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15 pages, 3496 KiB  
Article
Influence of Geometrical Design on Defect Formation of Commercial Al-Si-Cu-Mg Alloy Fabricated by High-Pressure Diecasting: Structural Observation and Simulation Validation
by Warda Bahanan, Siti Fatimah, Dong-Ju Kim, I Putu Widiantara, Jee-Hyun Kang and Young Gun Ko
Metals 2025, 15(1), 42; https://doi.org/10.3390/met15010042 - 4 Jan 2025
Viewed by 376
Abstract
Near-net-shaped metal products manufactured by high-pressure diecasting (HPD) encountered more or less critical failure during operation, owing to the development of micro-defects and structural inhomogeneity attributed to the complexity of geometrical die design. Because the associated work primarily relies on technical experience, it [...] Read more.
Near-net-shaped metal products manufactured by high-pressure diecasting (HPD) encountered more or less critical failure during operation, owing to the development of micro-defects and structural inhomogeneity attributed to the complexity of geometrical die design. Because the associated work primarily relies on technical experience, it is necessary to perform the structural analysis of the HPDed component in comparison with simulation-based findings that forecast flow behavior, hence reducing trial and error for optimization. This study validated the fluidity and solidification behaviors of a commercial-grade Al-Si-Cu-Mg alloy (ALDC12) that is widely used in electric vehicle housing parts using the ProCAST tool. Both experimental and simulation results exhibited that defects at the interface of a compact mold filling were barely detected. However, internal micro-pores were seen in the bolt region, resulting in a 17.27% drop in micro-hardness compared to other parts, for which the average values from distinguished observation areas were 111.24 HV, 92.03 HV, and 103.87 HV. The simulation aligns with structural observations on defect formation due to insufficient fluidity in local geometry. However, it may underestimate the cooling rate under isothermal conditions. Thus, the simulation used in this work provides reliable predictions for optimizing HPD processing of the present alloy. Full article
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<p>The view of real and simulation-generated samples from (1) front, (2, 4, 5, 6) sides, (3) back, and (7) tilted view. (<b>a</b>) real casted sample and (<b>b</b>) software-generated sample design.</p>
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<p>Filling progress from (<b>a</b>) front and (<b>b</b>) side view within the filling percentage of 60%, 80%, and 100% from left to right.</p>
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<p>ProCAST modelling results for the (<b>a</b>) cooling rate, (<b>b</b>) solidification time, and (<b>c</b>) pore presence.</p>
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<p>Microstructure results for the thick part (R1), bolt part (R2), and corner part (R3). Lower figures showing the magnification view of the white square on the upper side. The presence of ESCs (externally solidified crystals) can be seen in the corner body (R3). The porosity percentage and average pore size (micron) are presented in the histogram.</p>
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<p>3D morphology and elemental analysis of bolt area (R2).</p>
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<p>(<b>a</b>) Microhardness distribution (obtained using 0.5 kgf) and (<b>b</b>) micrograph of the indentation marks on the regions of interest in the final product corresponding to thick part (R1), bolt part (R2), and corner part (R3).</p>
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<p>Schematic illustration of (<b>a</b>) weld formation around R2 and (<b>b</b>) different cooling rates at different positions.</p>
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14 pages, 3253 KiB  
Article
Carbon Footprint of Additively Manufactured Precious Metals Products
by Mario Schmidt, Jochen Heinrich and Ingwar Huensche
Resources 2024, 13(11), 162; https://doi.org/10.3390/resources13110162 - 20 Nov 2024
Viewed by 797
Abstract
Traditionally, precious metals are processed by either lost-wax casting or the casting of semi-finished products followed by cold or hot working, machining, and surface finishing. Long process chains usually conclude in a high material input factor and a significant amount of new scrap [...] Read more.
Traditionally, precious metals are processed by either lost-wax casting or the casting of semi-finished products followed by cold or hot working, machining, and surface finishing. Long process chains usually conclude in a high material input factor and a significant amount of new scrap to be refined. The maturing of Additive Manufacturing (AM) technologies is advantageous with regard to resources among other criteria by opening up new processing techniques like laser-based powder bed fusion (LPBF) for the production of near net shape metal products. This paper gives an insight into major advantages of the powder-based manufacturing of precious metal components over conventional methods focusing on product carbon footprints (PCF). Material Flow Cost Accounting (MFCA) for selected applications show energy and mass flows and inefficient recoverable losses in detail. An extended MFCA approach also shows the greenhouse gas (GHG) savings from avoiding recoverable material losses and provides PCF for the products. The PCF of the precious metals used is based on a detailed Life Cycle Assessment (LCA) of the refining process of end-of-use precious metals. In the best case, the refining of platinum from end-of-life recycling, for example, causes 60 kg CO2e per kg of platinum. This study reveals recommended actions for improvements in efficiency and gives guidance for a more sustainable production of luxury or technical goods made from precious metals. This exemplary study on the basis of an industrial application shows that the use of AM leads to a carbon footprint of 2.23 kg CO2e per piece in comparison with 3.17 kg CO2e by conventional manufacturing, which means about a 30 percent reduction in GHG emissions and also in energy, respectively. Full article
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<p>The carbon footprint of various precious metals at C.Hafner, recovered from high value scrap. Source: [<a href="#B12-resources-13-00162" class="html-bibr">12</a>].</p>
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<p>The illustrative scheme for the treatment of internal returns of material with notional figures for the carbon footprint of metal flows (in yellow).</p>
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<p>Near net shape AM electrode head (numbers in mm), AM batch production, and cross section.</p>
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<p>Sankey diagram of the conventional manufacturing of electrode heads made of Pt-Ir 200‰. The width of the arrows indicates the amount of the carbon footprint of the various energy and material flows in kg CO<sub>2e</sub>.</p>
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<p>Sankey diagram of the Additive Manufacturing of electrode heads made of Pt-Ir 200‰. The width of the arrows indicates the amount of the carbon footprint of the various energy and material flows in kg CO<sub>2e</sub>.</p>
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<p>Carbon footprint (in kg CO<sub>2</sub> equivalent) of electrode heads made of Pt-Ir 200‰ and the contributions of various sources. Comparison of Conventional and Additive Manufacturing.</p>
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24 pages, 6909 KiB  
Review
Research Status and Development Trend of Wire Arc Additive Manufacturing Technology for Aluminum Alloys
by Pan Dai, Ao Li, Jianxun Zhang, Runjie Chen, Xian Luo, Lei Wen, Chen Wang and Xianghong Lv
Coatings 2024, 14(9), 1094; https://doi.org/10.3390/coatings14091094 - 28 Aug 2024
Cited by 2 | Viewed by 2162
Abstract
It is difficult for traditional aluminum alloy manufacturing technology to meet the requirements of large-scale and high-precision complex shape structural parts. Wire Arc additive manufacturing technology (WAAM) is an innovative production method that presents the unique advantages of high material utilization, a large [...] Read more.
