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Search Results (63,084)

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22 pages, 6234 KiB  
Article
Alkali-Polymer Flooding in an Austrian Brownfield: From Laboratory to Field—Insights
by Muhammad Tahir, Rafael Hincapie, Torsten Clemens, Dominik Steineder, Amir Farzaneh and Silvan Mikulic
Polymers 2024, 16(24), 3607; https://doi.org/10.3390/polym16243607 (registering DOI) - 23 Dec 2024
Abstract
We focus on optimizing oil displacement in brownfields using alkali polymers (AP) flooding. The goal is to enhance rock–fluid and fluid–fluid interactions to improve oil recovery. The evaluation includes detailed screening of AP mixtures to ensure cost-effectiveness and maximize chemical slug efficiency, using [...] Read more.
We focus on optimizing oil displacement in brownfields using alkali polymers (AP) flooding. The goal is to enhance rock–fluid and fluid–fluid interactions to improve oil recovery. The evaluation includes detailed screening of AP mixtures to ensure cost-effectiveness and maximize chemical slug efficiency, using an AP pilot project in Austria as a case study. Key aspects of the study involve assessing fluid properties to select appropriate chemical concentrations. Important parameters include the stability of produced emulsions, interfacial tension (IFT) measurements, and rheological analyses. Rock–fluid interactions were examined through core flooding experiments on both low- and high-permeability core plugs to understand fluid dynamics in heterogeneous reservoirs. A novel part of the research involved simulating the in situ aging of the AP slug, which increases its anionicity over time. Two-phase core flooding with aged chemicals provided insights into the evolution of chemical effectiveness and interactions. We found that an alkali concentration of 7500 ppm was optimal for the AP slug, particularly in its interaction with dead oil with a high total acid number (TAN), leading to emulsions with microscopic instability. Single-phase core flooding showed that the AP slug from Vendor B outperformed that from Vendor A despite mechanical stability issues. However, the additional recovery factor (RF) for polymer A-based slugs was higher in both high- and low-permeability core plugs. The findings suggest that in situ aging of the AP slug could reduce costs and enhance injection performance. Full article
(This article belongs to the Section Polymer Applications)
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<p>Impact of increasing alkali concentration on the increase in pH value.</p>
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<p>Experimental setup used for injectivity tests.</p>
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<p>IFT measurements for AP slugs and two base cases without alkali (Polymer A and soft 8 TH WTP Brine).</p>
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<p>Produced emulsions on Day 2 for Polymer A-based AP slug. Three samples are for the same AP slug to consider the error bar in <a href="#polymers-16-03607-f005" class="html-fig">Figure 5</a>.</p>
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<p>Change in produced emulsion volume versus time (days) measured in glass pipettes.</p>
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<p>Change in emulsion viscosity measured over time (days) at a shear rate of 7.94 s<sup>−1</sup> and temperature of 49 °C.</p>
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<p>Mechanical degradation rate (%) of AP slugs injected at an injection velocity of 10 ft/day.</p>
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<p>XRD analysis of low-permeability plugs for pre- and post-AP flooding conditions.</p>
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<p>XRD analysis of high-permeability plugs for pre- and post-AP flooding conditions.</p>
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<p>Two-phase core flood in high-permeability plugs using AP slugs from two vendors (aged and un-aged slugs).</p>
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<p>Two-phase core flood in low-permeability plugs using AP slugs from two vendors (aged and un-aged slugs).</p>
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<p>Results of low-permeability core floods with normalized pressure differential data.</p>
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<p>Injector-producer well pattern selected for AP pilot project [<a href="#B49-polymers-16-03607" class="html-bibr">49</a>].</p>
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<p>History production and Voidage Replacement Ratio (VRR) for the AP pattern area.</p>
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15 pages, 2582 KiB  
Article
A Long-Range and Low-Cost Emergency Radio Beacon for Small Drones
by Juana M. Martínez-Heredia, Jorge Olivera, Francisco Colodro, Manuel Bravo and Manuel R. Arahal
Drones 2024, 8(12), 785; https://doi.org/10.3390/drones8120785 (registering DOI) - 23 Dec 2024
Abstract
The increasing use of unmanned aerial vehicles (UAVs) in the commercial and recreational sectors has led to a heightened demand for effective recovery solutions after a crash, particularly for lightweight drones. This paper presents the development of a long-range and low-cost emergency radio [...] Read more.
The increasing use of unmanned aerial vehicles (UAVs) in the commercial and recreational sectors has led to a heightened demand for effective recovery solutions after a crash, particularly for lightweight drones. This paper presents the development of a long-range and low-cost emergency radio beacon designed specifically for small UAVs. Unlike traditional emergency locator transmitters (ELTs), our proposed beacon addresses the unique needs of UAVs by reducing size, weight, and cost, while maximizing range and power efficiency. The device utilizes a global system for mobile (GSM)-based communication module to transmit location data via short message service (SMS), eliminating the need for specialized receivers and expanding the operational range even in obstacle-rich environments. Additionally, a built-in global navigation satellite system (GNSS) receiver provides precise coordinates, activated only upon impact detection through an accelerometer, thereby saving power during normal operations. Experimental tests confirm the extended range, high precision, and compatibility of the prototype with common mobile networks. Cost-effective and easy to use, this beacon improves UAV recovery efforts by providing reliable localization data to users in real time, thus safeguarding the UAV investment. Full article
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<p>General structure of the proposed radio beacon system.</p>
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<p>General flowchart of the main program of the microcontroller.</p>
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<p>Prototype of the control circuit.</p>
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<p>Proposed radio beacon: (<b>a</b>) implemented prototype; (<b>b</b>) box container.</p>
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<p>The radio beacon prototype mounted on a multirotor for testing.</p>
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<p>Text message with the link to the location received during the accident drill and a map of the location.</p>
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23 pages, 13780 KiB  
Article
Intuitionistic Fuzzy Set Guided Fast Fusion Transformer for Multi-Polarized Petrographic Image of Rock Thin Sections
by Bowei Chen, Bo Yan, Wenqiang Wang, Wenmin He, Yongwei Wang, Lei Peng, Andong Wang and Li Chen
Symmetry 2024, 16(12), 1705; https://doi.org/10.3390/sym16121705 (registering DOI) - 23 Dec 2024
Abstract
The fusion of multi-polarized petrographic images of rock thin sections involves the fusion of feature information from microscopic images of rock thin sections illuminated under both plane-polarized and orthogonal-polarized light. During the fusion process of rock thin section images, the inherent high resolution [...] Read more.
