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28 pages, 1206 KiB  
Article
A Configuration Model for Hospital Design Support Systems
by Zhuoran Jia, Pirouz Nourian, Peter Luscuere and Cor Wagenaar
Buildings 2025, 15(2), 163; https://doi.org/10.3390/buildings15020163 - 8 Jan 2025
Abstract
Hospital layout significantly influences hospital service quality, demanding robust tools for informed decision-making during the layout design stage. This study presents a novel Hospital Configuration Model as the foundational component of a Hospital Design Support System, which utilizes simulation modeling to provide evaluation [...] Read more.
Hospital layout significantly influences hospital service quality, demanding robust tools for informed decision-making during the layout design stage. This study presents a novel Hospital Configuration Model as the foundational component of a Hospital Design Support System, which utilizes simulation modeling to provide evaluation mechanisms on hospital efficiencies and functionalities. The Hospital Configuration Model integrates four critical data types—geometric, topological, semantic, and operational—into a machine-readable digital twin, enabling comprehensive spatial and procedural analyses. The Hospital Configuration Model facilitates simulation modeling to optimize hospital layouts and predict performance metrics such as crowdingness, patient waiting times, patient walking distance, and difficulty in wayfinding. In conclusion, the Hospital Configuration Model is the core and foundation of developing the Hospital Design Support System for evaluating hospital functionalities and efficiencies, and the potential applications of the model include digital twin development, facility management, and safety enhancement. Future research directions should, in particular, include developing the proposed Hospital Design Support System and establishing a standard way of extracting hospital operational information into an industry-standard data model. Full article
(This article belongs to the Section Construction Management, and Computers & Digitization)
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<p>Patients’ paths in the Outpatient Department of Panyu Central Hospital, image source: [<a href="#B29-buildings-15-00163" class="html-bibr">29</a>].</p>
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<p>Patients’ paths in the Inpatient Department of Panyu Central Hospital, image source: [<a href="#B29-buildings-15-00163" class="html-bibr">29</a>].</p>
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<p>Patients’ paths in the Emergency Department of Panyu Central Hospital, image source: [<a href="#B29-buildings-15-00163" class="html-bibr">29</a>].</p>
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<p>Activity relationship chart of procedures in Panyu Central Hospital, red cells indicate strong connecting relationship between two procedures, blue cells indicate the weak connecting relationship between two procedures, image source: [<a href="#B29-buildings-15-00163" class="html-bibr">29</a>].</p>
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<p>Metro network diagram of patients’ paths in Panyu Central Hospital.</p>
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<p>A UML diagram illustrating data included in a Hospital Configuration Model.</p>
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<p>An illustration of IndoorGML’s data structure.</p>
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<p>An example of a hospital IndoorGML model, image source: [<a href="#B42-buildings-15-00163" class="html-bibr">42</a>].</p>
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<p>The workflow from Hospital IFC Model to Hospital Configuration Model, source: [<a href="#B42-buildings-15-00163" class="html-bibr">42</a>].</p>
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<p>The basic architecture of MVC, image source [<a href="#B49-buildings-15-00163" class="html-bibr">49</a>].</p>
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<p>View function for extracting semantic information, source: [<a href="#B42-buildings-15-00163" class="html-bibr">42</a>].</p>
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35 pages, 1705 KiB  
Review
Mitigation of Asphaltene Deposit Formation via Chemical Additives: A Review
by Dicho Stratiev, Radoslava Nikolova, Anife Veli, Ivelina Shishkova, Vesislava Toteva and Georgi Georgiev
Processes 2025, 13(1), 141; https://doi.org/10.3390/pr13010141 - 7 Jan 2025
Viewed by 331
Abstract
The deposition of asphaltenes in the petroleum industry has been found to be a significant factor affecting the profitability of petroleum production and refining. For this reason, many efforts have been made to clarify the mechanism of deposition formation and to find measures [...] Read more.
The deposition of asphaltenes in the petroleum industry has been found to be a significant factor affecting the profitability of petroleum production and refining. For this reason, many efforts have been made to clarify the mechanism of deposition formation and to find measures to reduce its harmful impact on the efficiency of oil production and refining. Recent reports on the mechanism of deposit formation by asphaltenes suggest that it is a phase transition phenomenon. Many studies have shown that this process can be slowed by using chemical inhibitors. Different classes of chemical substances (non-polymeric, organic compounds, polymers, ionic liquids and nanomaterials) have been found to be capable of inhibiting asphaltene precipitation. This paper presents a comprehensive review of asphaltene deposition research and makes an attempt to decipher the convoluted asphaltene deposition phenomena and relate the chemistry of asphaltene inhibitors to the nature of treated petroleum oils. The choice of appropriate additives to mitigate asphaltene deposition in commercial oil and gas facilities requires comprehensive knowledge of chemistry of oils, asphaltenes, and the chemical substances, along with the appropriate laboratory techniques that best mimic the commercial operation conditions. Full article
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<p>Number of published articles for the period 1975–2024 with search words “asphaltene + inhibitor”.</p>
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<p>Reduction in asphaltene content in H-Oil HMPS bottom product by the addition of different percentages of <span class="html-italic">FCC SLO</span>.</p>
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<p>Dependence between crude oil toluene equivalence and the required concentration of dispersant to achieve zero toluene equivalence.</p>
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<p>Distribution of chemical additives by type employed as asphaltene inhibitors and dispersants reported in the literature.</p>
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<p>Asphaltene precipitation onset (APO) test used to evaluate the performance of several different chemical additives as asphaltene inhibitors when treating three crude oils with 1000 ppm additive and availing n-heptane (<b>a</b>) and CO<sub>2</sub> (<b>b</b>) as antisolvents [<a href="#B319-processes-13-00141" class="html-bibr">319</a>], and one crude oil and two model oils treated with 10,000 ppm additive and employing n-heptane as antisolvent (<b>c</b>) [<a href="#B67-processes-13-00141" class="html-bibr">67</a>,<a href="#B72-processes-13-00141" class="html-bibr">72</a>,<a href="#B203-processes-13-00141" class="html-bibr">203</a>].</p>
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24 pages, 4641 KiB  
Article
Development of a Novel Retrofit Framework Considering Industry 4.0 Concepts: A Case Study of a Modular Production System
by Rafael S. Mendonca, Mariélio da Silva, Florindo A. C. Ayres, Iury V. Bessa, Renan L. P. Medeiros and Vicente F. Lucena
Processes 2025, 13(1), 136; https://doi.org/10.3390/pr13010136 - 7 Jan 2025
Viewed by 309
Abstract
Retrofitting legacy systems provides significant advantages by addressing compatibility issues with new devices and technologies, meeting current process requirements, and increasing security and regulatory compliance. The process starts by collecting requirements and evaluating the legacy system’s attributes and limitations, followed by integrating modern [...] Read more.