It is difficult for traditional aluminum alloy manufacturing technology to meet the requirements of large-scale and high-precision complex shape structural parts. Wire Arc additive manufacturing technology (WAAM) is an innovative production method that presents the unique advantages of high material utilization, a large degree of design freedom, fast prototyping speed, and low cast. As a result, WAAM is suitable for near-net forming of large-scale complex industrial production and has a wide range of applications in aerospace, automobile manufacturing, and marine engineering fields. In order to serve as a reference for the further development of WAAM technology, this paper provides an overview of the current developments in WAAM both from the digital control system and processing parameters in summary of the recent research progress. This work firstly summarized the principle of simulation layering and path planning and discussed the influence of relative technological parameters, such as current, wire feeding speed, welding speed, shielding gas, and so on. It can be seen that both the welding current and wire feeding speed are directly proportional to the heat input while the travel speed is inversely proportional to the heat input. This process regulation is an important means to improve the quality of deposited parts. This paper then summarized various methods including heat input, alloy composition, and heat treatment. The results showed that in the process of WAAM, it is necessary to control the appropriate heat input to achieve minimum heat accumulation and improve the performance of the deposited parts. To obtain higher mechanical properties (tensile strength has been increased by 28%–45%), aluminum matrix composites by WAAM have proved to be an effective method. The corresponding proper heat treatment can also increase the tensile strength of WAAM Al alloy by 104.3%. In addition, mechanical properties are always assessed to evaluate the quality of deposited parts. The mechanical properties including the tensile strength, yield strength, and hardness of the deposited parts under different processing conditions have been summarized to provide a reference for the quality evaluation of the deposition. Examples of industrial products fabricated by WAAM are also introduced. Finally, the application status of WAAM aluminum alloy is summarized and the corresponding future research direction is prospected. Full article
(This article belongs to the Special Issue Advancement in Heat Treatment and Surface Modification for Metals)
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<p>Schematic of the WAAM process contains the welding machine, shielding gas, robot, torch, controller, computer, sensor, and wire feeder [<a href="#B28-coatings-14-01094" class="html-bibr">28</a>].</p>
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<p>Diagram of the slicing method workflow [<a href="#B31-coatings-14-01094" class="html-bibr">31</a>].</p>
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<p>(<b>a</b>) Two-and-a-half-dimensional parametric surfaces slicing [<a href="#B34-coatings-14-01094" class="html-bibr">34</a>], (<b>b</b>) novel non-planar slicing [<a href="#B35-coatings-14-01094" class="html-bibr">35</a>], (<b>c</b>) decomposition–regrouping method for multi-direction slicing [<a href="#B33-coatings-14-01094" class="html-bibr">33</a>], (<b>d</b>) hybrid slicing [<a href="#B36-coatings-14-01094" class="html-bibr">36</a>].</p>
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<p>(<b>a</b>) The unidirectional path, (<b>b</b>) the reciprocal path, (<b>c</b>,<b>f</b>) the contour offset path, (<b>d</b>) the spiral path, and (<b>e</b>) the fractal line path [<a href="#B40-coatings-14-01094" class="html-bibr">40</a>].</p>
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<p>(<b>a</b>) Complete forming paths with hybrid path-planning [<a href="#B40-coatings-14-01094" class="html-bibr">40</a>], (<b>b</b>) surface curved layer path planning [<a href="#B41-coatings-14-01094" class="html-bibr">41</a>], (<b>c</b>) support-free path planning method [<a href="#B42-coatings-14-01094" class="html-bibr">42</a>], (<b>d</b>) cone geometry with offset deposition paths [<a href="#B43-coatings-14-01094" class="html-bibr">43</a>], (<b>e</b>) generation of a continuous path on the closed part [<a href="#B44-coatings-14-01094" class="html-bibr">44</a>].</p>
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<p>IPFS of WAAM samples from three different current modes [<a href="#B48-coatings-14-01094" class="html-bibr">48</a>].</p>
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<p>(<b>a</b>) Surface morphologies, (<b>b</b>) cross sections, (<b>c</b>) inverse pole figures of WAAM deposition samples fabricated at several travel speeds [<a href="#B51-coatings-14-01094" class="html-bibr">51</a>].</p>
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<p>The superficial aspect and cross-sections of the deposits under different O<sub>2</sub> contents [<a href="#B52-coatings-14-01094" class="html-bibr">52</a>].</p>
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<p>(<b>a</b>) Ultrasonic treatment [<a href="#B53-coatings-14-01094" class="html-bibr">53</a>], (<b>b</b>) ultrasonic nanocrystal surface modification [<a href="#B55-coatings-14-01094" class="html-bibr">55</a>], (<b>c</b>) ultrasonically assisted [<a href="#B54-coatings-14-01094" class="html-bibr">54</a>].</p>
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<p>(<b>a</b>) Interlayer rolling technology [<a href="#B58-coatings-14-01094" class="html-bibr">58</a>,<a href="#B62-coatings-14-01094" class="html-bibr">62</a>], (<b>b</b>) interlayer rapid cooling [<a href="#B61-coatings-14-01094" class="html-bibr">61</a>], (<b>c</b>) interlayer hammering [<a href="#B59-coatings-14-01094" class="html-bibr">59</a>].</p>
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<p>The experimental rig representation of the NIAC concept [<a href="#B65-coatings-14-01094" class="html-bibr">65</a>].</p>
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<p>Grain refinement of WAAM and particles reinforcement aluminum alloy: (<b>a</b>–<b>c</b>) the Inverse pole figures of 2219 aluminum alloy + TiC particles [<a href="#B69-coatings-14-01094" class="html-bibr">69</a>]; (<b>d</b>–<b>f</b>) the Inverse pole figures and Engineering stress–strain curves of 7075 aluminum alloy + TiC particles [<a href="#B67-coatings-14-01094" class="html-bibr">67</a>]; (<b>g</b>–<b>k</b>) the Inverse pole figures and microhardness results of 4043 aluminum alloy + La<sub>2</sub>O<sub>3</sub> [<a href="#B68-coatings-14-01094" class="html-bibr">68</a>].</p>
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<p>(<b>a</b>) Microstructure of precipitates of AD, (<b>b</b>,<b>c</b>) the fracture principle of AD sample, (<b>d</b>,<b>e</b>) Microstructure of precipitates under T6 condition, (<b>f</b>–<b>h</b>) the fracture principle under T6 condition, (<b>g</b>) mechanical properties of AD and T6 heat treatment [<a href="#B73-coatings-14-01094" class="html-bibr">73</a>].</p>
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<p>(<b>a</b>) Multi-intersection aircraft components [<a href="#B84-coatings-14-01094" class="html-bibr">84</a>], (<b>b</b>) impellers for the oil and gas industry [<a href="#B87-coatings-14-01094" class="html-bibr">87</a>].</p>
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12 pages, 7727 KiB  
Article
Microstructure and Mechanical Behavior Comparison between Cast and Additive Friction Stir-Deposited High-Entropy Alloy Al0.35CoCrFeNi
by Zackery McClelland, Kyle Dunsford, Brady Williams, Haley Petersen, Keivan Devami, Mark Weaver, J. Brian Jordan and Paul G. Allison
Materials 2024, 17(4), 910; https://doi.org/10.3390/ma17040910 - 16 Feb 2024
Cited by 2 | Viewed by 1329
Abstract
High-entropy alloys (HEAs) are new alloy systems that leverage solid solution strengthening to develop high-strength structural materials. However, HEAs are typically cast alloys, which may suffer from large as-cast grains and entrapped porosity, allowing for opportunities to further refine the microstructure in a [...] Read more.
High-entropy alloys (HEAs) are new alloy systems that leverage solid solution strengthening to develop high-strength structural materials. However, HEAs are typically cast alloys, which may suffer from large as-cast grains and entrapped porosity, allowing for opportunities to further refine the microstructure in a non-melting near-net shape solid-state additive manufacturing process, additive friction stir deposition (AFSD). The present research compares the microstructure and mechanical behavior of the as-deposited AFSD Al0.35CoCrFeNi to the cast heat-treated properties to assess its viability for structural applications for the first time. Scanning electron microscopy (SEM) revealed the development of fine particles along the layer interfaces of the deposit. Quasi-static and intermediate-rate compression testing of the deposited material revealed a significant strain-rate sensitivity with a difference in yield strength of ~400 MPa. Overall, the AFSD process greatly reduced the grain size for the Al0.35CoCrFeNi alloy and approximately doubled the strength at both quasi-static and intermediate strain rates. Full article
(This article belongs to the Section Metals and Alloys)
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<p>Schematic of the additive friction stir deposition process (<b>a</b>), deposited AlxCoCrFeNi high-entropy alloy (<b>b</b>), and schematic of mechanical specimen geometry and sample naming nomenclature (<b>c</b>).</p>
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<p>Scanning electron microscope images of the Al<sub>0.35</sub>CoCrFeNi HEA depicting the ID and DR regions of the microstructure (<b>a</b>) and a higher-magnification image (<b>b</b>) showing multiphase transformation products in each region.</p>
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<p>XRD patterns for the Al<sub>0.35</sub>CoCrFeNi high-entropy alloy for the annealed condition and then after additive friction stir deposition for the advancing side (AS), middle (MD), and retreating side (RS).</p>
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<p>Scanning electron microscope image of additive friction stir-deposited HEA material overview (<b>a</b>), deposition layer interface (<b>b</b>,<b>c</b>), and energy dispersive spectroscopy depicting higher concentration of Al at layer interfaces (<b>d</b>).</p>
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<p>Scanning electron microscope backscatter electron images of the additive friction stir deposited overview (<b>a</b>), retreating side (<b>b</b>), advancing side (<b>c</b>), and middle (<b>d</b>).</p>
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<p>Electron backscatter diffraction inverse pole figure maps of the additive friction stir deposited overview (<b>a</b>), retreating side (<b>b</b>), advancing side (<b>c</b>), and middle (<b>d</b>). Bands of dynamically recrystallized grains can be seen in (<b>b</b>,<b>d</b>) with a significantly smaller grain size due to Zener pinning.</p>
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<p>Microhardness map of the Al<sub>0.35</sub>CoCrFeNi alloy system deposited via additive friction stir deposition. Overall map with ~500 μm spacing between indents.</p>
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<p>Stress–strain response of annealed and additive friction stir-deposited Al<sub>0.35</sub>CoCrFeNi evaluated using compression at 0.001 s<sup>−1</sup> (QS) and 1 s<sup>−1</sup> (intermediate) strain rates.</p>
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<p>Kocks–Mecking plot showing variation in dσ/dε as a function of flow stress for the (<b>a</b>) annealed HEA material and (<b>b</b>) additive friction stir-deposited (AFSD) HEA material evaluated using compression at 0.001 s<sup>−1</sup> (QS) and 1 s<sup>−1</sup> (intermediate) strain rates.</p>
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19 pages, 37911 KiB  
Article
Near Net Shape Manufacturing of Sheets from Al-Cu-Li-Mg-Sc-Zr Alloy
by Barbora Kihoulou, Rostislav Králík, Lucia Bajtošová, Olexandr Grydin, Mykhailo Stolbchenko, Mirko Schaper and Miroslav Cieslar
Materials 2024, 17(3), 644; https://doi.org/10.3390/ma17030644 - 28 Jan 2024
Cited by 1 | Viewed by 1242
Abstract
Thin twin-roll cast strips from a model Al-Cu-Mg-Li-Zr alloy with a small addition of Sc were prepared. A combination of a fast solidification rate and a favorable effect of Sc microalloying refines the grain size and the size of primary phase particles and [...] Read more.
