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Search Results (2,226)

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Keywords = material reuse

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18 pages, 7978 KiB  
Article
Accessible Non-Invasive Techniques for Museums: Extending Sustainability to Resource-Limited Institutions
by Anahí N. Herrera Cano, Clara A. Tomasini, Milagros Córdova, Ana Laura García, Melina Bernasconi, Lucila Iglesias, Gabriela Siracusano and Eugenia Tomasini
Sustainability 2025, 17(3), 1208; https://doi.org/10.3390/su17031208 - 2 Feb 2025
Viewed by 416
Abstract
This work provides a synthesis of an initial experience in the development of accessible imaging techniques and their implementation on a real case: the analysis of colonial Hispano-American paintings at the Complejo Museográfico Provincial “Enrique Udaondo” (Luján, Buenos Aires). It discusses different aspects [...] Read more.
This work provides a synthesis of an initial experience in the development of accessible imaging techniques and their implementation on a real case: the analysis of colonial Hispano-American paintings at the Complejo Museográfico Provincial “Enrique Udaondo” (Luján, Buenos Aires). It discusses different aspects related to the possibilities of obtaining, using, and reusing equipment and materials locally, as well as details of the ways of acquiring images for photography on site. It also provides information about the composition and conservation state of selected artworks, complementing image analysis with portable X-ray fluorescence (XRF) data, and reflects on articulated/collaborative work in situ as a methodology for transferring knowledge and skills. The project aims to contribute to strengthening Latin American sustainability by creating accessible non-invasive tools for heritage conservation institutions, highlighting the value of regional capacities to approach heritage studies from collaborative and ethical proposals that promote sovereignty and reduce dependence on external inputs. Full article
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<p>Calibration targets for UV photography. Top: Teflon-coated zinc plate; bottom: cardboard coated with metal tape and Teflon. (<b>a</b>) Visible photograph. (<b>b</b>) UVF photograph. The reflection of the violet visible light from the UV tube can be seen.</p>
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<p>Kremer colour chart green pigments. (<b>a</b>) Visible photograph. (<b>b</b>) IR photograph, 720 nm filter. (<b>c</b>) IR photograph, 850 nm filter.</p>
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<p>Working at the Complejo Museográfico Provincial “Enrique Udaondo”. (<b>a</b>) Acquisition of visible images and exchange of knowledge. (<b>b</b>) In situ analysis by portable X-ray fluorescence spectroscopy.</p>
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<p>Lighting schemes used for visible-light photography. (<b>a</b>) General lighting. (<b>b</b>) Raking light. (<b>c</b>) Specular light.</p>
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<p>Visible-light photography: Immaculate Conception with St. Joachim and St. Anne and Presentation of the Virgin in the Temple (author unknown). (<b>a</b>) Visible light. (<b>b</b>) Raking light. (<b>c</b>) Specular light.</p>
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<p>Ultraviolet-light photograph: Immaculate Conception with St. Joachim and St. Anne and Presentation of the Virgin in the Temple (unknown artist). (<b>a</b>) UVF photograph, general shot. (<b>b</b>) UVF photograph, detail of the Virgin. The presence of repainting and missing painting areas is noticeable. (<b>c</b>) Visible photograph, detail of the Virgin. References: repainting (red arrows); missing painting (green arrows).</p>
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<p>Infrared photograph, Immaculate Conception with St. Joachim and St. Anne and Presentation of the Virgin in the Temple (unknown artist); (<b>a</b>) 720 nm filter, general shot; (<b>b</b>) 850 nm filter, general shot. (<b>c</b>) Visible photograph.</p>
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<p>Detail of Immaculate Conception with St. Joachim and St. Anne and Presentation of the Virgin in the Temple (unknown artist). (<b>a</b>) Infrared photograph. (<b>b</b>) Visible photograph.</p>
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19 pages, 2603 KiB  
Article
Raw and Calcined Eggshells as P-Reactive Materials in a Circular Economy Approach
by Agnieszka Bus, Kamila Budzanowska, Agnieszka Karczmarczyk and Anna Baryła
Sustainability 2025, 17(3), 1191; https://doi.org/10.3390/su17031191 - 1 Feb 2025
Viewed by 588
Abstract
Phosphorus (P) is a crucial factor influencing both plant growth and the enrichment of the aquatic environment. Agriculture is the primary sector of the economy where the demand for phosphorus is the highest. Due to the depletion of P, more and more attention [...] Read more.
Phosphorus (P) is a crucial factor influencing both plant growth and the enrichment of the aquatic environment. Agriculture is the primary sector of the economy where the demand for phosphorus is the highest. Due to the depletion of P, more and more attention is being paid to the possibility of recovering and reusing P through the idea of a circular economy (CE). The main objective of this study was to compare raw eggshells (R-ESs) and calcined eggshells (C-ESs) for P removal from wastewater and assess the possible use of agro-waste materials according to CE requirements in non-flow conditions. A synthetic indicator, the zeroed unitarization method, was calculated to evaluate the critical aspects of materials according to the CE. The sorption of R-ESs and C-ESs equaled 0.90 and 1.66 mgP-PO4/g for an initial concentration of 17.3 mgP-PO4/L. The C-ESs were characterized by an almost two times higher reduction rate than R-ESs. The calculated indicator for the CE requirements equaled 0.89 and 0.72 for R-ESs and C-ESs, respectively. This means that R-ESs are more sustainable than C-ESs. Although C-ESs potentially have a more significant environmental impact, it is worth considering that this method of P elimination is beneficial from an ecological perspective. Full article
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<p>Micrographs of R-ESs (on the right) and C-ESs (on the left).</p>
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<p>P-PO<sub>4</sub>, pH, ORP, and EC changes for raw eggshells (R-ESs) and calcined eggshells (C-ESs). The horizontal line indicates this study’s initial wastewater (WW) values.</p>
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<p>Median with quartiles and min–max values for P-PO<sub>4</sub>, pH, ORP, and EC for wastewater (WW), raw eggshells (R-ESs), and calcined eggshells (C-ESs); a, b, and c indicate significant differences at <span class="html-italic">p</span> &lt; 0.05 between the values obtained by the ANOVA Kruskal–Wallis test.</p>
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<p>Median with quartiles and min–max values for P-PO<sub>4</sub>, pH, ORP, and EC for wastewater (WW), raw eggshells (R-ESs), and calcined eggshells (C-ESs); a, b, and c indicate significant differences at <span class="html-italic">p</span> &lt; 0.05 between the values obtained by the ANOVA Kruskal–Wallis test.</p>
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<p>P-PO<sub>4</sub> reduction (R) and sorption (S) of raw eggshells (R-ESs) and calcined eggshells (C-ESs).</p>
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<p>Graphical presentation of experimental data and examined models of R-CEs and C-ESs.</p>
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12 pages, 950 KiB  
Perspective
Handheld Laser-Induced Breakdown Spectroscopy (hLIBS) Applied to On-Site Mine Waste Analysis/Evaluation in View of Its Recycling/Reuse
by Giorgio S. Senesi
Chemosensors 2025, 13(2), 41; https://doi.org/10.3390/chemosensors13020041 - 1 Feb 2025
Viewed by 211
Abstract
Nowadays, the recovery/recycling/reuse of mining and mineral processing wastes is considered the best approach to support the circular economy and sustainability of mining and metal extraction industries. Mine wastes can be used to restore surface and subsurface land damaged by mining operations, generate [...] Read more.