Retrofitting legacy systems provides significant advantages by addressing compatibility issues with new devices and technologies, meeting current process requirements, and increasing security and regulatory compliance. The process starts by collecting requirements and evaluating the legacy system’s attributes and limitations, followed by integrating modern technologies to improve efficiency, streamline processes, and enhancing performance and interoperability while leveraging existing facilities to reduce costs. A systematic approach ensures that updates align with modern technological standards, with performance evaluations conducted via qualitative and quantitative methods and system maturity assessed according to the Reference Architecture Model for Industries 4.0 (RAMI 4.0 model’s) criteria for intelligent factories. By incorporating digital twin (DT) capabilities, which replicate the physical state of systems and provide real-time data updates, the retrofit strategy aligns the physical system with Industry 4.0 contexts, facilitating continuous improvement and seamless integration with modern processes. The goal is to advance the legacy system technologically to ensure seamless integration with contemporary processes, validated through RAMI criteria analysis for smart factories. As part of this process, digital twin architecture was built. This architecture was the basis for building and operating digital twins in the process. The methodology was used to enhance and transform legacy systems, creating the foundation for creating a fully digital twin. Using this method, these systems can be updated to meet the requirements of Industry 4.0. This ensures that they can work with new systems and share data in real time, which improves general operations. Full article
(This article belongs to the Section Advanced Digital and Other Processes)
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<p>General step diagram of the proposed retrofitting framework.</p>
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<p>Flowchart of the proposed retrofit framework. (<b>a</b>) flow for the implementation of step 1: Survey and operational limitations of the plant; (<b>b</b>) flow for the implementation of step 2: Definition of goals; (<b>c</b>) flow for the implementation of step 3: Selection of components and technologies to be updated; (<b>d</b>) flow for the implementation of step 4: Integration of new components and technologies; (<b>e</b>) flow for the implementation of step 5: Testing and validation of new components and technologies.</p>
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<p>Layers of Digital Twin Architecture.</p>
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<p>Example of MPS operation script.</p>
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<p>Updated MPS platform.</p>
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<p>Digital twin application—reproduction of the operation of the physical twin and its synchronization with the virtual twin. (<b>A</b>) Process in the handling module: The piece is collected from the feeder and sent to the next module; (<b>B</b>) Process in the pressing module: resources are inserted into the piece according to the production script; (<b>C</b>) Process in the pick and place module: the piece is covered with the respective lid of the same type.</p>
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<p>Diagram of communication implemented.</p>
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<p>Result obtained after applying the retrofitting methodology aiming at the digital twin.</p>
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<p>Comparison of maturity level in Legacy System and Updated System.</p>
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16 pages, 9676 KiB  
Article
Analysis of Falling Block Characteristics in Salt Caverns Energy Storage Space
by Shengwei Dong, Taian Fang, Jifang Wan, Shan Wang, Yanqi Zhao, Xiaowen Chen, Xiaofeng Yang and Yangqing Sun
Energies 2025, 18(1), 215; https://doi.org/10.3390/en18010215 - 6 Jan 2025
Viewed by 315
Abstract
In the current global energy sector where energy storage technology is highly regarded, the development of storage technology is crucial. Utilizing specific underground space for the storage of oil and gas and other energy sources is the direction of future development, and the [...] Read more.
In the current global energy sector where energy storage technology is highly regarded, the development of storage technology is crucial. Utilizing specific underground space for the storage of oil and gas and other energy sources is the direction of future development, and the space formed by deep-salt-mine water dissolution extraction has gradually become the preferred choice. However, in actual operation, multi-layer salt cavities are prone to collapse of interlayer and bending of pipes, seriously affecting the progress, quality, and safety of the entire energy storage space construction. Therefore, based on relevant principles, a targeted experimental platform was established, by taking photos and measurements of the falling process of specific falling objects, simulating the situation of falling objects in actual energy storage spaces and their impact on related components. In-depth research was conducted on the probability of falling objects hitting the inner pipe and the horizontal impact force under different conditions, and the experimental results were verified by rigorous numerical simulation analysis. The research results show that falling objects impacts can cause related components to bend, with the maximum impact probability reaching 5.1% and the maximum horizontal impact force reaching 24.6 N. In addition, the hydraulic fluctuations caused by the suction and drainage of the cavity pipe column have a relatively small impact on the falling object trajectory. The research findings can provide practical and effective guidance for the safe construction of specific energy storage facilities, ensuring that construction can be carried out safely and efficiently, and contribute to the steady development of the energy storage industry as a whole. Full article
(This article belongs to the Special Issue The Technology of Oil and Gas Production with Low Energy Consumption)
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<p>Schematic diagram of the experimental principle and procedure: (<b>a</b>) experimental principle and (<b>b</b>) experimental procedure.</p>
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<p>Experimental flume: (<b>a</b>) side view and (<b>b</b>) vertical view.</p>
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<p>Falling block model.</p>
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<p>Six-component force sensor.</p>
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<p>Structure of the model device.</p>
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<p>Motion observation camera position: (<b>a</b>) side view and (<b>b</b>) vertical view.</p>
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<p>Schematic diagram of the initial experimental conditions.</p>
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<p>Falling process of a flake-shaped block.</p>
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<p>Falling process of a cuboid block.</p>
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<p>Falling process of a cubic block.</p>
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<p>Typical horizontal impact force progression for a falling block.</p>
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<p>Influence of annular water discharge on small block movement.</p>
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<p>Grid range for the cavern mathematical model.</p>
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<p>Flow field distribution within the cylindrical cavern.</p>
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17 pages, 1378 KiB  
Article
Prototype Instrumentation for the Spatial and Temporal Characterisation of Voltage Supply Based on Two-Dimensional Higher-Order Statistics
by Juan-José González-de-la-Rosa, Olivia Florencias-Oliveros, José-María Sierra-Fernández, Manuel-Jesús Espinosa-Gavira, Agustín Agüera-Pérez, José-Carlos Palomares-Salas, Victor Pallarés-López, Rafael-Jesús Real-Calvo and Isabel Santiago-Chiquero
Energies 2025, 18(1), 175; https://doi.org/10.3390/en18010175 - 3 Jan 2025
Viewed by 346
Abstract
This paper presents a proof-of-concept of a versatile Power Quality (PQ) analyser for tracking the voltage supply in industrial and residential sectors. It implements 2D Higher-Order Statistics (HOS) to assess voltage quality, based more on the sinusoidal waveform than on power fluctuations. Beyond [...] Read more.
