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25 pages, 2276 KiB  
Article
Fast and Accurate Prediction of Refractive Index of Organic Liquids with Graph Machines
by François Duprat, Jean-Luc Ploix, Jean-Marie Aubry and Théophile Gaudin
Molecules 2023, 28(19), 6805; https://doi.org/10.3390/molecules28196805 - 26 Sep 2023
Cited by 2 | Viewed by 5762
Abstract
The refractive index (RI) of liquids is a key physical property of molecular compounds and materials. In addition to its ubiquitous role in physics, it is also exploited to impart specific optical properties (transparency, opacity, and gloss) to materials and various end-use products. [...] Read more.
The refractive index (RI) of liquids is a key physical property of molecular compounds and materials. In addition to its ubiquitous role in physics, it is also exploited to impart specific optical properties (transparency, opacity, and gloss) to materials and various end-use products. Since few methods exist to accurately estimate this property, we have designed a graph machine model (GMM) capable of predicting the RI of liquid organic compounds containing up to 16 different types of atoms and effective in discriminating between stereoisomers. Using 8267 carefully checked RI values from the literature and the corresponding 2D organic structures, the GMM provides a training root mean square relative error of less than 0.5%, i.e., an RMSE of 0.004 for the estimation of the refractive index of the 8267 compounds. The GMM predictive ability is also compared to that obtained by several fragment-based approaches. Finally, a Docker-based tool is proposed to predict the RI of organic compounds solely from their SMILES code. The GMM developed is easy to apply, as shown by the video tutorials provided on YouTube. Full article
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<p>Structure of 1,3-diketones and keto-enol forms for 1,1,1-trifluoropentane-2,4-dione and 2-acetylcyclohexan-1-one, and SMILES codes used for RI computations with the GM24 model.</p>
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<p>Structures (<b>a</b>–<b>c</b>) of the test set compounds that have the largest negative and positive deviations for their computed RI using the GM24 model. <span class="html-italic">RI<sub>exp</sub></span>., <span class="html-italic">RI<sub>est</sub></span>. and Dev. stand for experimental RI, estimated RI, and deviation.</p>
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<p>Scatter plot of refractive index estimations for the 3516 molecules of the TCI training set (blue disks) and of refractive index predictions for the 3515 molecules of the TCI test set (red circles) computed by graph machines vs. measured refractive index values. The black line is the bisector of the plot.</p>
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<p>Scatter plot of refractive index predictions computed by geometrical fragment method [<a href="#B20-molecules-28-06805" class="html-bibr">20</a>] (blue disks) and graph machines (red circles) vs. measured refractive index values for the 1366 molecules in the CRC test set. The black line is the bisector of the plot.</p>
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<p>Example of dataset simplification for the three 2-ethyloxiranes shown with their structure, registry number, isomeric SMILES, and refractive index value. The stereogenic center is marked with an asterisk.</p>
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<p>Refractive index vs. number of (<b>a</b>) CH<sub>2</sub> repeated groups for five homologous series, (<b>b</b>) repeat units for three homologous series. Experimental data were extracted from [<a href="#B32-molecules-28-06805" class="html-bibr">32</a>,<a href="#B34-molecules-28-06805" class="html-bibr">34</a>,<a href="#B35-molecules-28-06805" class="html-bibr">35</a>,<a href="#B38-molecules-28-06805" class="html-bibr">38</a>]. The dotted lines were drawn using Equation (10).</p>
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<p>Coding of (<b>a</b>) (<span class="html-italic">Z</span>)-1,2-dichloroethene and (<b>b</b>) (2<span class="html-italic">S</span>,3<span class="html-italic">S</span>)-2,3-dimethyloxirane from their 2D-structure into their directed graph (①) and graph machine (②). To simplify the GM representations, some bias inputs are omitted, and the implemented node functions are MLPs with zero hidden neurons. The red wavy line indicates a cycle opening in step ① to obtain an acyclic graph. The asterisks on the nodes of graph machine (<b>b</b>) correspond to the carbon atoms between which a bond has been broken.</p>
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<p>Scatter plot of refractive index predictions computed by graph machines vs. measured refractive index values for the 175 compounds of the MIX test. Red disks are for pairs of diastereomers, and blue disks are for other compounds. The dashed line (y = 0.998x + 0.004) is the regression line for the total set.</p>
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25 pages, 9185 KiB  
Article
Stone Endurance: A Comparative Analysis of Natural and Artificial Weathering on Stone Longevity
by Carla Lisci, Fabio Sitzia, Vera Pires, Marco Aniceto and José Mirão
Heritage 2023, 6(6), 4593-4617; https://doi.org/10.3390/heritage6060244 - 2 Jun 2023
Cited by 3 | Viewed by 3029
Abstract
The long-term endurance of building stones must be assured since their longevity has repercussions for their economic and social value. Frequently, slabs for flooring and cladding are installed with polished finishing in outdoor environments for technical and ornamental purposes in cultural heritage sites [...] Read more.
