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14 pages, 4751 KiB  
Article
The Influence of an Alternating Current Field on Pack Boriding for Medium Carbon Steel at Moderate Temperature
by Xiaoxiao Li, Wei Liu, Jianguang Yuan, Jiaye Yuan, Xiaobao Zhou, Taijun Pan and Yanjie Ren
Coatings 2025, 15(1), 39; https://doi.org/10.3390/coatings15010039 (registering DOI) - 3 Jan 2025
Abstract
The influence of alternating current (AC) field on the pack boriding process for medium carbon steel was investigated through characterization of microstructure, phase composition, microhardness, and corrosion resistance of the boride layer and its mechanism was revealed. Results showed that the boride layer [...] Read more.
The influence of alternating current (AC) field on the pack boriding process for medium carbon steel was investigated through characterization of microstructure, phase composition, microhardness, and corrosion resistance of the boride layer and its mechanism was revealed. Results showed that the boride layer obtained by AC field boriding was composed of the outer FeB and the inner Fe2B phase, which was similar to that of conventional boriding. Meanwhile, the effective thickness of the boride layer and proportion of Fe2B increased gradually with increasing current during AC field boriding. The introduction of an AC field during the boriding process served dual purposes. First, it facilitated the decomposition of the boriding medium, leading to an elevation in the concentration of active boron atoms. Second, it reduced the activation energy required for atomic diffusion, thereby accelerating the diffusion of both boron and iron atoms. These combined effects significantly enhanced the hardness distribution and corrosion resistance of the steel. Further insights into the process were gained by fitting the parabolic kinetics curves, which confirmed that the boriding process in an AC field was exclusively controlled by diffusion. This study also clarified the growth mechanism of the boride layer within an AC field. Full article
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Figure 1
<p>Schematic diagram of the experimental device for pack boriding enhanced by AC field.</p>
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<p>Microstructure of boride layer for (<b>a</b>) CPB, (<b>b</b>) ACFPB-1, (<b>c</b>) ACFPB-2, (<b>d</b>) ACFPB-3, (<b>e</b>) ACFPB-4, (<b>f</b>) ACFPB-5, (<b>g</b>) ACFPB-6.</p>
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<p>XRD analysis of 4145H steel after conventional boriding and AC field boriding with 1 A, 2 A, 4 A and 6 A.</p>
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<p>The thickness of boriding layer for 4145H steel obtained by different boriding treatments.</p>
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<p>Microhardness curves of 4145H steel surface after AC field boriding.</p>
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<p>Polarization curves of (<b>a</b>) 4145H steel substrate and boriding samples at different current in 3.5 wt.% NaCl solution: (<b>b</b>) 1 A, (<b>c</b>) 2 A, (<b>d</b>) 3 A, (<b>e</b>) 4 A, (<b>f</b>) 5 A, (<b>g</b>) 6 A.</p>
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<p>Relationship between boride layer thickness and boriding time at various boriding temperature.</p>
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<p>The relationship between the square value of boride layer thickness and boriding time.</p>
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<p>The relationship between ln<span class="html-italic">K</span> and 1/<span class="html-italic">T.</span></p>
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<p>Schematic diagram of boride layer growth.</p>
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21 pages, 18920 KiB  
Article
A Feasibility Analysis of Wind Energy Potential and Seasonal Forecasting Trends in Thatta District: A Project to Combat the Energy Crisis in Pakistan
by Jahangeer Khan Bhutto, Zhijun Tong, Tayyab Raza Fraz, Mazhar Baloch, Haider Ali, Jiquan Zhang, Xingpeng Liu and Yousef A. Al-Masnay
Energies 2025, 18(1), 158; https://doi.org/10.3390/en18010158 (registering DOI) - 3 Jan 2025
Viewed by 252
Abstract
Wind energy has emerged as a viable alternative to fossil fuels due to its clean and cost-effective nature. Pakistan, facing growing energy demands and the imperative to reduce carbon emissions, has invested significantly in wind power to supply electric power in rural and [...] Read more.
