</p>
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<p>Comparisons of the area of data collection using four different tests (SASW, crosshole, downhole, and PS logging) when profiling at (<b>a</b>) 0.9 m, (<b>b</b>) 3.6 m, (<b>c</b>) 18 m, and (<b>d</b>) 72 m.</p>
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<p>An example of defect detection using the SASW test.</p>
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19 pages, 925 KiB  
Article
Can Ecological Outcomes Be Used to Assess Soil Health?
by Isabella C. F. Maciel, Guilhermo F. S. Congio, Eloa M. Araujo, Morgan MathisonSlee, Matt R. Raven and Jason E. Rowntree
Environments 2025, 12(3), 85; https://doi.org/10.3390/environments12030085 - 12 Mar 2025
Abstract
Soil health is typically evaluated using physical, chemical, and biological parameters. However, identifying cost-effective and interpretable metrics remains a challenge. The effectiveness of ecological outcome verification (EOV) in predicting soil health in grazing lands was assessed at 22 ranches. Sixty-four soil samples were [...] Read more.
Soil health is typically evaluated using physical, chemical, and biological parameters. However, identifying cost-effective and interpretable metrics remains a challenge. The effectiveness of ecological outcome verification (EOV) in predicting soil health in grazing lands was assessed at 22 ranches. Sixty-four soil samples were analyzed using the Haney soil health test (HSHT) and phospholipid fatty acid (PLFA). Of 104 variables, 13 were retained following principal component analysis (PCA), including variables associated with plant community, carbon dynamics, and microbial community structure. Soils with enriched microbial and organic matter (SOM) characteristics supported a healthier ecological status, as corroborated by greater EOV scores. Water-extractable organic carbon (WEOC) was positively correlated to plant functional groups, whereas SOM was positively correlated with plant biodiversity and functional groups. Total bacteria were positively correlated with all EOV parameters. Microbial biomass (MB) was positively correlated with both water and energy cycle indexes, whereas arbuscular mycorrhizal fungi (AMF) was positively correlated with the water cycle. From the multiple regression analyses, water infiltration emerged as a key predictor of soil respiration and WEOC. Overall, the ecological outcomes measured by EOV have the potential to serve as a proxy for soil health, providing a practical tool for producers to make informed land management decisions. Full article
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<p>Scheme of a 6 ha monitoring site (dotted line) within a given pasture (solid line) including twelve sampling locations (STM protocol, green circles) and the three transects (T1, T2, and T3) of the long-term monitoring (LTM protocol, gray bars) with locations where soil cores (yellow triangles) and water infiltration (red squares) samples were taken.</p>
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<p>Principal component analysis biplot of Haney soil heath test and phospholipid fatty acid test parameters, including 32 monitoring sites (blue dots). SR: soil respiration, WEOC: water-extractable organic carbon, SOM: soil organic matter, MB: total microbial biomass, Bacteria: total bacteria, Fungi: total fungi, AMF: arbuscular mycorrhizal fungi, SF: saprophytic fungi.</p>
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19 pages, 5060 KiB  
Article
Subsurface Drip Irrigation Combined with Ammonium Enhances Root Growth in Rice (Oryza sativa L.), Leading to Improved N Uptake and Higher Yield Formation
by Yuman Cui, Weidong Ma, Changnan Yang, Ruxiao Bai, Tianze Xia, Changzhou Wei, Xinjiang Zhang and Guangwei Zhou
Plants 2025, 14(6), 891; https://doi.org/10.3390/plants14060891 - 12 Mar 2025
Abstract
Coordinating the spatial distribution of crop roots with soil nutrients, along with selecting appropriate types of fertilizers, is an effective strategy to enhance root nutrient absorption and increase crop yield. In Xinjiang’s current surface drip irrigation practices for rice (Oryza sativa L.), [...] Read more.