Thin twin-roll cast strips from a model Al-Cu-Mg-Li-Zr alloy with a small addition of Sc were prepared. A combination of a fast solidification rate and a favorable effect of Sc microalloying refines the grain size and the size of primary phase particles and reduces eutectic cell dimensions to 10–15 μm. Long-term homogenization annealings used in conventionally cast materials lasting several tens of hours followed by a necessary dimension reduction through rolling/extruding could be substituted by energy and material-saving procedure. It consists of two-step short annealings at 300 °C/30 min and 450 °C/30 min, followed by the refinement and hardening of the structure using constrained groove pressing. A dense dispersion of 10–20 nm spherical Al3(Sc,Zr) precipitates intensively forms during this treatment and effectively stabilizes the structure and inhibits the grain growth during subsequent solution treatment at 530 °C/30 min. Small (3%) pre-straining after quenching assures more uniform precipitation of strengthening Al2Cu (θ), Al2CuMg (S), and Al2CuLi (T1) particles during subsequent age-hardening annealing at 180 °C/14 h. The material does not contain a directional and anisotropic structure unavoidable in rolled or extruded sheets. The proposed procedure thus represents a model near net shape processing strategy for manufacturing lightweight high-strength sheets for cryogenic applications in aeronautics. Full article
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<p>LOM images of the as-cast materials showing grain distributions in (<b>a</b>) AlLi MC, (<b>b</b>) AlLiSc MC, (<b>c</b>) AlLi TRC, and (<b>d</b>) AlLiSc TRC.</p>
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<p>SEM BSE images of eutectic cells in as-cast materials: (<b>a</b>) AlLi MC, (<b>b</b>) AlLiSc MC, (<b>c</b>) AlLi TRC, and (<b>d</b>) AlLiSc TRC, demonstrating a positive influence of TRC and Sc addition on the refinement of the structure.</p>
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<p>BSE image with corresponding EDS maps showing the distribution of Al, Cu, Fe, Sc, and Mg in a selected zone containing rare Sc-rich particles in the MC AlLiSc alloy in the as-cast state.</p>
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<p>EBSD inverse pole figures of as-cast materials: (<b>a</b>) AlLi MC, (<b>b</b>) AlLiSc MC, (<b>c</b>) AlLi TRC, and (<b>d</b>) AlLiSc TRC. Central parts of strips were selected in the TRC materials.</p>
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<p>TEM micrographs of the as-cast AlLiSc materials: (<b>a</b>,<b>b</b>) MC, (<b>c</b>,<b>d</b>) TRC. Zone [001], both the yellow arrows in insets of diffraction patterns (<b>b</b>,<b>d</b>) pointing at the position of the superstructural spots and streaks highlighted by the yellow dashed lines reflect the presence of fine <math display="inline"><semantics> <msup> <mi>θ</mi> <mo>′</mo> </msup> </semantics></math>-Al<sub>2</sub>Cu precipitates.</p>
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<p>LOM images of materials after annealing at 300 °C/30 min, 450 °C/30 min, and one CGP cycle performed at 300 °C: (<b>a</b>) AlLi MC, (<b>b</b>) AlLiSc MC, (<b>c</b>) AlLi TRC, and (<b>d</b>) AlLiSc TRC.</p>
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<p>EBSD IPF maps of materials after annealing at 300 °C/30 min, 450 °C/30 min, and one CGP cycle performed at 300 °C: (<b>a</b>) AlLi MC, (<b>b</b>) AlLiSc MC, (<b>c</b>) AlLi TRC, and (<b>d</b>) AlLiSc TRC.</p>
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<p>TEM micrographs showing the distribution of Cu and Mg-rich particles in materials after annealing at 300 °C/30 min, 450 °C/30 min, and one CGP cycle performed at 300 °C: (<b>a</b>) AlLi MC, (<b>b</b>) AlLiSc MC, (<b>c</b>) AlLi TRC, and (<b>d</b>) AlLiSc TRC.</p>
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<p>SEM BSE images and corresponding EDS maps of materials after annealing at 300 °C/30 min, 450 °C/30 min, and one CGP cycle performed at 300 °C: (<b>a</b>,<b>e</b>,<b>i</b>,<b>m</b>,<b>q</b>) AlLi MC, (<b>b</b>,<b>f</b>,<b>j</b>,<b>n</b>,<b>r</b>) AlLiSc MC, (<b>c</b>,<b>g</b>,<b>k</b>,<b>o</b>,<b>s</b>) AlLi TRC, and (<b>d</b>,<b>h</b>,<b>l</b>,<b>p</b>,<b>t</b>) AlLiSc TRC.</p>
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<p>SEM BSE images and corresponding EDS maps of materials after annealing at 300 °C/30 min, 450 °C/30 min, one CGP cycle, and one solution treatment at 530 °C/30 min: (<b>a</b>,<b>e</b>,<b>i</b>,<b>m</b>,<b>q</b>) AlLi MC, (<b>b</b>,<b>f</b>,<b>j</b>,<b>n</b>,<b>r</b>) AlLiSc MC, (<b>c</b>,<b>g</b>,<b>k</b>,<b>o</b>,<b>s</b>) AlLi TRC, and (<b>d</b>,<b>h</b>,<b>l</b>,<b>p</b>,<b>t</b>) AlLiSc TRC.</p>
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<p>LOM images of materials after annealing at 300 °C/30 min, 450 °C/30 min, one CGP cycle, and one solution treatment at 530 °C/30 min: (<b>a</b>) AlLi MC, (<b>b</b>) AlLiSc MC, (<b>c</b>) AlLi TRC, and (<b>d</b>) AlLiSc TRC.</p>
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<p>EBSD IPF maps of materials after annealing at 300 °C/30 min, 450 °C/30 min, one CGP cycle, and one solution treatment at 530 °C/30 min: (<b>a</b>) AlLi MC, (<b>b</b>) AlLiSc MC, (<b>c</b>) AlLi TRC, and (<b>d</b>) AlLiSc TRC.</p>
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<p>Microhardness evolution during aging: (<b>a</b>) specimen without pre-straining after the solution treatment, (<b>b</b>) specimen pre-strained by 3% after the solution treatment.</p>
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<p>Distribution of microhardness through the sample thickness of materials after annealing at 300 °C/30 min, 450 °C/30 min, one CGP cycle performed at 300 °C, one solution treatment at 530 °C/30 min, 3% pre-straining and aging at 180 °C/110 h: (<b>a</b>) AlLi MC, (<b>b</b>) AlLiSc MC, (<b>c</b>) AlLi TRC, and (<b>d</b>) AlLiSc TRC.</p>
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<p>TEM micrograph of materials after annealing at 300 °C/30 min, 450 °C/30 min, one CGP cycle performed at 300 °C, one solution treatment at 530 °C/30 min, and aging at 180 °C/40 h: (<b>a</b>) AlLi MC, (<b>b</b>) AlLiSc MC, (<b>c</b>) AlLi TRC, and (<b>d</b>) AlLiSc TRC.</p>
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<p>TEM micrograph of materials after annealing at 300 °C/30 min, 450 °C/30 min, one CGP cycle performed at 300 °C, one solution treatment at 530 °C/30 min, and aging at 180 °C/40 h (near peak age condition), dark field, zone [001]: (<b>a</b>) AlLi MC, (<b>b</b>) AlLiSc MC, (<b>c</b>) AlLi TRC, and (<b>d</b>) AlLiSc TRC. Small Al<sub>3</sub>Zr particles are highlighted in insets in (<b>a</b>,<b>c</b>).</p>
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<p>TEM micrograph of materials after annealing at 300 °C/30 min, 450 °C/30 min, one CGP cycle performed at 300 °C, one solution treatment at 530 °C/30 min, and aging at 180 °C/40 h (near peak age condition), zone [110]: (<b>a</b>) AlLi MC, (<b>b</b>) AlLiSc MC, (<b>c</b>) AlLi TRC, and (<b>d</b>) AlLiSc TRC.</p>
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<p>Schematic diagrams of the diffraction pattern along: (<b>a</b>) 〈100〉, (<b>b</b>) 〈110〉 zone axes.</p>
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<p>TEM images showing the same area in [100] and [110] orientations and corresponding EDS maps of needle-shaped subgrain boundary particles containing Cu and Mg. Arrows indicate Mg maps of selected particles highlighted by circles.</p>
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<p>TEM micrographs of boundaries in materials after annealing at 300 °C/30 min, 450 °C/30 min, one CGP cycle performed at 300 °C, one solution treatment at 530 °C/30 min, 3% pre-straining and aging at 180 °C/14 h (near peak age condition), bright field: (<b>a</b>) AlLi MC, (<b>b</b>) AlLiSc MC, (<b>c</b>) AlLi TRC, and (<b>d</b>) AlLiSc TRC.</p>