Wind energy has emerged as a viable alternative to fossil fuels due to its clean and cost-effective nature. Pakistan, facing growing energy demands and the imperative to reduce carbon emissions, has invested significantly in wind power to supply electric power in rural and urban communities, particularly in the Thatta district of Sindh Province of Pakistan. However, the sustainability of wind energy generation is contingent upon consistent and sufficient wind resources. This study examines the wind potential of Thatta district from 2004 to 2023 to assess its suitability for large-scale wind power development. To evaluate the wind potential of Thatta district, seasonal wind speed and direction data were collected and analyzed. Wind shear at different heights was determined using the power law, and wind potential maps were generated using GIS interpolation techniques. Betz’s law was employed to assess wind turbine power density. Box–Jenkins ARIMA and SARIMA models were applied to predict future wind patterns. This study revealed that Thatta district experienced sufficient wind speeds during the study period, with averages of 9.7 m/s, 7.6 m/s, 7.4 m/s, and 4.8 m/s for summer, autumn, spring, and winter, respectively. However, a concerning trend of decreasing wind speeds has been observed since 2009. The most significant reductions occurred in summer, coinciding with Pakistan’s peak electricity demand. While Thatta district has historically demonstrated potential for wind energy, the declining wind speeds pose a challenge to the sustainability of wind power projects. Further research is necessary to identify the causes of this trend and to explore mitigation strategies. Full article
(This article belongs to the Section A3: Wind, Wave and Tidal Energy)
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<p>(<b>a</b>) Total cumulative installed capacity, (<b>b</b>) new capacity, (<b>c</b>) growth rates, and (<b>d</b>) wind power capacity by country [<a href="#B7-energies-18-00158" class="html-bibr">7</a>].</p>
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<p>Average wind velocity in different provinces of Pakistan.</p>
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<p>Spatial variation in wind velocity in Sindh province of Pakistan.</p>
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<p>Study area location.</p>
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<p>(<b>a</b>) Study area and its adjacent districts. (<b>b</b>) The exact location of wind power plants in Thatta, Sindh, Pakistan.</p>
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<p>Illustration of spatiotemporal variation in average wind speed and direction calculated at (50 m) during summer (2004–2023).</p>
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<p>Illustration of spatiotemporal variation in average wind speed and direction calculated at (50 m) during summer (2004–2023).</p>
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<p>Illustration of spatiotemporal variation in average wind speed and direction calculated at (50 m) during autumn (2004–2023).</p>
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<p>Illustration of spatiotemporal variation in average wind speed and direction calculated at (50 m) during autumn (2004–2023).</p>
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<p>Illustration of spatiotemporal variation in average wind speed and direction calculated at (50 m) during spring (2004–2023).</p>
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<p>Illustration of spatiotemporal variation in average wind speed and direction calculated at (50 m) during spring (2004–2023).</p>
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<p>Illustration of spatiotemporal variation in average wind speed and direction calculated at (50 m) during winter (2004–2023).</p>
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<p>(<b>a</b>): Original wind time−series data. (<b>b</b>) Wind data after taking transformation. (<b>c</b>) One−step−ahead forecast comparison from ARIMA models based on RMSE criteria. The red line indicates the forecasted values from the best-selected model. (<b>d</b>) Expected forecasted wind speed from the ARIMA model. (<b>e</b>) One−step-ahead forecast comparison from SARIMA models based on RMSE criteria. The red line indicates the forecasted values from the best-selected model (<b>f</b>) Expected forecasted wind speed from the SARIMA models.</p>
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22 pages, 26989 KiB  
Review
Electrocatalytic and Photocatalytic N2 Fixation Using Carbon Catalysts
by Changchun Xu, Hongli Su, Shuaifei Zhao, Azadeh Nilghaz, Kunning Tang, Luxiang Ma and Zhuo Zou
Nanomaterials 2025, 15(1), 65; https://doi.org/10.3390/nano15010065 - 2 Jan 2025
Viewed by 522
Abstract
Carbon catalysts have shown promise as an alternative to the currently available energy-intensive approaches for nitrogen fixation (NF) to urea, NH3, or related nitrogenous compounds. The primary challenges for NF are the natural inertia of nitrogenous molecules and the competitive hydrogen [...] Read more.