Nowadays, the recovery/recycling/reuse of mining and mineral processing wastes is considered the best approach to support the circular economy and sustainability of mining and metal extraction industries. Mine wastes can be used to restore surface and subsurface land damaged by mining operations, generate fuel for power plants, further extract their component minerals, and as building materials additives. The aim of this perspective paper is to briefly highlight and focus on the most recent analytical potential and performance achieved by handheld laser-induced breakdown spectroscopy (hLIBS) instrumentation in the perspective of its future application in the mine waste sector to quickly identify on-site the presence of useful chemical elements for their possible sustainable recovery. Full article
(This article belongs to the Section Analytical Methods, Instrumentation and Miniaturization)
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<p>Example of an hLIBS instrument (<b>a</b>); onscreen display of the instrument which shows the spectrum acquired and the chemical information on the elements detected (<b>b</b>); example of microscale mapping of the distribution of Fe, Ni, and Cr elements in an iron meteorite achieved using a single laser shot by raster scanning over a 2-mm<sup>2</sup> area and shown in a gradient of colors that varies from red for high relative abundance to blue for low relative abundance. The spectral lines used to construct these microchemical maps are Fe = 404.58 nm; Ni = 227.01 and 338.06 nm; Cr = 428.97 nm (<b>c</b>).</p>
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<p>Averaged broadband LIBS spectrum acquired from a metamorphic rock. Some specific emission lines of the elements Mg, Si, Al, and K are detected, together with that of Li at 610.79 nm, which highlights the capacity of hLIBS to detect light elements.</p>
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24 pages, 5780 KiB  
Article
Tea Waste as a Sustainable Catalyst Support for Enhanced Removal of Contaminants of Emerging Concern via the Electro-Fenton Process: A Circular Economy Approach
by Lucas Moreno-Bermedo, Jonathan Correa-Puerta, Claudio González-Fuentes, Néstor Escalona, Christian Onfray and Abdoulaye Thiam
Appl. Sci. 2025, 15(3), 1418; https://doi.org/10.3390/app15031418 - 30 Jan 2025
Viewed by 727
Abstract
Contaminants of emerging concern (CECs) in water, including pharmaceuticals and personal care products, represent a significant threat to environmental and human health. In this context, the electro-Fenton (EF) process has emerged as a highly effective technique for the removal of such pollutants. This [...] Read more.
Contaminants of emerging concern (CECs) in water, including pharmaceuticals and personal care products, represent a significant threat to environmental and human health. In this context, the electro-Fenton (EF) process has emerged as a highly effective technique for the removal of such pollutants. This study investigates the innovative use of tea waste material (TWM) in combination with copper-iron nanoparticles (FeCuNPs) to degrade a mixture of CECs. A central aspect of this research is the sustainable reuse of organic waste material, such as TWM, to support catalytic nanoparticles. This approach not only utilizes a resource that would otherwise be discarded but also promotes sustainability in the treatment of contaminated water, aligning with the principles of the circular economy. The as-prepared FeCuNPs@TWM catalyst was fully characterized, and critical parameters influencing the pollutant removal were assessed, including adsorption capacity, catalyst load, and applied current. Under optimized conditions, the EF process, enhanced by FeCuNPs@TWM, achieved complete degradation of the contaminants within 15 min of the electrochemical process, and the activity remained after five catalytic cycles. Results demonstrate that using tea waste functionalized with FeCu nanoparticles as a catalyst not only improves the efficiency of the EF process but also offers an eco-friendly and cost-effective alternative. Full article
(This article belongs to the Special Issue Resource Utilization of Solid Waste and Circular Economy)
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<p>XRD diffractogram obtained for: (<b>a</b>) TWM, (<b>b</b>) CuFeNPs, and (<b>c</b>) CuFeNP@TWM.</p>
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<p>Raman spectra of (<b>a</b>) TWM, (<b>b</b>) CuFeNPs, and (<b>c</b>) CuFeNP@TWM.</p>
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<p>Elemental high-resolution spectra obtained by XPS for the CuFeNPs@TWM sample: (<b>a</b>) C 1s, (<b>b</b>) N 1s, (<b>c</b>) O 1s, (<b>d</b>) Fe 2p, and (<b>e</b>) Cu 2p.</p>
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<p>FT-IR spectra acquired from the samples.</p>
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<p>SEM images for (<b>a</b>) TWM, (<b>b</b>) CuFeNPs, and (<b>c</b>) CuFeNPs@TWM; and (<b>d</b>) EDS elemental mapping for (<b>c</b>).</p>
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<p>Magnetization curves obtained for: (<b>a</b>) TWM, (<b>b</b>) CuFeNPs, and (<b>c</b>) CuFeNPs@TWM.</p>