This paper presents a proof-of-concept of a versatile Power Quality (PQ) analyser for tracking the voltage supply in industrial and residential sectors. It implements 2D Higher-Order Statistics (HOS) to assess voltage quality, based more on the sinusoidal waveform than on power fluctuations. Beyond the second-order parameters and permissible deviations regulated by the norm, EN 50160, the two-dimensional traces and probability density functions, along with a previously studied differential index, manage to identify different states of the electrical grid. Waveforms were measured in the wall plugs of a public building. In regard to analysing reliability and voltage waveform, the results corroborate that incorporating skewness and kurtosis indicators improves the characterisation, as well as extracting the customers’ supply behaviour under normal and anomalous operations. The instrument showed good behaviour in site characterisation, and the implemented method was considered as a probabilistic approach for the risk assessment of an installation. The prototype was tested in the facilities of a public building of the university, being able to detect deviations in 10 s traces of 3.9% in variance and 0.6% in kurtosis. Full article
(This article belongs to the Special Issue Power Quality Monitoring with Energy Saving Goals)
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<p>Conceptual diagram that shows the location of the Virtual Instrument (the PQA) in the electrical network and the types of measurements that can be carried out. The variance-vs.-kurtosis graphs indicate the state of the network for different time windows.</p>
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<p>Two versions of the measurement chain. The set is connected (Ethernet) to a laptop computer, in which a <math display="inline"><semantics> <mrow> <mi>L</mi> <mi>a</mi> <mi>b</mi> <mi>V</mi> <mi>I</mi> <mi>E</mi> <msup> <mi>W</mi> <mrow> <mi>T</mi> <mi>M</mi> </mrow> </msup> </mrow> </semantics></math>-based program performs the analysis: (<b>a</b>) The single-phase version of the instrument consists of the chassis NI (<math display="inline"><semantics> <mrow> <mi>N</mi> <mi>a</mi> <mi>t</mi> <mi>i</mi> <mi>o</mi> <mi>n</mi> <mi>a</mi> <mi>l</mi> <mi>I</mi> <mi>n</mi> <mi>s</mi> <mi>t</mi> <mi>r</mi> <mi>u</mi> <mi>m</mi> <mi>e</mi> <mi>n</mi> <mi>t</mi> <msup> <mi>s</mi> <mrow> <mi>T</mi> <mi>M</mi> </mrow> </msup> </mrow> </semantics></math>) cDAQ-9188, in which the DAQ module-card NI-9125 is inserted. (<b>b</b>) Measurement chain with the NI-9225 module that substitutes the differential probe.</p>
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<p>Differential probe: (<b>a</b>) Differential probe <math display="inline"><semantics> <mrow> <mi>H</mi> <mi>A</mi> <mi>M</mi> <mi>E</mi> <msup> <mi>G</mi> <mrow> <mi>T</mi> <mi>M</mi> </mrow> </msup> </mrow> </semantics></math> model HZ-115, and chassis. (<b>b</b>) <math display="inline"><semantics> <mrow> <mi>N</mi> <msup> <mi>I</mi> <mrow> <mi>T</mi> <mi>M</mi> </mrow> </msup> </mrow> </semantics></math> c-DAQ 9191 chassis and <math display="inline"><semantics> <mrow> <mi>N</mi> <msup> <mi>I</mi> <mrow> <mi>T</mi> <mi>M</mi> </mrow> </msup> </mrow> </semantics></math> 9215 card (inside) that hosts the DAQ card model NI-9215.</p>
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<p>Acquisition panel of the VI, where the user starts or interrupts the acquisition.</p>
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<p>Configuration panel of the VI, where the user can set the ideal values of the statistics and range and the time to be accumulated in the 2D plots.</p>
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<p>Panel implementing the <span class="html-italic">energy trace</span> for the variance–kurtosis: one example of the energy trace from 1 week to 10 s window, previously set in the <span class="html-italic">Configuration</span> panel.</p>
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<p>Panel that implements the <span class="html-italic">energy trace</span> for the variance–kurtosis pairs. The centroid of the clusters (dashed cross) establishes the bias from the ideal operation state of the electrical network (continuous cross). The hourly graph shows a more stable network than in <a href="#energies-18-00175-f006" class="html-fig">Figure 6</a>.</p>
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<p>Flow diagram for the code that implements the trace of the statistics associated with the PQ behaviour.</p>
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<p>Histograms for the statistic estimators of variance, skewness and kurtosis obtained for averaging times of 1 h, 1 min and 10 s, respectively.</p>
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<p>The <math display="inline"><semantics> <mrow> <mi>L</mi> <mi>a</mi> <mi>b</mi> <mi>V</mi> <mi>I</mi> <mi>E</mi> <msup> <mi>W</mi> <mrow> <mi>T</mi> <mi>M</mi> </mrow> </msup> </mrow> </semantics></math> programming code that implements the 2D tool path tracing. The associated graphs are depicted in <a href="#energies-18-00175-f011" class="html-fig">Figure 11</a>.</p>
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<p>Variance vs. kurtosis 1-h trajectory.</p>
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<p>The <math display="inline"><semantics> <mrow> <mi>L</mi> <mi>a</mi> <mi>b</mi> <mi>V</mi> <mi>I</mi> <mi>E</mi> <msup> <mi>W</mi> <mrow> <mi>T</mi> <mi>M</mi> </mrow> </msup> </mrow> </semantics></math> programming code that implements the block <span class="html-italic">Trajectories from HOS</span> computing block, included in <a href="#energies-18-00175-f010" class="html-fig">Figure 10</a>.</p>
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<p>Behaviour of the measured frequency, in accordance with the UNE-EN 50160 standard. The measurement is displayed with a cycle-to-cycle cadence.</p>
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<p>Behaviour of the measured <math display="inline"><semantics> <msub> <mi>V</mi> <mrow> <mi>R</mi> <mi>M</mi> <mi>S</mi> </mrow> </msub> </semantics></math> in accordance with the UNE-EN 50160 standard. The measurement is displayed cycle-to-cycle.</p>
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26 pages, 22458 KiB  
Article
Coastal Sceneries of Albania, An Emerging 3S Destination: Analysis of Physical Characteristics and Human Activity Impacts
by Alfredo Fernández Enríquez, Alexis Mooser, Giorgio Anfuso and Javier García-Onetti
Land 2025, 14(1), 73; https://doi.org/10.3390/land14010073 - 2 Jan 2025
Viewed by 390
Abstract
The increase in tourism economic benefits is the most common purpose along the Mediterranean coastal regions but, very often, conflicts of interest arise between short-term benefits and long-term conservation goals. This is particularly the case of Albania, a very popular emerging “Sun, Sea [...] Read more.