Carbon catalysts have shown promise as an alternative to the currently available energy-intensive approaches for nitrogen fixation (NF) to urea, NH3, or related nitrogenous compounds. The primary challenges for NF are the natural inertia of nitrogenous molecules and the competitive hydrogen evolution reaction (HER). Recently, carbon-based materials have made significant progress due to their tunable electronic structure and ease of defect formation. These properties significantly enhance electrocatalytic and photocatalytic nitrogen reduction reaction (NRR) activity. While transition metal-based catalysts have solved the kinetic constraints to activate nitrogen bonds via the donation-back-π approach, there is a problem: the d-orbital electrons of these transition metal atoms tend to generate H-metal bonds, inadvertently amplifying unwanted HER. Because of this, a timely review of defective carbon-based electrocatalysts for NF is imperative. Such a review will succinctly capture recent developments in both experimental and theoretical fields. It will delve into multiple defective engineering approaches to advance the development of ideal carbon-based electrocatalysts and photocatalysts. Furthermore, this review will carefully explore the natural correlation between the structure of these defective carbon-based electrocatalysts and photocatalysts and their NF activity. Finally, novel carbon-based catalysts are introduced to obtain more efficient performance of NF, paving the way for a sustainable future. Full article
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<p>Schematic illustration of the ammonia and urea synthesis scheme in the conventional energy-intensive pathway and the alternative C-N coupling pathway under ambient conditions.</p>
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<p>Schematic illustration of carbon catalysts for nitrogen fixation: (<b>A</b>) Carbon catalysts ranging from 0 D to 3 D. (<b>B</b>) Non-metal and metal doping carbon catalysts. (<b>C</b>) C/N products.</p>
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<p>Possible mechanism of ammonia generation by nitrogen. Reprinted with permission from [<a href="#B42-nanomaterials-15-00065" class="html-bibr">42</a>], copyright 2023, Wiley-VCH.</p>
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<p>Various coupling mechanisms of urea generation by CO<sub>2</sub> with various nitrogen sources: (<b>A</b>) *CO + *N<sub>2</sub>. (<b>B</b>) *CO + *NH<sub>2</sub>. (<b>C</b>) *CO + *NO. (<b>D</b>) *CO<sub>2</sub> + *NO<sub>2</sub>. Reprinted with permission from [<a href="#B44-nanomaterials-15-00065" class="html-bibr">44</a>], copyright 2024, Wiley-VCH.</p>
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<p>Schematic illustration of intrinsic graphene: (<b>A</b>) Perfect graphene cluster, (<b>B</b>) Stone–Wales defect (SW), (<b>C</b>) single vacancy (SV), (<b>D</b>) double vacancies (DV), (<b>E</b>) edge-defect with pentagon ring at zigzag edge (PZ), octagon, and fused pentagon carbon rings line defect with (<b>F</b>) odd number of octagon rings (GLD-558-01) and (<b>G</b>) even number of octagon rings (GLD-558-02), and pentagon–heptagon pairs line defects with (<b>H</b>) odd number of heptagon rings (GLD-57-01) and (<b>I</b>) even number of heptagon rings (GLD-57-02). The large gray ball: carbon atom; and the small white ball: hydrogen atom, respectively. Reprinted with permission from [<a href="#B67-nanomaterials-15-00065" class="html-bibr">67</a>], copyright 2015, Royal Society of Chemistry.</p>
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<p>Metal-free heteroatom doping carbon catalysts: (<b>A</b>) N-doped porous carbon. Reprinted with permission from [<a href="#B55-nanomaterials-15-00065" class="html-bibr">55</a>], copyright 2018, American Chemical Society. (<b>B</b>) B-doped graphene. Reprinted with permission from [<a href="#B54-nanomaterials-15-00065" class="html-bibr">54</a>], copyright 2018, Cell Press. (<b>C</b>) O, S, Se, Te-doped carbon catalysts. Reprinted with permission from [<a href="#B76-nanomaterials-15-00065" class="html-bibr">76</a>], copyright 2020, Wiley-VCH.</p>