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<p>Concentration decay of each CEC using different materials as catalysts for heterogeneous EF process: (<b>a</b>) TWM, (<b>b</b>) CuFeNPs, and (<b>c</b>) CuFeNPs@TWM. Experimental conditions: Catalyst load, 20 mg L<sup>−1</sup>; applied current, 20 mA; electrolyte, Na<sub>2</sub>SO<sub>4</sub> 50 mmol L<sup>−1</sup>; pH, 3.0.</p>
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<p>Normalized concentration decay for each CEC in the function of different applied currents by heterogeneous EF process: (<b>a</b>) Adsorption (0 mA), (<b>b</b>) 10 mA, (<b>c</b>) 20 mA, and (<b>d</b>) 50 mA. Experimental conditions: Catalyst, CuFeNPs@TWM; catalyst load, 20 mg L<sup>−1</sup>; electrolyte, Na<sub>2</sub>SO<sub>4</sub> 50 mmol L<sup>−1</sup>; pH, 3.0.</p>
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<p>Normalized concentration decay for each CEC in the function of different catalyst loads by heterogeneous EF process: (<b>a</b>) 10 mg L<sup>−1</sup> (<b>b</b>) 20 mg L<sup>−1</sup>, and (<b>c</b>) 50 mg L<sup>−1</sup>. Experimental conditions: Catalyst, CuFeNPs@TWM; applied current, 20 mA; electrolyte, Na<sub>2</sub>SO<sub>4</sub> 50 mmol L<sup>−1</sup>; pH, 3.0.</p>
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<p>Normalized concentration of the mixture of CECs in the function of time of treatment at different catalytic cycles. Each cycle considered 30 min of adsorption and 30 min of EF process. Experimental conditions: Catalyst, CuFeNPs@TWM; catalyst load, 20 mg L<sup>−1</sup>; applied current, 20 mA; electrolyte, Na<sub>2</sub>SO<sub>4</sub> 50 mmol L<sup>−1</sup>; pH, 3.</p>
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26 pages, 7965 KiB  
Review
Efficient Recycling Processes for Lithium-Ion Batteries
by Sabyasachi Paul and Pranav Shrotriya
Materials 2025, 18(3), 613; https://doi.org/10.3390/ma18030613 - 29 Jan 2025
Viewed by 370
Abstract
Lithium-ion batteries (LIBs) are an indispensable power source for electric vehicles, portable electronics, and renewable energy storage systems due to their high energy density and long cycle life. However, the exponential growth in production and usage has necessitated highly effective recycling of end-of-life [...] Read more.
Lithium-ion batteries (LIBs) are an indispensable power source for electric vehicles, portable electronics, and renewable energy storage systems due to their high energy density and long cycle life. However, the exponential growth in production and usage has necessitated highly effective recycling of end-of-life LIBs to recover valuable resources and minimize the environmental impact. Pyrometallurgical and hydrometallurgical processes are the most common recycling methods but pose considerable difficulties. The energy-intensive pyrometallurgical recycling process results in the loss of critical materials such as lithium and suffers from substantial emissions and high costs. Solvent extraction, a hydrometallurgical method, offers energy-efficient recovery for lithium, cobalt, and nickel but requires hazardous chemicals and careful waste management. Direct recycling is an alternative to traditional methods as it preserves the cathode active material (CAM) structure for quicker and cheaper regeneration. It also offers environmental advantages of lower energy intensity and chemical use. Hybrid pathways, combining hydrometallurgical and direct recycling methods, provide a cost-effective, scalable solution for LIB recycling, maximizing material recovery with minimal waste and environmental risk. The success of recycling methods depends on factors such as battery chemistry, the scalability of recovery processes, and the cost-effectiveness of waste material recovery. Though pyrometallurgical and hydrometallurgical processes have secured their position in LIB recycling, research is proceeding toward newer approaches, such as direct and hybrid methods. These alternatives are more efficient both environmentally and in terms of cost with a broader perspective into the future. In this review, we describe the current state of direct recycling as an alternative to traditional pyrometallurgical and hydrometallurgical methods for recuperating these critical materials, particularly lithium. We also highlight some significant advancements that make these objectives possible. As research progresses, direct recycling and its variations hold great potential to reshape the way LIBs are recycled, providing a sustainable pathway for battery material recovery and reuse. Full article
(This article belongs to the Section Energy Materials)
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22 pages, 23199 KiB  
Article
Lo-Fi Adaptive Re-Use in the Ouseburn Valley: What the Physical Materiality of Everyday Historical Industrial Buildings Can Tell Us About Sustaining Cultural and Creative Clusters
by Kevin Muldoon-Smith, Leo Moreton and Jane Loxley
Buildings 2025, 15(3), 427; https://doi.org/10.3390/buildings15030427 - 29 Jan 2025
Viewed by 433
Abstract
In the adaptive re-use of buildings, the physicality of buildings—the way they are designed, planned, constructed and maintained—has fallen out of fashion in favour of socio-economic conceptualisations and critical urban interpretations of the redevelopment process. However, the materiality of buildings plays a key [...] Read more.