The increase in tourism economic benefits is the most common purpose along the Mediterranean coastal regions but, very often, conflicts of interest arise between short-term benefits and long-term conservation goals. This is particularly the case of Albania, a very popular emerging “Sun, Sea and Sand” (3S) destination characterized by massive fluxes of national/international visitors during the summer period. Among beach users’ preferences, global studies show that five parameters of greater importance stand out from the rest, i.e., safety, facilities, water quality, no litter, and scenery, and the latter is the main concern of this study. Albania is well known for its outstanding natural coastal beauty which was assessed at 40 sites by using the Coastal Scenic Evaluation System (CSES) method. Based on the evaluation of 26 physical/human parameters and using weighting matrix parameters and fuzzy logic mathematics, the technique enables one to obtain an Evaluation Index (D) that allows one to classify each investigated site into five scenic classes, from Class I (extremely attractive natural sites; D ≥ 0.85) to Class V (very unattractive developed urban/industrial sites; D < 0.00). Pragmatically, the higher the “D” value is, the better the site scenery is. After a long process of field testing along the whole Albanian coastline (ca. 523 km in length), selected sites were chosen in rural/remote environments (22), villages (6), and urban (4) and resort areas (8) to reflect the Albanian coastal typicity and characterize the scenic impact of human activities. Most sites belonged to Class III (14), Class IV (13), Class II (8), and Class I (1). Several sites could be upgraded to Class I or Class II with slight management efforts, e.g., by carrying out cleaning operations or by reducing intrusive beach facilities. Full article
(This article belongs to the Special Issue Mediterranean Marine-Coastal Ecosystems: Changes and Dynamics)
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<p>Albania: location map (<b>a</b>); relief and hydrography (<b>b</b>).</p>
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<p>Location map of investigated sites including coastal counties, municipalities, administrative units (3rd level), and nationally designated/protected areas (CDDA).</p>
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<p>Site classification according to their evaluation index values ‘D’ and scenic classes (<b>A</b>); Site classification according to their beach typologies, i.e., rural, village, urban and resort areas—only a single beach were categorized as “remote”, i.e., Kakomes (<b>B</b>).</p>
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<p>Zvernec beach (<b>A</b>) and corresponding CSES rating (<b>B</b>); membership degree vs. rating (<b>C</b>); and weighted averages vs. rating (<b>D</b>).</p>
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<p>Tales beach (<b>A</b>) and corresponding CSES rating (<b>B</b>); membership degree vs. rating (<b>C</b>); and weighted averages vs. rating (<b>D</b>).</p>
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<p>Borsh beach (<b>A</b>) and corresponding CSES rating (<b>B</b>); membership degree vs. rating (<b>C</b>); and weighted averages vs. rating (<b>D</b>).</p>
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<p>Qeparo (<b>A</b>) and corresponding CSES rating (<b>B</b>); membership degree vs. rating (<b>C</b>); and weighted averages vs. rating (<b>D</b>).</p>
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<p>Shengjin (<b>A</b>) and corresponding CSES rating (<b>B</b>); membership degree vs. rating (<b>C</b>); and weighted averages vs. rating (<b>D</b>).</p>
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<p>Human parameters’ scores vs. typologies: Box plot including minimum and maximum D values, interquartile range, mean value (cross), and extreme values (point) for each investigated typology, i.e., rural, village, urban, and resort.</p>
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<p>Example of overcrowding resort beaches along the southern Albanian coast: Ksamil (<b>A</b>), Gjiri i Hartes (<b>B</b>), Plazhi i Pasqyrave (<b>C</b>), and Pema e Thate (<b>D</b>).</p>
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16 pages, 2261 KiB  
Article
Extractive Ethanol Fermentation with Ethanol Recovery by Absorption in Open and Closed Systems
by Kaio César da Silva Rodrigues, Ivan Ilich Kerbauy Veloso, Diego Andrade Lemos, Antonio José Gonçalves Cruz and Alberto Colli Badino
Fermentation 2025, 11(1), 12; https://doi.org/10.3390/fermentation11010012 - 2 Jan 2025
Viewed by 426
Abstract
Conventional ethanol production has limitations, including substrate and product inhibitions, which increase both energy requirements for ethanol recovery and vinasse generation. Extractive fermentation, which removes ethanol as it is produced within the fermentation vat, offers an effective alternative to reducing the inhibitory effects [...] Read more.
Conventional ethanol production has limitations, including substrate and product inhibitions, which increase both energy requirements for ethanol recovery and vinasse generation. Extractive fermentation, which removes ethanol as it is produced within the fermentation vat, offers an effective alternative to reducing the inhibitory effects in conventional processes. However, an efficient method for recovering the extracted ethanol is also crucial. Thus, this study investigated an alternative ethanol production process using extractive ethanol fermentation integrated with ethanol recovery by absorption in both open and closed systems, specifically, comparing scenarios with and without CO2 recirculation produced during fermentation. The recovery system used two absorbers connected in series using monoethylene glycol (MEG) as an absorbent. Under extractive fermentation conditions without CO2 recirculation, the conversion of 300.0 g L−1 of substrate resulted in a total ethanol concentration of 135.2 g L−1, which is 68% higher than that achieved in conventional fermentation (80.4 g L−1). The absorption recovery efficiency reached 91.6%. In the closed system, with CO2 recirculation produced by fermentation, 280.0 g L−1 of substrate was consumed, achieving ethanol production of 126.0 g L−1, with an absorption recovery percentage of 98.3%, similar to that of industrial facilities that use a gas scrubber tower. Additionally, the overall process efficiency was close to that of conventional fermentation (0.448 gethanol gsubstrate−1). These results highlight the potential of this alternative process to reduce vinasse volume and energy consumption for ethanol recovery, lowering total costs and making it a viable option for integrated distilleries that combines ethanol production with other related processing operations. Full article
(This article belongs to the Special Issue Bioprocesses for Biomass Valorization in Biorefineries)
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<p>Experimental apparatus used in fed-batch conventional fermentation (CF).</p>
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<p>Experimental apparatus used in fed-batch extractive fermentations without CO<sub>2</sub> recirculation (open system).</p>
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<p>Experimental apparatus used in fed-batch extractive fermentations with CO<sub>2</sub> recirculation (closed system). P1, P2, P3, P4, P5, and P6 represent pressure measurement points.</p>
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<p>Experimental (symbols) and simulated values (lines) of substrate (C<sub>S</sub>, circles), viable cells (C<sub>X</sub>, squares), and ethanol (C<sub>E</sub>, triangles) concentrations over time in conventional batch fermentation (CF, C<sub>ST</sub> = 180.0 g L<sup>−1</sup>).</p>
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<p>Experimental (symbols) and simulated values (lines) of substrate (C<sub>S</sub>, red circles), viable cells (C<sub>X</sub>, black squares), and ethanol (C<sub>E</sub>, blue triangles) concentrations over time in the extractive fermentations (<b>a</b>) EF1 and (<b>b</b>) EF2 (C<sub>ST</sub> = 180.0 and 300.0 g L<sup>−1</sup>, respectively) of the integrated process without CO<sub>2</sub> recirculation (open system).</p>
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<p>Experimental values of ethanol (black squares) concentrations over time in the absorbers (1st absorber—filled symbols, 2nd absorber—empty symbols) for the (<b>a</b>) EF1 and (<b>b</b>) EF2 fermentations (C<sub>ST</sub> = 180.0 and 300.0 g L<sup>−1</sup>, respectively). The arrows indicate the moments when the absorbers were replaced.</p>
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<p>Experimental values of substrate (C<sub>S</sub>, red circles), viable cells (C<sub>X</sub>, black squares), and ethanol (C<sub>E</sub>, blue triangles) concentrations over time in the extractive fermentations (<b>a</b>) EFR1 and (<b>b</b>) EFR2 (C<sub>ST</sub> = 180.0 and 280.0 g L<sup>−1</sup>, respectively) of the integrated process with CO<sub>2</sub> recirculation (closed system).</p>
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<p>Experimental values of ethanol concentration (black squares) over time in the first absorber (filled symbols) and second absorber (empty symbols) over extractive ethanol fermentations with CO<sub>2</sub> recirculation: (<b>a</b>) EFR1 (C<sub>ST</sub> = 180.0 g L<sup>−1</sup>) and (<b>b</b>) EFR2 (C<sub>ST</sub> = 280.0 g L<sup>−1</sup>). The arrows indicate the moments when the absorbers were replaced.</p>
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13 pages, 1979 KiB  
Article
Efficiency Analysis of the Integrated Application of Hazard Operability (HAZOP) and Job Safety Analysis (JSA) Compared to HAZOP Alone for Preventing Fire and Explosions in Chemical Plants
by Seungho Jung, Hangi Kim and Chankyu Kang
Processes 2025, 13(1), 88; https://doi.org/10.3390/pr13010088 - 2 Jan 2025
Viewed by 422
Abstract
Hazard and Operability (HAZOP) is the most widely used safety evaluation method because it systematically reviews the causes and results of all abnormal deviations in chemical plant facilities. However, fires and explosions caused by human error occur frequently. This study combined HAZOP and [...] Read more.