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<p>Schematic illustration of metal single-atom-doped carbon catalysts: (<b>A</b>) Fe single-atom-doped ZIF-8. (<b>B</b>) Free-energy profiles for ammonia generation on Fe single-atom-doped carbon catalysts. Reprinted with permission from [<a href="#B83-nanomaterials-15-00065" class="html-bibr">83</a>], copyright 2019, Elsevier. (<b>C</b>) Cu single-atom-doped carbon catalyst structures. (<b>D</b>) Reaction pathway from NO<sub>3</sub><sup>−</sup> to NH<sub>3</sub>. Reprinted with permission from [<a href="#B84-nanomaterials-15-00065" class="html-bibr">84</a>], copyright 2022, Wiley-VCH.</p>
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<p>Schematic illustration of metal diatom-doped carbon catalysts: (<b>A</b>) Zn/Fe diatomic carbon catalysts. Reprinted with permission from [<a href="#B85-nanomaterials-15-00065" class="html-bibr">85</a>], copyright 2020, Royal Society of Chemistry. (<b>B</b>–<b>D</b>) Fe/Cu diatomic graphene structure, electrochemical nitrogen reduction process, and catalytic conversion steps from NO<sub>3</sub><sup>−</sup> to NH<sub>3</sub>. Reprinted with permission from [<a href="#B86-nanomaterials-15-00065" class="html-bibr">86</a>], copyright 2023, Nature Publishing Group.</p>
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<p>Illustration of reaction cells for E-NF: (<b>A</b>) Single-cell reactor. (<b>B</b>) H-cell reactor with a selective membrane. (<b>C</b>) H-cell reactor with a selective membrane. Organic electrolyte on the left side of the H-cell reactor and aqueous electrolyte on the right side of the H-cell reactor. (<b>D</b>) Three compartments cell reactor with a GDE. (<b>E</b>) Four compartments cell reactor with two GDE. Organic electrolyte on the left side of the H-cell reactor and aqueous electrolyte on the right side of the H-cell reactor. Reprinted with permission from [<a href="#B98-nanomaterials-15-00065" class="html-bibr">98</a>], copyright 2024, Wiley-VCH.</p>
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<p>Illustration of reaction cells for P-NF. Reprinted with permission from [<a href="#B119-nanomaterials-15-00065" class="html-bibr">119</a>], copyright 2022, Nature Publishing Group.</p>
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14 pages, 4654 KiB  
Article
The Effects of Laxogenin and 5-Alpha-hydroxy-laxogenin on Myotube Formation and Maturation During Cultured Meat Production
by Jeong Ho Lim, Syed Sayeed Ahmad, Ye Chan Hwang, Ananda Baral, Sun Jin Hur, Eun Ju Lee and Inho Choi
Int. J. Mol. Sci. 2025, 26(1), 345; https://doi.org/10.3390/ijms26010345 - 2 Jan 2025
Viewed by 299
Abstract
Cultured meat (CM) is derived from the in vitro myogenesis of muscle satellite (stem) cells (MSCs) and offers a promising alternative protein source. However, the development of a cost-effective media formulation that promotes cell growth has yet to be achieved. In this study, [...] Read more.
Cultured meat (CM) is derived from the in vitro myogenesis of muscle satellite (stem) cells (MSCs) and offers a promising alternative protein source. However, the development of a cost-effective media formulation that promotes cell growth has yet to be achieved. In this study, laxogenin (LAX) and 5-alpha-hydroxy-laxogenin (5HLAX) were computationally screened against myostatin (MSTN), a negative regulator of muscle mass, because of their antioxidant properties and dual roles as MSTN inhibitors and enhancers of myogenesis regulatory factors. In silico analysis showed LXG and 5HLXG bound to MSTN with binding free energies of −7.90 and −8.50 kcal/mol, respectively. At a concentration of 10 nM, LAX and 5HLAX effectively inhibited the mRNA and protein expressions of MSTN, promoted myogenesis, and enhanced myotube formation and maturation. In addition, by acting as agonists of ROS downregulating factors, they exhibited antioxidative effects. This study shows that supplementation with LAX or 5HLAX at 10 nM in CM production improves texture, quality, and nutritional value. We believe this study fills a research gap on media development for myotube formation and maturation, which are important factors for large-scale in vitro CM production that improve product quality, nutritional value, and efficacy. Full article
(This article belongs to the Section Bioactives and Nutraceuticals)