Coordinating the spatial distribution of crop roots with soil nutrients, along with selecting appropriate types of fertilizers, is an effective strategy to enhance root nutrient absorption and increase crop yield. In Xinjiang’s current surface drip irrigation practices for rice (Oryza sativa L.), premature leaf senescence and N deficiency are common issues, resulting in decreased yields. This study investigated whether different N forms under subsurface drip irrigation can modulate rice root morphological strategies to delay senescence in later growth stages, enhancing rice N uptake and yield formation. A field experiment compared the effects of different drip irrigation positions (surface drip irrigation at the surface, DI0; subsurface drip irrigation at 10 cm depth, DI10) and N forms (urea N, UN; ammonium N, AN) in four combination treatments (DI0-UN, DI0-AN, DI10-UN, DI10-AN) on rice root morphology, aboveground growth, and yield formation. During the grain-filling stage, the total root length (RL) and root number (RN) in the DI10-AN treatment were higher than in other treatments. Root vitality increased by 23.24–133.72% during the later filling stages, while the root decline rate decreased by 1.16–32.80%. The root configuration parameters β in the DI10-AN treatment were superior to those in other treatments, indicating that roots tend to distribute deeper in the soil. The DI10-AN treatment reduced Malondialdehyde (MDA) levels and increased Superoxide Dismutase (SOD) activity, thereby alleviating water and N stress on the leaves in later growth stages and maintaining higher photosynthetic parameter values. The DI10-AN treatment significantly increased N absorption (14.37–52.88%) and yield (13.32–46.31%). Correlation analysis showed that RL, RN, and root activity (Ra) were significantly positively correlated with transpiration rate (Tr), intercellular CO2 concentration (Ci), N uptake (NUP), one thousand-kernel weight (TKW), seed setting rate (SR), Efficient panicle (EP), and yield (r > 0.90). This study presents a new rice drip fertigation technique that combines subsurface irrigation with ammonium to enhance root growth and increase crop productivity. Full article
(This article belongs to the Section Crop Physiology and Crop Production)
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<p>Precipitation and average temperature during the rice-growing season (2023–2024).</p>
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<p>Microroot canal space layout.</p>
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<p>Effects of different drip irrigation depths and N forms on MDA and SOD in rice leaves during the grain-filling stage from 2023–2024. (<b>a</b>): SOD content during the grain-filling stage in 2023; (<b>b</b>): SOD content during the grain-filling stage in 2024; (<b>c</b>): MDA content during the grain-filling stage in 2023; (<b>d</b>): MDA content during the grain-filling stage in 2024. Different lowercase letters within the same column indicate significant differences between treatments (<span class="html-italic">p</span> &lt; 0.05; LSD). DI0-UN: Conventional surface drip irrigation with urea N management; DI10-UN: Subsurface drip irrigation at 10 cm depth with urea N management; DI0-AN: Conventional surface drip irrigation with ammonium N management; DI10-AN: Subsurface drip irrigation at 10 cm depth with ammonium N management.</p>
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<p>Root dry matter mass of rice at different soil depths during the grain-filling stage under various drip irrigation depths and N forms (2023–2024). Letters indicate significant differences among management practices within the same soil layer (<span class="html-italic">p</span> ≤ 0.05). Treatment abbreviations: DI0-UN: Conventional surface drip irrigation with urea N management; DI10-UN: Subsurface drip irrigation at 10 cm depth with urea N management; DI0-AN: Conventional surface drip irrigation with ammonium N management; DI10-AN: Subsurface drip irrigation at 10 cm depth with ammonium N management.</p>
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<p>Dynamic changes in root length and root number decay across soil layers during the grain-filling stage under varying drip irrigation depths and N forms. (<b>A</b>): Total root length; (<b>B</b>): Total root number. Treatment abbreviations: DI0-UN: Conventional surface drip irrigation with urea N management; DI10-UN: Subsurface drip irrigation at 10 cm depth with urea N management; DI0-AN: Conventional surface drip irrigation with ammonium N management; DI10-AN: Subsurface drip irrigation at 10 cm depth with ammonium N management. The numbers 5, 10, and 15 denote the 5th, 10th, and 15th days of observation during the grain-filling stage.</p>
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<p>Changes in daily root elongation rate and root activity under different drip irrigation depths and N forms. (<b>A</b>): Root activity during the grain-filling stage from 2023–2024. (<b>B</b>): Dynamic changes in daily root elongation rate during the grain-filling stage in 2024. Treatment abbreviations: DI0-UN: Conventional surface drip irrigation with urea N management; DI10-UN: Subsurface drip irrigation at 10 cm depth with urea N management; DI0-AN: Conventional surface drip irrigation with ammonium N management; DI10-AN: Subsurface drip irrigation at 10 cm depth with ammonium N management. The numbers 5, 10, and 15 denote the 5th, 10th, and 15th days of observation. Different lowercase letters indicate significant differences between treatments (<span class="html-italic">p</span> &lt; 0.05; LSD).</p>