The fusion of multi-polarized petrographic images of rock thin sections involves the fusion of feature information from microscopic images of rock thin sections illuminated under both plane-polarized and orthogonal-polarized light. During the fusion process of rock thin section images, the inherent high resolution and abundant feature information of the images pose substantial challenges in terms of computational complexity when dealing with massive datasets. In engineering applications, to ensure the quality of image fusion while meeting the practical requirements for high-speed processing, this paper proposes a novel fast fusion Transformer. The model leverages a soft matching algorithm based on intuitionistic fuzzy sets to merge redundant tokens, effectively mitigating the negative effects of asymmetric dependencies between tokens. The newly generated artificial tokens serve as brokers for the Query (Q), forming a novel lightweight fusion strategy. Both subjective visual observations and quantitative analyses demonstrate that the Transformer proposed in this paper is comparable to existing fusion methods in terms of performance while achieving a notable enhancement in its inference efficiency. This is made possible by the attention paradigm, which is equivalent to a generalized form of linear attention, and the newly designed loss function. The model has been experimented on with multiple datasets of different rock types and has exhibited robust generalization capabilities. It provides potential for future research in diverse geological conditions and broader application scenarios. Full article
(This article belongs to the Section Computer)
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<p>Thin section images of rocks of different species and polarization modes with a scaling dimension of 500 micrometer.</p>
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<p>Structure of the proposed fast rock thin sections image fusion broker Transformer.</p>
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<p>The diagrams on the <b>left</b> and <b>right</b> are respectively the schematic representations of the broker attention module and the linear attention module.</p>
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<p>The demonstration of the fusion process of various types of rock thin section images. Each row represents a set of rock data, while each column corresponds to an image category. “Pp” and “Op” are abbreviations for “plane-polarized” and “orthogonal polarization”, respectively. The small red circles represent feature markers that have been detected.</p>
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<p>The fusion results of images of dacitic crystal–lithic–vitric welded tuff by different models. (<b>a</b>) Nestfuse. (<b>b</b>) SEDRFuse. (<b>c</b>) DDcGAN. (<b>d</b>) DenseFuse. (<b>e</b>) DIDFuse. (<b>f</b>) U2Fusion. (<b>g</b>) STDFusion. (<b>h</b>) Our proposed model. The small red boxes are areas of significant difference that have been selected. The larger box is a zoomed-in display of the area, for a clearer comparison of the fusion effect.</p>
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<p>The fusion results of granite images by different models. (<b>a</b>) Nestfuse. (<b>b</b>) SEDRFuse. (<b>c</b>) DDcGAN. (<b>d</b>) DenseFuse. (<b>e</b>) DIDFuse. (<b>f</b>) U2Fusion. (<b>g</b>) STDFusion. (<b>h</b>) Our proposed model. The small red boxes are areas of significant difference that have been selected. The larger box is a zoomed-in display of the area, for a clearer comparison of the fusion effect.</p>
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<p>Fusion results for high- and low-resolution images: (<b>a</b>–<b>d</b>) show fused images with a resolution of 480 × 384, while (<b>e</b>–<b>h</b>) show fused images with a resolution of 1280 × 1024.</p>
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<p>Feature matching results: (<b>a</b>–<b>d</b>) show images with a resolution of 1280 × 1024, while (<b>e</b>–<b>h</b>) represent images with a resolution of 480 × 384. Red lines indicate correctly matched feature pairs.</p>
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<p>Correlation between the estimated spatial error and the Dice coefficient in three attention mechanisms: (<b>a</b>) Softmax, (<b>b</b>) Linear, and (<b>c</b>) Broker.</p>
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<p>Comparison of cumulative probability distributions for different loss functions on image fusion performance. The metrics represented by each graph are: (<b>a</b>) MI, (<b>b</b>) PSNR, (<b>c</b>) SF, (<b>d</b>) SSIM, (<b>e</b>) <math display="inline"><semantics> <msup> <mi>Q</mi> <mrow> <mi>A</mi> <mi>B</mi> <mo>/</mo> <mi>F</mi> </mrow> </msup> </semantics></math>, (<b>f</b>) CE, and (<b>g</b>) RMSE.</p>
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<p>Panels (<b>a</b>–<b>h</b>) represent the CEST MRI images acquired at saturation durations of 17, 25, 33, 52, 60, 68, 76, and 84 min, respectively. Panel (<b>i</b>) shows the output result obtained by fusing this series of images.</p>
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18 pages, 2967 KiB  
Article
Modified Biochar Adsorption Combined with Alkaline Solution Absorption for Sulfur-Containing Odor Gases Removal from Domestic Waste Transfer Stations
by Wei Wei, Ningjie Wang and Xiaolei Zhang
Separations 2024, 11(12), 361; https://doi.org/10.3390/separations11120361 (registering DOI) - 23 Dec 2024
Abstract
Odor emission has become a major issue in waste transfer stations. Hydrogen sulfide, methyl mercaptan (MM), and dimethyl disulfide (DMDS) are the main odorous gases. They have a low odor threshold and are difficult to remove. In this study, pine bark biochar was [...] Read more.
Odor emission has become a major issue in waste transfer stations. Hydrogen sulfide, methyl mercaptan (MM), and dimethyl disulfide (DMDS) are the main odorous gases. They have a low odor threshold and are difficult to remove. In this study, pine bark biochar was produced and modified with metal ions, including Ni2+, Ti2+, Mn2+, Zn2+, Mg2+, and Cu2+. It was then used for the removal of hydrogen sulfide, methyl mercaptan, and dimethyl disulfide. Among all modifications, the Cu2+ modified biochar showed the best sorption capacity, and the maximum sorption amounts were 20.50 mg/g for H2S, 36.50 mg/g for MM, and 57.98 mg/g for DMDS. To understand the adsorption, BET, SEM, and XPS of the original and modified biochar were performed. This illustrated that modification with Cu2+ increased the surface area and porosity, thus enhancing the adsorption capacity. In the alkaline absorption study, it was found that the removal of the three odor gases increased with the pH increase. Based on the results, a combined process called absorption–adsorption was established to treat the odor gas generated in a local waste transfer station. Thirty-one gas components were detected in the odor gas of the waste transfer station. The process proceeded for 30 days, and these gas components were not found in the effluent during treatment. Regarding H2S, MM, and DMDS, they were not detected even after 90 days. This indicates the high adsorption capacity of the modified biochar toward the three odor gases. In addition, the process is simple and easy to operate. This suggests that it is suitable for treating odor in places where there is no technician, and the odor needs efficient treatment. The study provides a feasible alternative for domestic waste transfer stations to control the odor problem. Full article
(This article belongs to the Topic Advances in Separation Engineering)
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<p>The deodorization system employed for the removal of H<sub>2</sub>S, MM, and DMDS.</p>
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<p>Removal of odor gases by chemical absorption under different conditions: (<b>a</b>) Scrubbing solution pH; (<b>b</b>) Empty bed residence time of the reactor; and (<b>c</b>) NaOH solution dosage.</p>
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<p>Removal of odor gases by chemical absorption under different conditions: (<b>a</b>) Scrubbing solution pH; (<b>b</b>) Empty bed residence time of the reactor; and (<b>c</b>) NaOH solution dosage.</p>
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<p>Biochar adsorption capacity: (<b>a</b>) Biochar modified with different metal ions; (<b>b</b>) Biochar modified with various concentrations of Cu<sup>2+</sup>; (<b>c</b>) Cu<sup>2+</sup>-modified biochar obtained at different combustion temperatures.</p>
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<p>Biochar adsorption capacity: (<b>a</b>) Biochar modified with different metal ions; (<b>b</b>) Biochar modified with various concentrations of Cu<sup>2+</sup>; (<b>c</b>) Cu<sup>2+</sup>-modified biochar obtained at different combustion temperatures.</p>
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<p>Characteristics of the original and modified biochar: (<b>a</b>) Nitrogen adsorption–desorption curve of biochar; (<b>b</b>) Pore size distribution from 0 to 300 nm; (<b>c</b>) Pore size distribution on a smaller scale compared to (<b>b</b>), which is from 0 to 4 nm.</p>
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<p>SEM analysis of the original and Cu<sup>2+</sup>-modified biochar.</p>
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<p>SEM analysis of the original and Cu<sup>2+</sup>-modified biochar.</p>
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<p>The XPS spectra of elements in the modified biochar before and after utilization in adsorption. (<b>a</b>,<b>b</b>) Original biochar with the appearance of observed elements; (<b>c</b>–<b>e</b>) Biochar after utilization in adsorption of H<sub>2</sub>S, MM, and DMDS, respectively.</p>
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17 pages, 7886 KiB  
Article
A Potent Antibacterial Peptide (P6) from the De Novo Transcriptome of the Microalga Aureococcus anophagefferens
by Kexin Zhang, Xiaoting Yin, Yu Huang, Chao Liu, Qingchun Zhang, Qing Liu, Senyu Wang, Wenwu Fei, Qiong Shi and Limei Qiu
Int. J. Mol. Sci. 2024, 25(24), 13736; https://doi.org/10.3390/ijms252413736 (registering DOI) - 23 Dec 2024
Abstract
Marine microalgae are a rich source of natural products, and their amino acid-based antimicrobial agents are usually obtained by enzymatic hydrolysis, which is inefficient and limits the research on antimicrobial peptides (AMPs) from microalgae. In this study, Aureococcus anophagefferens is used as a [...] Read more.