The long-term endurance of building stones must be assured since their longevity has repercussions for their economic and social value. Frequently, slabs for flooring and cladding are installed with polished finishing in outdoor environments for technical and ornamental purposes in cultural heritage sites and modern civil architecture. Compared to any other finishing, glossy surfaces are rather vulnerable to wear, particularly when they interact with slightly acidic rainwater. Several hydrophobic treatments are applied to prevent this damage by preventing contact between rain and stone; such treatments are efficient but sometimes non-durable. Stakeholders and conservation scientists need better methods to anticipate the future behaviour of this building material and hydrophobic solutions. Complying with this demand, a comparison is made between outdoor natural ageing and artificial weathering, reproduced by UVA radiation, moisture and spray accelerated weathering. Artificial weathering is applied to predict the behaviour of stones over time in the real environment. Data obtained through the measurement of gloss and colour parameters, the detection of micro-textures through SEM, and the calculation of micro-roughness using a digital rugosimeter demonstrate that weakly acidic rainwater is the main cause of superficial decay of stone finishing over just six months of outdoor exposure. This period corresponds to 7–14 days of artificial weathering. Furthermore, the loss of efficiency and durability of the hydrophobic coatings is detected by measuring the static contact angle. This highlights that even if a protective treatment was proficient, it could easily deteriorate in normal weathering conditions if applied on polished, low-porosity stone. Additionally, water vapour permeability indicates variations of regular vapour transmission through the stones due to ageing. The first solution to threats is the prevention of pathologies, including aesthetic ones. A careful choice of the most suitable lithotype finish and an environmental study represent an existing solution to the problem. It must be highlighted that aesthetic requirements should not be prioritised to detriment of the technical requirements of architectural quality, performance, durability, and safety. Full article
(This article belongs to the Special Issue Challenges in Stone Heritage Conservation)
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<p>Ancient and contemporary buildings built with Portuguese stones. Lioz limestones were used for constructing the (<b>a</b>) Belem Tower and (<b>b</b>) Palace of Parliament in Lisbon (Portugal). Rosa and BW marble were used in ancient architecture, as well as in (<b>c</b>) Estremoz Castle (Portugal) and (<b>d</b>) residential buildings in Lisbon; (<b>e</b>) Alpinina is used in civil modern architecture; (<b>f</b>) is an example of Azul limestone used as cladding with weathered polished finishing.</p>
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<p>Macroscopic appearance of the lithotypes selected for this study. (<b>a</b>) Lioz A, (<b>b</b>) Alpinina, (<b>c</b>) Lioz B, (<b>d</b>) black and white marble, (<b>e</b>) Lioz C, (<b>f</b>) Rosa marble, (<b>g</b>) blue limestone.</p>
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<p>Characterisation through optical observations: (<b>a</b>) Lioz A (biosparite), (<b>b</b>) Lioz B (biosparite), (<b>c</b>) Lioz C (biomicrite), (<b>d</b>) Alpinina (pel-biomicrite-sparite), (<b>e</b>) BW marble, (<b>f</b>) Rosa marble, (<b>g</b>) blue limestone (biomicrite).</p>
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<p>Gloss unit variation (60° reflected light) for each stone before and during the outdoor ageing, correlated with the date of collection of the rainwater. Histograms show the gloss reduction mainly after rain events (27 December 2021 and 21 March 2022).</p>
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<p>Gloss variation (60° reflected light) for each stone before the QUV-spray ageing and after 3, 7, and 14 days.</p>