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<p>The interactions between LXG and 5HLXG with MSTN. (<b>A</b>) The amino acid residues of MSTN that interact with LAX or 5HLAX during complex formation. (<b>B</b>) Interaction between MSTN and LAX. (<b>C</b>) Interaction between MSTN and 5HLAX. Five hydrophobic interactions were observed during MSTN + LXG and MSTN + 5HLXG complex formation (<a href="#ijms-26-00345-t001" class="html-table">Table 1</a>).</p>
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<p>Differentiation of bovine MSCs treated with LXG or 5HLXG. (<b>A</b>,<b>D</b>) Differentiation was assessed using a creatine kinase activity assay on LXG and 5HLXG treated cells. (<b>B</b>,<b>E</b>) mRNA and protein levels of myogenic markers and MSTN were determined by Real-time RT-PCR and Western blot. (<b>C</b>,<b>F</b>) ROS levels in LXG and 5HLAX treated cells were determined using a 2′,7′-dichlorofluorescein assay. Means ± SD (n &gt; 3). * <span class="html-italic">p</span> ≤ 0.05, ** <span class="html-italic">p</span> ≤ 0.01, *** <span class="html-italic">p</span> ≤ 0.001.</p>
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<p>Differentiation of porcine MSCs treated with LXG or 5HLXG. (<b>A</b>,<b>D</b>) Differentiation was assessed using a creatine kinase activity assay. (<b>B</b>,<b>E</b>) mRNA and protein levels of myogenic markers and MSTN were determined by Real-time RT-PCR and Western blot. (<b>C</b>,<b>F</b>) ROS levels were determined using a 2′,7′-dichlorofluorescein assay. Means ± SD (n &gt; 3). * <span class="html-italic">p</span> ≤ 0.05, ** <span class="html-italic">p</span> ≤ 0.01, *** <span class="html-italic">p</span> ≤ 0.001.</p>
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<p>Differentiation of chicken MSCs treated with LXG or 5HLXG. (<b>A</b>,<b>D</b>) Differentiation was assessed using a creatine kinase activity assay. (<b>B</b>,<b>E</b>) mRNA and protein levels of myogenic markers and MSTN were determined by real-time RT-PCR and Western blot. (<b>C</b>,<b>F</b>) ROS levels were determined using a 2′,7′-dichlorofluorescein assay. Means ± SD (n &gt; 3). * <span class="html-italic">p</span> ≤ 0.05, ** <span class="html-italic">p</span> ≤ 0.01, *** <span class="html-italic">p</span> ≤ 0.001.</p>
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<p>Differentiation of C2C12 cells treated with LXG or 5HLXG. (<b>A</b>,<b>C</b>) Myotube formation was observed by immunocytochemistry for MYH. (<b>B</b>,<b>D</b>) Differentiation was assessed using a creatine kinase activity assay. (<b>E</b>,<b>F</b>) mRNA and protein levels of myogenic markers were determined by Real-time RT-PCR and Western blot. Means ± SD (n &gt; 3). * <span class="html-italic">p</span> ≤ 0.05, ** <span class="html-italic">p</span> ≤ 0.01, *** <span class="html-italic">p</span> ≤ 0.001.</p>
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<p>Effects of LXG and 5HLXG on the differentiation of C2C12 cells. (<b>A</b>,<b>C</b>) mRNA and protein levels of MSTN, SMAD2, SMAD3, and ACVR2b were determined by real-time RT-PCR and Western blot. (<b>B</b>,<b>D</b>) ROS levels were determined using a 2′,7′-dichlorofluorescein assay and mRNA levels of NRF2 and SOD2. Means ± SD (n &gt; 3). * <span class="html-italic">p</span> ≤ 0.05, ** <span class="html-italic">p</span> ≤ 0.01, *** <span class="html-italic">p</span> ≤ 0.001.</p>
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<p>Inhibition of MSTN for SM development during CM production. LAX or 5HLAX inhibited MSTN and ROS production, increased the expressions of muscle regulatory factors, and thus, enhanced myogenesis. LAX and 5HLAX both increased NRF2 and SOD2 expressions and downregulated ROS levels.</p>
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13 pages, 6092 KiB  
Article
Solar-Powered Freeze-Melting Desalination Model for Water and Simultaneous Cooling Applications
by Beatriz Castillo-Téllez, Margarita Castillo Téllez and Rosenberg J. Romero
Water 2025, 17(1), 107; https://doi.org/10.3390/w17010107 - 2 Jan 2025
Viewed by 414
Abstract
Freeze-melting (F/M) desalination presents a sustainable and energy-efficient alternative to conventional desalination methods. In this study, we evaluated two solar-powered refrigeration systems, using BaCl2–NH3 and NH3–LiNO3 sorbent–refrigerant pairs, for seawater desalination and cooling applications. The NH3 [...] Read more.
