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Search Results (27,422)

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17 pages, 4059 KiB  
Article
A Deep Learning-Based Framework Oriented to Pathological Gait Recognition with Inertial Sensors
by Lucia Palazzo, Vladimiro Suglia, Sabrina Grieco, Domenico Buongiorno, Antonio Brunetti, Leonarda Carnimeo, Federica Amitrano, Armando Coccia, Gaetano Pagano, Giovanni D’Addio and Vitoantonio Bevilacqua
Sensors 2025, 25(1), 260; https://doi.org/10.3390/s25010260 (registering DOI) - 5 Jan 2025
Viewed by 40
Abstract
Abnormal locomotor patterns may occur in case of either motor damages or neurological conditions, thus potentially jeopardizing an individual’s safety. Pathological gait recognition (PGR) is a research field that aims to discriminate among different walking patterns. A PGR-oriented system may benefit from the [...] Read more.
Abnormal locomotor patterns may occur in case of either motor damages or neurological conditions, thus potentially jeopardizing an individual’s safety. Pathological gait recognition (PGR) is a research field that aims to discriminate among different walking patterns. A PGR-oriented system may benefit from the simulation of gait disorders by healthy subjects, since the acquisition of actual pathological gaits would require either a higher experimental time or a larger sample size. Only a few works have exploited abnormal walking patterns, emulated by unimpaired individuals, to perform PGR with Deep Learning-based models. In this article, the authors present a workflow based on convolutional neural networks to recognize normal and pathological locomotor behaviors by means of inertial data related to nineteen healthy subjects. Although this is a preliminary feasibility study, its promising performance in terms of accuracy and computational time pave the way for a more realistic validation on actual pathological data. In light of this, classification outcomes could support clinicians in the early detection of gait disorders and the tracking of rehabilitation advances in real time. Full article
23 pages, 1111 KiB  
Article
A Hierarchical Cache Architecture-Oriented Cache Management Scheme for Information-Centric Networking
by Yichao Chao and Rui Han
Future Internet 2025, 17(1), 17; https://doi.org/10.3390/fi17010017 (registering DOI) - 5 Jan 2025
Viewed by 33
Abstract
Information-Centric Networking (ICN) typically utilizes DRAM (Dynamic Random Access Memory) to build in-network cache components due to its high data transfer rate and low latency. However, DRAM faces significant limitations in terms of cost and capacity, making it challenging to meet the growing [...] Read more.
Information-Centric Networking (ICN) typically utilizes DRAM (Dynamic Random Access Memory) to build in-network cache components due to its high data transfer rate and low latency. However, DRAM faces significant limitations in terms of cost and capacity, making it challenging to meet the growing demands for cache scalability required by increasing Internet traffic. Combining high-speed but expensive memory (e.g., DRAM) with large-capacity, low-cost storage (e.g., SSD) to construct a hierarchical cache architecture has emerged as an effective solution to this problem. However, how to perform efficient cache management in such architectures to realize the expected cache performance remains challenging. This paper proposes a cache management scheme for hierarchical cache architectures in ICN, which introduces a differentiated replica replacement policy to accommodate the varying request access patterns at different cache layers, thereby enhancing overall cache performance. Additionally, a probabilistic insertion-based SSD cache admission filtering mechanism is designed to control the SSD write load, addressing the issue of balancing SSD lifespan and space utilization. Extensive simulation results demonstrate that the proposed scheme exhibits superior cache performance and lower SSD write load under various workloads and replica placement strategies, highlighting its broad applicability to different application scenarios. Additionally, it maintains stable performance improvements across different cache capacity settings, further reflecting its good scalability. Full article
20 pages, 2818 KiB  
Article
Effective Combination of Advancing Transplantation Date with High-Yielding Cultivars for Paddy Rice Could Increase the Yield Potential Under Climate Warming in China
by He Zhang, Guangsheng Zhou and Qijin He
Agronomy 2025, 15(1), 119; https://doi.org/10.3390/agronomy15010119 (registering DOI) - 5 Jan 2025
Viewed by 96
Abstract
Climate change will have a significant impact on agricultural productivity. Rice is one of the main grains in the world, the stability of its production and supply is directly related to global food security. Based on field observation data from 2000 to 2012 [...] Read more.