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<p>(<b>a</b>) Gloss variation in blue limestone treated with protective coatings before and during the outdoor ageing. Additionally, in this case the graph points out the gloss reduction mainly after rain events (27 December 2021 and 21 March 2022). (<b>b</b>) Gloss unit variation (60° reflected light) for blue limestone treated with protective coatings. Coating 1 (aminopropyltriethoxysilane), coating 2 (aminopropyltriethoxysilane in 1:2 diluition), coating 3 (tripotassium propylsilanetriolate).</p>
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<p>Colour variation and colour difference, ΔE%. An overall whitening of all stones can be seen. ΔE% of stones before, during, and after natural and QUV-spray ageing. Irregular trends characterised almost all samples during natural ageing. In the QUV-chamber, ΔE% increased regularly, probably due to the limited and fixed parameters of the ASTM G154-cycle7.</p>
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<p>Colour variation and colour distance (ΔE%) of blue limestone coated with hydrophobic coating 1 (aminopropyltriethoxysilane), coating 2 (aminopropyltriethoxysilane in 1:2 dilution), and coating 3 (tripotassium propylsilanetriolate). An overall whitening of all stones was discerned. ΔE% of stones before, during, and after natural and QUV-spray ageing. An irregular trend characterised almost all samples during natural ageing. In the chamber, ΔE% increased regularly, probably due to the limited and fixed parameters of the ASTM G154-cycle7.</p>
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<p>Micro-texture analyses through SEM and according to the roughness parameters, Ra, Rz, and Rq, measured with the digital rugosimeter. (<b>a</b>–<b>c</b>) Lioz A before and after natural ageing and after QUV-spray ageing, (<b>d</b>–<b>f</b>) Lioz B before and after natural ageing and after QUV-spray ageing, (<b>g</b>–<b>i</b>) Lioz C before and after natural ageing and after QUV-spray ageing, (<b>j</b>–<b>l</b>) Alpinina before and after natural ageing and after QUV ageing, (<b>m</b>–<b>o</b>) BW marble before and after natural ageing and after QUV ageing, (<b>p</b>–<b>r</b>) Rosa before and after natural ageing and after QUV ageing, (<b>s</b>–<b>u</b>) Blue limestone before and after natural ageing and after QUV ageing. The data support the argument that weathering significantly affects superficial texture, resulting in increased roughness and irregularity in both limestones and marbles, as evidenced by the changes in Ra values before and after natural and artificial weathering.</p>
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<p>Micro-texture of blue limestone coated with hydrophobics. (<b>m</b>) coating 1 before the tests, (<b>n</b>) after natural ageing, and (<b>o</b>) after QUV-spray ageing; (<b>p</b>) coating 2 before the tests, (<b>q</b>) after natural ageing, and (<b>r</b>) after QUV-spray ageing; (<b>s</b>) coating 3 before the test, (<b>t</b>) after natural ageing, and (<b>u</b>) after QUV-spray ageing. The white minerals and spots are pyrite inclusions.</p>
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<p>Contact angles of blue limestone. (<b>a</b>) Untreated blue limestone; (<b>b</b>–<b>d</b>) coating 1 before the tests, after natural ageing, and after QUV-spray ageing; (<b>e</b>–<b>g</b>) coating 2 before the tests, after natural ageing, and after QUV-spray ageing; (<b>h</b>–<b>j</b>) coating 3 before the test, after natural ageing, and after QUV-spray ageing, respectively.</p>
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23 pages, 20417 KiB  
Article
Sign2Pose: A Pose-Based Approach for Gloss Prediction Using a Transformer Model
by Jennifer Eunice, Andrew J, Yuichi Sei and D. Jude Hemanth
Sensors 2023, 23(5), 2853; https://doi.org/10.3390/s23052853 - 6 Mar 2023
Cited by 12 | Viewed by 3602
Abstract
Word-level sign language recognition (WSLR) is the backbone for continuous sign language recognition (CSLR) that infers glosses from sign videos. Finding the relevant gloss from the sign sequence and detecting explicit boundaries of the glosses from sign videos is a persistent challenge. In [...] Read more.