Freeze-melting (F/M) desalination presents a sustainable and energy-efficient alternative to conventional desalination methods. In this study, we evaluated two solar-powered refrigeration systems, using BaCl2–NH3 and NH3–LiNO3 sorbent–refrigerant pairs, for seawater desalination and cooling applications. The NH3–LiNO3 system demonstrated a superior performance, achieving evaporator temperatures below −3 °C and producing up to 8 kg/day of ice. The system operated with a significantly lower energy consumption than the 3–6 kWh/m3 required by reverse osmosis (RO). Practical tests confirmed the dual functionality of the system, providing cooling for food preservation (maintaining 4 °C for 5 h) and climate control while producing desalinated water with total dissolved solids (TDS) levels of 3650 k/m3. Although the TDS remained above the WHO potable water standard, the output is suitable for irrigation and livestock watering. These results highlight the F/M desalination system’s potential to address water scarcity and cooling needs in resource-limited, off-grid regions, contributing to sustainable desalination technologies powered by renewable energy. Full article
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<p>(<b>a</b>) BaCl<sub>2</sub>–NH<sub>3</sub> solar refrigeration equipment for freeze-melting desalination. (<b>b</b>) Flowchart illustrating the working mechanism of the BaCl<sub>2</sub>–NH<sub>3</sub> system.</p>
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<p>Flowchart demonstrating the working mechanism of the LiNO<sub>3</sub>–NH<sub>3</sub> system.</p>
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<p>LiNO<sub>3</sub>–NH<sub>3</sub> solar refrigeration system with CPC for freeze-melting desalination.</p>
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<p>(<b>a</b>) Food preservation chamber and (<b>b</b>) climate control space.</p>
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<p>Integrated ice-based cooling and water distribution system for food preservation and climate control.</p>
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<p>Temperature profile in the evaporator and saline solution for the BaCl<sub>2</sub>–NH<sub>3</sub> solar refrigeration system.</p>
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<p>Temperature profile in the evaporator and saline solution for the NH<sub>3</sub>–LiNO<sub>3</sub> solar refrigeration system.</p>
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<p>Ice formation in the LiNO<sub>3</sub>–NH<sub>3</sub> solar refrigeration system for freeze-melting desalination.</p>
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<p>Salinity levels in ice and remaining liquid after freeze-melting desalination.</p>
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<p>Schematic behavior of normalized temperature (<b>left figure</b>) and saline diffusion (<b>right figure</b>) during the brine separation process.</p>
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<p>Saline ion concentration as a function of radius for a pipe with r= 0.015 m.</p>
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<p>Saline ion concentration as a function of radius for a pipe with r= 0.02 m.</p>
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<p>Saline ion concentration as a function of radius for a pipe with r= 0.025 m.</p>
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<p>Schematic of the generalized saline ion non-linear concentration as a function of radius, based on Equation (3).</p>
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16 pages, 2261 KiB  
Article
Extractive Ethanol Fermentation with Ethanol Recovery by Absorption in Open and Closed Systems
by Kaio César da Silva Rodrigues, Ivan Ilich Kerbauy Veloso, Diego Andrade Lemos, Antonio José Gonçalves Cruz and Alberto Colli Badino
Fermentation 2025, 11(1), 12; https://doi.org/10.3390/fermentation11010012 - 2 Jan 2025
Viewed by 265
Abstract
Conventional ethanol production has limitations, including substrate and product inhibitions, which increase both energy requirements for ethanol recovery and vinasse generation. Extractive fermentation, which removes ethanol as it is produced within the fermentation vat, offers an effective alternative to reducing the inhibitory effects [...] Read more.