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<p>TEM micrograph of materials after annealing at 300 °C/30 min, 450 °C/30 min, one CGP cycle performed at 300 °C, one solution treatment at 530 °C/30 min, 3% pre-straining and aging at 180 °C/14 h (near peak age condition), zone [110]: (<b>a</b>) AlLi MC, (<b>b</b>) AlLiSc MC, (<b>c</b>) AlLi TRC, and (<b>d</b>) AlLiSc TRC.</p>
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4 pages, 189 KiB  
Editorial
Recent Advances in Cast Irons
by Annalisa Fortini and Chiara Soffritti
Metals 2023, 13(5), 980; https://doi.org/10.3390/met13050980 - 19 May 2023
Cited by 3 | Viewed by 2002
Abstract
Cast irons are widely used in industry due to their excellent castability, allowing for the production of near-net shape components with complex geometries without the need for additional forging or machining processes [...] Full article
(This article belongs to the Special Issue Recent Advances in Cast Irons)
19 pages, 64672 KiB  
Article
Investigations of Abrasive Wear Behaviour of Hybrid High-Boron Multi-Component Alloys: Effect of Boron and Carbon Contents by the Factorial Design Method
by Yuliia Chabak, Ivan Petryshynets, Vasily Efremenko, Michail Golinskyi, Kazumichi Shimizu, Vadym Zurnadzhy, Ivan Sili, Hossam Halfa, Bohdan Efremenko and Viktor Puchy
Materials 2023, 16(6), 2530; https://doi.org/10.3390/ma16062530 - 22 Mar 2023
Cited by 5 | Viewed by 1765
Abstract
This paper is devoted to the evaluation of the “three-body-abrasion” wear behaviour of (wt.%) 5W–5Mo–5V–10Cr-2.5Ti-Fe (balance) multi-component (C + B)-added alloys in the as-cast condition. The carbon (0.3 wt.%, 0.7 wt.%, 1.1 wt.%) and boron (1.5 wt.%, 2.5 wt.%, 3.5 wt.%) contents were [...] Read more.
This paper is devoted to the evaluation of the “three-body-abrasion” wear behaviour of (wt.%) 5W–5Mo–5V–10Cr-2.5Ti-Fe (balance) multi-component (C + B)-added alloys in the as-cast condition. The carbon (0.3 wt.%, 0.7 wt.%, 1.1 wt.%) and boron (1.5 wt.%, 2.5 wt.%, 3.5 wt.%) contents were selected using a full factorial (32) design method. The alloys had a near-eutectic (at 1.5 wt.% B) or hyper-eutectic (at 2.5–3.5 wt.% B) structure. The structural micro-constituents were (in different combinations): (a) (W, Mo, and V)-rich borocarbide M2(B,C)5 as the coarse primary prismatoids or as the fibres of a “Chinese-script” eutectic, (b) Ti-rich carboboride M(C,B) with a dispersed equiaxed shape, (c) Cr-rich carboboride M7(C,B)3 as the plates of a “rosette”-like eutectic, and (d) Fe-rich boroncementite (M3(C,B)) as the plates of “coarse-net” and ledeburite eutectics. The metallic matrix was ferrite (at 0.3–1.1 wt.% C and 1.5 wt.% B) and “ferrite + pearlite” or martensite (at 0.7–1.1 wt.% C and 2.5–3.5 wt.% B). The bulk hardness varied from 29 HRC (0.3 wt.% C–1.5 wt.% B) to 53.5 HRC (1.1 wt.% C–3.5 wt.% B). The wear test results were mathematically processed and the regression equation of the wear rate as a function of the carbon and boron contents was derived and analysed. At any carbon content, the lowest wear rate was attributed to the alloy with 1.5 wt.% B. Adding 2.5 wt.% B led to an increase in the wear rate because of the appearance of coarse primary borocarbides (M2(B,C)5), which were prone to chipping and spalling-off under abrasion. At a higher boron content (3.5 wt.%), the wear rate decreased due to the increase in the volume fraction of the eutectic carboborides. The optimal chemical composition was found to be 1.1 wt.% C–1.5 wt.% B with a near-eutectic structure with about 35 vol.% of hard inclusions (M2(B,C)5, M(C,B), M3(C,B), and M7(C,B)3) in total. The effect of carbon and boron on the abrasive behaviour of the multi-component cast alloys with respect to the alloys’ structure is discussed, and the mechanism of wear for these alloys is proposed. Full article
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<p>Microstructure (BSE images) of the alloys: (<b>a</b>) 0.3C–1.5B, (<b>b</b>) 0.3C–2.5B, (<b>c</b>) 0.3C–3.5B, (<b>d</b>) 0.7C–1.5B, (<b>e</b>) 0.7C–2.5B, (<b>f</b>) 0.7C–3.5B, (<b>g</b>) 1.1C–1.5B, (<b>h</b>) 1.1C–2.5B, (<b>i</b>) 1.1C–3.5B (CS is a “Chinese-script” eutectic; P is a primary carboboride M<sub>2</sub>(B,C)<sub>5</sub>; R is a “rosette” eutectic; F is a “fish-bone” eutectic; L is a ledeburite eutectic).</p>
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<p>Microstructural constituents: (<b>a</b>) “Chinese-script” eutectic, (<b>b</b>) primary carboboride prismatoids M<sub>2</sub>(B,C)<sub>5</sub>, (<b>c</b>) “rosette”-like eutectic, (<b>d</b>) equiaxed angular carboborides M(C,B), (<b>e</b>) “coarse-net” eutectic, (<b>f</b>) ledeburite eutectic (<b>a</b>) (<b>right</b>), (<b>b</b>,<b>c</b>) present SEM/BSE images; (<b>d</b>) presents SEM/secondary electron (SE) (<b>left</b>) and SEM/BSE (<b>right</b>) images; (<b>a</b>) (<b>left</b>), (<b>e</b>,<b>f</b>) present OM images).</p>
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<p>Representative EDS spectra of hard compounds: (<b>a</b>) primary M<sub>2</sub>(B,C)<sub>5</sub>, (<b>b</b>) Ti-rich equiaxed M(C,B), (<b>c</b>) (Cr/Fe)-rich eutectic M<sub>7</sub>(C,B)<sub>3</sub>, (<b>d</b>) Fe-rich eutectic M<sub>3</sub>(C,B).</p>
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<p>The wear behaviour of the studied alloys: (<b>a</b>) resistance of eutectic particles and primary carboboride to the abrasive sliding of SiC particles (in alloy 0.3C–3.5B); (<b>b</b>) the “shadow zones” after abrasive particle movement. The representative patterns of the worn surfaces of the alloys: (<b>c</b>) 0.3C–1.5B, (<b>d</b>,<b>h</b>) 0.3C–2.5B, (<b>e</b>,<b>g</b>) 1.1C–1.5B, (<b>f</b>) 1.1C–3.5B (<b>b</b>–<b>f</b>) are OM images; (<b>a</b>,<b>g</b>,<b>h</b>) are SEM images; CN refers to a ”coarse-network” eutectic)). Circles in (<b>b</b>) show the “shadow zones”.</p>
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<p>(<b>a</b>) The response surface of Equation (5) and (<b>b</b>) its projections on the “wt.% C-wt.% B” plot (the numbers next to the curve in (<b>b</b>) are the wear rate values × 10<sup>−6</sup> (g·mm<sup>−1</sup>·s<sup>−1</sup>)).</p>
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<p>Individual effects of (<b>a</b>) carbon and (<b>b</b>) boron on the wear rate according to Equation (5).</p>
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<p>Effect of the total amount of hard compounds on (<b>a</b>) the bulk hardness and (<b>b</b>) the wear rate of the alloys. (<b>c</b>) Effect of the bulk hardness on the wear rate of the alloys.</p>
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<p>Effects of (<b>a</b>) carbon and (<b>b</b>) boron on the total amount of hard particles in the alloys.</p>
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<p>Effects of carbon on the volume fractions of carboborides: (<b>a</b>) equiaxed Ti-rich particles, (<b>b</b>) Cr-rich particles that belong to the “rosette”, “coarse-net”, and ledeburite eutectics, (<b>c</b>) primary prisms, (<b>d</b>) the particles that belong to the “Chinese-script” eutectic.</p>
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<p>Effects of boron on the volume fractions of carboborides: (<b>a</b>) the particles that belong to the “Chinese-script” eutectic, (<b>b</b>) primary prisms, (<b>c</b>) Cr-rich particles that belong to the “rosette”, “coarse-net”, and ledeburite eutectics, (<b>d</b>) equiaxed Ti-rich particles.</p>
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<p>(<b>a</b>) The “shadow zones” at close-together and remote eutectic particles. (<b>b</b>) Destruction of the primary prismatic inclusion with the wear of the surrounding matrix: (<b>b</b>) the different stages of the primary borocarbide fracture (from initial state to surface chipping (small debris particles) and to volumetric spalling-off (big debris particles)).</p>