Hazard and Operability (HAZOP) is the most widely used safety evaluation method because it systematically reviews the causes and results of all abnormal deviations in chemical plant facilities. However, fires and explosions caused by human error occur frequently. This study combined HAZOP and JSA, a chemical plant risk assessment technique, to determine the effectiveness of preventing significant industrial accidents whereby fires and explosions injure workers. The effectiveness of the 96-step distillation container cleaning process was assessed by identifying risk factors, using three different methods: HAZOP, JSA and HAZOP, and HAZOP and JSA. After completing HAZOP, JSA was used to determine the most severe risk factors. Thirty-seven additional recommendations were discovered using the JSA for the storage container cleaning operation, which was not included in the risk factors identified through the HAZOP work process. For additional risks, factors directly related to fires and explosions were identified. It was concluded that HAZOP and JSA must be combined in high-risk processes to minimize the risk of fires and explosions. Full article
(This article belongs to the Special Issue Fire and Explosion in Process Safety Prevention and Protection)
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<p>(<b>a</b>) Process drawings for cleaning operations of storage containers used in a HAZOP study (marked as a red rectangle), and (<b>b</b>) process drawings used to conduct cleaning operations.</p>
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<p>(<b>a</b>) Risk matrix used for HAZOP, (<b>b</b>) description of criteria for determining severity, and (<b>c</b>) description of criteria for determining probability.</p>
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<p>HAZOP worksheet obtained using the PHAWorks program.</p>
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<p>Risk matrix applied when performing JSA (High (red) and Medium (blue): Enforcement of rapid safety measures, Low (yellow): compliance with safety regulations).</p>
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<p>Example of JSA analysis.</p>
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19 pages, 3368 KiB  
Article
Comprehensive Evaluation Method for Electric Vehicle Charging Network Service Quality Considering User Satisfaction
by Shukang Lyu, Yi Pan, Huiyu Miao, Xiaodong Yuan and Fei Zeng
World Electr. Veh. J. 2025, 16(1), 17; https://doi.org/10.3390/wevj16010017 - 30 Dec 2024
Viewed by 418
Abstract
With the rapid development of the electric vehicle (EV) industry, various issues, such as the suboptimal deployment of charging facilities and inadequate distribution, hinder improvements in user satisfaction with EVs. Moreover, the interests of multiple stakeholders, including power grid companies and transportation departments, [...] Read more.
With the rapid development of the electric vehicle (EV) industry, various issues, such as the suboptimal deployment of charging facilities and inadequate distribution, hinder improvements in user satisfaction with EVs. Moreover, the interests of multiple stakeholders, including power grid companies and transportation departments, are not sufficiently addressed. To tackle these challenges, this paper proposes a comprehensive evaluation method for EV charging network service quality that integrates user satisfaction. First, considering the coupled dynamics of the EV charging network, we construct a service quality evaluation index system. Then, using a combination of the entropy weight method (EWM) and the analytic hierarchy process (AHP) with game theory, we determine the composite weights for the index system. Finally, we use the improved R-method evaluation model to theoretically verify the charging network in a particular area. The results show that the evaluation method proposed in this paper realizes differentiated evaluation for different planning schemes, highlights the weak links in the operation process of the charging network, and provides a theoretical reference for decision making about charging station planning. Full article
(This article belongs to the Special Issue Smart Charging Strategies for Plug-In Electric Vehicles)
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<p>Electric vehicle charging network service quality index system.</p>
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<p>The framework of the evaluation model.</p>
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<p>The coupling system of the transportation network and distribution network.</p>
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<p>The number of electric vehicles in each period of summer weekend at each charging station.</p>
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<p>Traffic performance index variations of the summer weekend and winter weekend.</p>
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<p>Voltage distribution before and after the charging load is connected on the summer weekend.</p>
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<p>Voltage distribution before and after the charging load is connected on the winter weekends.</p>
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<p>Comprehensive evaluation score.</p>
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20 pages, 4737 KiB  
Article
Multi-Stage Hybrid Planning Method for Charging Stations Based on Graph Auto-Encoder
by Andrew Y. Wu, Juai Wu and Yui-yip Lau
Electronics 2025, 14(1), 114; https://doi.org/10.3390/electronics14010114 - 30 Dec 2024
Viewed by 401
Abstract
To improve the operational efficiency of electric vehicle (EV) charging infrastructure, this paper proposes a multi-stage hybrid planning method for charging stations (CSs) based on graph auto-encoder (GAE). First, the network topology and dynamic interaction process of the coupled “Vehicle-Station-Network” system are characterized [...] Read more.