Marine microalgae are a rich source of natural products, and their amino acid-based antimicrobial agents are usually obtained by enzymatic hydrolysis, which is inefficient and limits the research on antimicrobial peptides (AMPs) from microalgae. In this study, Aureococcus anophagefferens is used as a model to predict antimicrobial peptides through high-throughput methods, and 471 putative peptides are identified based on the de novo transcriptome technique. Among them, three short peptides, P1, P6, and P7 were found to have antimicrobial activity against Escherichia coli, Staphylococcus aureus, Micro1coccus luteus, and yeast Pichia pastoris, and they showed no hemolytic activity even at higher concentrations up to 10 mg/mL. Especially P6, a 12-amino acid peptide with three positive charges, which exhibited the most significant microbicidal effect with the lowest MIC of 31.25 μg/mL against E. coli, and electron microscope observations showed the surface of P6 treated E. coli with granular protrusions and ruptures, suggesting that it likely caused cell death by directly destroying the bacterial cell membrane. This study may enrich the database of microalgal AMPs and demonstrate an efficient process for searching and validating microalgal source AMPs by combining computer analysis with bioactivity experiments. Full article
(This article belongs to the Special Issue Advances in Research on Antifungal Resistance)
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<p>Growth inhibition of various microorganisms by synthesized AMPs. (<b>A</b>) <span class="html-italic">E. coli</span> growth inhibition by P1. (<b>B</b>) <span class="html-italic">E. coli</span> growth inhibition by P6. (<b>C</b>) <span class="html-italic">E. coli</span> growth inhibition by P7. (<b>D</b>) <span class="html-italic">S. aureus</span> growth inhibition by P1. (<b>E</b>) <span class="html-italic">S. aureus</span> growth inhibition by P6. (<b>F</b>) <span class="html-italic">S. aureus</span> growth inhibition by P7. (<b>G</b>) <span class="html-italic">M. luteus</span> growth inhibition by P1. (<b>H</b>) <span class="html-italic">M. luteus</span> growth inhibition by P6. (<b>I</b>) <span class="html-italic">M. luteus</span> growth inhibition by P7. Three control groups were used in the assay. “<span class="html-italic">E. coli</span>, <span class="html-italic">S. aureus, M. luteus</span>” represents only microorganisms, “PBS” represents only PBS, and each peptide name represents only a single peptide. * denotes significant differences (<span class="html-italic">p</span> &lt; 0.01) between the treatment groups and the control group.</p>
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<p>Growth inhibition of <span class="html-italic">P. pastoris</span> by synthesized AMPs. (<b>A</b>) <span class="html-italic">P. pastoris</span> growth inhibition by P1. (<b>B</b>) <span class="html-italic">P. pastoris</span> growth inhibition by P6. (<b>C</b>) <span class="html-italic">P. pastoris</span> growth inhibition by P7. Three control groups were used in the assay. “<span class="html-italic">P. pastoris</span>” represents only <span class="html-italic">P. pastoris</span>, “PBS” represents only PBS, and each peptide name represents only a single peptide. * denotes significant differences (<span class="html-italic">p</span> &lt; 0.01) between the treatment groups and the control group.</p>
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<p>The hemolytic activity of synthesized AMPs. (<b>A</b>) Hemolytic activity of DMSO at different concentrations. (<b>B</b>) “P1” represents the hemolytic activity of peptide P1, “P6” represents the hemolytic activity of peptide P6, and “P7” represents the hemolytic activity of peptide P7. Two control groups were used in the assay. DMSO treatment was the positive control and 0.9% NaCl treatment was the negative control.</p>
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<p>Structure comparison of three peptides. (<b>A</b>) The predicted 3D structures of P1 (4fasD as template). (<b>B</b>) The predicted 3D structures of P6 (2w4lE as template). (<b>C</b>) The predicted 3D structures of P7 (3g8bB as template). (<b>D</b>) Helical wheel projections of P1. (<b>E</b>) Helical wheel projections of P6. (<b>F</b>) Helical wheel projections of P7, where the yellow circles refer to the hydrophobic amino acid residues, the blue ones to the cationic charged residues, the purple circles to the polar uncharged residues, the red circle to an aspartate residue, the pink circle to a glutamine residue, and the green circle to a proline residue. The black arrows indicate hydrophobic faces of the amphipathic structures.</p>
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<p>SEM observations of P6-treated <span class="html-italic">E. coli</span>. (<b>A</b>,<b>B</b>) The effect of PBS on <span class="html-italic">E. coli</span> observed at 2 h. (<b>C</b>,<b>D</b>) The effect of P6 on <span class="html-italic">E. coli</span> observed at 2 h. The red arrows indicate granular protrusions and the leakage of intracellular materials.</p>
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11 pages, 5362 KiB  
Article
Carbon Felts Uniformly Modified with Bismuth Nanoparticles for Efficient Vanadium Redox Flow Batteries
by Huishan Chen, Sen Li, Yongxin Zhao, Xinyue Li, Hui Zhao, Longzhen Cheng, Renting Li and Pengcheng Dai
Nanomaterials 2024, 14(24), 2055; https://doi.org/10.3390/nano14242055 (registering DOI) - 23 Dec 2024
Abstract
The integration of intermittent renewable energy sources into the energy supply has driven the need for large-scale energy storage technologies. Vanadium redox flow batteries (VRFBs) are considered promising due to their long lifespan, high safety, and flexible design. However, the graphite felt (GF) [...] Read more.
The integration of intermittent renewable energy sources into the energy supply has driven the need for large-scale energy storage technologies. Vanadium redox flow batteries (VRFBs) are considered promising due to their long lifespan, high safety, and flexible design. However, the graphite felt (GF) electrode, a critical component of VRFBs, faces challenges due to the scarcity of active sites, leading to low electrochemical activity. Herein, we developed a bismuth nanoparticle uniformly modified graphite felt (Bi-GF) electrode using a bismuth oxide-mediated hydrothermal pyrolysis method. The Bi-GF electrode demonstrated significantly improved electrochemical performance, with higher peak current densities and lower charge transfer resistance than those of the pristine GF. VRFBs utilizing Bi-GF electrodes achieved a charge-discharge capacity exceeding 700 mAh at 200 mA/cm2, with a voltage efficiency above 84%, an energy efficiency of 83.05%, and an electrolyte utilization rate exceeding 70%. This work provides new insights into the design and development of efficient electrodes, which is of great significance for improving the efficiency and reducing the cost of VRFBs. Full article
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<p>(<b>a</b>) The synthetic strategy; (<b>b</b>) SEM image; (<b>c</b>) TEM image and (<b>d</b>) HRTEM images of Bi-GF; (<b>e</b>) EDS elemental mapping; (<b>f</b>) XRD pattern of the Bi-GF; (<b>g</b>) Raman spectra of Bi-GF and GF.</p>
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<p>(<b>a</b>) The XPS survey spectrum; High-resolution XPS spectra of (<b>b</b>) C 1s and (<b>c</b>) Bi 4f for Bi-GF.</p>
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<p>CV curves of (<b>a</b>) positive electrode of Bi-GF and GF at 5 mV/s scanning rate; (<b>b</b>) negative electrode of Bi-GF and GF at 2 mV/s scanning rate; Nyquist plots of Bi-GF and GF (<b>c</b>) as positive electrodes; and (<b>d</b>) as negative electrodes.</p>
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<p>(<b>a</b>) Charge-discharge capacity curves of the Bi-GF electrode and GF electrode at a current density of 200 mA/cm<sup>2</sup>; (<b>b</b>) average voltage; (<b>c</b>) voltage loss.</p>
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<p>(<b>a</b>) The charge-discharge capacity curves of the Bi-GF electrode at different current densities; (<b>b</b>) voltage efficiency; (<b>c</b>) energy efficiency; (<b>d</b>) electrolyte utilization rate of Bi-GF and GF electrodes at different current densities.</p>
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<p>(<b>a</b>) Coulomb efficiency; (<b>b</b>) voltage efficiency (VE); (<b>c</b>) energy efficiency (EE); (<b>d</b>) discharge capacity and (<b>e</b>) capacity retention of Bi-GF and GF electrodes for 10 charge-discharge cycles; (<b>f</b>) VE and EE of the Bi-GF electrode after 500 charge-discharge cycles at 200 mA/cm<sup>2</sup> current density.</p>
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17 pages, 766 KiB  
Review
A Survey of Scenario Generation for Automated Vehicle Testing and Validation
by Ziyu Wang, Jing Ma and Edmund M-K Lai
Future Internet 2024, 16(12), 480; https://doi.org/10.3390/fi16120480 (registering DOI) - 23 Dec 2024
Abstract
This survey explores the evolution of test scenario generation for autonomous vehicles (AVs), distinguishing between non-adaptive and adaptive scenario approaches. Non-adaptive scenarios, where dynamic objects follow predetermined scripts, provide repeatable and reliable tests but fail to capture the complexity and unpredictability of real-world [...] Read more.
This survey explores the evolution of test scenario generation for autonomous vehicles (AVs), distinguishing between non-adaptive and adaptive scenario approaches. Non-adaptive scenarios, where dynamic objects follow predetermined scripts, provide repeatable and reliable tests but fail to capture the complexity and unpredictability of real-world traffic interactions. In contrast, adaptive scenarios, which adapt in real time to environmental changes, offer a more realistic simulation of traffic conditions, enabling the assessment of an AV system’s adaptability, safety, and robustness. The shift from non-adaptive to adaptive scenarios is increasingly emphasized in AV research, to better evaluate system performance in complex environments. However, generating adaptive scenario is more complex and faces challenges. These include the limited diversity in behaviors, low model interpretability, and high resource requirements. Future research should focus on enhancing the efficiency of adaptive scenario generation and developing comprehensive evaluation metrics to improve the realism and effectiveness of AV testing. Full article
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<p>Lane-changing ODD representation.</p>
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<p>Car-following ODD Representation.</p>
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<p>Test scenario category.</p>
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<p>Taxonomy of scenario generation methods.</p>
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<p>Cut-in scenario representation.</p>
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<p>Adaptive scenario generation framework.</p>
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24 pages, 5566 KiB  
Article
Validation of CRU TS v4.08, ERA5-Land, IMERG v07B, and MSWEP v2.8 Precipitation Estimates Against Observed Values over Pakistan
by Haider Abbas, Wenlong Song, Yicheng Wang, Kaizheng Xiang, Long Chen, Tianshi Feng, Shaobo Linghu and Muneer Alam
Remote Sens. 2024, 16(24), 4803; https://doi.org/10.3390/rs16244803 (registering DOI) - 23 Dec 2024
Abstract
Global precipitation products (GPPs) are vital in weather forecasting, efficient water management, and monitoring floods and droughts. However, the precision of these datasets varies considerably across different climatic regions and topographic conditions. Therefore, the accuracy assessment of the precipitation dataset is crucial at [...] Read more.