In the adaptive re-use of buildings, the physicality of buildings—the way they are designed, planned, constructed and maintained—has fallen out of fashion in favour of socio-economic conceptualisations and critical urban interpretations of the redevelopment process. However, the materiality of buildings plays a key part in how locations are re-produced in response to socio-economic circumstances—in this case, the creation and sustaining of cultural and creative clusters. In response, this paper adopts a forensic approach to the characteristics of physical buildings in order to develop an original taxonomy of lo-fi adaptive features and interventions that enable the authors to infer which types and aspects of industrial buildings lend themselves to sustaining cultural and creative clusters. The focus on lo-fi interventions is an original contribution to the adaptive re-use literature where attention tends to focus on more formal and traditional design-based interactions with existing buildings. In doing so, the research utilises a comparative case study approach of several former industrial buildings associated with the contemporary independent food and drink industry in the Ouseburn Valley cultural and creative quarter of Newcastle upon-Tyne in England. The research finds that it is the functional tolerance and malleability of the case study buildings—their inherent adaptive capacity, that in part helps to sustain the cultural and creative cluster in this location. Full article
(This article belongs to the Section Architectural Design, Urban Science, and Real Estate)
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<p>The Ouseburn Valley.</p>
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<p>Visual Analysis.</p>
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<p>Visual Analysis.</p>
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<p>Visual Analysis.</p>
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<p>Visual Analysis.</p>
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<p>Visual Analysis.</p>
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22 pages, 959 KiB  
Review
Red Mud as an Adsorbent for Hazardous Metal Ions: Trends in Utilization
by Maja Rajković, Ivana Jelić, Marija Janković, Dragi Antonijević and Marija Šljivić-Ivanović
Toxics 2025, 13(2), 107; https://doi.org/10.3390/toxics13020107 - 28 Jan 2025
Viewed by 447
Abstract
The increasing importance of waste materials utilization with the necessary modification to remove various pollutants from industrial wastewater has been a research focus over the past few decades. Using waste material from one industry to solve pollution problems in another ultimately leads toward [...] Read more.
The increasing importance of waste materials utilization with the necessary modification to remove various pollutants from industrial wastewater has been a research focus over the past few decades. Using waste material from one industry to solve pollution problems in another ultimately leads toward sustainable and circular approaches in environmental engineering, solving waste management and wastewater treatment issues simultaneously. In contemporary research and industry, there is a notable trend toward utilizing industrial wastes as precursors for adsorbent formation with a wide application range. In line with this trend, red mud, a byproduct generated during alumina production, is increasingly viewed as a material with the potential for beneficial reuse rather than strictly a waste. One of the potential uses of red mud, due to its specific composition, is in the removal of heavy metal and radionuclide ions. This study summarizes red mud’s potential as an adsorbent for wastewater treatment, emphasizing techno-economic analysis and sorption capacities. An overview of the existing research includes a critical evaluation of the adsorption performance, factors influencing efficiency rather than efficacy, and the potential for specific pollutant adsorption from aqueous solutions. This review provides a new approach to a circular economy implementation in wastewater treatment while guiding future research directions for sustainable and cost-effective solutions. Full article
31 pages, 1282 KiB  
Review
Boron Nitride-Supported Metal Catalysts for the Synthesis and Decomposition of Ammonia and Formic Acid
by Marta Yruela-Garrido, Eduardo Campos-Castellanos, María V. Morales, Inmaculada Rodríguez-Ramos and Antonio Guerrero-Ruiz
Nanomaterials 2025, 15(3), 212; https://doi.org/10.3390/nano15030212 - 28 Jan 2025
Viewed by 360
Abstract
This review explores the recent advancements in the application of boron nitride (BN) as a support material for metallic nanoparticles, highlighting its potential in fostering sustainable chemical reactions when employed as a heterogeneous catalyst. Two key processes, both critical to hydrogen storage and [...] Read more.
This review explores the recent advancements in the application of boron nitride (BN) as a support material for metallic nanoparticles, highlighting its potential in fostering sustainable chemical reactions when employed as a heterogeneous catalyst. Two key processes, both critical to hydrogen storage and transport, are examined in detail. First, the reversible synthesis and decomposition of ammonia using BN-supported metallic catalysts has emerged as a promising technology. This approach facilitates the preparation of Ru nanoparticles with precisely structured surface atomic ensembles, such as B5 sites, which are critical for maximizing catalytic efficiency. Second, the review emphasizes the role of BN-supported catalysts in the production of formic acid (FA), a process intrinsically linked to the reuse of carbon dioxide. In this context, hydrogen and carbon dioxide—potentially sourced from atmospheric capture—serve as reactants. BN’s high CO2 adsorption capacity makes it an ideal support material for such applications. Moreover, FA can serve as a source of hydrogen through decomposition or as a precursor to alternative chemicals like carbon monoxide (CO) via dehydration, further underscoring its versatility in sustainable catalysis Full article
(This article belongs to the Section Energy and Catalysis)
17 pages, 6056 KiB  
Article
Waste Recovery and Thermal Analysis of Refurbished Buildings’ Walls: The Sustainable Big Bag
by Valentina Vecchi, Gianni Di Giovanni, Stefania De Gregorio, Eleonora Laurini and Tullio de Rubeis
Buildings 2025, 15(3), 417; https://doi.org/10.3390/buildings15030417 - 28 Jan 2025
Viewed by 703
Abstract
The construction sector has a high environmental impact, especially due to C&D waste. At the same time, the increase in the temperature of the Earth’s surface due to pollution requires interventions on the built environment, aimed at improving the performance of the envelope [...] Read more.