Climate change will have a significant impact on agricultural productivity. Rice is one of the main grains in the world, the stability of its production and supply is directly related to global food security. Based on field observation data from 2000 to 2012 and a biophysical process-oriented CERES-Rice crop model at three typical sites, we investigated the effects of cultivar improvement, different transplanting dates and their interactions on rice yield potential in the major paddy rice production areas of China. Rice planting systems were optimized with an optimal combination of varieties and transplanting dates, and their adaptability under future climate conditions (climate projections from five global climate models under four typical concentration path scenarios) was assessed. The results showed that cultivar improvement could increase the rice yield potential by 18.0–41.4%. The appropriate transplanting date might increase the yield potential of the existing rice by 1.9–6.7%. The advance in the transplanting date combined with the application of high-yielding cultivars would prolong the growth period of rice and increase the rice yield potential by 26.3–51.8%. An effective combination of the transplanting date and cultivar is an efficient approach to increase the yield potential of rice. The results provided an important reference and choice for the scientific management of and yield increase in rice in China. Full article
(This article belongs to the Section Agroecology Innovation: Achieving System Resilience)
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<p>Locations of the study sites.</p>
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<p>Growing season boundary of early rice and late rice in simulation scenarios.</p>
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<p>Comparison of simulated and measured values for heading date (<b>a</b>), maturity date (<b>b</b>) and yield (<b>c</b>) of rice. dap: days after transplanting.</p>
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<p>Sensitivity of cultivar parameters to rice yield at the study sites.</p>
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<p>Changes in the vegetative growth period (transplanting–heading, TH), reproductive growth period (heading–maturity, HM) and the whole growth period (transplanting–maturity, TM) of existing cultivars under different conditions of transplanting date.</p>
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<p>Yield changes of existing rice cultivars with different transplanting dates.</p>
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<p>Change in the vegetative growth period (transplanting–heading, TH), reproductive growth period (heading–maturity, HM) and total growth period (transplanting–maturity, TM) of the optimal rice cultivars with different transplanting dates. * Significant at <span class="html-italic">p</span> &lt; 0.05; ** Significant at <span class="html-italic">p</span> &lt; 0.01.</p>
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<p>Yield change in optimal cultivars with different transplanting dates (<b>left</b>) and yield change in double rice under a combination of different management practices (<b>right</b>).</p>
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<p>Effects of transplanting date, cultivar and their interaction on rice yield change.</p>
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<p>Effects of optimal cultivar and transplanting date combination (top whisker line of single box) and current cultivar and transplanting date combination (bottom whisker line of single box) on potential rice yield under future climate scenarios. The dots in the whisker line represent the average potential yield; the bottom and top whisker lines indicate minimum and maximum potential yields, respectively. The black five-pointed star represents the potential rice yield in the baseline period (1985–2004).</p>
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12 pages, 3878 KiB  
Article
Al-5Er-Ti Master Alloy with Both Grain Refinement and Microalloying Effects
by Jingrui Ma, Zhiguo Lei, Shengping Wen, Guang Yang, Wu Wei, Hui Huang and Zuoren Nie
Metals 2025, 15(1), 43; https://doi.org/10.3390/met15010043 (registering DOI) - 5 Jan 2025
Viewed by 113
Abstract
The phase structure, grain refinement, and microalloying effect of the Al-5Er-Ti master alloy were analyzed by a refining experiment, microhardness test, OM, SEM, and XRD. The results show that when the Er/Ti atomic ratio is 2.7, the refining effect of the Al-5Er-0.5Ti master [...] Read more.
The phase structure, grain refinement, and microalloying effect of the Al-5Er-Ti master alloy were analyzed by a refining experiment, microhardness test, OM, SEM, and XRD. The results show that when the Er/Ti atomic ratio is 2.7, the refining effect of the Al-5Er-0.5Ti master alloy is significantly better than Al-5Er, which is due to the Ti2Al20Er phase. There are three crystal orientations of Ti2Al20Er and α-Al that satisfy the E2E model, among which (620)Ti2Al20Er<260>Ti2Al20Er//(111)Al<110>Al is the least mismatched one. When the Er/Ti atomic ratio is reduced to below 1.3, the Ti-containing phase of the Al-5Er-Ti master alloy is composed of Ti2Al20Er and Al3Ti. The primary phase size of the Al-5Er-1.5Ti master alloy decreases with the increase in cooling rate, and the grain refining effect improved more significantly. The optimum size of the Ti2Al20Er phase and Al3Ti phase is 6.0 μm and 9.5 μm, respectively. The grain size of pure aluminum is reduced from 14,000 μm to 300 μm by Al-5Er-1.5Ti master alloy refinement, and the refinement rate is 97.9%. Direct aging of the refined sample did not have a precipitation strengthening effect. After the solution and aging treatment, the peak aging of the refined sample was reached in 15 min, and the microhardness increased by 41%. Full article
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<p>XRD and SEM microstructure of Al-5Er and Al-5Er-0.5Ti master alloy: (<b>a</b>) XRD; (<b>b</b>) SEM microstructure of Al-5Er; (<b>c</b>) SEM microstructure of Al-5Er-0.5Ti.</p>
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<p>The macroscopic morphology and grain size change curve of pure Al refined by the master alloy: (<b>a</b>) added Al-5Er; (<b>b</b>) added Al-5Er-0.5Ti; (<b>c</b>) without master alloy addition; (<b>d</b>) the grain size of the Al as a function of the holding time.</p>
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<p>XRD and SEM microstructure of Al-vr-Ti and Al-Ti master alloys: (<b>a</b>) XRD; (<b>b</b>) SEM microstructure of Al-5Er-1.5Ti; (<b>c</b>) SEM microstructure of Al-1.5Ti.</p>
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<p>The morphology and grain size change curves of pure aluminum refined by the Al-5Er(-1.5Ti) master alloy: (<b>a</b>) added Al-1.5Ti; (<b>b</b>) added Al-5Er/Al-1.5Ti; (<b>c</b>) added Al-5Er-1.5Ti; (<b>d</b>) the grain size of the Al as a function of the holding time.</p>
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<p>Microstructure and grain refinement effect of Al-5Er-1.5Ti master alloy with different ingot thicknesses: (<b>a</b>) microstructure of 5 mm ingot thickness; (<b>b</b>) microstructure of 12 mm ingot thickness; (<b>c</b>) microstructure of 22 mm ingot thickness; (<b>d</b>) size of Ti<sub>2</sub>Al<sub>20</sub>Er with different ingot thicknesses; (<b>e</b>) size of Al<sub>3</sub>Ti with different ingot thicknesses; (<b>f</b>) refined grain size with different holding times for Al-5Er-1.5Ti master alloy with different ingot thicknesses.</p>
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<p>The grain sizes of pure Al refined by the Al-5Er-1.5Ti master alloy with a high-temperature treatment.</p>
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<p>Atomic arrangement of phase Ti<sub>2</sub>Al<sub>20</sub>Er:(<b>a</b>) (531); (<b>b</b>) (533); (<b>c</b>) (620).</p>
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<p>Hardness curves of the refined aluminum after different heat treatments: (<b>a</b>) direct aging at 350 °C; (<b>b</b>) 620 °C × 20 h + 350 °C.</p>
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17 pages, 597 KiB  
Article
How Do Foreign Students from Different Collectivist Countries Perceive Interpersonal Emotion Regulation? A Thematic Analysis in Lithuania
by Tomas Saulius and Romualdas Malinauskas
Educ. Sci. 2025, 15(1), 46; https://doi.org/10.3390/educsci15010046 (registering DOI) - 4 Jan 2025
Viewed by 286
Abstract
The main aim of our qualitative research is to find out how foreign students from different Collectivistic countries perceive interpersonal emotion regulation (IER). Using semi-structured interviews as a method of data collection and thematic analysis as a method of data analysis, we found [...] Read more.