Global precipitation products (GPPs) are vital in weather forecasting, efficient water management, and monitoring floods and droughts. However, the precision of these datasets varies considerably across different climatic regions and topographic conditions. Therefore, the accuracy assessment of the precipitation dataset is crucial at the local scale before its application. The current study initially compared the performance of recently modified and upgraded precipitation datasets, including Climate Research Unit Time-Series (CRU TS v4.08), fifth-generation ERA5-Land (ERA-5), Integrated Multi-satellite Retrievals for GPM (IMERG) final run (IMERG v07B), and Multi-Source Weighted-Ensemble Precipitation (MSWEP v2.8), against ground observations on the provincial basis across Pakistan from 2003 to 2020. Later, the study area was categorized into four regions based on the elevation to observe the impact of elevation gradients on GPPs’ skills. The monthly and seasonal precipitation estimations of each product were validated against in situ observations using statistical matrices, including the correlation coefficient (CC), root mean square error (RMSE), percent of bias (PBias), and Kling–Gupta efficiency (KGE). The results reveal that IMERG7 consistently outperformed across all the provinces, with the highest CC and lowest RMSE values. Meanwhile, the KGE (0.69) and PBias (−0.65%) elucidated, comparatively, the best performance of MSWEP2.8 in Sindh province. Additionally, all the datasets demonstrated their best agreement with the reference data toward the southern part (0–500 m elevation) of Pakistan, while their performance notably declined in the northern high-elevation glaciated mountain regions (above 3000 m elevation), with considerable overestimations. The superior performance of IMERG7 in all the elevation-based regions was also revealed in the current study. According to the monthly and seasonal scale evaluation, all the precipitation products except ERA-5 showed good precipitation estimation ability on a monthly scale, followed by the winter season, pre-monsoon season, and monsoon season, while during the post-monsoon season, all the datasets showed weak agreement with the observed data. Overall, IMERG7 exhibited comparatively superior performance, followed by MSWEP2.8 at a monthly scale, winter season, and pre-monsoon season, while MSWEP2.8 outperformed during the monsoon season. CRU TS showed a moderate association with the ground observations, whereas ERA-5 performed poorly across all the time scales. In the current scenario, this study recommends IMERG7 and MSWEP2.8 for hydrological and climate studies in this region. Additionally, this study emphasizes the need for further research and experiments to minimize bias in high-elevation regions at different time scales to make GPPs more reliable for future studies. Full article
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<p><b>Left side</b>: topographical map demonstrating the geographic position of Pakistan, location of selected Pakistan Meteorological Department stations, administrative boundaries of provinces and elevations. <b>Right side</b>: map shows four defined regions based on the elevation gradient.</p>
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<p>Annual mean precipitation spatial distribution maps for the rain gauge observations and selected datasets.</p>
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<p>Columns 1, 2, 3, and 4 present box plots of the correlation, RMSE, KGE, and PBias, respectively. Additionally, the first, second, third, fourth, and fifth rows represent GB, KPK, Punjab, Sindh, and Balochistan, respectively. The orange line in the box plot shows the standard score for each measure.</p>
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<p>Scatter plots of the rain gauge observations and datasets at a monthly temporal scale across different provinces of Pakistan. Plot (<b>a</b>) show the monthly estimates in GB province, plot (<b>b</b>) represents KPK, (<b>c</b>) Punjab, (<b>d</b>) Sindh, (<b>e</b>) Balochistan, and plot (<b>f</b>) exhibits the average all over the country.</p>
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<p>Precipitation distribution pattern derived for all the seasons (winter, pre-monsoon, monsoon, and post-monsoon) using rain gauge data and selected datasets.</p>
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<p>Correlation boxplots (<b>a</b>–<b>e</b>) derived for selected datasets for the monthly, winter, pre-monsoon, monsoon, and post-monsoon seasons across Pakistan, respectively. The orange line in the box plot shows the standard score for each measure.</p>
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<p>RMSE boxplots (<b>a</b>–<b>e</b>) derived for selected datasets for the monthly, winter, pre-monsoon, monsoon, post-monsoon and seasons across Pakistan, respectively. The orange line in the box plot shows the standard score for each measure.</p>
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<p>PBias boxplots (<b>a</b>–<b>e</b>) derived for selected datasets for the monthly, winter, pre-monsoon, monsoon, and post-monsoon seasons across Pakistan, respectively. The orange line in the box plot shows the standard score for each measure.</p>
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<p>KGE boxplots (<b>a</b>–<b>e</b>) derived for selected datasets for the monthly, winter, pre-monsoon, monsoon, and post-monsoon seasons across Pakistan, respectively. The orange line in the box plot shows the standard score for each measure.</p>
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<p>Rows 1, 2, 3, and 4 present box plots of the correlation, RMSE, KGE, and PBias, respectively. Additionally, the first, second, third, and fourth columns represent region I, region II, region III, and region IV, respectively. The orange line in the plot shows the standard score for each measure.</p>
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<p>Time series plots for each province of Pakistan exhibit the level of fitness of the monthly scale precipitation estimates of the datasets with the ground observations.</p>
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16 pages, 2660 KiB  
Review
Enabling Catalysts for Carbonyl Sulfide Hydrolysis
by Xun Zhang, Xiaoyu Qiu and Rui Wang
Catalysts 2024, 14(12), 952; https://doi.org/10.3390/catal14120952 (registering DOI) - 23 Dec 2024
Abstract
Carbonyl sulfide (COS), an organosulfur compound commonly present in industrial gases, poses significant challenges for environmental protection and industrial processes due to its toxicity. This paper reviews recent advancements in the development of catalysts for COS hydrolysis, emphasizing the effects of various supports [...] Read more.