To improve the operational efficiency of electric vehicle (EV) charging infrastructure, this paper proposes a multi-stage hybrid planning method for charging stations (CSs) based on graph auto-encoder (GAE). First, the network topology and dynamic interaction process of the coupled “Vehicle-Station-Network” system are characterized as a graph-structured model. Second, in the first stage, a GAE-based deep neural network is used to learn the graph-structured model and identify and classify different charging station (CS) types for the network nodes of the coupled system topology. The candidate CS set is screened out, including fast-charging stations (FCSs), fast-medium-charging stations, medium-charging stations, and slow-charging stations. Then, in the second stage, the candidate CS set is re-optimized using a traditional swarm intelligence algorithm, considering the interests of multiple parties in CS construction. The optimal CS locations and charging pile configurations are determined. Finally, case studies are conducted within a practical traffic zone in Hong Kong, China. The existing CS planning methods rely on simulation topology, which makes it difficult to realize efficient collaboration of charging networks. However, the proposed scheme is based on the realistic geographical space and large-scale traffic topology. The scheme determines the station and pile configuration through multi-stage planning. With the help of an artificial intelligence (AI) algorithm, the user behavior characteristics are captured adaptively, and the distribution rule of established CSs is extracted to provide support for the planning of new CSs. The research results will help the power and transportation departments to reasonably plan charging facilities and promote the coordinated development of EV industry, energy, and transportation systems. Full article
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<p>Overall architecture of the proposed multi-stage hybrid planning method for CSs.</p>
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<p>Loss function for training with different GCLs.</p>
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<p>Classification accuracy of the proposed GAE method for candidate CS nodes.</p>
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<p>Identification result of the candidate CS nodes.</p>
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<p>PSO-based iterative process of CS planning.</p>
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<p>Relationship between the total cost and quantity of CS planning.</p>
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<p>Distribution results of the optimal hybrid planning for CSs.</p>
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<p>Heat map of spatial distribution of pre-post-planning charging demand. (<b>a</b>) Spatial distribution of pre-planning charging demand. (<b>b</b>) Spatial distribution of post-planning charging demand.</p>
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<p>Average traveling and charging costs of users of pre-post-planning.</p>
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<p>Comparison of distribution network loads for different planning methods.</p>
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<p>Comparison of node voltages for different planning methods.</p>
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12 pages, 2493 KiB  
Article
Tungsten Carbide/Tungsten Oxide Catalysts for Efficient Electrocatalytic Hydrogen Evolution
by Jian Ouyang, Yu Sun, Yiqiong Zhang, Juzhe Liu, Xin Bo and Zenglin Wang
Molecules 2025, 30(1), 84; https://doi.org/10.3390/molecules30010084 - 29 Dec 2024
Viewed by 425
Abstract
Catalyzing hydrogen evolution reaction (HER) is a key process in high-efficiency proton exchange membrane water electrolysis (PEMWE) devices. To replace the use of Pt-based HER catalyst, tungsten carbide (W2C) is one of the most promising non-noble-metal-based catalysts with low cost, replicable [...] Read more.
Catalyzing hydrogen evolution reaction (HER) is a key process in high-efficiency proton exchange membrane water electrolysis (PEMWE) devices. To replace the use of Pt-based HER catalyst, tungsten carbide (W2C) is one of the most promising non-noble-metal-based catalysts with low cost, replicable catalytic performance, and durability. However, the preparation access to scalable production of W2C catalysts is inevitable. Herein, we introduced a facile protocol to achieve the tungsten carbide species by plasma treatment under a CH4 atmosphere from the WO3 precursor. Moreover, the heterogeneous structure of the tungsten carbide/tungsten oxide nanosheets further enhances the catalytic activity for HER with the enlarged specific surface area and the synergism on the interfaces. The prepared tungsten carbide/tungsten oxide heterostructure nanosheets (WO3-x-850-P) exhibit exceptional HER catalytic activity and stable longevity in acid electrolytes. This work provides a facile and effective method to construct high-performance and non-precious-metal-based electrocatalysts for industrial-scale water electrolysis. Full article
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<p>Preparation diagram of tungsten carbide/tungsten oxide heterostructure nanosheets.</p>
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<p>SEM images of WO<sub>3</sub> (<b>a</b>), WO<sub>3-x</sub>-850-P (<b>b</b>), Raman and (<b>c</b>), XRD patterns of WO<sub>3</sub> (<b>d</b>), WO<sub>3-x</sub>-850 (<b>e</b>), WO<sub>3-x</sub>-850-P (<b>f</b>), respectively.</p>
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<p>XPS spectra of (<b>a</b>,<b>d</b>,<b>g</b>) W 4f, (<b>b</b>,<b>e</b>,<b>h</b>) O 1s, and (<b>c</b>,<b>f</b>,<b>i</b>) C 1s for WO<sub>3-x</sub>-850-P, WO<sub>3-x</sub>-850, and WO<sub>3</sub>. Cyan, W<sup>6+</sup>; Orange, satellite peaks of W<sup>6+</sup>; Violet, W<sup>4+</sup>; Green, W<sup>2+</sup>.</p>
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<p>HER performance of WO<sub>3-x</sub>-850-P, WO<sub>3-x</sub>-850, and WO<sub>3</sub> catalysts in 0.5 M H<sub>2</sub>SO<sub>4</sub>. (<b>a</b>) Polarization curves; (<b>b</b>) the corresponding Tafel slopes; (<b>c</b>) durability measurement of the WO<sub>3-x</sub>-850-P catalyst at the applied potential of −0.17 V vs. RHE; (<b>d</b>) Nyquist of WO<sub>3</sub>, WO<sub>3-x</sub>-850 and WO<sub>3-x</sub>-850-P.</p>
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22 pages, 2704 KiB  
Article
Shanghai as a Model: Research on the Journey of Transportation Electrification and Charging Infrastructure Development
by Cong Zhang, Jingchao Lian, Haitao Min and Ming Li
Sustainability 2025, 17(1), 91; https://doi.org/10.3390/su17010091 - 26 Dec 2024
Viewed by 447
Abstract
As the world pivots to a greener paradigm, Shanghai emerges as an archetype in the sustainable urban transit narrative, particularly through the aggressive expansion and refinement of its electric vehicle (EV) charging infrastructure. This scholarly article provides a comprehensive examination of the current [...] Read more.