The main aim of our qualitative research is to find out how foreign students from different Collectivistic countries perceive interpersonal emotion regulation (IER). Using semi-structured interviews as a method of data collection and thematic analysis as a method of data analysis, we found that the majority of participants used IER to provide psychological support to their colleagues and friends in a variety of contexts—64% of participants highlighted cognitive strategies as key in emotional regulation, especially the use of temporal perspective shifting—and that, finally, the majority of the participants highlighted the evident results of the interventions, the most common of which was the increased adaptive behavior of the targets of IER. These findings highlight the persistence of cultural orientation in heterogeneous settings and suggest situational flexibility in IER strategies. They also highlight the importance of designing culturally sensitive interventions in international educational contexts. Full article
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<p>Thematic map summarizing results of qualitative data analysis.</p>
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23 pages, 205579 KiB  
Article
DDL R-CNN: Dynamic Direction Learning R-CNN for Rotated Object Detection
by Weixian Su and Donglin Jing
Algorithms 2025, 18(1), 21; https://doi.org/10.3390/a18010021 (registering DOI) - 4 Jan 2025
Viewed by 335
Abstract
Current remote sensing (RS) detectors often rely on predefined anchor boxes with fixed angles to handle the multi-directional variations of targets. This approach makes it challenging to accurately select regions of interest and extract features that align with the direction of the targets. [...] Read more.
Current remote sensing (RS) detectors often rely on predefined anchor boxes with fixed angles to handle the multi-directional variations of targets. This approach makes it challenging to accurately select regions of interest and extract features that align with the direction of the targets. Most existing regression methods also adopt angle regression to match the attributes of remote sensing detectors. Due to the inconsistent regression direction and massive anchor boxes with a high aspect ratio, the extracted target features change greatly, the loss function changes drastically, and the training is unstable. However, existing RS detectors and regression techniques have not been able to effectively balance the precision of directional feature extraction with the complexity of the models. To address these challenges, this paper introduces a novel approach known as Dynamic Direction Learning R-CNN (DDL R-CNN), which comprises a dynamic direction learning (DDL) module and a boundary center region offset generation network (BC-ROPN). The DDL module pre-extracts the directional features of targets to provide a coarse estimation of their angles and the corresponding weights. This information is used to generate rotationally aligned anchor boxes that better model the directional features of the targets. BC-ROPN represents an innovative method for anchor box regression. It utilizes the central features of the maximum bounding rectangle’s width and height, along with the coarse angle estimation and weights derived from DDL module, to refine the orientation of the anchor box. Our method has been proven to surpass existing rotating detection networks in extensive testing across two widely used remote sensing detection datasets, namely UCAS-AOD and HRSC2016. Full article
(This article belongs to the Special Issue Algorithms for Image Processing and Machine Vision)
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<p>Our motivation for this work originates from two crucial aspects: (<b>a</b>) In the detection of rotating targets, instances of targets with similar visual expressions are placed in arbitrary directions (for example, ships). Therefore, it is reasonable to learn the direction of the target in a data-driven manner and rotate the convolutional kernels accordingly. (<b>b</b>) Existing methods are troubled by the inconsistencies in regression direction and significant changes in features extracted from targets when rotating high-aspect-ratio anchor boxes. Thus, approximating the rotation direction of the anchor box by regressing towards the boundary center region is a solution to the problem of large changes in target features when rotating anchor boxes with high aspect ratios.</p>
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<p>The schematic diagram of the DDL module. From a broad perspective, the final feature map <math display="inline"><semantics> <mrow> <mi>y</mi> <mo>(</mo> <mo>Δ</mo> <mi>α</mi> <mo>,</mo> <mo>Δ</mo> <mi>β</mi> <mo>)</mo> </mrow> </semantics></math> is jointly guided by the original convolutional parameters <span class="html-italic">w</span> and the input feature map <span class="html-italic">x</span>, and is generated through the processing of dynamic directional convolution kernels and other related convolutions. (<b>a</b>) The rotating convolutional kernel is generated by combining the convolutional kernel parameters extracted from the original convolution with the rotation angles predicted by the routing function. (<b>b</b>) The functional makeup of the routing function involves encoding image features, represented by <span class="html-italic">x</span>, through deep convolutional layers that follow an average pooling layer. Parameters <math display="inline"><semantics> <mi>θ</mi> </semantics></math> and <math display="inline"><semantics> <mi>λ</mi> </semantics></math> are predicted by two distinct branches, each with its own specific activation function.</p>