Carbonyl sulfide (COS), an organosulfur compound commonly present in industrial gases, poses significant challenges for environmental protection and industrial processes due to its toxicity. This paper reviews recent advancements in the development of catalysts for COS hydrolysis, emphasizing the effects of various supports and active components on catalyst performance, as well as the mechanisms underlying the hydrolysis reaction. Traditional supports like γ-Al2O3 demonstrate high activity for COS hydrolysis but are susceptible to deactivation. In contrast, novel supports such as activated carbon, TiO2, and ZrO2 have garnered attention for their unique structures and properties. The incorporation of active components, including alkali metals, alkaline earth metals, transition metals, and rare earth metals, significantly enhances the hydrolysis efficiency and resistance to deactivation of the catalysts. Additionally, this paper outlines three primary mechanisms for COS hydrolysis: the alkali-catalyzed mechanism, the Langmuir–Hinshelwood model, and the Eley–Rideal model mechanism, as well as the thiocarbonate intermediate mechanism, which collectively elucidate the conversion of COS into the H2S and CO2 catalyzed by these systems. Future research efforts will concentrate on developing high-activity, high-stability, and cost-effective COS hydrolysis catalysts, along with a more in-depth exploration of the reaction mechanisms to facilitate the efficient removal of COS from industrial emissions. Full article
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Graphical abstract

Graphical abstract
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<p>Catalytic COS process and possible side reactions. Reprinted with permission from the American Chemical Society [<a href="#B10-catalysts-14-00952" class="html-bibr">10</a>].</p>
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<p>Process flow chart of catalyst preparation. Reprinted with permission from Wiley [<a href="#B18-catalysts-14-00952" class="html-bibr">18</a>].</p>
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<p>Formation process of Al<sub>2</sub>O<sub>3</sub> hollow spheres. Reprinted with permission from Springer Netherlands [<a href="#B25-catalysts-14-00952" class="html-bibr">25</a>].</p>
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<p>(<b>a</b>) XRD patterns and (<b>b</b>) FT-IR spectra of fresh and used K<sub>2</sub>CO<sub>3</sub>/Al<sub>2</sub>O<sub>3</sub> catalyst; XPS spectra of fresh and used K<sub>2</sub>CO<sub>3</sub>/Al<sub>2</sub>O<sub>3</sub>: (<b>c</b>) survey, (<b>d</b>) Al 2p, (<b>e</b>) K 2p, and (<b>f</b>) S 2p. Reprinted with permission from Acta Physica Sinica [<a href="#B16-catalysts-14-00952" class="html-bibr">16</a>].</p>
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<p>The optimization results of K<sub>0.1</sub>Al<sub>2</sub>O<sub>3</sub> and N<sub>0.1</sub>K<sub>0.1</sub>Al<sub>2</sub>O<sub>3</sub>. Reprinted with permission from Elsevier [<a href="#B38-catalysts-14-00952" class="html-bibr">38</a>].</p>
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<p>The synthesis path of mAl<sub>2</sub>O<sub>3</sub> (<b>a</b>) and Fe<sub>3</sub>O<sub>4</sub>@C (<b>b</b>), and the operation process of the physical mixing catalyst under IH mode (<b>c</b>). Reprinted with permission from Elsevier [<a href="#B43-catalysts-14-00952" class="html-bibr">43</a>].</p>
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<p>The illustration of “Synergetic Mechanism”. Reprinted with permission from Wiley [<a href="#B53-catalysts-14-00952" class="html-bibr">53</a>].</p>
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42 pages, 19761 KiB  
Article
Aerodynamic Effect of Winglet on NREL Phase VI Wind Turbine Blade
by Ziaul Huque, Mahmood Sabria Chowdhury, Haidong Lu and Raghava Rao Kommalapati
Energies 2024, 17(24), 6480; https://doi.org/10.3390/en17246480 (registering DOI) - 23 Dec 2024
Abstract
The primary goal in designing wind turbine blades is to maximize aerodynamic efficiency. One promising approach to achieve this is by modifying the blade geometry, with winglets to the tip. Winglets are intended to reduce the strength of the tip vortices, thereby reducing [...] Read more.
The primary goal in designing wind turbine blades is to maximize aerodynamic efficiency. One promising approach to achieve this is by modifying the blade geometry, with winglets to the tip. Winglets are intended to reduce the strength of the tip vortices, thereby reducing induced drag, increasing torque, and, ultimately, improving the power output of the wind turbines. In this study, computational fluid dynamics (CFD) simulations were utilized to assess the aerodynamic performance of wind turbine blades with and without winglets at various wind speeds (5, 7, 10, 13, 15, 20, and 25 m/s). The results indicate that winglets have a limited effect at low (5 and 7 m/s) and high (20 and 25 m/s) wind speeds due to fully attached and separated flows over the blade surface. However, within the 10–15 m/s range, winglets significantly enhance torque and power output. While this increased power generation is beneficial, it is essential to consider the potential impact of the associated increase in thrust force on turbine stability. Full article
(This article belongs to the Special Issue Wind Turbine and Wind Farm Flows)
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<p>Schematic diagram of NREL Phase VI wind turbine blade.</p>
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<p>NREL Phase VI wind turbine blade design.</p>
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<p>Velocity and aerodynamic force coefficient conventions for S809 airfoil.</p>
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<p>CFD computational domain with main particulars.</p>
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<p>The 3D geometry of turbine blades modified with different winglets.</p>
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<p>Mesh generation of the entire domain and near the winglet.</p>
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<p>Cross-section view of surrounding grids at selected spanwise positions.</p>
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<p>Lift and drag coefficient distributions for 2D S809 airfoil.</p>
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<p>Spanwise angle of attack distribution at various wind speeds.</p>
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<p>The pressure coefficient contours over the span at a wind speed of 5 m/s.</p>
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<p>Pressure coefficient contours over the span at wind speed of 7 m/s.</p>
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<p>Pressure coefficient contours over the span at wind speed of 10 m/s.</p>
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<p>Pressure coefficient contours over the span at wind speed of 13 m/s.</p>
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<p>Pressure coefficient contours over the span at wind speed of 15 m/s.</p>
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<p>Pressure coefficient contours over the span at wind speed of 20 m/s.</p>
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<p>Pressure coefficient contours over the span at wind speed of 25 m/s.</p>
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<p>Velocity contours for blades under wind speed of 5 m/s.</p>
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<p>Velocity contours for blades under wind speed of 7 m/s.</p>
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<p>Velocity contours for blades under wind speed of 10 m/s.</p>
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<p>Velocity contours for blades under wind speed of 13 m/s.</p>
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<p>Velocity contours for blades under wind speed of 15 m/s.</p>
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<p>Velocity contours for blades under wind speed of 20 m/s.</p>
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<p>Velocity contours for blades under wind speed of 25 m/s.</p>
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<p>Top view of flow contour around the original NREL blade.</p>
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<p>Top view of flow contour around the blade with WD-1 design.</p>
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<p>Top view of flow contour around the blade with WD-2 design.</p>
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<p>Top view of flow contour around the blade with WD-3 design.</p>
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<p><span class="html-italic">C<sub>p</sub></span> distribution comparison at wind speed of 5 m/s.</p>
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<p><span class="html-italic">C<sub>p</sub></span> distribution comparison at wind speed of 7 m/s.</p>
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<p><span class="html-italic">C<sub>p</sub></span> distribution comparison at wind speed of 10 m/s.</p>
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<p><span class="html-italic">C<sub>p</sub></span> distribution comparison at wind speed of 13 m/s.</p>
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<p><span class="html-italic">C<sub>p</sub></span> distribution comparison at wind speed of 15 m/s.</p>
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<p><span class="html-italic">C<sub>p</sub></span> distribution comparison at wind speed of 20 m/s.</p>
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<p><span class="html-italic">C<sub>p</sub></span> distribution comparison at wind speed of 25 m/s.</p>
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<p>Comparison of tangential and normal force coefficients at wind speed of 5 m/s.</p>
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<p>Comparison of tangential and normal force coefficients at wind speed of 7 m/s.</p>
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<p>Comparison of tangential and normal force coefficients at wind speed of 10 m/s.</p>
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<p>Comparison of tangential and normal force coefficients at wind speed of 13 m/s.</p>
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<p>Comparison of tangential and normal force coefficients at wind speed of 15 m/s.</p>
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<p>Comparison of tangential and normal force coefficients at wind speed of 20 m/s.</p>
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<p>Comparison of tangential and normal force coefficients at wind speed of 25 m/s.</p>
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<p>Comparison of torque at different wind speeds.</p>
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<p>Comparison of thrust forces under different wind speeds.</p>
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22 pages, 5914 KiB  
Article
The Effect of Oral Care Product Ingredients on Oral Pathogenic Bacteria Transcriptomics Through RNA-Seq
by Ping Hu, Sancai Xie, Baochen Shi, Cheryl S. Tansky, Benjamin Circello, Paul A. Sagel, Eva Schneiderman and Aaron R. Biesbrock
Microorganisms 2024, 12(12), 2668; https://doi.org/10.3390/microorganisms12122668 - 23 Dec 2024
Abstract
Various ingredients are utilized to inhibit the growth of harmful bacteria associated with cavities, gum disease, and bad breath. However, the precise mechanisms by which these ingredients affect the oral microbiome have not been fully understood at the molecular level. To elucidate the [...] Read more.