Word-level sign language recognition (WSLR) is the backbone for continuous sign language recognition (CSLR) that infers glosses from sign videos. Finding the relevant gloss from the sign sequence and detecting explicit boundaries of the glosses from sign videos is a persistent challenge. In this paper, we propose a systematic approach for gloss prediction in WLSR using the Sign2Pose Gloss prediction transformer model. The primary goal of this work is to enhance WLSR’s gloss prediction accuracy with reduced time and computational overhead. The proposed approach uses hand-crafted features rather than automated feature extraction, which is computationally expensive and less accurate. A modified key frame extraction technique is proposed that uses histogram difference and Euclidean distance metrics to select and drop redundant frames. To enhance the model’s generalization ability, pose vector augmentation using perspective transformation along with joint angle rotation is performed. Further, for normalization, we employed YOLOv3 (You Only Look Once) to detect the signing space and track the hand gestures of the signers in the frames. The proposed model experiments on WLASL datasets achieved the top 1% recognition accuracy of 80.9% in WLASL100 and 64.21% in WLASL300. The performance of the proposed model surpasses state-of-the-art approaches. The integration of key frame extraction, augmentation, and pose estimation improved the performance of the proposed gloss prediction model by increasing the model’s precision in locating minor variations in their body posture. We observed that introducing YOLOv3 improved gloss prediction accuracy and helped prevent model overfitting. Overall, the proposed model showed 17% improved performance in the WLASL 100 dataset. Full article
(This article belongs to the Special Issue Sensor Systems for Gesture Recognition II)
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<p>Overview of gloss prediction from sign poses—WLASL using a standard transformer.</p>
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<p>Illustrating the augmentation techniques applied to a single frame while pre-processing.</p>
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<p>Sample visualization of normalized pose using YOLOv3.</p>
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<p>Proposed architecture of the Sign2Pose Gloss prediction transformer.</p>
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<p>Sample images of key-frame extraction for the Gloss “Drink” from the WLASL 100 dataset (<b>a</b>) sample of extracted frames for the mentioned gloss. (<b>b</b>) Discarded redundant frames. (<b>c</b>) Preserved key-frame sample from extracted frames.</p>
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<p>Sample images of key-frame extraction for the Gloss “Drink” from the WLASL 100 dataset (<b>a</b>) sample of extracted frames for the mentioned gloss. (<b>b</b>) Discarded redundant frames. (<b>c</b>) Preserved key-frame sample from extracted frames.</p>
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<p>Performance analysis of proposed work with existing appearance and pose-based models. (<b>a</b>) Graphical representation comparing our approach with the pose-based as well as appearance-based model. (<b>b</b>) Comparing top 1% recognition accuracy on both pose-based and appearance-based models; (<b>c</b>) comparing top K macro recognition accuracy on pose-based models.</p>
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<p>Performance analysis of proposed work with existing appearance and pose-based models. (<b>a</b>) Graphical representation comparing our approach with the pose-based as well as appearance-based model. (<b>b</b>) Comparing top 1% recognition accuracy on both pose-based and appearance-based models; (<b>c</b>) comparing top K macro recognition accuracy on pose-based models.</p>
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<p>Validation accuracy and validation loss of our model.</p>
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<p>Comparison of the pose-based approaches’ top 1 accuracies (%) and scalability on four subsets of the WLASL dataset.</p>
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20 pages, 2915 KiB  
Article
Continuous Sign Language Recognition through a Context-Aware Generative Adversarial Network
by Ilias Papastratis, Kosmas Dimitropoulos and Petros Daras
Sensors 2021, 21(7), 2437; https://doi.org/10.3390/s21072437 - 1 Apr 2021
Cited by 46 | Viewed by 6918
Abstract
Continuous sign language recognition is a weakly supervised task dealing with the identification of continuous sign gestures from video sequences, without any prior knowledge about the temporal boundaries between consecutive signs. Most of the existing methods focus mainly on the extraction of spatio-temporal [...] Read more.