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<p>DDL R-CNN’s overarching architecture functions as a two-stage detection system, predicated on the Feature Pyramid Network (FPN). Initially, it employs an oriented Region Proposal Network (RPN) to produce oriented proposal boxes. Subsequently, the directed R-CNN head combined with the DDL module and the Boundary Center Region Offset Proposal Network (BC-ROPN) are used in the subsequent stage to classify these proposal boxes and fine-tune their spatial coordinates. For clarity, we have not depicted the FPN and classification branches oriented towards the RPN.</p>
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<p>Visualization of the rotating anchor box generated by DDL R-CNN on the UCAS-AOD dataset. The figure displays the top 200 anchor boxes for each image.</p>
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<p>Comparison of detection results between DDL R-CNN and existing methods on UCAS-AOD dataset.</p>
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<p>Visualization result of rotating anchor box generated by DDL R-CNN on HRSC2016 dataset. The figure displays the top 200 anchor boxes for each image.</p>
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<p>Comparison of detection results between DDL R-CNN and existing methods on HRSC2016 dataset.</p>
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15 pages, 699 KiB  
Systematic Review
Pharmacist-Mediated Deprescribing in Long-Term Care Facilities: A Systematic Review
by João Rafael Gonçalves, Neuza Magalhães, Sara Machado, Isabel Ramalhinho and Afonso Miguel Cavaco
Pharmacy 2025, 13(1), 3; https://doi.org/10.3390/pharmacy13010003 (registering DOI) - 4 Jan 2025
Viewed by 243
Abstract
Multimorbidity and polypharmacy are prevalent among Long-Term Care (LTC) users. Older people, who most use LTC services, are more prone to drug-related problems, which polypharmacy aggravates. Deprescribing is a key intervention to address polypharmacy and inappropriate medication. Evidence shows that pharmacists’ expertise in [...] Read more.
Multimorbidity and polypharmacy are prevalent among Long-Term Care (LTC) users. Older people, who most use LTC services, are more prone to drug-related problems, which polypharmacy aggravates. Deprescribing is a key intervention to address polypharmacy and inappropriate medication. Evidence shows that pharmacists’ expertise in medicines and their growing involvement in clinical-oriented activities have proven to play an essential role across many healthcare settings, including LTC. Thus, this study aimed to identify and assess LTC pharmacist-mediated deprescribing. A systematic review was undertaken following the PRISMA checklist, using three literature databases (PubMed, Scopus, and Web of Knowledge). A set of 18 keywords, divided into three domains (professional, type of care, and type of setting), were combined into search equations. The studies selected were assessed through the Quality Assessment Tool for Quantitative Studies. Fifteen studies met the inclusion criteria out of 288 initial hits. Pharmacist-mediated deprescribing was divided into specific (targeted to a medicine group) and non-specific. Half of the studies were graded as low quality (53%). In total, the studies enrolled 6928 patients and 45 pharmacists. The ATC groups A, C, M, and N, as well as medicines with anticholinergic properties, were the most addressed medicines groups. Acceptance rates of pharmacists’ recommendations ranged between 30% and 100%. Generically, the number of medicines was reduced after the intervention. Mixed results were found for falls and quality of life outcomes. Cost savings associated with the interventions ranged from neutral to as high as 3800 €/patient/year. Barriers to deprescribing were mainly linked to patients’ or family members’ refusal to change. In conclusion, pharmacist-mediated deprescribing seems feasible in LTC. The studies’ methodological heterogeneity hampers robust comparisons and conclusions. The medicine groups targeted by deprescribing can help tailor interventions to optimize the use of medicines in LTC. A detailed understanding of barriers and enablers to deprescribing would support developing and implementing these interventions. Full article
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<p>PRISMA flow diagram for the study selection process.</p>
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24 pages, 3329 KiB  
Article
A Capacity-Utilization-Oriented Stop Planning Approach for High-Speed Railway Network with Stop Distribution Balance
by Shuo Zhao, Xinghua Shan, Jinfei Wu, Litao Zhang, Zhenyi Li and Xuying Liu
Appl. Sci. 2025, 15(1), 399; https://doi.org/10.3390/app15010399 - 3 Jan 2025
Viewed by 400
Abstract
Stop planning is aimed to provide proper services for passenger demand, but diverse stop patterns lead to differences in stop density and travel speeds, impacting the utilization of line capacity. This paper incorporates capacity utilization into stop planning in the strategic line planning [...] Read more.