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19 pages, 6048 KiB  
Article
Design Optimization of Hot Isostatic Pressing Capsules
by Samaneh Sobhani, Marc Albert, David Gandy, Ali Tabei and Zhaoyan Fan
J. Manuf. Mater. Process. 2023, 7(1), 30; https://doi.org/10.3390/jmmp7010030 - 25 Jan 2023
Cited by 6 | Viewed by 3389
Abstract
Power metallurgy hot isostatic pressing (PM-HIP) is a manufacturing technique capable of producing net shape or near-net shape components with complicated geometries from materials that are difficult to melt and cast, mechanically deform or weld. However, the process and soundness of the outcome [...] Read more.
Power metallurgy hot isostatic pressing (PM-HIP) is a manufacturing technique capable of producing net shape or near-net shape components with complicated geometries from materials that are difficult to melt and cast, mechanically deform or weld. However, the process and soundness of the outcome are extremely sensitive to the geometric design of the capsule (also known as the die or can) that is used in the process. The capsule design for each new component involves several trial–error iterations to achieve the desired geometry and shape of the component. For each iteration, costly HIP experiments need to be conducted and new capsules need be manufactured with small modifications. In this study, a robust finite element analysis (FEA) model of the HIP process is developed, then wrapped in a multi-objective genetic algorithm (MOGA) optimization framework to obtain the optimal pre-HIP capsule design, which yields the desired post-HIP component geometry in one HIP run. The FEA-based optimization algorithm is validated by HIP experiments, showing excellent agreement between the experiment and the model. Full article
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<p>The developed modeling framework.</p>
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<p>The 3D geometry and 2D axisymmetric section.</p>
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<p>(<b>a</b>) The dimensions of the desired geometry and (<b>b</b>) the input optimized parameters.</p>
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<p>The MOGA workflow [<a href="#B28-jmmp-07-00030" class="html-bibr">28</a>,<a href="#B31-jmmp-07-00030" class="html-bibr">31</a>], DP new population that MOGA generates.</p>
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<p>The simulation setup [<a href="#B33-jmmp-07-00030" class="html-bibr">33</a>].</p>
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<p>Meshed 2D axisymmetric section, capsule and compact.</p>
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<p>HIP temperature and pressure profiles.</p>
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<p>Contour plot of location-dependent relative density (<b>a</b>) for the part at the end of the HIP cycle and (<b>b</b>) during the HIP cycle.</p>
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<p>Convergence chart of the optimization processing, showing the stability percentage (2) of the population that reached the desired level of the stability by the 10th iteration.</p>
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<p>Sensitivity chart of selected parameters showing the sensitivity and inter-dependency levels of the four output parameters (<a href="#jmmp-07-00030-f003" class="html-fig">Figure 3</a>b).</p>
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<p>Trade off chart for the P3 parameter. Red points present the worst cases, while the blue points are the best-chosen results.</p>
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<p>All feasible possibilities for the non-dominated solutions (red lines), selected candidate points (green).</p>
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<p>Post-HIP dimensions for each point during optimization (for mentioned parameters from <a href="#jmmp-07-00030-f003" class="html-fig">Figure 3</a>a): (<b>a</b>) P1 parameter; (<b>b</b>) P2 parameter; (<b>c</b>) P3 parameter; (<b>d</b>) P4 parameter.</p>
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<p>Range of parameters and place of candidate points.</p>
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<p>Experimental capsule post-HIP (dots for 3D scanning).</p>
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<p>Pre-HIP and post-HIP geometries: (<b>a</b>) experiment; (<b>b</b>) FEM.</p>
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<p>Post-HIP FEM model geometry overlayed with the post-HIP physical experimental geometry.</p>
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9 pages, 536 KiB  
Review
Recent Developments in 3D Printing of Rare-Earth-Free Permanent Magnets
by Chitnarong Sirisathitkul and Yaowarat Sirisathitkul
Inventions 2022, 7(3), 71; https://doi.org/10.3390/inventions7030071 - 22 Aug 2022
Cited by 6 | Viewed by 3617
Abstract
This article reviews the advances in additive manufacturing of magnetic ceramics and alloys without rare-earth elements. Near-net-shaped permanent magnets with varying shapes and dimensions overcome traditional limitations of the cast, sintered, and bonded magnets. The published articles are categorized based on material types [...] Read more.
This article reviews the advances in additive manufacturing of magnetic ceramics and alloys without rare-earth elements. Near-net-shaped permanent magnets with varying shapes and dimensions overcome traditional limitations of the cast, sintered, and bonded magnets. The published articles are categorized based on material types and 3D printing techniques. Selective laser melting and electron beam melting were predominantly used to produce alnico magnets. In addition to the electron beam melting, manganese aluminium-based alloys were successfully printed by fuse filament fabrication. By incorporating magnetic powders in polymers and then printing via extrusion, the fuse filament fabrication was also used to produce strontium ferrite magnets. Moreover, hard ferrites were printed by stereolithography and extrusion free-forming, without drawing composites into filaments. Magnetic properties in some cases are comparable to those of conventional magnets with the same compositions. Currently, available software packages can simulate magnetic fields for designing magnets and optimize the integration in electrical machines. These developments open up opportunities for next-generation permanent magnet applications. Full article
(This article belongs to the Special Issue Innovations in 3D Printing 2.0)
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<p>Examples of traditional manufacturing processes: (<b>a</b>) compression molding; (<b>b</b>) injection molding.</p>
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<p>Examples of additive manufacturing processes for magnetic materials: (<b>a</b>) selective laser melting; (<b>b</b>) extrusion.</p>
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14 pages, 10153 KiB  
Article
Microstructure, Precipitates Behavior, and Mechanical Properties of Age-Hardened Al-Mg-Si Alloy Sheet Fabricated by Twin-Roll Casting
by Guanjun Gao, Xiwu Li, Baiqing Xiong, Zhihui Li, Yongan Zhang, Yanan Li and Lizhen Yan
Materials 2022, 15(16), 5638; https://doi.org/10.3390/ma15165638 - 16 Aug 2022
Cited by 2 | Viewed by 1467
Abstract
Twin-roll casting (TRC), as a near-net-shape technology, is employed to fabricate age-hardened Al-Mg-Si alloy. Compared with conventional direct chill (DC) casting, the TRC method is much more economical and efficient. In this work, the microstructure, precipitates behavior, and mechanical properties of age-hardened Al-Mg-Si [...] Read more.