Continuous sign language recognition is a weakly supervised task dealing with the identification of continuous sign gestures from video sequences, without any prior knowledge about the temporal boundaries between consecutive signs. Most of the existing methods focus mainly on the extraction of spatio-temporal visual features without exploiting text or contextual information to further improve the recognition accuracy. Moreover, the ability of deep generative models to effectively model data distribution has not been investigated yet in the field of sign language recognition. To this end, a novel approach for context-aware continuous sign language recognition using a generative adversarial network architecture, named as Sign Language Recognition Generative Adversarial Network (SLRGAN), is introduced. The proposed network architecture consists of a generator that recognizes sign language glosses by extracting spatial and temporal features from video sequences, as well as a discriminator that evaluates the quality of the generator’s predictions by modeling text information at the sentence and gloss levels. The paper also investigates the importance of contextual information on sign language conversations for both Deaf-to-Deaf and Deaf-to-hearing communication. Contextual information, in the form of hidden states extracted from the previous sentence, is fed into the bidirectional long short-term memory module of the generator to improve the recognition accuracy of the network. At the final stage, sign language translation is performed by a transformer network, which converts sign language glosses to natural language text. Our proposed method achieved word error rates of 23.4%, 2.1% and 2.26% on the RWTH-Phoenix-Weather-2014 and the Chinese Sign Language (CSL) and Greek Sign Language (GSL) Signer Independent (SI) datasets, respectively. Full article
(This article belongs to the Special Issue Towards Sign Language Recognition: Achievements and Challenges)
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<p>Overview of the proposed framework that performs continuous sign language recognition and sign language translation.</p>
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<p>The proposed generator extracts spatio-temporal features from a video and predicts the signed gloss sequences.</p>
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<p>The proposed discriminator aims to distinguish between the ground truth and predicted glosses by modeling text information at both the gloss and sentence levels.</p>
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<p>Context modeling on Deaf-to-hearing and Deaf-to-Deaf conversations. In the first case, the previous sentence (text) is passed through a word embedding and a Bidirectional Long Short-Term Memory (BLSTM) layer. In the Deaf-to-Deaf setting, the previous hidden state of the generator is passed through a mapper network. In both cases, the produced hidden state is fed into the BLSTM layer of the generator.</p>
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<p>Overall architecture of the sign language translation method. The proposed generator is extended by a transformer network to perform translation of the predicted glosses.</p>
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<p>CSLR performance comparison on a sign language conversation. It was observed that the context-aware SLRGAN performs better during recognition of a sign language conversation.</p>
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15 pages, 2237 KiB  
Article
Arabic Gloss WSD Using BERT
by Mohammed El-Razzaz, Mohamed Waleed Fakhr and Fahima A. Maghraby
Appl. Sci. 2021, 11(6), 2567; https://doi.org/10.3390/app11062567 - 13 Mar 2021
Cited by 26 | Viewed by 3645
Abstract
Word Sense Disambiguation (WSD) aims to predict the correct sense of a word given its context. This problem is of extreme importance in Arabic, as written words can be highly ambiguous; 43% of diacritized words have multiple interpretations and the percentage increases to [...] Read more.
Word Sense Disambiguation (WSD) aims to predict the correct sense of a word given its context. This problem is of extreme importance in Arabic, as written words can be highly ambiguous; 43% of diacritized words have multiple interpretations and the percentage increases to 72% for non-diacritized words. Nevertheless, most Arabic written text does not have diacritical marks. Gloss-based WSD methods measure the semantic similarity or the overlap between the context of a target word that needs to be disambiguated and the dictionary definition of that word (gloss of the word). Arabic gloss WSD suffers from a lack of context-gloss datasets. In this paper, we present an Arabic gloss-based WSD technique. We utilize the celebrated Bidirectional Encoder Representation from Transformers (BERT) to build two models that can efficiently perform Arabic WSD. These models can be trained with few training samples since they utilize BERT models that were pretrained on a large Arabic corpus. Our experimental results show that our models outperform two of the most recent gloss-based WSDs when we test them against the same test data used to evaluate our model. Additionally, our model achieves an F1-score of 89% compared to the best-reported F1-score of 85% for knowledge-based Arabic WSD. Another contribution of this paper is introducing a context-gloss benchmark that may help to overcome the lack of a standardized benchmark for Arabic gloss-based WSD. Full article
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<p>Histogram of benchmark senses per word.</p>
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<p>Transformer architecture, multi-head attention layer architecture, and scaled dot-product attention unit.</p>
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<p>Bidirectional Encoder Representation from Transformers (BERT) training input and BERT training tasks: the first task is to predict masked words, and the second task makes the next sentence prediction.</p>
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<p>Transfer learning strategies.</p>
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<p>Model I architecture.</p>
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<p>Model II architecture.</p>
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13 pages, 6339 KiB  
Article
Mathematical Modeling of Outdoor Natural Weathering of Polycarbonate: Regional Characteristics of Degradation Behaviors
by Takato Ishida and Ryoma Kitagaki
Polymers 2021, 13(5), 820; https://doi.org/10.3390/polym13050820 - 7 Mar 2021
Cited by 7 | Viewed by 3102
Abstract
Many natural exposure sites have been developed to ensure the reliability of materials intended for outdoor use. However, the effects of local climate on aging have not been completely understood. This study aimed to elucidate the regional characteristics of natural aging. Non-stabilized and [...] Read more.