Stop planning is aimed to provide proper services for passenger demand, but diverse stop patterns lead to differences in stop density and travel speeds, impacting the utilization of line capacity. This paper incorporates capacity utilization into stop planning in the strategic line planning stage to trade off the matching between supply and demand and the stop distribution balance among trains. A bi-level programming model is established to formulate the Stackelberg game relation between supply and demand, where the stop distribution imbalance and the passenger travel inefficiency are measured. An adaptive hybrid solving algorithm combined with Genetic Algorithm and Simulated Annealing Algorithm is proposed, with several adaptive operations according to the problem characteristics and optimization degree to improve searching efficiency. A case study on the local network of Beijing–Shanghai High-speed Railway Line demonstrates that the proposed approach can not only mitigate the stop distribution imbalance, but also improve the travel efficiency of passengers, indicating that it can benefit the simultaneous improvement of capacity utilization and service level. Full article
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<p>Illustration of capacity utilization impact of stop patterns.</p>
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<p>Illustration of double-coupled chromosome encoding form.</p>
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<p>Illustration of Tournament Selection.</p>
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<p>Illustration of crossover operator.</p>
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<p>Flowchart of the solving algorithm framework.</p>
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<p>Illustration of the local network of the Beijing–Shanghai High-speed Railway Line.</p>
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<p>Illustration of the distributions of train stop distribution imbalance indexes of each segment. (The red circles represent the changed ranges between the OSP and the ISP).</p>
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<p>Illustration of the distributions of train stop ratios on each segment.</p>
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<p>Illustration of the distributions of train stop ratios on each segment.</p>
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<p>Illustration of the distributions of the additional time ratios of passengers. (The squares show the zones with descent trend of the OSP, compared to the ISP).</p>
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19 pages, 3752 KiB  
Article
A Study on Community Unit Scale Construction in China Under the Orientation of Green Production
by Rui Zhang, Qingjian Zeng, Yanhang Lv, Huanjie Liu, Lixian Shi and Yukun Zhang
Land 2025, 14(1), 86; https://doi.org/10.3390/land14010086 - 3 Jan 2025
Viewed by 267
Abstract
Based on the principle of distributed layout, the community is chosen as the basic unit of the city, and an appropriate community scale is redefined based on the attributes and characteristics of green production. This article first summarizes the existing research models at [...] Read more.
Based on the principle of distributed layout, the community is chosen as the basic unit of the city, and an appropriate community scale is redefined based on the attributes and characteristics of green production. This article first summarizes the existing research models at the community level using bibliometric methods, and on this basis the process of researching the green productive community unit scale is constructed. Subsequently, the data on the scales of agriculture, energy, transport, and commercial facilities from the relevant Chinese national city standards are summarized, classified, and generalized. This is followed by the derivation of appropriate grid scales for green productive community units. Ultimately, a quadratic optimization scale was devised for community units at varying levels based on fractal and management unit theory. This paper presents a new community unit scale constructed for use in large- and medium-sized areas in China, which serves as an illustrative example. The newly developed community scale has the potential to improve the efficiency of resource allocation and support the transition from functional adjustment to structural adjustment in urban areas. Furthermore, the scale definition method and principle can be extended and applied to other large- and medium-sized urban areas globally. Full article
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<p>The number of articles related to productive urban research published in the last five years (data source: Web of Science Core Database).</p>
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<p>The relationship between productivity, scale (<b>A</b>), and community research in the process of constructing green productive community units (<b>B</b>). Source: author. Note: factors such as energy, transportation, and agriculture are interconnected and function collaboratively at the community and productive scales. Additionally, these factors may also be factors of other variables such as economics, politics, culture, climate, etc.</p>
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<p>Facility gridding. Source: author. Note: The letters within the grid in the figure represent different types of facilities. The number of facilities within the cells will be quantified in subsequent studies using Geographic Information Systems (GIS) and other technologies.</p>
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<p>Fractal unit combination mode. Source: author.</p>
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13 pages, 26837 KiB  
Article
Temperature Dependence on Microstructure, Crystallization Orientation, and Piezoelectric Properties of ZnO Films
by Ke Deng, Zhonghao Liu, Hulin Liu, Yanxiang Chen, Shang Li, Shuren Guo, Boyu Xiu, Xuanpu Dong and Huatang Cao
Sensors 2025, 25(1), 242; https://doi.org/10.3390/s25010242 - 3 Jan 2025
Viewed by 235
Abstract
This study has investigated the effects of different annealing temperatures on the microstructure, chemical composition, phase structure, and piezoelectric properties of ZnO films. The analysis focuses on how annealing temperature influences the oxygen content and the preferred c-axis (002) orientation of the films. [...] Read more.
This study has investigated the effects of different annealing temperatures on the microstructure, chemical composition, phase structure, and piezoelectric properties of ZnO films. The analysis focuses on how annealing temperature influences the oxygen content and the preferred c-axis (002) orientation of the films. It was found that annealing significantly increases the grain size and optimizes the columnar crystal structure, though excessive high-temperature annealing leads to structural degradation. This behavior is likely related to changes in oxygen content at different annealing temperatures. High resolution transmission electron microscopy (HR-TEM) reveals that the films exhibit high-resolution lattice stripes, confirming their high crystallinity. Although the films exhibit growth in multiple orientations, the c-axis (002) orientation remains the predominant crystallographic growth. Further piezoelectric property analysis demonstrates that the ZnO films annealed at 400 °C exhibit enhanced piezoelectric performance and stable linear piezoelectric behavior. These findings offer valuable support for optimizing the piezoelectric properties of ZnO films and their applications in piezoelectric sensors. Full article
(This article belongs to the Section Intelligent Sensors)
13 pages, 3091 KiB  
Article
Buried Interface Smoothing Boosts the Mechanical Durability and Efficiency of Flexible Perovskite Solar Cells
by Erxin Zhao, Yongshuai Gong, Yixin Dong, Wanlei Dai, Chou Liu, Tinghuan Yang, Nan Wu, Ye Yang, Zheng Zhang, Chenqing Tian, Buyi Yan, Dongxue Liu, Lu Zhang and Tianqi Niu
Energies 2025, 18(1), 174; https://doi.org/10.3390/en18010174 - 3 Jan 2025
Viewed by 229
Abstract
Flexible perovskite solar cells (F-PSCs) have the advantages of high power-per-weight, solution processability, and bending durability and have emerged as a competitive photovoltaic technology for various applications. As the core electron transport layer (ETL) in n-i-p-type device configurations, the solution-processed SnO2 generally [...] Read more.