As the world pivots to a greener paradigm, Shanghai emerges as an archetype in the sustainable urban transit narrative, particularly through the aggressive expansion and refinement of its electric vehicle (EV) charging infrastructure. This scholarly article provides a comprehensive examination of the current state of charging infrastructure in Shanghai, highlighting the challenges that the existing infrastructure may face in light of the burgeoning electric vehicle market. This paper delves into the strategic development approaches adopted by Shanghai to address these challenges, particularly emphasizing the expansion of high-power charging infrastructure to meet the anticipated increase in future electric vehicle charging demands. It also discusses the implementation of co-construction and sharing models, the enhancement of interconnectivity and standardized management of charging facilities, and the continuous improvement and strengthening of infrastructure construction and operations. Furthermore, this article explores the implementation of time-of-use electricity pricing policies and the ongoing conduct of demand response activities, which are instrumental in creating conditions for vehicle-to-grid interaction. The aim of our presentation is to foster a keen understanding among policymakers, industry stakeholders, and urban planners of the mechanisms necessary to effectively navigate the emerging electric vehicle market, thereby encouraging harmonious development between metropolises and transportation systems. Future research endeavors should delve into the realms of fast-charging technologies, intelligent operation and maintenance of charging infrastructure, and vehicle-to-grid interaction technologies. These areas of study are pivotal in fostering the harmonious development of electric vehicles (EVs) and their charging infrastructure, thereby aligning with the dual objectives of advancing urban transportation systems and sustainable green city development. The findings presented herein offer valuable insights for policymakers, urban planners, and industry leaders, guiding them in crafting informed strategies that not only address the immediate needs of the EV market but also lay the groundwork for a scalable and resilient charging infrastructure, poised to support the long-term vision of sustainable urban mobility. Full article
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<p>EV registrations and sales share in Europe, 2015–2023.</p>
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<p>The new energy vehicle sales volume for China and the world.</p>
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<p>Shanghai’s stock of new energy vehicles.</p>
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<p>The stock of public chargers in Shanghai.</p>
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<p>Vehicle-to-charger ratios for Shanghai and typical countries.</p>
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<p>Shanghai new energy vehicle travel time distribution (24 h).</p>
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<p>Historical average charging duration/hours.</p>
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<p>Shanghai new energy vehicle average daily travel duration (hours).</p>
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<p>Shanghai new energy vehicle average daily travel distance (km) distribution.</p>
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<p>Distribution of electric vehicle travel time in different cities.</p>
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<p>Peak demand from NEV charging (year: 2023).</p>
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<p>Peak electricity load in Shanghai during the summer from 2018 to 2022.</p>
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<p>Spatial distribution of charging capacity.</p>
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<p>The time utilization efficiency of charging facilities in Shanghai.</p>
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<p>Compensation funds and prices for residential demand response.</p>
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21 pages, 2730 KiB  
Article
Application of Life Cycle Assessment to Policy Environmental Impact Assessment—A Clean Energy Action Plan Case Study in Qinghai Region
by Yuan Li, Paul P. J. Gaffney, Fang Zhao, Xiangbo Xu and Mingbo Zhang
Sustainability 2025, 17(1), 84; https://doi.org/10.3390/su17010084 - 26 Dec 2024
Viewed by 485
Abstract
Due to significant political and environmental decisions regarding clean energy, rapid adoption of solar photovoltaic (PV), wind power, and hydropower is taking place. In China, policy environmental impact assessment (EIA) plays an important role in pollution prevention, while its practice is relatively limited [...] Read more.
Due to significant political and environmental decisions regarding clean energy, rapid adoption of solar photovoltaic (PV), wind power, and hydropower is taking place. In China, policy environmental impact assessment (EIA) plays an important role in pollution prevention, while its practice is relatively limited due to insufficient methodologies and weak legislative enforcement. Taking the clean energy action plan (CEAP) in the Qinghai region as a case study, this study explored the application of life cycle assessment (LCA) to evaluate the potential environmental impacts imposed by the installment capability of 70,000 MW solar PV in pristine areas. It was found that the CO2 emissions of solar PV are less than 3% of that of clean coal-fired power, while the emissions of pollutants such as sulfur dioxide, nitrogen oxides, and particulate matter only account for about 18~27% of coal-fired power. Meanwhile, from the full life cycle perspective, 4.61 million tons of solar PV panel waste will be generated, and 4172 square kilometers of land surface area will be occupied. Herein, implications for policy are proposed, including (1) advance planning of local waste disposal capacity and processing facilities, (2) the integration of clean energy planning with legal ecological environment protection schemes, and (3) rational planning of upstream and downstream solar PV industries. Full article
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<p>LCA framework flowchart.</p>
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<p>The life cycle of solar PV polysilicon power system boundaries. Note: the dashed line represents the system boundary, raw materials and energy are the inputs of this system, and pollutant emissions and electricity are the outputs.</p>
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<p>The full life cycle of coal-fired power system boundaries.</p>
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<p>The proportion of energy consumption, pollutants, and CO<sub>2</sub> emissions at different processes of solar PV power during the full life cycle.</p>
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<p>The land occupation area of solar PV power imposed by the CEAP.</p>
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<p>The amount of EOL solar PV panels imposed by the CEAP.</p>
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<p>The reduction in CO<sub>2</sub> emissions for solar PV power imposed by the CEAP.</p>
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31 pages, 7282 KiB  
Review
Ensuring Safety and Reliability: An Overview of Lithium-Ion Battery Service Assessment
by Cezar Comanescu
Batteries 2025, 11(1), 6; https://doi.org/10.3390/batteries11010006 - 25 Dec 2024
Viewed by 461
Abstract
Lithium-ion batteries (LIBs) are fundamental to modern technology, powering everything from portable electronics to electric vehicles and large-scale energy storage systems. As their use expands across various industries, ensuring the reliability and safety of these batteries becomes paramount. This review explores the multifaceted [...] Read more.