The construction sector has a high environmental impact, especially due to C&D waste. At the same time, the increase in the temperature of the Earth’s surface due to pollution requires interventions on the built environment, aimed at improving the performance of the envelope in hot climates. In the literature, there are studies on components to increase thermal efficiency, but they are limited by long or expensive production processes or high environmental impact. This research considers Italy as a reference area. The aim of this research is to design, prototype, and verify a sustainable component to be included in the stratigraphy of light mass vertical closures to increase their heat capacity that allows for the reuse of C&D waste and the optimization of site operations both in the selective demolition phase and in the redevelopment phase of the building. The method follows the following phases: analysis of the type of waste from C&D, analysis of international best practices, analysis of the possibilities of intervention on vertical closures according to the pre-existing structure and choice of cases of greatest scientific interest, design of the sustainable big bag by reusing inert materials from selective demolition and recycled polypropylene fabrics, prototyping and verification by laboratory tests, and software analysis to verify the thermal advantage. The use of the sustainable big bag allows for construction advantages, facilitating site operations both in the construction and waste disposal phases, energy advantages by improving the heat capacity of the envelope, and increases in the sustainability of the intervention through the reuse of waste materials. Full article
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<p>Phases of the research method.</p>
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<p>Construction details: (<b>a</b>) Moueix family’s winery; (<b>b</b>) “House in the Land scape”.</p>
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<p>Cases A, B, and C analyzed with respect to mass gain, air tightness, and light permeability.</p>
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<p>Sustainable big bag and its technical details in a standard vertical closure.</p>
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<p>Strategy 1 for the construction site at the foot of the building.</p>
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<p>Strategy 2 for the construction site at the foot of the building.</p>
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<p>Handling and lifting of the bags to the floor.</p>
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<p>Strategy 1 construction site on the floor of the building.</p>
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<p>Strategy 2 construction site on the floor of the building.</p>
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<p>(<b>a</b>) Internal view of the sample from the top; (<b>b</b>) internal side view of the sample; (<b>c</b>) external front view of the sample.</p>
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<p>Trend of the conductance and transmittance values of the three samples.</p>
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<p>Thermal comparison between vertical closure 1 (without sustainable big bag) and vertical closure 2 (with sustainable big bag).</p>
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22 pages, 4874 KiB  
Article
Tracking Secondary Raw Material Operational Framework—DataOps Case Study
by Gabriel Pestana, Marisa Almeida and Nelson Martins
Ceramics 2025, 8(1), 12; https://doi.org/10.3390/ceramics8010012 - 28 Jan 2025
Viewed by 458
Abstract
The ceramic and glass industries, integral to the EU Emissions Trading System (EU ETS), face significant challenges in achieving decarbonization despite advancements in energy efficiency. The circular economy offers a promising pathway, emphasizing the reuse and recycling of waste materials into secondary raw [...] Read more.
The ceramic and glass industries, integral to the EU Emissions Trading System (EU ETS), face significant challenges in achieving decarbonization despite advancements in energy efficiency. The circular economy offers a promising pathway, emphasizing the reuse and recycling of waste materials into secondary raw materials (SRMs) to reduce resource consumption and emissions. This study investigates a standardized waste supply chain framework, developed collaboratively with stakeholders, tailored for the ceramic sector. The Waste Resource Platform (WRP) integrates Industry 4.0 paradigms, utilizing a modular, layered architecture and a process-centric design. The framework includes experimental tests and co-creation methodologies to refine a digital marketplace that connects stakeholders, facilitates SRM exchange, and fosters industrial symbiosis. The WRP demonstrates the potential for SRMs to replace virgin materials, reducing environmental impacts and production costs. It enhances supply chain transparency through digital traceability, promotes predictive material sourcing, and streamlines logistics via algorithmic optimization. Challenges such as regulatory gaps and quality standards are addressed through standardized processes, open data governance, and innovative algorithms. The WRP project advances circular economy goals in the ceramic sector, promoting waste reuse, industrial symbiosis, and supply chain resilience. Its standardized, open-access platform offers a scalable model for other industries, fostering sustainable practices and resource efficiency while addressing global climate targets. Full article
(This article belongs to the Special Issue Ceramics in the Circular Economy for a Sustainable World)
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<p>A mindmap illustrating ceramic vs. non-ceramic circularity.</p>
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<p>Context diagram of the supply chain for secondary raw materials.</p>
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<p>Block diagram of the architecture approach.</p>
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<p>The domain model of the WRP Platform—collapsed view.</p>
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<p>Marketplace tab with a specific SRM record overview.</p>
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<p>The list of SRM data reported by an entity. (1) the Reported tab filters the information to list only the records related to the entity to which the logged-in user belongs; (2) the available actions allow the user to delete, edit, or clone a record.</p>
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<p>The layout for adding a new record to the marketplace. (1) This section presents the collapsed view of the SRM form, displaying attributes such as status, identifier, type of service, start/due date, and SRM record visibility; (2) this section provides a detailed view of the metadata used to characterize an SRM record; (3) this section outlines the elements that users can configure to set preferences for the matching algorithm to use as filtering criteria.</p>
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<p>Diagram showing the sequence of states that an entity’s record can assume.</p>
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23 pages, 9874 KiB  
Article
Sustainable Approach to Utilization of Waste Glass Fibers and Basalt Powder as Potential Additives in Epoxy-Based Composites for Reparation of Concrete Structures
by Krzysztof Adam Ostrowski, Marcin Piechaczek, Michał Lach, Oliwia Sikora, Kazimierz Furtak, Katarzyna Sajdak and Martyna Radecka-Trzop
Sustainability 2025, 17(3), 1064; https://doi.org/10.3390/su17031064 - 28 Jan 2025
Viewed by 749
Abstract
The growing production of glass fibers is a major challenge due to the later problem of their sustainable recycling. This article reports the potential use of post-production waste glass fibers and basalt powder as additives in resin compounds designed for repairing concrete elements. [...] Read more.