Flexible perovskite solar cells (F-PSCs) have the advantages of high power-per-weight, solution processability, and bending durability and have emerged as a competitive photovoltaic technology for various applications. As the core electron transport layer (ETL) in n-i-p-type device configurations, the solution-processed SnO2 generally suffers from serious defect stacking on films, compromising the charge transport properties and the performance of resulting devices. Herein, we proposed a media-filling strategy to optimize the contact quality at the buried interface by introducing Al2O3 nanoparticles on the SnO2 surface. Rather than forming a compact insulating layer, the Al2O3 can fill the grain boundaries of SnO2 and smooth the substrate surface. Optimized interfacial contact under careful concentration control can rationally minimize the contact area of the perovskite with the surface imperfections of SnO2 to mitigate trap-assisted charge recombination. Furthermore, the reduced surface roughness of SnO2 facilitates the uniform deposition and oriented growth of upper perovskite film. As a result, the target F-PSCs achieved an impressive efficiency of 23.83% and retained 80% of the initial performance after 5000 bending cycles at a radius of four mm. Full article
(This article belongs to the Section A2: Solar Energy and Photovoltaic Systems)
22 pages, 1617 KiB  
Review
Solution Deposition Planarization as an Alternative to Electro-Mechanical Polishing for HTS Coated-Conducters
by Laura Piperno and Giuseppe Celentano
Coatings 2025, 15(1), 45; https://doi.org/10.3390/coatings15010045 - 3 Jan 2025
Viewed by 190
Abstract
Mechanically flexible substrates are increasingly utilized in electronics and advanced energy technologies like solar cells and high-temperature superconducting coated conductors (HTS-CCs). These substrates offer advantages, such as large surface areas and reduced manufacturing costs through reel-to-reel processing, but often lack the surface smoothness [...] Read more.
Mechanically flexible substrates are increasingly utilized in electronics and advanced energy technologies like solar cells and high-temperature superconducting coated conductors (HTS-CCs). These substrates offer advantages, such as large surface areas and reduced manufacturing costs through reel-to-reel processing, but often lack the surface smoothness needed for optimal performance. For HTS-CCs, specific orientation and high crystalline quality are essential, requiring buffer layers to prepare the amorphous substrate for superconductor deposition. Techniques, such as mechanical polishing, electropolishing, and chemical-mechanical polishing, can help achieve an optimally levelled surface suitable for the subsequent steps of sputtering and ion-beam-assisted deposition (IBAD) necessary for texturing. This review examines Solution Deposition Planarization (SDP) as a cost-effective alternative to traditional electro-mechanical polishing for HTS coated conductors. SDP achieves surface roughness levels below 1 nm through multiple oxide layer coatings, offering reduced production costs. Comparative studies demonstrate planarization efficiencies of up to 20%. Ongoing research aims to enhance SDP’s efficiency for industrial applications in CC production. Full article
13 pages, 294 KiB  
Article
Beyond the Scalpel: Addressing Communication and Distress in ENT Cancer
by Bogdan Hirtie, Norberth-Istvan Varga, Andrada Oprisoni, Sonia Tanasescu, Estera Boeriu, Virgiliu Bogdan Sorop, Octavia Harich, Adrian Vasile Bota and Delia Ioana Horhat
Medicina 2025, 61(1), 69; https://doi.org/10.3390/medicina61010069 - 3 Jan 2025
Viewed by 277
Abstract
Background and Objectives: Effective communication in oncology is crucial, but challenging due to the complex information and emotional burden associated with a cancer diagnosis. This cross-sectional study investigated the communication preferences of 155 Romanian adults diagnosed with ENT cancers and explored the [...] Read more.
Background and Objectives: Effective communication in oncology is crucial, but challenging due to the complex information and emotional burden associated with a cancer diagnosis. This cross-sectional study investigated the communication preferences of 155 Romanian adults diagnosed with ENT cancers and explored the relationship between these preferences, their levels of psychological distress, and sociodemographic factors. Materials and Methods: Participants completed the KOPRA questionnaire, assessing communication preferences, and the Hospital Anxiety and Depression Scale (HADS) to measure psychological distress. Results: The results revealed that patients strongly prioritized active involvement in their care (Patient Participation and Patient Orientation—PPO) and open communication with healthcare providers (Effective and Open Communication—EOC). While emotional support was valued, it was considered less critical than PPO and EOC. Notably, communication about personal matters was deemed the least important aspect of communication. A high prevalence of psychological distress was observed, particularly among widowed individuals and females. No direct correlation was found between communication preferences and distress. Conclusions: These findings underscore the importance of shared decision-making, clear information exchange, and a patient-centered approach in the context of ENT cancer care, while also highlighting the need for routine screening and appropriate support for psychological well-being in this patient population. Full article
(This article belongs to the Section Psychiatry)
16 pages, 7942 KiB  
Article
Study on the Mechanism Between Weld Microstructure and Crack Tie Opening Displacement Fracture Toughness of the Steel Catenary Riser
by Yuxi Cao, Shubiao Yin, Ba Li, Shujun Jia, Yuan Li, Yuqin Qin, Rui Hong and Kangxin Shuai
Materials 2025, 18(1), 176; https://doi.org/10.3390/ma18010176 - 3 Jan 2025
Viewed by 317
Abstract
Fracture toughness is an important index related to the service safety of marine risers, and weld is an essential component of the steel catenary risers. In this paper, microscopic structure characterization methods such as scanning electron microscopy (SEM) and electron back scatter diffraction [...] Read more.