Many natural exposure sites have been developed to ensure the reliability of materials intended for outdoor use. However, the effects of local climate on aging have not been completely understood. This study aimed to elucidate the regional characteristics of natural aging. Non-stabilized and stabilized polycarbonates were monitored in terms of their appearance (yellowing and loss of gloss) during natural weathering at five exposure sites (Tokyo, Kagoshima, Okinawa, Florida, and Arizona) in conjunction with climate fluctuation for up to 24 months. Three approaches were employed to characterize the natural aging behaviors: (i) modeling the rate function of degradation, (ii) evaluating the contribution ratio of individual degradational factors, and (iii) estimating the “synchronicity” by cross-correlation analysis with the climate dataset. The aging rates were the highest in Arizona and lowest in Kagoshima among the five exposure sites. First, prediction curves were constructed from the degradation rate function (variables: UV irradiation, temperature, and humidity), and these curves were found to agree well with the measured aging behaviors. Second, the exposure data in Arizona demonstrated strong temperature dependence, while those in Okinawa and Florida had stronger dependence on UV irradiation compared to other sites. Lastly, the synchronicity between UV irradiation and temperature was the highest in Arizona and lowest in Kagoshima, which can explain the significantly faster deterioration in Arizona and the slow deterioration in Kagoshima. Full article
(This article belongs to the Special Issue Assessment of the Ageing and Durability of Polymers III)
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<p>Locations of the five natural exposure sites and their climate classifications.</p>
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<p>Fluctuations of daily average temperature, UV irradiation, and relative humidity (RH) for five exposure sites. The inserted red lines are shown to guide the eye.</p>
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<p>Temperature difference between polycarbonate (PC) surface and air in Tokyo. The red lines are inserted to guide the eye.</p>
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<p>Correlation between measured surface temperature and estimated surface temperature from Equation (11) for the Tokyo data. The two temperatures are strongly correlated (R<sup>2</sup> = 0.994).</p>
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<p>Outdoor aging behavior of appearance quality, (<b>a</b>): yellowing for non-stabilized PC samples, (<b>b</b>): gloss loss for non-stabilized PC samples, (<b>c</b>): yellowing for stabilized PC samples, (<b>d</b>): gloss loss for stabilized PC samples. The data are plotted against the integrated UV irradiation for each exposure site (Tokyo, Kagoshima, Okinawa, Florida, and Arizona).</p>
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<p>Change in ⊿YI during outdoor aging for non-stabilized PC samples (red dots) and the predicted values (solid lines) for each exposure site (Tokyo, Kagoshima, Okinawa, Florida, and Arizona).</p>
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<p>Gloss retention during outdoor aging for non-stabilized PC samples (red dots) and the predicted values (solid lines) for each exposure site (Tokyo, Kagoshima, Okinawa, Florida, and Arizona).</p>
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<p>Changes in ⊿YI during outdoor aging for stabilized PC samples (red dots) and the predicted values (solid lines) for each exposure site (Tokyo, Kagoshima, Okinawa, Florida, and Arizona).</p>
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<p>Loss of gloss during outdoor aging for stabilized PC samples (red dots) and the predicted values (solid lines) for each exposure site (Tokyo, Kagoshima, Okinawa, Florida, and Arizona).</p>
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<p>Calculated cross-correlation function between temperature and UV irradiation for each exposure site.</p>
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15 pages, 1644 KiB  
Article
Development of a Prediction Model for Demolition Waste Generation Using a Random Forest Algorithm Based on Small DataSets
by Gi-Wook Cha, Hyeun Jun Moon, Young-Min Kim, Won-Hwa Hong, Jung-Ha Hwang, Won-Jun Park and Young-Chan Kim
Int. J. Environ. Res. Public Health 2020, 17(19), 6997; https://doi.org/10.3390/ijerph17196997 - 24 Sep 2020
Cited by 49 | Viewed by 5037
Abstract
Recently, artificial intelligence (AI) technologies have been employed to predict construction and demolition (C&D) waste generation. However, most studies have used machine learning models with continuous data input variables, applying algorithms, such as artificial neural networks, adaptive neuro-fuzzy inference systems, support vector machines, [...] Read more.