The growing production of glass fibers is a major challenge due to the later problem of their sustainable recycling. This article reports the potential use of post-production waste glass fibers and basalt powder as additives in resin compounds designed for repairing concrete elements. The aim of this research was to develop a repair compound based on epoxy resin with the addition of waste materials, offering a competitive alternative to currently available repair compounds on the market by utilizing lower-cost materials and addressing pro-environmental aspects through waste reuse. The prepared research samples were characterized by varying proportions of basalt powder (0–20%), ground HP 12 fibers (40/60%), and HP 6 fibers (10/20%). A series of tests, including tensile strength tests, were conducted as part of this study to determine the effect of the applied additives on the ultimate tensile force and maximum deformations. Abrasion resistance tests were also carried out to evaluate the impact of basalt powder as a filler on enhancing the abrasion resistance of the designed repair compound. Additionally, SEM and EDS analyses were used to evaluate the uniformity and distribution of the additives within the sample. This study examined samples containing varying percentages of basalt powder and fibers, both virgin and milled. The most significant reinforcement effect was observed for sample E/20HP/20bp, where its tensile strength decreased by 8%, while its abrasion resistance increased by 44% compared to the reference sample. The obtained results confirm that incorporating waste materials as additives into epoxy resin can significantly enhance the mechanical properties of repair compounds while reducing cost and promoting environmental protection. In addition, the repair compound developed complies with the selected principles within the 6Rs environmental regulations: RECYCLING (reuse of waste glass fibers), RETHINK (reduce environmental impact by avoiding landfill), REDUCE (minimize the use of virgin glass fibers in the production of repair compounds) and REPAIR (increase the efficiency of repairing damaged concrete structures). Furthermore, as the percentage of basalt powder increases, the abrasion resistance of the repair compound improves. The obtained repair compounds may serve as an alternative to currently used compounds for the repair of bridges and factory floors. Full article
(This article belongs to the Section Waste and Recycling)
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<p>Visualization of the incidence and relationship of individual keywords (accessed on 21 October 2024).</p>
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<p>Milled materials: (<b>a</b>) 12 mm HP fiberglass; (<b>b</b>) waste basalt powder.</p>
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<p>Dimensions of test specimen type 1A for tensile strength test.</p>
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<p>Testing stand for tensile strength—Zwick/Roell Z050.</p>
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<p>Testing stand for abrasion testing—Schopper–Schlobach apparatus.</p>
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<p>Components of the Schopper–Schlobach apparatus.</p>
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<p>Average tensile strength of (40/60)mHP samples depending on the basalt powder content.</p>
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<p>Average tensile strength of (10/20)HP samples depending on the basalt powder content.</p>
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<p>Samples after the tensile strength test. From the left: reference sample, E/20HP/5bp, E/20HP/10bp, E/20HP/15bp, E/20HP/20bp.</p>
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<p>Cubic specimens for abrasion resistance testing (E/20HP/10bp).</p>
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<p>SEM images of (<b>a</b>) reference sample; (<b>b</b>) E/20HP/5bp; (<b>c</b>) E/20HP/10bp; (<b>d</b>) E/20HP/15bp; (<b>e</b>) E/20HP/20bp, blue: glass fiber fragments, yellow: basalt powder fragments; (<b>f</b>) glass fiber (E/20HP/20bp sample); (<b>g</b>) basalt powder (E/20HP/20bp sample).</p>
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<p>SEM images of (<b>a</b>) reference sample; (<b>b</b>) E/20HP/5bp; (<b>c</b>) E/20HP/10bp; (<b>d</b>) E/20HP/15bp; (<b>e</b>) E/20HP/20bp, blue: glass fiber fragments, yellow: basalt powder fragments; (<b>f</b>) glass fiber (E/20HP/20bp sample); (<b>g</b>) basalt powder (E/20HP/20bp sample).</p>
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<p>Results of EDS test of sample E/20HP/20bp: (<b>a</b>) surface area of test sample; (<b>b</b>) carbon; (<b>c</b>) oxygen; (<b>d</b>) silicon; (<b>e</b>) aluminum; (<b>f</b>) sodium; (<b>g</b>) zirconium; (<b>h</b>) calcium; (<b>i</b>) chlorine; (<b>j</b>) magnesium; (<b>k</b>) iron.</p>
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22 pages, 4342 KiB  
Article
A Circular Design Concept for Implementing Sustainable Building Practices in the KREIS-Haus Living Lab, Switzerland
by Devi Buehler, Tabea Vischer and Ranka Junge
Buildings 2025, 15(3), 409; https://doi.org/10.3390/buildings15030409 - 28 Jan 2025
Viewed by 554
Abstract
The KREIS-Haus, an inhabited living lab in Switzerland, serves as a demonstrator of the implementation of sustainable and circular building practices. Addressing the environmental impacts associated with construction, operation, and deconstruction, this study presents an innovative systematic design concept that synthesizes principles of [...] Read more.
The KREIS-Haus, an inhabited living lab in Switzerland, serves as a demonstrator of the implementation of sustainable and circular building practices. Addressing the environmental impacts associated with construction, operation, and deconstruction, this study presents an innovative systematic design concept that synthesizes principles of the circular economy, Cradle-to-Cradle design, and ecological engineering. The design process was applied to the KREIS-Haus as a lighthouse project, combining theoretical frameworks with real-word application to derive actionable insights. The novelty of the KREIS-Haus lies in the holistic integration of circular and sustainable concepts within a compact footprint, realized in a real-life, publicly accessible living lab. Its design maximizes resource efficiency by incorporating locally sourced materials, modular construction techniques, and flexible interior features, which allow for easy disassembly and reuse. At the heart of its circular design is the multifunctional conservatory, which provides heat and sound insulation, generates solar power, and expands the living space. Additionally, it supports plant cultivation and enables the reuse of treated wastewater and nutrients, as part of the off-grid water and nutrient management system to reduce reliance on external resources. The principles of solar architecture further minimize the building’s energy demands. Key insights from the design and construction process highlight the challenges of navigating conflicting goals, the importance of partner alignment, and considerations for scaling these concepts to larger developments. While technical challenges may arise, addressing systemic barriers will be essential for advancing sustainable and circular building practices on a broader scale. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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<p>(<b>a</b>) The manifold environmental impacts resulting from a building during its lifetime. (<b>b</b>) Aspects that need to be considered during the planning and construction processes of a fully sustainable building in order to minimize these multiple impacts.</p>
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<p>Floor plan of ground floor (<b>a</b>) and second floor (<b>b</b>); longitudinal section (<b>c</b>) and cross-section (<b>d</b>) of KREIS-Haus. The multifunctional conservatory is built over the living unit. Copyright 2024, Oikos &amp; Partner GmbH/Devi Buehler.</p>
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<p>Impressions of KREIS-Haus.</p>
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<p>Impressions of KREIS-Haus.</p>
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<p>Energy concept in KREIS-Haus is based on the principles of solar architecture. Adapted with permission from Ref. [<a href="#B15-buildings-15-00409" class="html-bibr">15</a>]. Copyright 2023, Basil Lehmann/Devi Buehler.</p>
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<p>Closed water and nutrient cycles in KREIS-Haus based on low-tech approaches to sanitation and water management. Copyright 2023, Basil Lehmann/Devi Buehler.</p>
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16 pages, 6988 KiB  
Article
Physico-Mechanical Properties of Alkali-Activated Based Composites Using Recycled Tire Fibers
by Edwin Gudiel, Jordi Payá, María Victoria Borrachero and José María Monzó
Appl. Sci. 2025, 15(3), 1346; https://doi.org/10.3390/app15031346 - 28 Jan 2025
Viewed by 421
Abstract
Used tires (UTs) are a global problem, especially in developing countries due to inadequate management systems. During retreading, when the worn tread is replaced, waste is generated in the form of tire fibers (TFs) and particles, which can be reused as raw materials [...] Read more.