Various ingredients are utilized to inhibit the growth of harmful bacteria associated with cavities, gum disease, and bad breath. However, the precise mechanisms by which these ingredients affect the oral microbiome have not been fully understood at the molecular level. To elucidate the molecular mechanisms, a high-throughput bacterial transcriptomics study was conducted, and the gene expression profiles of six common oral bacteria, including two Gram-positive bacteria (Actinomyces viscosus, Streptococcus mutans) and four Gram-negative bacteria (Porphyromonas gingivalis, Tannerella forsythia, Fusobacterium nucleatum, and Prevotella pallens), were analyzed. The bacteria were exposed to nine common ingredients in toothpaste and mouthwash at different concentrations (stannous fluoride, stannous chloride, arginine bicarbonate, cetylpyridinium chloride, sodium monofluorophosphate, sodium fluoride, potassium nitrate, zinc phosphate, and hydrogen peroxide). Across 78 ingredient–microorganism pairs with 360 treatment–control combinations, significant and reproducible ingredient-based transcriptional response profiles were observed, providing valuable insights into the effects of these ingredients on the oral microbiome at the molecular level. This research shows that oral care product ingredients applied at biologically relevant concentrations manifest differential effects on the transcriptomics of bacterial genes in a variety of oral periodontal pathogenic bacteria. Stannous fluoride, stannous chloride, and cetylpyridinium chloride showed the most robust efficacy in inhibiting the growth or gene expression of various bacteria and pathogenic pathways. Combining multiple ingredients targeting different mechanisms might be more efficient than single ingredients in complex oral microbiomes. Full article
(This article belongs to the Special Issue Oral Microbiomes and One Health Approach)
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<p>Heatmap of treatment-induced total bacterial RNA yield fold change compared to untreated control indicated that stannous and hydrogen peroxide down-regulated RNA synthesis in all tested oral bacteria.</p>
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<p>Heatmap of treatment-induced differential expressed gene ratio (DEGR) showed stannous compounds induced strong gene expression changes in all tested oral bacteria.</p>
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<p>Microbial transcriptomics response to oral hygiene product ingredients is used to evaluate and rank material for treatment effect, indicating that stannous is the top treatment for these groups of tested bacteria. (<b>a</b>) Heatmap of log2 fold change of all the 12,546 genes from the six tested bacteria strains. (<b>b</b>) PCA plot of the combined gene expression data from all the 12,546 genes, showing all the tested materials and their relative distance to the control samples. (<b>c</b>) The rank treatment effect of different materials based on the normalized distance to control based on the PCA plot indicated that the stannous compounds are a top treatment for disturbing microbial gene expression, and the color matches the PCA plot.</p>
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<p>Treatment-induced transcriptomics changes in genes involved in LPS biosynthesis. (<b>a</b>) Heatmap of log2 fold change of <span class="html-italic">P. gingivalis</span> genes involved in LPS biosynthesis (Lipid A, Core, O-Antigen, or APS biosynthesis) and LPS export compared to no-treatment controls. (<b>b</b>) KEGG pathway mapping of the first four genes of <span class="html-italic">P. gingivalis</span> LPS biosynthesis pathway highlights gene expression changes induced by ArgB, H<sub>2</sub>O<sub>2</sub>, SnCl<sub>2</sub>_L, and SnF<sub>2</sub>_L, showing that stannous compounds down-regulated LPS biosynthesis. ArgB up-regulated LPS biosynthesis. (<b>c</b>) Bar plot of the log2 fold change of <span class="html-italic">P. gingivalis LpxA</span> gene, the first step for Lipid A biosynthesis, a critical component for LPS biosynthesis. (<b>d</b>) Bar plot of the log2 fold change of <span class="html-italic">P. gingivalis LpxC</span> gene, which is a rate-limiting gene for the LPS biosynthesis pathway. (<b>e</b>) Heat map of log2 fold change of <span class="html-italic">LpxA</span> and <span class="html-italic">LpxC</span> genes from all four tested Gram-negative bacteria. The standard error is shown as an error bar in all bar figures; a single star indicates <span class="html-italic">p</span>-value ≤ 0.05, and double stars indicate fdr-adjusted <span class="html-italic">p</span>-value ≤ 0.05.</p>
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<p>Treatment-induced transcriptomics changes in genes involved in <span class="html-italic">P. gingivalis</span> toxin translocation, secretion system, and infection (<b>a</b>) Heatmap of Log2 fold change of <span class="html-italic">P. gingivalis</span> genes involved in toxin translocation, secretion system, and infection (including Type 9 Secretion System (T9SS), <span class="html-italic">PPAD</span>, <span class="html-italic">gingipain</span>, <span class="html-italic">frimbrium</span>, <span class="html-italic">humY</span>-<span class="html-italic">tonB</span>, <span class="html-italic">VIM</span>, quorum sensing gene <span class="html-italic">LuxS</span>, <span class="html-italic">LuxR</span>, NO stress-associated gene <span class="html-italic">cdrH</span>, and infection-associated gene <span class="html-italic">hflX</span>) compared to untreated control from all tested bacteria strains. (<b>b</b>) Bar plot of the log2 fold change of <span class="html-italic">P. gingivalis</span> Type 9 Secretion System gene <span class="html-italic">PorQ</span> encoded by pgi:PG_0602. (<b>c</b>) Bar plot of the log2 fold change of <span class="html-italic">P. gingivalis fimbrium subunit C (fimC)</span> gene encoded by pgi:PG_1881. (<b>d</b>) Bar plot of the log2 fold change of <span class="html-italic">P. gingivalis VimF Glycosyltransferase</span> gene encoded by pgi:PG_0884, a key virulence modulating component. (<b>e</b>) Bar plot of the log2 fold change of <span class="html-italic">P. gingivalis hflX</span> gene encoded by pgi:PG_1886, a key virulence factor for infection and invasion. (<b>f</b>) Bar plot of the log2 fold change of <span class="html-italic">P. gingivalis peptidylarginine deiminase (PPAD)</span> gene encoded by pgi:PG_1424. (<b>g</b>) Bar plot of the log2 fold change of <span class="html-italic">P. gingivalis cdhR</span> gene encoded by pgi:PG_1237, also named <span class="html-italic">luxR</span> as a component of quorum sensing, regulating NO stress resistance. The standard error is shown as an error bar in all bar figures; a single star indicates <span class="html-italic">p</span>-value ≤ 0.05, and double stars indicate fdr-adjusted <span class="html-italic">p</span>-value ≤ 0.05.</p>
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<p>Treatment-induced transcriptomic responses of degradative enzymes including proteases, peptidases, and hemolysins. (<b>a</b>) Heatmap of log2 fold change of degradative enzymes, such as proteases, peptidases, and hemolysins, from all the tested bacteria strains compared to the no-treatment controls. (<b>b</b>) Gene number of the degradation enzymes in each bacteria genome and representational ratio towards all the genes encoded in the genome. (<b>c</b>) Bar plot of the log2 fold change of <span class="html-italic">P. gingivalis gingipain A</span> gene encoded by pgi:PG_2024. (<b>d</b>) Bar plot of the log2 fold change of <span class="html-italic">P. gingivalis gingipain B</span> gene encoded by pgi:PG_0506. (<b>e</b>) Bar plot of the log2 fold change of <span class="html-italic">P. gingivalis hemolysin</span> gene encoded by pgi:PG_1875. (<b>f</b>) Bar plot of the log2 fold change of <span class="html-italic">F. nucleatum</span> prtC <span class="html-italic">collagenase</span> gene encoded by PKHDFLHN_00556 [<a href="#B73-microorganisms-12-02668" class="html-bibr">73</a>]. The standard error is shown as an error bar in all bar figures; a single star indicates <span class="html-italic">p</span>-value ≤ 0.05, and double stars indicate fdr-adjusted <span class="html-italic">p</span>-value ≤ 0.05.</p>
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<p>Transcriptomic changes in genes that are regulated by major oral care ingredients and involved in biofilm development, adhesion to, and infection of host cells. (<b>a</b>). Genes in biofilm development and survival. (<b>b</b>). Genes in attachment to and initial interaction with host cells, such as gingival keratinocytes. (<b>c</b>). Genes encoding products that directly degrade the cellular structure of gingiva and facilitate bacterial survival and infection. The directions of gene expression changes are based on the results observed with SnF<sub>2</sub>, SnCl<sub>2</sub>, and CPC, which had the strongest activity. Blue arrows designate down-regulation, and red arrows designate up-regulation.</p>
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21 pages, 14267 KiB  
Article
Optimisation of Heat Exchanger Performance Using Modified Gyroid-Based TPMS Structures
by Martin Beer and Radim Rybár
Processes 2024, 12(12), 2943; https://doi.org/10.3390/pr12122943 - 23 Dec 2024
Abstract
Triply periodic minimal surfaces (TPMS) represent an innovative approach to the design of heat exchangers, enabling the optimisation of thermal and hydraulic performance. This study presents a comparative analysis of three geometric TPMS configurations: sheet gyroid, skeletal gyroid, and the newly proposed combined [...] Read more.