Fracture toughness is an important index related to the service safety of marine risers, and weld is an essential component of the steel catenary risers. In this paper, microscopic structure characterization methods such as scanning electron microscopy (SEM) and electron back scatter diffraction (EBSD), as well as mechanical experiments like crack tip opening displacement (CTOD) and nanoindentation, were employed to conduct a detailed study on the influence of the microstructure characteristics of multi-wire submerged arc welded seams of steel catenary riser pipes on CTOD fracture toughness. The influence mechanisms of each microstructure characteristic on fracture toughness were clarified. The results show that the main structure in the weld of the steel catenary riser is acicular ferrite (AF), but there is also often side lath plate ferrite (FSP) and grain boundary ferrite (GBF). With the increase in the proportion of FSP and GBF in the weld microstructure, the CTOD fracture toughness of the weld decreases gradually. The weld AF is a braided cross arrangement structure, and most of the grain boundary orientation difference is higher than 45°. The effective grain size refinement of AF can effectively prevent crack propagation and significantly improve fracture toughness. GBF is distributed along proto-austenitic grain boundaries PAGB, and the large hardness difference between the GBF and the AF matrix weakens the grain boundary. Cracks can easy be initiated at the interface position of the two phases and can propagate along the GBF grain boundary, resulting in the deterioration of toughness. Although the hardness of FSP is between that of GBF and AF, it destroys the continuity of the overall weld microstructure and is also unfavorable to toughness. Full article
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<p>General process of experiment.</p>
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<p>SEM characterization of X65 grade experimental steel: (<b>a</b>) 2000 times; (<b>b</b>) 5000 times.</p>
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<p>(<b>a</b>) Actual welded joints and sampling locations. (<b>b</b>) CTOD schematic diagram.</p>
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<p>Microstructure of 1#–5# weld metal at 100 times (<b>a</b>–<b>e</b>), respectively.</p>
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<p>SEM characterization of AF, FSP, and GBF in weld metal. (<b>a</b>) 5# weld metal; (<b>b</b>) 1# weld metal.</p>
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<p>Comparison of microstructure ratio and CTOD value in 1#–5# welds.</p>
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<p>Nanoindentation experiment results of AF, FSP, and GBF in 1#, 2#, and 3# weld metals.</p>
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<p>EBSD characterization of AF in different welds: (<b>a</b>–<b>e</b>) are IPF diagrams of AF in 1#–5# welds; (<b>f</b>–<b>j</b>) are grain boundary diagrams of AF in 1#–5# welds.</p>
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<p>EBSD characterization of AF in different welds: (<b>a</b>–<b>e</b>) are IPF diagrams of AF in 1#–5# welds; (<b>f</b>–<b>j</b>) are grain boundary diagrams of AF in 1#–5# welds.</p>
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<p>AF crystal information analysis in 1#–5# weld metal: (<b>a</b>) distribution diagram of orientation difference angle; (<b>b</b>) aspect ratio chart; (<b>c</b>) grain circumference map; (<b>d</b>) grain boundary density map.</p>
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<p>EBSD characterization of 1# and 5# weld metals: (<b>a</b>–<b>c</b>) IPF diagram, grain boundary diagram, and MBS diagram of 5# weld metals; (<b>d</b>–<b>f</b>) IPF diagram, grain boundary diagram, and MBS diagram of 1# weld metal.</p>
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<p>SEM characterization of the crack trend in the brittle fracture zone of 1# and 5# weld metals: (<b>a</b>) the crack trend diagram of 5# weld metals; (<b>b</b>,<b>c</b>) a partial enlargement of (<b>a</b>); (<b>d</b>) diagram of the crack pattern of 1# weld metal; (<b>e</b>,<b>f</b>) a partial enlargement of (<b>d</b>).</p>
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<p>EBSD characterization of crack trend in the brittle fracture zone of 1# and 5#WM: (<b>a</b>–<b>c</b>) IPF diagram of 5# weld metal, grain boundary diagram of size and angle, and MBS diagram; (<b>d</b>–<b>f</b>) IPF diagram of 1# weld metal, the grain boundary diagram of size and angle, and the MBS diagram; (<b>g</b>–<b>i</b>) IPF diagram, the grain boundary diagram, and the MBS diagram of the secondary cracks in the 1# weld metal matrix.</p>
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25 pages, 10105 KiB  
Article
Assessing the Potential of Volcanic and Sedimentary Rock Aquifers in Africa: Emphasizing Transmissivity, Water Quality, and Recharge as Key Evaluation Metrics
by Kristine Walraevens, George Bennett, Nawal Alfarrah, Tesfamichael Gebreyohannes, Gebremedhin Berhane, Miruts Hagos, Abdelwassie Hussien, Fenta Nigate, Ashebir Sewale Belay, Adugnaw Birhanu and Alemu Yenehun
Water 2025, 17(1), 109; https://doi.org/10.3390/w17010109 - 3 Jan 2025
Viewed by 358
Abstract
This study provides a comprehensive analysis of the groundwater potential of hard rock aquifers in five diverse African case study areas: Lake Tana Basin and Beles Basin in northwestern Ethiopia and Mount Meru in northern Tanzania (comprising volcanic aquifers); the Mekelle area in [...] Read more.