Recently, artificial intelligence (AI) technologies have been employed to predict construction and demolition (C&D) waste generation. However, most studies have used machine learning models with continuous data input variables, applying algorithms, such as artificial neural networks, adaptive neuro-fuzzy inference systems, support vector machines, linear regression analysis, decision trees, and genetic algorithms. Therefore, machine learning algorithms may not perform as well when applied to categorical data. This article uses machine learning algorithms to predict C&D waste generation from a dataset, as a way to improve the accuracy of waste management in C&D facilities. These datasets include categorical (e.g., region, building structure, building use, wall material, and roofing material), and continuous data (particularly, gloss floor area), and a random forest (RF) algorithm was used. Results indicate that RF is an adequate machine learning algorithm for a small dataset consisting of categorical data, and even with a small dataset, an adequate prediction model can be developed. Despite the small dataset, the predictive performance according to the demolition waste (DW) type was R (Pearson’s correlation coefficient) = 0.691–0.871, R2 (coefficient of determination) = 0.554–0.800, showing stable prediction performance. High prediction performance was observed using three (for mortar), five (for other DW types), or six (for concrete) input variables. This study is significant because the proposed RF model can predict DW generation using a small amount of data. Additionally, it demonstrates the possibility of applying AI to multi-purpose DW management. Full article
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<p>Structure of the random forest (RF) algorithm.</p>
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<p>Schematic representation of the leave-one-out cross-validation (LOOCV) method.</p>
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<p>The methodology of the RF model developed in this study.</p>
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<p>Performance of the RT model for demolition waste generation prediction.</p>
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<p>Modeling results for each demolition waste type produced by RF.</p>
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16 pages, 3416 KiB  
Article
Optimization of Process Parameters for Anti-Glare Spray Coating by Pressure-Feed Type Automatic Air Spray Gun Using Response Surface Methodology
by Yu-Hui Huang, Lung-Chuan Chen and Huann-Ming Chou
Materials 2019, 12(5), 751; https://doi.org/10.3390/ma12050751 - 5 Mar 2019
Cited by 12 | Viewed by 3920
Abstract
The process of preparing anti-glare thin films by spray-coating silica sol-gel to soda-lime glass was exclusively and statistically studied in this paper. The effects of sol-gel deliver pressure, air transport pressure, and spray gun displacement speed on the gloss, haze, arithmetic mean surface [...] Read more.
The process of preparing anti-glare thin films by spray-coating silica sol-gel to soda-lime glass was exclusively and statistically studied in this paper. The effects of sol-gel deliver pressure, air transport pressure, and spray gun displacement speed on the gloss, haze, arithmetic mean surface roughness, and total transmittance light were analyzed. The experimental results indicate that the factors of sol-gel deliver pressure, air transport pressure, and displacement speed exhibit a significant effect on the haze, gloss, and Ra. In contrast, the variation of total transmittance light with these three factors are insignificant. Because the anti-glare property is predominantly determined by low gloss and high haze, we therefore aim to minimize gloss and maximize haze to achieve high anti-glare. Central composite design and response surface methodology are employed to analyze the main and interaction effects of the three factors through quadratic polynomial equations, which are confirmed by the analysis of variance and R2. The response surface methodology predict the lowest gloss and highest haze are 9.2 GU and 57.0%, corresponding to the sol-gel deliver pressure, air-transport pressure, and displacement speed of 250 kPa, 560 kPa, and 140 mm/s, and 340 kPa, 620 kPa, and 20 mm/s, respectively. Comparing the predicted optimal data with the real experimental results validates the applicability of the mathematical model. This study provides an important basis for the subsequent production of anti-glare glass with different specifications to satisfy the market demand. Full article