Triply periodic minimal surfaces (TPMS) represent an innovative approach to the design of heat exchangers, enabling the optimisation of thermal and hydraulic performance. This study presents a comparative analysis of three geometric TPMS configurations: sheet gyroid, skeletal gyroid, and the newly proposed combined gyroid geometry. Using numerical analysis based on simulations of fluid flow and heat transfer, key parameters such as the heat transfer coefficient, Nusselt number, friction factor, Chilton–Colburn j-factor, and pressure drop were evaluated. The results demonstrated that the combined gyroid geometry achieves the highest heat transfer efficiency, exhibiting significant improvements in the Nusselt number and heat transfer coefficient across the entire flow range. Simultaneously, it maintains low pressure losses, making it well suited for applications demanding high thermal performance with minimal energy losses. This study highlights the potential of TPMS geometries for optimising heat exchanger design and opens new paths for their implementation in industrial systems. Full article
(This article belongs to the Special Issue Fluid Dynamics and Processes of Heat Transfer Enhancement)
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<p>A visual representation of the creation process for the combined gyroid TPMS structure, derived from the sheet gyroid structure with a size of 2π and the skeletal gyroid structure with a size of π.</p>
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<p>The visualisation of the simulation boundary conditions, placement, and dimensions of the computational domain.</p>
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<p>Grid independence study.</p>
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<p>Three-dimensional visualisation of velocity maps in flow cross-sections at a volumetric flow rate of 1.2 m<sup>3</sup>/h.</p>
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<p>Velocity map and streamline visualisation in the transverse cross-section of the channel at the outlet of the heat transfer medium from the TPMS structure at a volumetric flow rate of 1.2 m<sup><span class="html-small-caps">3</span></sup>/h.</p>
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<p>Visualisation of flow velocity and streamlines in the longitudinal section at half the width of the geometry at a volumetric flow rate of 1.2 m<sup>3</sup>/h.</p>
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<p>Visualisation of flow trajectories and temperature values of the heat transfer medium in a cross-sectional view at a volumetric flow rate of 1.2 m<sup>3</sup>/h, excluding the depiction of the TPMS geometry.</p>
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<p>Visualisation of turbulent dissipation at a volumetric flow rate of 1.2 m<sup>3</sup>/h, excluding the depiction of the TPMS geometry.</p>
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<p>Graphical representation of the heat transfer coefficient for the applied volumetric flow rates of the heat transfer medium (<b>left</b>) and the graphical depiction of the Nusselt number as a function of the achieved Reynolds number (<b>right</b>).</p>
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<p>Pressure drop per unit length analysis.</p>
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<p>The results of the comparison of the heat transfer coefficient from CFD and the ε-NTU method (<b>left</b>: sheet gyroid; <b>centre</b>: combined gyroid; <b>right</b>: skeletal gyroid).</p>
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<p>Visualisation of temperature maps in individual cross-sections for the compared geometries at a volumetric flow rate of 1.2 m<sup>3</sup>/h.</p>
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<p>Friction factor (<b>left</b>) and Chilton–Colburn j-factor analysis (<b>right</b>).</p>
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29 pages, 20951 KiB  
Article
Design and SAR Analysis of an AMC-Integrated Wearable Cavity-Backed SIW Antenna
by Yathavi Thangavelu, Balakumaran Thangaraju and Rajagopal Maheswar
Micromachines 2024, 15(12), 1530; https://doi.org/10.3390/mi15121530 - 23 Dec 2024
Abstract
Wearable communication technologies necessitate antenna designs that harmonize ergonomic compatibility, reliable performance, and minimal interaction with human tissues. However, high specific absorption rate (SAR) levels, limited radiation efficiency, and challenges in integration with flexible materials have significantly constrained widespread deployment. To address these [...] Read more.
Wearable communication technologies necessitate antenna designs that harmonize ergonomic compatibility, reliable performance, and minimal interaction with human tissues. However, high specific absorption rate (SAR) levels, limited radiation efficiency, and challenges in integration with flexible materials have significantly constrained widespread deployment. To address these limitations, this manuscript introduces a novel wearable cavity-backed substrate-integrated waveguide (SIW) antenna augmented with artificial magnetic conductor (AMC) structures. The proposed architecture is meticulously engineered using diverse textile substrates, including cotton, jeans, and jute, to synergistically integrate SIW and AMC technologies, mitigating body-induced performance degradation while ensuring safety and high radiation efficiency. The proposed design demonstrates significant performance enhancements, achieving SAR reductions to 0.672 W/kg on the spine and 0.341 W/kg on the forelimb for the cotton substrate. Furthermore, the AMC-backed implementation attains ultra-low reflection coefficients, as low as −26.56 dB, alongside a gain improvement of up to 1.37 dB, culminating in a total gain of 7.09 dBi. The impedance bandwidth exceeds the ISM band specifications, spanning 150 MHz (2.3–2.45 GHz). The design maintains remarkable resilience and operational stability under varying conditions, including dynamic bending and proximity to human body models. By substantially suppressing back radiation, enhancing directional gain, and preserving impedance matching, the AMC integration optimally adapts the antenna to body-centric communication scenarios. This study uniquely investigates the dielectric and mechanical properties of textile substrates within the AMC-SIW configuration, emphasizing their practicality for wearable applications. This research sets a precedent for wearable antenna innovation, achieving an unprecedented balance of flexibility, safety, and electromagnetic performance while establishing a foundation for next-generation wearable systems. Full article
(This article belongs to the Topic Innovation, Communication and Engineering)
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<p>Geometry of cavity-backed SIW antenna on a wearable substrate showing (<b>a</b>) front-end view, (<b>b</b>) ground plane, (<b>c</b>) surface current distribution on the cavity-backed SIW antenna patch, and (<b>d</b>) microstrip feedline structure.</p>
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<p>SIW vias structures.</p>
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<p>Performance analysis of S-parameter characteristics of proposed cavity-backed SIW textile antenna.</p>
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<p>Performance analysis (gain) of cavity-backed SIW textile antenna.</p>
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<p>Boundary conditions for in-phase reflection characteristics.</p>
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<p>(<b>a</b>) Geometry of circular-shaped patch-type AMC array cell. (<b>b</b>) Equivalent circuit.</p>
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<p>In-phase simulation of 2.45 GHz AMC unit cells with normal plane incidence.</p>
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<p>Simulated reflection coefficient of (<b>a</b>) cotton, (<b>b</b>) jean, and (<b>c</b>) jute with varying separation distances from the AMC Plane.</p>
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<p>Isolation of AMC plane with textile antennas using a 3 mm thick layer of polyurethane foam. (<b>a</b>) Cotton, (<b>b</b>) jean, and (<b>c</b>) jute.</p>
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<p>Simulated reflection coefficient characteristics of cotton, jean, and jute textile antennas separated from the AMC plane using a 3 mm layer of polyurethane foam.</p>
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<p>Simulated gain radiation patterns of AMC-integrated cotton, jean, and jute substrate normalized radiation patterns [dBi] at 2.45 GHz.</p>
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<p>Resonant frequency and reflection coefficient for y-axis bending at 30 degrees for cotton, jean, and jute materials.</p>
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<p>Resonant frequency and reflection coefficient for x-axis bending at 30 degrees for cotton, jean, and jute materials.</p>
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<p>Three-layer test person’s body models were tested on (<b>a</b>) wearable antenna with cotton Substrate. (<b>b</b>) Antenna affixed on AMC structure.</p>
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<p>Simulated resonant frequency and reflection coefficient of all antennas affixed on three-layer test person’s body models.</p>
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<p>Simulated radiation patterns normalized to 0 dBi are shown for a frequency of 2.45 GHz affixed on three-layer test person’s body models.</p>
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<p>Fabricated cavity-backed SIW textile antenna and AMC reflector plane with cotton fabric (<b>a</b>) front and (<b>b</b>) back view.</p>
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<p>Fabricated cavity-backed SIW textile antenna and AMC reflector plane with jean fabric (<b>a</b>) front and (<b>b</b>) back view.</p>
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<p>Fabricated cavity-backed SIW textile antenna and AMC reflector plane with jute fabric (<b>a</b>) front and (<b>b</b>) back view.</p>
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<p>Fabricated cavity-backed SIW textile antenna and AMC reflector plane with jute fabric (<b>a</b>) front and (<b>b</b>) back view.</p>
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<p>Testing setup: AMC-integrated cavity-backed SIW textile antenna with cotton fabric affixed on the body of test person. (<b>a</b>) Spine and (<b>b</b>) forelimb.</p>
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<p>Testing setup: AMC-integrated cavity-backed SIW textile antenna with jean fabric affixed on the body of test person. (<b>a</b>) Spine and (<b>b</b>) forelimb.</p>
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<p>Testing setup: AMC-integrated cavity-backed SIW textile antenna with jute fabric affixed on the body of test person. (<b>a</b>) Spine and (<b>b</b>) forelimb.</p>
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<p>Snapshot of reflection coefficient S<sub>11</sub> (dB) measurement using VNA for the AMC-supported cotton antenna placed close to a test person’s (<b>a</b>) human spine. (<b>b</b>) Forelimb of radius 50 mm.</p>
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<p>Snapshot of reflection coefficient S<sub>11</sub> (dB) measurement using VNA for the AMC-supported jean antenna placed close to a test person’s (<b>a</b>) human spine. (<b>b</b>) Forelimb of radius 50 mm.</p>
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<p>Snapshot of reflection coefficient S<sub>11</sub> (dB) measurement using VNA for the AMC-supported jute antenna placed close to a test person’s (<b>a</b>) human spine. (<b>b</b>) Forelimb of radius 50 mm.</p>
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<p>Reflection coefficient S<sub>11</sub> (dB) of the AMC-supported cotton antenna placed close to a test person’s (<b>a</b>) human spine. (<b>b</b>) Forelimb of radius 50 mm. Solid red line: measured results. Solid black line: simulated results.</p>
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<p>Reflection coefficient S<sub>11</sub> (dB) of the AMC-supported jean antenna placed close to a test person’s (<b>a</b>) human spine. (<b>b</b>) Forelimb of radius 50 mm. Solid red line: measured results. Solid black line: simulated results.</p>
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<p>Reflection coefficient S<sub>11</sub> (dB) of the AMC-supported jute antenna placed close to a test person’s (<b>a</b>) human spine. (<b>b</b>) Forelimb of radius 50 mm. Solid red line: measured results. Solid black line: simulated results.</p>
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<p>Measurement setup of cotton textile antenna in a microwave-shielded far-field anechoic chamber.</p>
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<p>Tested radiation patterns (degree vs. dB) of an antenna placed close to a test person’s (<b>a</b>) human spine. (<b>b</b>) Forelimb of radius 50 mm.</p>
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<p>SAR analysis of SIW wearable antennas made of cotton, jean, and jute fabrics on (<b>a</b>) human spine and (<b>b</b>) forelimb at 2.45 GHz using 3-layer body phantoms with a mass of 10 g.</p>
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25 pages, 3319 KiB  
Article
Load Optimization for Connected Modern Buildings Using Deep Hybrid Machine Learning in Island Mode
by Seyed Morteza Moghimi, Thomas Aaron Gulliver, Ilamparithi Thirumarai Chelvan and Hossen Teimoorinia
Energies 2024, 17(24), 6475; https://doi.org/10.3390/en17246475 (registering DOI) - 23 Dec 2024
Abstract
This paper examines Connected Smart Green Buildings (CSGBs) in Burnaby, BC, Canada, with a focus on townhouses with one to four bedrooms. The proposed model integrates sustainable materials and smart components such as recycled insulation, Photovoltaic (PV) solar panels, smart meters, and high-efficiency [...] Read more.