Twin-roll casting (TRC), as a near-net-shape technology, is employed to fabricate age-hardened Al-Mg-Si alloy. Compared with conventional direct chill (DC) casting, the TRC method is much more economical and efficient. In this work, the microstructure, precipitates behavior, and mechanical properties of age-hardened Al-Mg-Si alloy sheet fabricated by TRC were investigated by hardness measurements and tensile tests, metallographic microscopy, field emission gun scanning electron microscope, electron backscatter diffraction, transmission electron microscopy, and differential scanning calorimetry analyses. It was found that the size of recrystallized grains for DC casting alloy with finely dispersed particles was larger than that of TRC alloy with coarse particles. Typical CubeND texture accompanied by P texture formed after solution treatment made the value of r reach ~0.7 in the TRC alloy due to the PSN effect caused by the segregation of particles. More GP zones resulted in the strength of TRC alloy being higher than that of DC casting alloy after T8X treatment. With the time of paint-bake hardening extended to 8 h, few segregation particles remained in the TRC alloy. This decreased the concentration of supersaturated atoms. The hardness of the TRC alloy with the lower density of the β″ strengthening phase was lower compared to the DC casting alloy. Full article
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<p>Schematic diagram of DC and TRC process of Al-Mg-Si alloy sheet.</p>
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<p>Schematic illustration of TRC technique and physical map of TRC experimental device.</p>
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<p>OM and SEM images of the second particles’ distribution in the cold-rolled alloy sheets: (<b>a</b>,<b>d</b>) A1 alloy, (<b>b</b>,<b>e</b>) A2 alloy, and (<b>c</b>,<b>f</b>) A3 alloy.</p>
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<p>TEM images and EDS analysis of the second particles’ distribution in the cold-rolled alloy sheets: (<b>a</b>,<b>d</b>) A1 alloy, (<b>b</b>,<b>e</b>) A2 alloy, and (<b>c</b>,<b>f</b>) A3 alloy.</p>
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<p>Recrystallized structure of A1, A2, and A3 alloys after solution treatment: (<b>a</b>) A1 alloy, (<b>b</b>) A2 alloy, and (<b>c</b>) A3 alloy.</p>
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<p>The ODF maps showing recrystallization texture of A1, A2, and A3 alloys after solution treatment: (<b>a</b>) A1 alloy, (<b>b</b>) A2 alloy, and (<b>c</b>) A3 alloy.</p>
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<p>TEM bright field images of A1, A2, and A3 alloys after T8X treatment: (<b>a</b>) dislocations introduced by 2% tensile deformation; (<b>b</b>–<b>d</b>) strengthened precipitates of A1, A2, and A3 alloys.</p>
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<p>HRTEM images and corresponding FFT patterns of the precipitates marked with the arrows in <a href="#materials-15-05638-f007" class="html-fig">Figure 7</a>: (<b>a</b>,<b>b</b>) GP zone and (<b>c</b>,<b>d</b>) β″ precipitates.</p>
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<p>TEM bright field images of A1, A2, and A3 alloys after paint-bake hardening at 185 °C for 8 h: (<b>a</b>) A1 alloy, (<b>b</b>) A2 alloy, and (<b>c</b>) A3 alloy.</p>
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<p>Engineering stress–strain curves of T4P-treated A1, A2 and A3 alloys in three directions: (<b>a</b>) A1 alloy, (<b>b</b>) A2 alloy, (<b>c</b>) A3 alloy, (<b>d</b>) Schematic diagram of the tensile direction.</p>
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<p>Average <span class="html-italic">r</span> and Δ<span class="html-italic">r</span> values of alloys with T4P state.</p>
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<p>Yield strength and hardness increment of alloys after T8X and T6 treatment: (<b>a</b>) yield strength and (<b>b</b>) Vickers hardness.</p>
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<p>Schematic illustration of recrystallization during solution treatment: (<b>a</b>) before solution treatment, (<b>b</b>) initial stage of grain growth, and (<b>c</b>) post stage of grain growth.</p>
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<p>DSC curves of the alloys with PA treatment.</p>
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34 pages, 6650 KiB  
Review
An Overview on the Process Development and the Formation of Non-Dendritic Microstructure in Semi-Solid Processing of Metallic Materials
by Shouxun Ji, Kai Wang and Xixi Dong
Crystals 2022, 12(8), 1044; https://doi.org/10.3390/cryst12081044 - 27 Jul 2022
Cited by 14 | Viewed by 5707
Abstract
Semi-solid metal (SSM) processing has been an attractive method for manufacturing near-net-shape components with high integrity due to its distinct advantages over conventional forming technologies. SSM processing employs a mixture of solid phase and liquid metal slurries and/or non-dendritic feedstocks as starting materials [...] Read more.
Semi-solid metal (SSM) processing has been an attractive method for manufacturing near-net-shape components with high integrity due to its distinct advantages over conventional forming technologies. SSM processing employs a mixture of solid phase and liquid metal slurries and/or non-dendritic feedstocks as starting materials for shaping. Since the original development from 1970s, a number of SSM processes have been developed for shaping components using the unique rheological and/or thixotropic properties of metal alloys in the semi-solid state, in which the globular solid particles of primary phase are dispersed into a liquid matrix. In this paper, the progress of the development of shaping technologies and the formation of non-dendritic microstructure in association with the scientific understanding of microstructural evolution of non-dendritic phase are reviewed, in which the emphasis includes the new development in rheomoulding, rheo-mixing, rheo/thixo-extrusion and semi-solid twin roll casting, on the top of traditional rheocasting, thixoforming and thixomoulding. The advanced microstructural control technologies and processing methods for different alloys are also compared. The mechanisms to form non-dendritic microstructures are summarised from the traditional understanding of mechanical shear/bending and dendrite multiplication to the spheroidal growth of primary phase under intensively forced convection. In particular, the formation of spheroidal multiple phases in eutectic alloys is summarised and discussed. The concluding remarks focus on the current challenges and developing trends of semi-solid processing. Full article
(This article belongs to the Special Issue Semi-solid Processing: Fundamentals and Applications)
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<p>Typical microstructure of (<b>a</b>) dendritic morphology formed under conventional solidification, (<b>b</b>) non-dendritic solid particles formed under intensively forced convection for SSM processing.</p>
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<p>Schematic illustration of the stages of new rheocasting (NRC) process. Reprinted with permission from Ref. [<a href="#B23-crystals-12-01044" class="html-bibr">23</a>]. Copyright 2001 John Wiley and Sons.</p>
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<p>Schematic layout of different semi-solid process. Reprinted with permission from Ref. [<a href="#B26-crystals-12-01044" class="html-bibr">26</a>]. Copyright 2003 Springer Nature Customer Service Centre GmbH, Springer Nature.</p>
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<p>Schematic of rheomoulding process. Reprinted from [<a href="#B29-crystals-12-01044" class="html-bibr">29</a>] with permission of Advanced Manufacturing Research Institute, National Institute of Advanced Industrial Science and Technology (AIST).</p>
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<p>Schematic showing the thixomoulding process according to reference [<a href="#B32-crystals-12-01044" class="html-bibr">32</a>,<a href="#B33-crystals-12-01044" class="html-bibr">33</a>]. Reprinted under the Creative Commons Attribution License (CC-BY) 4.0.</p>
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<p>Schematic of the rheomixing process to achieve fine and homogeneous microstructure in immiscible alloys, (<b>a</b>) homogeneous liquid (above the Tc); (<b>b</b>) creation of the L′′ droplets in L′; (<b>c</b>) rheomixing: formation of a primary α-Al solid phase (S) in L′ through a monotectic reaction. Reprinted with permission from Ref. [<a href="#B99-crystals-12-01044" class="html-bibr">99</a>]. Copyright 2009 Springer Nature Customer Service Centre GmbH, Springer Nature.</p>
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<p>Schematic diagram of different flow modes system (<b>a</b>) horizontal agitation; (<b>b</b>) vertical agitation; (<b>c</b>) helical agitation [<a href="#B108-crystals-12-01044" class="html-bibr">108</a>]. Reprinted under the Creative Commons Attribution License (CC-BY) 4.0.</p>
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<p>Schematic of the slope cooling technique for SSM processing [<a href="#B121-crystals-12-01044" class="html-bibr">121</a>]. Reprinted under the Creative Commons Attribution License (CC-BY) 4.0.</p>
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<p>Schematic illustration of the continuous rheoconversion process (CRP) [<a href="#B123-crystals-12-01044" class="html-bibr">123</a>].</p>
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<p>Illustration of the steps of the Semi-solid rheocasting, in which molten alloy is held above the liquidus (Step 1), then rapidly cooled and agitated for a controlled duration to a temperature below the liquidus (Step 2) before agitation and cooling ceases (Step 3) [<a href="#B125-crystals-12-01044" class="html-bibr">125</a>].</p>