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<p>Correlation analysis between root morphology, root activity, and N uptake during the grain-filling stage (2023–2024). Note: ** indicates <span class="html-italic">p</span> &lt; 0.01. (<b>A</b>): Correlation analysis between NUP and RDM. (<b>B</b>): Correlation analysis between NUP and RL. (<b>C</b>): Correlation analysis between NUP and RN. (<b>D</b>): Correlation analysis between NUP and Ra. Abbreviations: NUP: N uptake; RDM: Root dry matter; RL: Total root length; RN: Total root number; Ra: Root activity.</p>
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<p>Cluster analysis and Pearson correlation analysis of various rice indicators (2023–2024). Data are presented as means (<span class="html-italic">n</span> = 3); * indicates significant correlation at <span class="html-italic">p</span> &lt; 0.05; ** indicates significant correlation at <span class="html-italic">p</span> &lt; 0.01. (<b>A</b>): the cluster analysis among indicators; (<b>B</b>): Pearson correlation analysis between indicators. Treatment abbreviations: DI0-UN: Conventional surface drip irrigation with urea N management; DI10-UN: Subsurface drip irrigation at 10 cm depth with urea N management; DI0-AN: Conventional surface drip irrigation with ammonium N management; DI10-AN: Subsurface drip irrigation at 10 cm depth with ammonium N management. Indicator abbreviations: RDM: Root dry matter; RL: Total root length; RN: Total root number; Ra: Root activity; RER: Root elongation rate; NUP: N uptake; GNP: Grain number per panicle; SR: Seed setting rate; TKW: 1000-kernel weight; EP: Efficient panicle.</p>
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20 pages, 5049 KiB  
Article
Quantitative Analysis of Bound Water Content in Marine Clay and Its Influencing Factors During the Freezing Process by Nuclear Magnetic Resonance
by Xuehan Shan, Huie Chen, Chuqiao Meng, Zuojun Lv, Qingbo Yu, Zhaoxi Wang and Qing Wang
J. Mar. Sci. Eng. 2025, 13(3), 546; https://doi.org/10.3390/jmse13030546 - 12 Mar 2025
Abstract
The change in bound water content with temperature is a core issue in studying temperature effects in clayey soils. This study used nuclear magnetic resonance (NMR) techniques to measure pore water in three types of marine clay, ranging from inland to coastal areas. [...] Read more.
The change in bound water content with temperature is a core issue in studying temperature effects in clayey soils. This study used nuclear magnetic resonance (NMR) techniques to measure pore water in three types of marine clay, ranging from inland to coastal areas. The T2 cutoff values were proposed to distinguish between bulk water, capillary water, and bound water, and the curves of unfrozen water and bound water content with changing temperatures were obtained during the freezing process. Additionally, the impact of soil properties on bound water content was analyzed. The research findings indicated that the pore water in marine clay is dominated by bound water, and the change in bound water content with temperature in each soil layer can be divided into four stages: the trace phase change stage, the intense phase change stage, the transitional phase change stage, and the stabilizing stage. Further, the effect of soil properties such as organic matter content, soluble salt content, and cation exchange capacity on bound water content was illustrated, and clay content and bound water content were found not to be strictly positively correlated. Full article
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<p>Geographical location of the study area.</p>
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<p><span class="html-italic">T</span><sub>2</sub> distribution curves during the freezing process.</p>
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<p>Relationships between <span class="html-italic">M</span><sub>0</sub> and <span class="html-italic">T</span>.</p>
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<p>(<b>a</b>–<b>c</b>) Relationships between <span class="html-italic">θ<sub>u</sub></span> and <span class="html-italic">T</span>. (<b>d</b>–<b>f</b>) Relationships between <span class="html-italic">θ<sub>b</sub></span> and <span class="html-italic">T</span>.</p>
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<p>Particle size distribution of soil samples at sampling sites (<b>a</b>) A, (<b>b</b>) B, and (<b>c</b>) C.</p>
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<p>(<b>a</b>) Clay content of all soil samples. (<b>b</b>) Bound water fraction (S) of all soil samples.</p>
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<p>SEM images of soil samples (<b>a</b>) A-MC, (<b>b</b>) B-MC, (<b>c</b>) C-MC, (<b>d</b>) A-C, (<b>e</b>) B-C, (<b>f</b>) C-C, (<b>g</b>) A-SC, (<b>h</b>) B-SC, (<b>i)</b> C-SC. (2000× magnification).</p>