Used tires (UTs) are a global problem, especially in developing countries due to inadequate management systems. During retreading, when the worn tread is replaced, waste is generated in the form of tire fibers (TFs) and particles, which can be reused as raw materials to produce economically and environmentally low-cost prefabricated elements. Using TFs as a lightweight aggregate in nonstructural geopolymer-based elements is a sustainable valorization option. This study aims to valorize used tires by incorporating them as TFs into lightweight geopolymer mixes and analyzing their physico-mechanical, thermal, and thermography properties for building and civil engineering applications. The geopolymer is produced from a precursor (spent catalyst residue from catalytic cracking, FCC) and an alkaline activator composed of rice husk ash (RHA), sodium hydroxide, and water. The control sample’s (mortar with siliceous sand, CTRLSIL) compressive strength came close to 50 MPa, while the TF mixes ranged from 32 to 3 MPa, which meet the masonry standards. The thermal conductivity and thermography analyses showed that increasing the TF content reduced the heat transmission and achieved a similar performance to expanded-clay concrete and better performance than for conventional concrete. Full article
(This article belongs to the Special Issue Alkali-Activated Materials: Advances and Novel Applications)
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<p>Tire fibers (TFs).</p>
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<p>Particle size distributions for TFs and aggregates.</p>
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<p>Box (thermally insulated sides) used for the thermography test.</p>
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<p>Physico-mechanical properties of mortars: (<b>a</b>) dry density for the control mortars and for those with 15% or 25% volume replacement with TFs; (<b>b</b>) dry density for the composite mortars without aggregate; (<b>c</b>) water absorption for the control mortars and the mortars with 15% or 25% volume replacement with TFs; (<b>d</b>) water absorption for the composite mortars without aggregate. In (<b>a</b>,<b>c</b>), SIL (green columns) corresponds to mortars with the siliceous aggregate, CAL (red columns) corresponds to mortars with the limestone aggregate.</p>
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<p>FESEM micrographs of the selected mortars cured for 7 days at 65 °C: (<b>a</b>) the mortar with siliceous sand and 25% TFs; (<b>b</b>) the mortar with limestone sand and 25% TFs; (<b>c</b>) the mortar with 100% TFs.</p>
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<p>Mechanical properties of the mortars with siliceous and limestone aggregates incorporating TFs (0, 15, and 25% replacement by volume): (<b>a</b>) flexural strength (Rf) for the mortars cured at 65 °C; (<b>b</b>) compressive strength (Rc) for the mortars cured at 65 °C.</p>
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<p>Mechanical properties of the mortars with siliceous and limestone aggregates incorporating TFs (0, 15 and 25% replacement by volume): (<b>a</b>) flexural strength (Rf) for the mortars cured at 20 °C; (<b>b</b>) compressive strength (Rc) for the mortars cured at 20 °C.</p>
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<p>Comparison of the Rc values of the mortars with siliceous and limestone aggregates cured at 65 °C for 7 days vs. 20 °C for 28 days.</p>
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<p>Mechanical properties of the composites with 100% TFs as an aggregate cured at 65 °C with different FCC/TF volume ratios: (<b>a</b>) flexural strength (Rf); (<b>b</b>) compressive strength (Rc).</p>
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<p>Mechanical properties of the composites with 100% TF aggregate cured at 20 °C, with different FCC/TF volume ratios: (<b>a</b>) flexural strength (Rf); (<b>b</b>) compressive strength (Rc).</p>
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<p>Comparison of the Rc of mortars with 100% TFs, cured at 65 °C for 7 days vs. 20 °C for 28 days.</p>
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<p>Surface of specimen breakage: left, the control mortar with the siliceous aggregate (CTRLSIL); center, the control mortar with the limestone aggregate (CTRLCAL); right, the composite with the 100% TF aggregate and the FCC-based geopolymer (TF2/1).</p>
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<p>Infrared thermal images taken at different times (minutes) demonstrating the temperature increase during the test. Sample FT 2/1 subjected to 80 °C (heat source) from 0 to 30 min.</p>
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<p>Thermography analysis: (<b>a</b>) infrared thermal image showing section P1, red circle represents the maximum temperature zone, and horizontal black line represent the points in which the temperature was calculated for representing in (<b>b</b>); (<b>b</b>) quantitative curve for section P1; (<b>c</b>) curves taken every 5 min for section P1.</p>
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<p>Thermography results: maximum temperature values measured on the external side of mortar plates taken every 5 min.</p>
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14 pages, 3379 KiB  
Article
Recovery and Reuse of Acetone from Pharmaceutical Industry Waste by Solar Distillation
by Eva Carina Tarango Brito, Carlos Eduardo Barrera Díaz, Liliana Ivette Ávila Córdoba, Bernardo Antonio Frontana Uribe and Dora Alicia Solís Casados
Processes 2025, 13(2), 361; https://doi.org/10.3390/pr13020361 - 28 Jan 2025
Viewed by 516
Abstract
Solvents are particularly hazardous among the mixture of pollutants found in the air, as their low vapor pressure allows them to reach the atmosphere, causing damage to ecosystems, and producing secondary deleterious effects on living organisms through a wide variety of possible reactions. [...] Read more.