This study provides a comprehensive analysis of the groundwater potential of hard rock aquifers in five diverse African case study areas: Lake Tana Basin and Beles Basin in northwestern Ethiopia and Mount Meru in northern Tanzania (comprising volcanic aquifers); the Mekelle area in northern Ethiopia and Jifarah Plain in Libya (consisting of sedimentary aquifers). The evaluation of recharge, transmissivity, and water quality formed the basis of qualitative and quantitative assessment. Multiple methods, including water table fluctuation (WTF), chloride mass balance (CMB), physical hydrological modeling (WetSpass), baseflow separation (BFS), and remote sensing techniques like GRACE satellite data, were employed to estimate groundwater recharge across diverse hydrogeological settings. Topographic contrast, fractured orientation, lineament density, hydro-stratigraphic connections, hydraulic gradient, and distribution of high-flux springs were used to assess IGF from Lake Tana to Beles Basin. The monitoring, sampling, and pumping test sites took into account the high hydromorphological and geological variabilities. Recharge rates varied significantly, with mean values of 315 mm/year in Lake Tana Basin, 193 mm/year in Mount Meru, and as low as 4.3 mm/year in Jifarah Plain. Transmissivity ranged from 0.4 to 6904 m2/day in Lake Tana Basin, up to 790 m2/day in Mount Meru’s fractured lava aquifers, and reached 859 m2/day in the sedimentary aquifers of the Mekelle area. Water quality issues included high TDS levels (up to 3287 mg/L in Mekelle and 11,141 mg/L in Jifarah), elevated fluoride concentrations (>1.5 mg/L) in 90% of Mount Meru samples, and nitrate pollution in shallow aquifers linked to agricultural practice. This study also highlights the phenomenon of inter-basin deep groundwater flow, emphasizing its role in groundwater potential assessment and challenging conventional water balance assumptions. The findings reveal that hard rock aquifers, particularly weathered/fractured basalt aquifers in volcanic regions, exhibit high potential, while pyroclastic aquifers generally demonstrate lower potential. Concerns regarding high fluoride levels are identified in Mount Meru aquifers. Among sedimentary aquifers in the Mekelle area and Jifarah Plain, limestone intercalated with marl or dolomite rock emerges as having high potential. However, high TDS and high sulfate concentrations are quality issues in some of the areas, quite above the WHO’s and each country’s drinking water standards. The inter-basin groundwater flow, investigated in this study of Beles Basin, challenges the conventional water balance assumption that the inflow into a hydrological basin is equivalent to the outflow out of the basin, by emphasizing the importance of considering groundwater influx from neighboring basins. These insights contribute novel perspectives to groundwater balance and potential assessment studies, challenging assumptions about groundwater divides. Full article
(This article belongs to the Section Hydrogeology)
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<p>Location map of the five case study areas: (<b>A</b>) Lake Tana Basin; (<b>B</b>) Beles Basin; (<b>C</b>) Mount Meru; (<b>D</b>) Mekelle Basin; (<b>E</b>) Jifarah Plain.</p>
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<p>(<b>a</b>) Hydrogeological map of Lake Tana Basin; (<b>b</b>) hydrogeological cross-section of Lake Tana Basin from the southern tip to the north.</p>
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<p>Geological map showing the various geological formations and the spatial distribution of F<sup>−</sup> concentrations at the sampled water points around Mount Meru (adapted from Bennett et al. [<a href="#B18-water-17-00109" class="html-bibr">18</a>]).</p>
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<p>Geological map and lithological cross-section view of the study area, showing the spatial distribution of complex volcanic rock system at Tana and Beles Basin (modified after Belay et al. [<a href="#B20-water-17-00109" class="html-bibr">20</a>]).</p>
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<p>Litho-hydrostratigraphy of the southwestern flank of Mount Meru in Ngaramtoni showing the aquifer structure [<a href="#B22-water-17-00109" class="html-bibr">22</a>]. BH stands for boreholes and W stands for shallow hand-dug wells.</p>
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<p>The spatial variability of water resources in Beles Basin. (<b>a</b>) Photo showing the difficulty of access to water in most Upper Beles areas, where precipitation is higher, and (<b>b</b>) photo showing the middle of Beles Basin (precipitation relatively lower), with relative water supply abundance from high-discharge springs.</p>
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<p>Geological map and cross-sections along east-to-west and north-to-south directions through the Mekelle area.</p>
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<p>Geological cross-section in the coastal area of Jifarah Plain, including Tripoli region [<a href="#B29-water-17-00109" class="html-bibr">29</a>]. The cross-section shows the hydrostratigraphy of the Jifarah Plain main groundwater aquifer system. The labels with codes PZBG7, RDBG7, etc. are the wells along the A-A” profile line.</p>
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<p>Cross-plot of Ca<sup>2+</sup> vs. TDS (<b>a</b>) and of SO<sub>4</sub><sup>2−</sup> vs. Ca<sup>2+</sup> (<b>b</b>).</p>
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<p>(<b>a</b>) Schematic of conceptualized regional groundwater flow system of Tana-Beles basins contact (Landsat image with a false color composite of RGB band 7, 5, and 1, respectively, with lithostratigraphy cross-section). Blue arrows represent local and regional flow paths and location of high-flux springs that are the result of IGF. (<b>b</b>) Cross-section showing the relation of groundwater level at the deep boreholes to the land surface topography along a perpendicular axis to the Tana-Beles basin boundary (<b>a</b>), modified after [<a href="#B20-water-17-00109" class="html-bibr">20</a>].</p>
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