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<p>Microstructure of mucky clay.</p>
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<p>Microstructure of clay.</p>
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<p>Microstructure of silty clay.</p>
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<p>(<b>a</b>) Organic matter content of each soil layer. (<b>b</b>) Relationship between bound water fraction and organic matter content.</p>
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<p>(<b>a</b>) Soluble salt content of each soil layer. (<b>b</b>) Relationship between bound water fraction and soluble salt content.</p>
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<p>(<b>a</b>) Cation exchange content of each soil layer. (<b>b</b>) Relationship between bound water fraction and cation exchange capacity.</p>
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13 pages, 2023 KiB  
Article
Assessment of the Nitrification Inhibitor Nitrapyrin on Nitrogen Losses and Brassica oleracea Growth: A Preliminary Sustainable Research
by Mariangela Triozzi, Annamaria Ilacqua, Marina Tumolo, Valeria Ancona and Daniela Losacco
Nitrogen 2025, 6(1), 15; https://doi.org/10.3390/nitrogen6010015 - 12 Mar 2025
Abstract
The use of nitrification inhibitors (NIs) with nitrogen fertilizers represents an effective strategy to reduce nitrogen loss. In addition, nitrification inhibitors are widely applied to improve agricultural yield. However, it is necessary to continue investigating the crop-specific agricultural practice. In this study, a [...] Read more.
The use of nitrification inhibitors (NIs) with nitrogen fertilizers represents an effective strategy to reduce nitrogen loss. In addition, nitrification inhibitors are widely applied to improve agricultural yield. However, it is necessary to continue investigating the crop-specific agricultural practice. In this study, a nitrapyrin-based nitrification inhibitor was used to assess its effects on Brassica oleracea L. var. botrytis growth and on the environment. In a pot experiment, cauliflower plants were grown in fertilized soils based on calcium nitrate (SF) and SF + nitrapyrin. At the end of the experiment, the content of nitrogen compounds in soil and percolation water and the cauliflower yield were determined, and the plant tissues were characterized by Fourier-transform infrared spectroscopy. The application of the NI significantly reduced nitrogen losses, increasing nutrient availability in the soil and the element’s absorption in the plant. Co-application of fertilizers and NIs reduced NO3 leaching from 925 to 294 mg/L. Plant tissue characterization by FTIR spectroscopy highlighted variations in the functional groups in response to the application of NIs. These results suggest that applying nitrogen fertilizer in combination with nitrapyrin can mitigate nitrate pollution and improve element absorption and plant growth. Our research has shown that application methods and cropping systems need to be studied to maximize the effectiveness of nitrapyrin-based NIs. Full article
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<p>Representation of the action of a nitrification inhibitor (N-Lock<sup>TM</sup>, Corteva Agriscience, Cremona, Italy) in agroecosystems.</p>
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<p>Experimental set-up. From (<b>left</b>) to (<b>right</b>): greenhouse for cauliflower cultivation, detailed overview of crop mesocosms, cauliflower at induction phase of inflorescence, N-Lock<sup>TM</sup> treatment, and cauliflower at growth phase of curd.</p>
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<p>Soil parameter changes in the cauliflower mesocosms experiment. The lines indicated the error standard of means (<span class="html-italic">n</span> = 3). Control soil (SC), soil fertilized with calcium nitrate (SF), and SI with nitrapyrin-based nitrification inhibitor (FSI).</p>
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<p>Effect of agricultural practice on normalized difference vegetation index (NDVI) and nitrification inhibitor (SFI). Each value was reported as means ± standard errors (<span class="html-italic">n</span> = 3).</p>
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<p>Nitrogen budgets of <span class="html-italic">Brassica oleracea</span> treated with and without the nitrapyrin-based nitrification inhibitor.</p>
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<p>FTIR spectra of cauliflower functional groups under treatment with N fertilizer (<b>left</b>) and N fertilizer with nitrapyrin (<b>right</b>).</p>
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12 pages, 1782 KiB  
Article
Research on Soil Inorganic Nitrogen Detection Technology Based on Dielectric Response
by Zhenyu Jia, Xuan Han, Ri Hu, Jiangyang Yu, Xiaoqing Yan and Jinghui Xu
Sustainability 2025, 17(6), 2491; https://doi.org/10.3390/su17062491 - 12 Mar 2025
Abstract
Efficient monitoring of soil inorganic nitrogen is crucial for precision agriculture fertilization and ecological environmental protection. Traditional detection methods are complex and challenging for real-time in situ measurements. This study proposes an innovative approach based on dielectric response characteristics, enabling non-destructive and rapid [...] Read more.