Solvents are particularly hazardous among the mixture of pollutants found in the air, as their low vapor pressure allows them to reach the atmosphere, causing damage to ecosystems, and producing secondary deleterious effects on living organisms through a wide variety of possible reactions. In response, innovative, sustainable, and ecological methods are being developed to recover solvents from industrial wastewater, which is typically contaminated with other organic compounds. This study describes the procedure for recovering acetone from a residue from the pharmaceutical industry. This compound contains a high amount of solid organic compounds, which are generated during the manufacture of medicines. The treatment consisted of performing a simple solar distillation using a single-slope glass solar still, which separated the acetone from the mother solution. Under ideal circumstances, the use of solar radiation allowed an efficiency rate of 80% using solar concentration by means of mirrors to increase the temperature and 85% without the use of mirrors in the production of distilled acetone, which was characterized to evaluate its quality using instrumental analytical techniques: NMR, IR, and GC. The results obtained indicate that the acetone recovered by this procedure has a good quality of 84%; however, due to this percentage obtained, its reuse is limited for certain applications where a high degree of purity is required, such as its reuse for pharmaceutical use; for this reason, it was proposed to use said compound to eliminate the organic impurities contained in the catalyst waste granules used in a Mexican oil refinery. The resulting material was examined by SEM and EDS, revealing a high initial carbon content that decreased by 29% after treatment. Likewise, as an additional study, a study was carried out to evaluate the characteristics of the residues obtained at the end of the distillation where rubidium, silicon, carbon, nitrogen, oxygen, and chlorine contents were observed. Full article
(This article belongs to the Section Chemical Processes and Systems)
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<p>Solar still: (<b>a</b>) without mirror adaptation, and (<b>b</b>) with mirrors as solar concentrators.</p>
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<p>The determination of the temperature in the solar still without mirror adaptation (˗) and with mirrors (- - -) as solar concentrators.</p>
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<p>Nuclear magnetic resonance analysis of distilled acetone: (<b>a</b>) <sup>1</sup>H NMR, 300 MHz; (<b>b</b>) <sup>13</sup>C NMR, 75 MHz.</p>
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<p>IR absorption spectrum obtained for distilled acetone.</p>
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<p>Gas chromatography of distilled acetone.</p>
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<p>(<b>a1</b>,<b>a2</b>) The morphological analysis of the catalyst before and after the impurity removal process using distilled acetone by SEM. (<b>b1</b>,<b>b2</b>) The EDS spectrum of the catalyst before and after the impurity removal process using distilled acetone.</p>
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<p>The wide spectrum of the solid from distillation.</p>
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<p>(<b>a</b>) Deconvoluted rubidium, (<b>b</b>) silicon, (<b>c</b>) carbon, and (<b>d</b>) oxygen region spectrums. Note: Different color lines were used in order to get differences between the several binding energies deconvoluted in each spectrum.</p>
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<p>(<b>a</b>) Deconvoluted rubidium, (<b>b</b>) silicon, (<b>c</b>) carbon, and (<b>d</b>) oxygen region spectrums. Note: Different color lines were used in order to get differences between the several binding energies deconvoluted in each spectrum.</p>
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<p>The EDS spectrum of the solid from distillation.</p>
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<p>The XRD analysis of the solid from distillation.</p>
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25 pages, 2854 KiB  
Article
From Waste to Worth: Innovative Pyrolysis of Textile Waste into Microporous Carbons for Enhanced Environmental Sustainability
by Anastasia Anceschi, Francesco Trotta, Marina Zoccola, Fabrizio Caldera, Giuliana Magnacca and Alessia Patrucco
Polymers 2025, 17(3), 341; https://doi.org/10.3390/polym17030341 - 26 Jan 2025
Viewed by 709
Abstract
The generation of synthetic textile waste is a growing global concern, with an unsustainable rate of expansion. This study addresses the growing issue of synthetic textile waste by converting polyester–polyurethane (PET-PU) post-industrial scraps into microporous carbon materials, which can be utilized for wastewater [...] Read more.
The generation of synthetic textile waste is a growing global concern, with an unsustainable rate of expansion. This study addresses the growing issue of synthetic textile waste by converting polyester–polyurethane (PET-PU) post-industrial scraps into microporous carbon materials, which can be utilized for wastewater treatment. Using a straightforward pyrolysis process, we achieved a high specific surface area (632 m2/g) and narrow porosity range (2–10 Å) without requiring chemical activation. The produced carbon materials effectively adsorbed methylene blue and orange II dyes, with maximum adsorption capacities of 169.49 mg/g and 147.56 mg/g, respectively. Kinetic studies demonstrated that adsorption followed a pseudo-second-order model, indicating strong interactions between the adsorbent and dyes. Regeneration tests showed that the C-PET-PU could be reused for multiple cycles with over 85% retention of its original adsorption capacity. Preliminary life cycle assessment (LCA) and life cycle cost (LCC) analysis highlighted the environmental and economic advantages of this upcycling approach, showing a reduced global warming potential and a production cost of approximately 1.65 EUR/kg. These findings suggest that transforming PET-PU waste into valuable adsorbents provides a sustainable solution for the circular economy and highlights the potential for broader applications in environmental remediation. Full article
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<p>TGA (<b>a</b>) and DTG (<b>b</b>) curves of PET-PU.</p>
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<p>Isotherm plot (<b>a</b>) and incremental pore volume (<b>b</b>) of C-PET-PU.</p>
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<p>SEM micrographs of (<b>a</b>) PET-PU (100×); (<b>b</b>) C-PET-PU (20×); (<b>c</b>) C-PET-PU (100×).</p>
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<p>IR spectrum of PET-PU (<b>a</b>) and C-PET-PU (<b>b</b>).</p>
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<p>Effect of contact time for OII and MB on C-PET-PU.</p>
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<p>LogKc vs 1/T curves for (<b>a</b>) OII adsorption and (<b>b</b>) MB adsorption.</p>
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<p>(<b>a</b>) Langmuir and (<b>b</b>) Freundlich isotherm plots for adsorption of OII (solid line) and MB (dotted line) onto C-PET-PU.</p>
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