This paper examines Connected Smart Green Buildings (CSGBs) in Burnaby, BC, Canada, with a focus on townhouses with one to four bedrooms. The proposed model integrates sustainable materials and smart components such as recycled insulation, Photovoltaic (PV) solar panels, smart meters, and high-efficiency systems. These elements improve energy efficiency and promote sustainability. Operating in island mode, CSGBs can function independently of the grid, providing resilience during power outages and reducing reliance on external energy sources. Real data on electricity, gas, and water consumption are used to optimize load management under isolated conditions. Electric Vehicles (EVs) are also considered in the system. They serve as energy storage devices and, through Vehicle-to-Grid (V2G) technology, can supply power when needed. A hybrid Machine Learning (ML) model combining Long Short-Term Memory (LSTM) and a Convolutional Neural Network (CNN) is proposed to improve the performance. The metrics considered include accuracy, efficiency, emissions, and cost. The performance was compared with several well-known models including Linear Regression (LR), CNN, LSTM, Random Forest (RF), Gradient Boosting (GB), and hybrid LSTM–CNN, and the results show that the proposed model provides the best results. For a four-bedroom Connected Smart Green Townhouse (CSGT), the Mean Absolute Percentage Error (MAPE) is 4.43%, the Root Mean Square Error (RMSE) is 3.49 kWh, the Mean Absolute Error (MAE) is 3.06 kWh, and R2 is 0.81. These results indicate that the proposed model provides robust load optimization, particularly in island mode, and highlight the potential of CSGBs for sustainable urban living. Full article
(This article belongs to the Section A: Sustainable Energy)
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<p>The SGT components in island mode.</p>
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<p>The proposed algorithm flowchart.</p>
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<p>The data processing flowchart [<a href="#B61-energies-17-06475" class="html-bibr">61</a>].</p>
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<p>Monthly electricity consumption for one- to four-bedroom SGTs and CSGTs in island mode (2012–2014).</p>
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<p>Monthly gas consumption for one- to four-Bd SGTs and CSGTs in island mode (2012–2014).</p>
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<p>Monthly water consumption for one- to four-Bd SGTs and CSGTs for January to December 2013 in island mode.</p>
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<p>Actual versus predicted monthly electricity consumption with 7 ML models for a one-Bd CSGT in island mode (2012–2014).</p>
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<p>Actual versus predicted monthly electricity consumption with 7 ML models for a two-Bd CSGT in island mode (2012–2014).</p>
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<p>Actual versus predicted monthly electricity consumption with 7 ML models for a three-Bd CSGT in island mode (2012–2014).</p>
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<p>Actual versus predicted monthly electricity consumption with 7 ML models for a four-Bd CSGT in island mode (2012–2014).</p>
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<p>Hourly one-day-ahead prediction of MAPE and MAE for 3 January 2013.</p>
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14 pages, 13287 KiB  
Article
Large-Bandwidth Lithium Niobate Electro-Optic Modulator for Frequency-Division Multiplexing RFID Systems
by Xueting Luo, Zhenqian Gu, Chong Wang, Chao Fan and Weijia Zhang
Electronics 2024, 13(24), 5054; https://doi.org/10.3390/electronics13245054 (registering DOI) - 23 Dec 2024
Abstract
In the face of increasingly complex application scenarios, there is an urgent need for (Radio Frequency Identification) RFID systems that are capable of accurately identifying microwave signals of different frequency bands. Based on the acumen detection characteristics of microwave signals by lithium niobate [...] Read more.
In the face of increasingly complex application scenarios, there is an urgent need for (Radio Frequency Identification) RFID systems that are capable of accurately identifying microwave signals of different frequency bands. Based on the acumen detection characteristics of microwave signals by lithium niobate electro-optic modulators, applying large-bandwidth thin-film lithium niobate electro-optic modulation to RFID systems can achieve efficient operation across multiple frequency bands. This study discusses, in detail, the design, simulation, fabrication, and testing process of the electro-optic modulator to obtain a high-performance, large-bandwidth lithium niobate electro-optic modulator. By using multilayer lithography techniques to prepare thick traveling-wave electrodes, the problem of irregular cross-sections during the fabrication of thick electrodes has been successfully reduced, improving the stability and controllability of the device. Test results show that the insertion loss of the electro-optic modulator is about 6 dB, the extinction ratio is 36.5 dB, the optical waveguide mode field is 1 μm, the full-band characteristic impedance is 50 Ω, the test bandwidth is 50 GHz, and the half-wave voltage is 1.8 V. Compared with existing optimization schemes, this design not only achieves a large bandwidth and a small half-wave voltage, but also proposes a new fabrication process scheme, optimizing the process and resulting in samples with stable performance. Full article
(This article belongs to the Special Issue RFID Applied to IoT Devices)
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<p>Cross-sectional view of the thin-film lithium niobate electro-optic modulator.</p>
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<p>Analysis diagrams of the electric field patterns generated by electrodes with different thicknesses: (<b>a</b>) the electric field pattern for an electrode thickness of 1 μm, (<b>b</b>) 3 μm, (<b>c</b>) 5 μm, and (<b>d</b>) 10 μm.</p>
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<p>(<b>a</b>) The influence of different electrode structure parameters on the effective refractive index; (<b>b</b>) the impact of different electrode structure parameters on the characteristic impedance.</p>
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<p>Lithium niobate electro-optic modulator fabrication process diagram.</p>
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<p>Traveling-wave electrode mask pattern.</p>
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<p>Under the microscope, the development effect of MZ optical waveguides.</p>
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<p>(<b>a</b>) A top view of the electrode surface under the metallographic microscope; (<b>b</b>) a top view of the electrode surface under the scanning electron microscope.</p>
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<p>(<b>a</b>) The left electrical signal introduction area; (<b>b</b>) the proper electrical signal introduction area.</p>
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<p>Photos of the prepared samples, with the left side showing the sample to be tested taken out from the self-adhesive box, and the right side showing the sample stored inside the self-adhesive box.</p>
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<p>Primary sources of insertion loss.</p>
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<p>Schematic diagram of the insertion loss testing system.</p>
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<p>Schematic diagram of near-field scanning technology for testing mode field.</p>
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<p>S-parameters test system schematic diagram.</p>
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<p>Test results of S-parameters for G-1, G-2, and G-3.</p>
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<p>Diagram of the half-wave voltage system tested by the frequency-doubling modulation method.</p>
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