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<p>Schematic diagram of the steps of the GISS method [<a href="#B130-crystals-12-01044" class="html-bibr">130</a>,<a href="#B132-crystals-12-01044" class="html-bibr">132</a>]. Reprinted with permission from Ref. [<a href="#B130-crystals-12-01044" class="html-bibr">130</a>]. Copyright 2010 Elsevier.</p>
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<p>Schematic diagram of the SEED process. Reprinted with permission from Ref. [<a href="#B133-crystals-12-01044" class="html-bibr">133</a>]. Copyright 2006 SAE International.</p>
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<p>Schematic diagrams of the ultrasonic vibration device. Reprinted with permission from Ref. [<a href="#B142-crystals-12-01044" class="html-bibr">142</a>]. Copyright 2011 Elsevier.</p>
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<p>Schematic diagram of SCR process. Reprinted from [<a href="#B149-crystals-12-01044" class="html-bibr">149</a>] with permission from Elsevier.</p>
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<p>Comparison of (<b>a</b>) SIMA and (<b>b</b>) RAP [<a href="#B151-crystals-12-01044" class="html-bibr">151</a>,<a href="#B153-crystals-12-01044" class="html-bibr">153</a>]. T denotes temperature.</p>
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<p>Schematic diagram of RSF process, consisting of pouring liquid metal into an insulated container (Step 1), then submerging a solid metal alloy, usually in the form of a bar of the same composition, into the melt (Step 2), and obtaining semi-solid slurry after the stirring operation (Step 3) [<a href="#B165-crystals-12-01044" class="html-bibr">165</a>].</p>
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<p>Schematic of dendrite arm fragmentation mechanism, (<b>a</b>) un-deformed dendrite; (<b>b</b>) after bending; (<b>c</b>) formation of high angle grain boundary by recrystallization; (<b>d</b>) fragmentation through wetting of grain boundary by liquid metal. <span class="html-italic">L</span> stands for liquid phase, and <span class="html-italic">S</span> stands for solid dendritic grain. Reprinted with permission from Ref. [<a href="#B173-crystals-12-01044" class="html-bibr">173</a>]. Copyright 1984 Elsevier.</p>
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<p>Schematic diagram of dendrite multiplication [<a href="#B108-crystals-12-01044" class="html-bibr">108</a>]. Reprinted under the Creative Commons Attribution License (CC-BY) 4.0.</p>
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<p>Schematic illustration of morphological transition from dendritic to spherical via rosette with increase in shear rate and intensity of turbulence. Reprinted with permission from Ref. [<a href="#B183-crystals-12-01044" class="html-bibr">183</a>]. Copyright 2002 Springer Nature Customer Service Centre GmbH, Springer Nature.</p>
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<p>Morphological evolution of spheroidal α-Mg particles in AZ91D alloy during isothermal shearing at low shear rate at 589 °C for different times, (<b>a</b>) 0 min; (<b>b</b>) 70 min; (<b>c</b>) 110 min. Reprinted with permission from Ref. [<a href="#B190-crystals-12-01044" class="html-bibr">190</a>]. Copyright 2006 Elsevier.</p>
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<p>The shear stress and velocity distribution and the schematic of the microstructural development during melt flow over the inclined surface. Reprinted with permission from Ref. [<a href="#B210-crystals-12-01044" class="html-bibr">210</a>]. Copyright 2012 Springer Nature Customer Service Centre GmbH, Springer Nature.</p>
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<p>Backscattered SEM micrographs showing water-quenched microstructures of Zn-5 wt% Al alloy at initial stage of eutectic solidification, the alloy was continuously sheared at 4082 s<sup>−1</sup>, cooled at 1 °C/min from 385 °C to 380.6 °C, and times after reaching 380.6 °C for 120 s (white: Zn phase, black: Al phase) [<a href="#B218-crystals-12-01044" class="html-bibr">218</a>]. Reprinted under the Creative Commons Attribution License (CC-BY) 4.0.</p>
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<p>Diagram showing the effect of forced convection during eutectic solidification on the morphology of eutectic phases in binary alloys: (<b>a</b>) without forced convection, (<b>b</b>) low intensity of forced convection, (<b>c</b>) moderate intensity of forced convection, and (<b>d</b>) high intensity of forced convection [<a href="#B218-crystals-12-01044" class="html-bibr">218</a>]. Reprinted under the Creative Commons Attribution License (CC-BY) 4.0.</p>
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17 pages, 5036 KiB  
Article
Characterization of Microstructure and High Temperature Compressive Strength of Austenitic Stainless Steel (21-4N) through Powder Metallurgy Route
by Arun Prasad Murali, Dharmalingam Ganesan, Sachin Salunkhe, Emad Abouel Nasr, João Paulo Davim and Hussein Mohamed Abdelmoneam Hussein
Crystals 2022, 12(7), 923; https://doi.org/10.3390/cryst12070923 - 29 Jun 2022
Cited by 3 | Viewed by 2196
Abstract
Exposure of the engine valve to high temperatures led to the degradation of the valve material due to microstructural instability and deteriorating mechanical properties. Performance enhancement and alteration in microstructures can be attained through the powder metallurgy route which is a viable method [...] Read more.
Exposure of the engine valve to high temperatures led to the degradation of the valve material due to microstructural instability and deteriorating mechanical properties. Performance enhancement and alteration in microstructures can be attained through the powder metallurgy route which is a viable method to produce near net shape components. In this current study, the development of austenitic stainless steel (21-4N) through the powder metallurgy route as an alternate material for engine valves was investigated. Mechanical alloying was carried out for the pre-alloyed mixtures and consolidated using vacuum hot pressing. Sintering parameters were fixed at 1200 °C, 50 MPa and at a vacuum level of 10-3 Torr. A scanning electron microscope was used to analyze the morphology of the milled powders. Densities for the hot pressed powders were compared with theoretical densities and found to be around 98–99%. Observations regarding grain size, the presence of austenitic grain, heterogeneous distribution of metal carbides and analysis of chemical composition along the metal matrix were determined using both optical and electron microscopes. X-ray diffraction was carried out for both the consolidated and powder samples. The hot pressed samples exhibited a hardness value of 410 ± 10 Hv. An isothermal compression test for the sintered samples was carried out at a temperature of 650 °C and strain rate of 0.001 s−1. It is showed that the compressive strength of 1380 MPa. An analysis between the room temperature yield strength obtained from hardness measurement and the strengthening mechanism based on the microstructure was conducted. Grain size, dislocation and solid solution are the major strengthening mechanisms which strengthen the material. Overall, the development of valve steel material through the powder metallurgy route exhibited improved metallurgical and mechanical properties in comparison to the corresponding cast product. Full article
(This article belongs to the Special Issue Crystal Plasticity (Volume II))
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<p>Schematic representation of vacuum hot pressing.</p>
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<p>Schematic representation of vacuum hot pressed sample.</p>
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<p>(<b>a</b>–<b>c</b>) Morphology of milled powders at regular milling interval.</p>
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<p>Density of hot pressed samples developed through powder metallurgy route.</p>
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<p>Optical micrograph of (<b>a</b>) 21-4N, (<b>b</b>) corresponding grain size.</p>
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<p>SEM-EDS analysis of 21-4N both at (<b>a</b>) grains and (<b>b</b>) grain boundaries.</p>
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<p>X-ray diffraction pattern for vacuum hot pressed sample.</p>
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<p>X-ray diffraction pattern for milled powder.</p>
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<p>TEM micrograph of heat resistant austenitic steel of 21-4N (<b>a</b>) bright field image where arrow mark indicates dislocation lines, (<b>b</b>) distribution of grain size for the austenitic matrix, (<b>c</b>) corresponding SAD pattern.</p>
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<p>Hot compressive strength of the sintered sample, sample before and after compression (insert).</p>
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<p>SEM micrograph of hot compressed sample (<b>a</b>) Overview of bulged sample (<b>b</b>) indication of serrated boundaries.</p>
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12 pages, 3027 KiB  
Review
Continuous Casting Practices for Steel: Past, Present and Future
by Roderick I. L. Guthrie and Mihaiela M. Isac
Metals 2022, 12(5), 862; https://doi.org/10.3390/met12050862 - 18 May 2022
Cited by 15 | Viewed by 15903
Abstract
This historical review of casting methods used to produce sheets of steel for automobiles, household products, rocket bodies, etc., all point toward the development of one-step commercial processes, which are capable of casting liquid steel directly into a final sheet product. Progress towards [...] Read more.