(This article belongs to the Special Issue Selected Papers from IEEE ICICE 2018)
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Figure 1
<p>Schematic diagram of light path for normal and anti-glare glass.</p>
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<p>Schematic diagram of the anti-glare thin film production by the auto-spray system.</p>
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<p>The influence of sol-gel deliver pressure on (<b>a</b>) TTL and haze (<b>b</b>) gloss and Ra with air transport pressure and displacement speed of 300 kPa and 300 mm/s, respectively.</p>
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<p>The digital microscope pictures of microstructure morphology of anti-glare samples by different sol-gel deliver pressure: (<b>a</b>) 60 kPa (90°); (<b>b</b>) 120 kPa (90°); (<b>c</b>) 210 kPa (90°); (<b>d</b>) 300 kPa (90°); (<b>e</b>) 600 kPa (90°); (<b>f</b>) 60 kPa (25°); (<b>g</b>) 120 kPa (25°); (<b>h</b>) 210 kPa (25°); (<b>i</b>) 300 kPa (25°); and (<b>j</b>) 600 kPa (25°) with air transport pressure and displacement speed of 300 kPa and 300 mm/s, respectively.</p>
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<p>The influence of air transport pressure on (<b>a</b>) haze and TTL and (<b>b</b>) gloss and Ra with the sol-gel deliver pressure and displacement speed of 120 kPa and 300 mm/s, respectively.</p>
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<p>The digital microscope pictures of microstructure morphology of anti-glare samples by different air transport pressure (<b>a</b>) 60 kPa (90°); (<b>b</b>) 120 kPa (90°); (<b>c</b>) 210 kPa (90°); (<b>d</b>) 300 kPa (90°); (<b>e</b>) 600 kPa (90°); (<b>f</b>) 60 kPa (25°); (<b>g</b>) 120 kPa (25°); (<b>h</b>) 210 kPa (25°); (<b>i</b>) 300 kPa (25°); and (<b>j</b>) 600 kPa (25°) with the sol-gel deliver pressure and displacement speed of 120 kPa and 300 mm/s, respectively.</p>
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<p>The influences of spray displacement speed on (<b>a</b>) haze and TTL, and (<b>b</b>) gloss and Ra with the sol-gel deliver and air transport pressures of 120 kPa and 300 kPa, respectively.</p>
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<p>The digital microscope pictures of microstructure morphology of anti-glare sample by different the spray gun displacement speed (<b>a</b>) 170 mm/s (90°); (<b>b</b>) 235 mm/s (90°); (<b>c</b>) 300 mm/s (90°); (<b>d</b>) 400 mm/s (90°); (<b>e</b>) 500 mm/s (90°); (<b>f</b>) 170 mm/s (25°); (<b>g</b>) 235 mm/s (25°); (<b>h</b>) 300 mm/s (25°); (<b>i</b>) 400 mm/s (25°); and (<b>j</b>) 500 mm/s (25°) with the sol-gel deliver and air transport pressures of 120 kPa and 300 kPa, respectively.</p>
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<p>The response surface plots of gloss against the factors of (<b>a</b>) sol-gel deliver pressure (X<sub>1</sub>) and air transport pressure (X<sub>2</sub>) with X<sub>3</sub> of 140 mm/s; (<b>b</b>) displacement speed (X<sub>3</sub>) and sol-gel deliver pressure (X<sub>1</sub>) with X<sub>2</sub> of 560 kPa; and (<b>c</b>) displacement speed (X<sub>3</sub>) and air transport pressure (X<sub>2</sub>) with X<sub>1</sub> of 250 kPa.</p>
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<p>The response surface plots of gloss against the factors of (<b>a</b>) sol-gel deliver pressure (X<sub>1</sub>) and air transport pressure (X<sub>2</sub>) with X<sub>3</sub> of 140 mm/s; (<b>b</b>) displacement speed (X<sub>3</sub>) and sol-gel deliver pressure (X<sub>1</sub>) with X<sub>2</sub> of 560 kPa; and (<b>c</b>) displacement speed (X<sub>3</sub>) and air transport pressure (X<sub>2</sub>) with X<sub>1</sub> of 250 kPa.</p>
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<p>The response surface plots of haze against the factors of (<b>a</b>) sol-gel deliver pressure (X<sub>1</sub>) and air transport pressure (X<sub>2</sub>) with X<sub>3</sub> of 20 mm/s; (<b>b</b>) displacement speed (X<sub>3</sub>) and sol-gel deliver pressure (X<sub>1</sub>) with X<sub>2</sub> of 620 kPa; and (<b>c</b>) displacement speed (X<sub>3</sub>) and air transport pressure (X<sub>2</sub>) with X<sub>1</sub> of 340 kPa.</p>
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