Efficient monitoring of soil inorganic nitrogen is crucial for precision agriculture fertilization and ecological environmental protection. Traditional detection methods are complex and challenging for real-time in situ measurements. This study proposes an innovative approach based on dielectric response characteristics, enabling non-destructive and rapid detection by analyzing soil polarization behavior in an electromagnetic field. Using a vector network analyzer (E5071-C), we systematically measured the complex dielectric spectra of red soil and yellow clay loam across a wide frequency range from 10 MHz to 4.5 GHz. Coupled with water–nitrogen interaction experiments (volume water content: 0.05–0.25 cm3/cm3; nitrogen concentration: 0–0.2 mol/L), we established a high-frequency–low-frequency collaborative detection model. The study found that at the 3.8 GHz high-frequency band, the interface polarization weakening effect allows for the precise measurement of soil water content (R2 = 0.82; RMSE = 0.030 cm3/cm3). In the 100–200 MHz low-frequency band, based on ion migration dynamics, we successfully identified characteristic sensitive frequency bands for NH4+ (136–159 MHz) and NO3 (97–129 MHz). Notably, at 127 MHz, the water–nitrogen coupling model predicted inorganic nitrogen content with a determination coefficient of 0.721. This method effectively overcomes the water interference issue inherent in traditional single-frequency dielectric methods through a dual-frequency decoupling mechanism. The findings lay a theoretical foundation for developing in situ sensors for farmland. Real-time monitoring can significantly improve nitrogen fertilizer utilization efficiency and reduce environmental pollution, offering substantial application value for advancing precision agriculture and sustainable development. Full article
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<p>Main test steps in soil sample preparation. (<b>a</b>) Configuration of the solution. (<b>b</b>) Resting of the soil sample. (<b>c</b>) Soil sample to be tested.</p>
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<p>Soil inorganic nitrogen dielectric measurement system.</p>
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<p>Real part of the soil dielectric constant under water content change. (<b>a1</b>) Laterite (NH<sub>4</sub>Cl) and (<b>a2</b>) laterite (KNO<sub>3</sub>); (<b>b1</b>) loess (NH<sub>4</sub>Cl) and (<b>b2</b>) loess (KNO<sub>3</sub>).</p>
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<p>Imaginary part of the soil dielectric constant under water content change. (<b>a1</b>) Laterite (NH<sub>4</sub>Cl) and (<b>a2</b>) laterite (KNO<sub>3</sub>); (<b>b1</b>) loess (NH<sub>4</sub>Cl) and (<b>b2</b>) loess (KNO<sub>3</sub>).</p>
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<p>R<sup>2</sup> and RMSE values of the fitted equations at each frequency point.</p>
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<p>Fitted curves of water content versus dielectric constant for two soils. (<b>a</b>) Laterite; (<b>b</b>) loess.</p>
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<p>Comparison of the fitting effects of adding nitrogen-containing ionic solutions to soil at each characteristic frequency point separately. (<b>a</b>) KNO<sub>3</sub>; (<b>b</b>) NH<sub>4</sub>Cl.</p>
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<p>Soil dielectric modeling under 127 MHz water–nitrogen coupling.</p>
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