This historical review of casting methods used to produce sheets of steel for automobiles, household products, rocket bodies, etc., all point toward the development of one-step commercial processes, which are capable of casting liquid steel directly into a final sheet product. Progress towards this goal is confirmed by successful advances being made, but there remain major difficulties in reaching it. We concur that the conventional continuous casting method remains the current process of choice for highest-quality steel sheet products, but the ESP TSC (Endless Strip Production—Thin Slab Caster) approach is now highly competitive. Similarly, the original goal of Sir Henry Bessemer to produce a direct strip-making twin-drum caster, in 1856, finally came to lasting commercial fruition at CASTRIP/NUCOR. Nonetheless, a newer approach, promoted by Salzgitter, termed DSP (Direct Strip Production), or promoted by MMPC/MetSim as HSBC (Horizontal Single Belt Casting), has several advantages over CASTRIP in terms of microstructures and productivity. As such, the pros and cons of current methods are reviewed within this brief history of casting. Full article
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<p>The past, present, and future of steel processing steps, as predicted in 1990 [<a href="#B3-metals-12-00862" class="html-bibr">3</a>].</p>
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<p>Typical process layout and equipment for various forms of continuous casting; Two-strand continuous slab caster [<a href="#B4-metals-12-00862" class="html-bibr">4</a>].</p>
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<p>Past and recent commercial developments in strip casting technologies. Typical process layout and equipment for various forms of continuous casting. [<a href="#B5-metals-12-00862" class="html-bibr">5</a>].</p>
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<p>A thin slab caster operation, taken from An Introduction to Iron and steel making [<a href="#B4-metals-12-00862" class="html-bibr">4</a>].</p>
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<p>Schematic of the industrial scale pilot plant of Direct Strip Castin (DSC) at Peine, Germany [<a href="#B11-metals-12-00862" class="html-bibr">11</a>].</p>
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<p>(<b>A</b>) Typical defect that can lead to oscillation marks on a cast slab in a continuous casting mold, together with a schematic diagram showing the cross-section around an oscillation mark. (<b>B</b>) represents the results of a Computational Fluid Dynamic (CFD) predicting how the initial steel shell is formed [<a href="#B12-metals-12-00862" class="html-bibr">12</a>].</p>
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<p>Ab initio computations of the first moments of solidification of an aluminum alloy, AA6111 strip, being cast, iso-kinetically, onto a 1 cm. thick copper substrate (depicted as a grey substrate). The idealized copper surface is modeled as an array of rectangular pyramids, whose peaks contact the melt at discrete points. The interfacial gas conducts the heat from the freezing metal into the copper substrate, as per our experimental results [<a href="#B13-metals-12-00862" class="html-bibr">13</a>].</p>
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15 pages, 1628 KiB  
Review
Colloidal Processing of Complex-Shaped ZrB2-Based Ultra-High-Temperature Ceramics: Progress and Prospects
by Guoqian Liu, Changhai Yan and Hua Jin
Materials 2022, 15(8), 2886; https://doi.org/10.3390/ma15082886 - 14 Apr 2022
Cited by 8 | Viewed by 3005
Abstract
Ultra-high-temperature ceramics (UHTCs), such as ZrB2-based ceramics, are the most promising candidates for ultra-high-temperature applications. Due to their strong covalent bonding and low self-diffusion, ZrB2-based UHTCs are always hot-pressed at temperatures above 1800 °C. However, the hot-pressing technique typically [...] Read more.
Ultra-high-temperature ceramics (UHTCs), such as ZrB2-based ceramics, are the most promising candidates for ultra-high-temperature applications. Due to their strong covalent bonding and low self-diffusion, ZrB2-based UHTCs are always hot-pressed at temperatures above 1800 °C. However, the hot-pressing technique typically produces disks or cylindrical objects limiting to relatively simple geometrical and moderate sizes. Fabrication of complex-shaped ZrB2-based UHTC components requires colloidal techniques. This study reviews the suspension dispersion and colloidal processing of ZrB2-based UHTCs. The most important issues during the colloidal processing of ZrB2-based UHTCs are summarized, and an evaluation of colloidal processing methods of the ZrB2-based UHTCs is provided. Gel-casting, a net or near-net colloidal processing technique, is believed to exhibit a great potential for the large-scale industrialization of ZrB2-based UHTCs. In addition, additive manufacturing, also known as 3D printing, which has been drawing great attention recently, has a great potential in the manufacturing of ZrB2-based UHTC components in the future. Full article
(This article belongs to the Special Issue High-Performance Structural Ceramics and Hybrid Materials)
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<p>Corrosion and hydrolysis of the ZrB<sub>2</sub> particle in water.</p>
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<p>Schematic drawing of the double-charge layer structure of the ZrB<sub>2</sub> particle.</p>
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<p>Interparticle interaction calculations for ZrB<sub>2</sub> particles in aqueous medium. Reproduced with permission from [<a href="#B41-materials-15-02886" class="html-bibr">41</a>].</p>
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<p>ZrB<sub>2</sub>-SiC ultra-high-temperature ceramic crucibles prepared by slip-casting. Reproduced with permission from [<a href="#B46-materials-15-02886" class="html-bibr">46</a>].</p>
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<p>ZrB<sub>2</sub> green tapes: (<b>a</b>) side view bend, (<b>b</b>) front view bend, (<b>c</b>) top view, and (<b>d</b>) wrapped around a pencil as a demonstration of the tape’s flexibility. Reproduced with permission from [<a href="#B50-materials-15-02886" class="html-bibr">50</a>].</p>
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<p>(<b>a</b>) Laminated ZrB<sub>2</sub>-SiC/graphite ceramic produced by tape-casting. Reproduced with permission from [<a href="#B66-materials-15-02886" class="html-bibr">66</a>]. (<b>b</b>) ZrB<sub>2</sub>-SiC/BN ceramic produced by tape-casting. Reproduced with permission from [<a href="#B67-materials-15-02886" class="html-bibr">67</a>].</p>
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<p>ZrB<sub>2</sub>-SiC ultra-high-temperature ceramic components. Reproduced with permission from [<a href="#B77-materials-15-02886" class="html-bibr">77</a>].</p>
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<p>(<b>a</b>) Robocasting of HfB<sub>2</sub>-based UHTC. Reproduced with permission from [<a href="#B110-materials-15-02886" class="html-bibr">110</a>]. (<b>b</b>) Direct ink writing of ZrB<sub>2</sub>-SiC UHTC chopped fiber ceramic composites, all scale bars were 1 cm. Reproduced with permission from [<a href="#B111-materials-15-02886" class="html-bibr">111</a>].</p>
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2 pages, 161 KiB  
Editorial
Casting and Solidification Processing
by Paolo Ferro
Metals 2022, 12(4), 559; https://doi.org/10.3390/met12040559 - 25 Mar 2022
Cited by 1 | Viewed by 1778
Abstract
Casting is one of the most important shaping processes, largely used and consolidated throughout the world to produce near-net-shaping parts [...] Full article
(This article belongs to the Special Issue Casting and Solidification Processing)
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