Lithium-ion batteries (LIBs) are fundamental to modern technology, powering everything from portable electronics to electric vehicles and large-scale energy storage systems. As their use expands across various industries, ensuring the reliability and safety of these batteries becomes paramount. This review explores the multifaceted aspects of LIB reliability, highlighting recent advancements and ongoing challenges. The importance of safety has been underscored by numerous incidents, such as the well-known smartphone battery explosions and more than 10,000 fires a year at facilities throughout Australia, both linked to LIB failures. These events emphasize the need for robust reliability and safety measures to ensure consistent performance and longevity. Factors like battery chemistry, design, manufacturing, and operating conditions can all influence the reliability of LIBs. Despite their widespread use, the mechanisms of failure, failure rates, and consequences of LIB failures are still not well understood, raising significant safety concerns. Current reliability assessment techniques include experimental methods, computational models, and data-driven approaches. Emerging trends, such as advanced characterization techniques and standardized testing protocols, advocate for improved practices to enhance the reliability and safety of LIBs across all applications. Full article
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<p>Main aspects affecting battery reliability.</p>
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<p>(<b>a</b>) Illustration of HF scavenging and stabilization of PF5 by TMSNCS additive. (<b>b</b>) Comparison of capacity retention of NCM622/graphite full cells with and without the TMSNCS additive after storage at 60 °C for 14 days. (<b>c</b>) Cycle performance of the NCM622/graphite full cells with the baseline electrolyte and 0.1 wt% TMSNCS-containing electrolyte at 45 °C, a 2C charge rate, and a 1C discharge rate during 200 cycles. Reprinted with permission from [<a href="#B75-batteries-11-00006" class="html-bibr">75</a>].</p>
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<p>(<b>a</b>) Energy diagrams for the formation of POF3 from PF<sub>5</sub> and Li<sub>2</sub>CO<sub>3</sub>. LiPOF4 forms via simultaneous elimination of LiF and CO<sub>2</sub> from a PF<sub>5</sub>-Li<sub>2</sub>CO<sub>3</sub> adduct. LiPOF4 can then eliminate LiF to form POF3. (<b>b</b>) Reactions between POF3 and simple inorganic carbonates Li<sub>2</sub>CO<sub>3</sub> to form CO<sub>2</sub> and LiPF<sub>2</sub>O<sub>2</sub>. (<b>c</b>) Possible routes for the re-formation of POF3 from LiPF<sub>2</sub>O<sub>2</sub> [<a href="#B76-batteries-11-00006" class="html-bibr">76</a>]. Color codes: red (oxygen), violet (lithium), orange (phosphorus), green (fluorine), black (carbon). Copyright © 2022 The Authors. Published by American Chemical Society. This publication is licensed under CC-BY 4.0.</p>
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<p>Key point in battery data workflow.</p>
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<p>Comprehensive framework from combined experimental and computational data.</p>
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<p>(<b>a</b>) Comparison between the model predicted and experimental battery capacity at 1C charge/discharge cycling at the battery operation temperature of 35 °C. (<b>b</b>) Degradation of battery capacity as a function of the discharge and charge cycles for isothermal discharge/charge rate at 1C at various battery operation temperatures, at normalized capacity. Reproduced with permission from [<a href="#B96-batteries-11-00006" class="html-bibr">96</a>].</p>
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<p>XRD patterns of different cathodes after 1 and 100 charge/discharge cycles: (<b>a</b>) bare NCM622, (<b>b</b>) NCM@LFP. Reproduced under a Creative Commons Attribution-Noncommercial 3.0 Unported License from [<a href="#B97-batteries-11-00006" class="html-bibr">97</a>].</p>
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<p>(<b>a</b>) In situ light microscopy of needle-like lithium growth in 1 M LiPF<sub>6</sub> electrolyte. The structure of image (<b>a</b>) (traced in white) remains unchanged, while more segments are added at the base of the structure as shown in the subsequent pictures, i.e., the images demonstrate that in this case, the growth occurred exclusively at the base of the needle. A kink forms in (<b>c</b>) and is marked by an arrow. Image (<b>b</b>) was taken 15 s, (<b>c</b>) 180 s, and (<b>d</b>) 450 s after figure (<b>a</b>) was recorded; (<b>e</b>) SEM image (1 kV) of lithium filaments deposited on tungsten at −100 mV. Several filaments show structures at the tip, e.g., contrast changes, contaminants such as particles, or a broadening of the tip. (<b>f</b>) In situ light microscopy of needle-like growth in 1 M LiPF6 on a lithium substrate. The view on the tip and the base of the needle is obstructed by other lithium structures; three straight segments connected by two kinks can be seen. Images (<b>g</b>,<b>h</b>) show that the segment between the kinks grew in length (marked by white arrow). Image (<b>g</b>) was taken after 45 s, and (<b>h</b>) after 135 s. Reproduced with permission from [<a href="#B98-batteries-11-00006" class="html-bibr">98</a>].</p>
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<p>The SOC-OCV curves of the LIBs obtained under different discharge conditions: (<b>a</b>) when the battery is discharged at 1C, and (<b>b</b>) when the battery is discharged with a different current; (<b>c</b>) degradation prediction results obtained when the cells operate at a constant temperature. Reproduced with permission from [<a href="#B99-batteries-11-00006" class="html-bibr">99</a>].</p>
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<p>World map with representative safety standards in highly industrialized countries.</p>
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<p>Main factors related to LIB integration into an end product and the two major influences on its overall performance, safety, and reliability: software control and environment/external factors.</p>
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<p>Further innovation expected for LIB technology.</p>
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17 pages, 4652 KiB  
Article
Using Food Industry Byproduct to Stabilize an Expansive Clay
by Nicole L. Shaw, Arvin Farid and Zahra Taheri Sarteshnizi
Waste 2025, 3(1), 1; https://doi.org/10.3390/waste3010001 - 24 Dec 2024
Viewed by 390
Abstract
The process of purifying agricultural products, at various food processing plants, generates waste materials that consist of precipitated calcium carbonate, organic debris, and trace amounts of soil and agricultural contaminants. A specific food-processing waste, hereafter referred to as a food industry byproduct, FIBP, [...] Read more.
The process of purifying agricultural products, at various food processing plants, generates waste materials that consist of precipitated calcium carbonate, organic debris, and trace amounts of soil and agricultural contaminants. A specific food-processing waste, hereafter referred to as a food industry byproduct, FIBP, is typically stockpiled on land adjacent to the corresponding food processing facilities due to its large volume and chemical composition. The FIBP also contains commercially available unspent lime products, which makes its reuse viable in various applications. An example is construction applications where an organic content of up to 5% by weight is allowed, such as treating expansive clays. Traditionally, lime stabilization has been used for improving the properties of expansive clays, where ground improvement methods are necessary for a large area. However, the process of producing lime is resource- and energy-intensive as it includes crushing and heating limestone in kilns to extract lime. Therefore, one specific doubly sustainable application is the treatment of expansive clays using the FIBP instead of lime. The main application tested here is the treatment of expansive clayey soils underneath a stretch of State Highway 95 near Marsing, ID. Other potential applications are in road and embankment construction. To evaluate the potential of expansive clay stabilization utilizing the FIBP, a series of geotechnical and environmental laboratory testing were conducted to measure the engineering properties (e.g., swell potential, permeability, and strength properties) of expansive clay amended with FIBP. Preliminary testing on blends with an expansive clay suggests benefits such as decreased swelling potential, increased density, and leachate immobilization. Full article
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<p>(<b>a</b>) FIBP-amended road base. (<b>b</b>) Finished gravel surface upon project completion.</p>
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<p>(<b>a</b>) FIBP in powdery and clumped forms. (<b>b</b>) Expansive clay.</p>
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<p>Hydrometer analysis for all samples.</p>
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<p>Combined moisture–density results for all samples.</p>
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<p>(<b>a</b>) Optimum moisture trends. (<b>b</b>) Maximum dry-density trends.</p>
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<p>Direct shear test data to demonstrate how peak effective stress points are selected.</p>
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<p>Mohr–Coulomb failure parameters were measured for all blends.</p>
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<p>Unconfined compressive strength trends for all samples.</p>
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<p>Hydraulic conductivity trends.</p>
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<p>Hydraulic conductivity trends with outlier removed.</p>
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<p>Experimental setup (permeameters) for measuring hydraulic conductivity.</p>
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<p>Swell strain trends.</p>
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<p>Experimental setup (consolidation testing apparatus) used for swell tests.</p>
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<p>Final evaluation of FIBP blends based on strength and swelling properties (Arrow colors correspond to the colors of the bar chart).</p>
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