Conventional ethanol production has limitations, including substrate and product inhibitions, which increase both energy requirements for ethanol recovery and vinasse generation. Extractive fermentation, which removes ethanol as it is produced within the fermentation vat, offers an effective alternative to reducing the inhibitory effects in conventional processes. However, an efficient method for recovering the extracted ethanol is also crucial. Thus, this study investigated an alternative ethanol production process using extractive ethanol fermentation integrated with ethanol recovery by absorption in both open and closed systems, specifically, comparing scenarios with and without CO2 recirculation produced during fermentation. The recovery system used two absorbers connected in series using monoethylene glycol (MEG) as an absorbent. Under extractive fermentation conditions without CO2 recirculation, the conversion of 300.0 g L−1 of substrate resulted in a total ethanol concentration of 135.2 g L−1, which is 68% higher than that achieved in conventional fermentation (80.4 g L−1). The absorption recovery efficiency reached 91.6%. In the closed system, with CO2 recirculation produced by fermentation, 280.0 g L−1 of substrate was consumed, achieving ethanol production of 126.0 g L−1, with an absorption recovery percentage of 98.3%, similar to that of industrial facilities that use a gas scrubber tower. Additionally, the overall process efficiency was close to that of conventional fermentation (0.448 gethanol gsubstrate−1). These results highlight the potential of this alternative process to reduce vinasse volume and energy consumption for ethanol recovery, lowering total costs and making it a viable option for integrated distilleries that combines ethanol production with other related processing operations. Full article
(This article belongs to the Special Issue Bioprocesses for Biomass Valorization in Biorefineries)
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<p>Experimental apparatus used in fed-batch conventional fermentation (CF).</p>
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<p>Experimental apparatus used in fed-batch extractive fermentations without CO<sub>2</sub> recirculation (open system).</p>
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<p>Experimental apparatus used in fed-batch extractive fermentations with CO<sub>2</sub> recirculation (closed system). P1, P2, P3, P4, P5, and P6 represent pressure measurement points.</p>
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<p>Experimental (symbols) and simulated values (lines) of substrate (C<sub>S</sub>, circles), viable cells (C<sub>X</sub>, squares), and ethanol (C<sub>E</sub>, triangles) concentrations over time in conventional batch fermentation (CF, C<sub>ST</sub> = 180.0 g L<sup>−1</sup>).</p>
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<p>Experimental (symbols) and simulated values (lines) of substrate (C<sub>S</sub>, red circles), viable cells (C<sub>X</sub>, black squares), and ethanol (C<sub>E</sub>, blue triangles) concentrations over time in the extractive fermentations (<b>a</b>) EF1 and (<b>b</b>) EF2 (C<sub>ST</sub> = 180.0 and 300.0 g L<sup>−1</sup>, respectively) of the integrated process without CO<sub>2</sub> recirculation (open system).</p>
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<p>Experimental values of ethanol (black squares) concentrations over time in the absorbers (1st absorber—filled symbols, 2nd absorber—empty symbols) for the (<b>a</b>) EF1 and (<b>b</b>) EF2 fermentations (C<sub>ST</sub> = 180.0 and 300.0 g L<sup>−1</sup>, respectively). The arrows indicate the moments when the absorbers were replaced.</p>
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<p>Experimental values of substrate (C<sub>S</sub>, red circles), viable cells (C<sub>X</sub>, black squares), and ethanol (C<sub>E</sub>, blue triangles) concentrations over time in the extractive fermentations (<b>a</b>) EFR1 and (<b>b</b>) EFR2 (C<sub>ST</sub> = 180.0 and 280.0 g L<sup>−1</sup>, respectively) of the integrated process with CO<sub>2</sub> recirculation (closed system).</p>
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<p>Experimental values of ethanol concentration (black squares) over time in the first absorber (filled symbols) and second absorber (empty symbols) over extractive ethanol fermentations with CO<sub>2</sub> recirculation: (<b>a</b>) EFR1 (C<sub>ST</sub> = 180.0 g L<sup>−1</sup>) and (<b>b</b>) EFR2 (C<sub>ST</sub> = 280.0 g L<sup>−1</sup>). The arrows indicate the moments when the absorbers were replaced.</p>
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34 pages, 5374 KiB  
Review
A Comprehensive Review of Green Energy Technologies: Towards Sustainable Clean Energy Transition and Global Net-Zero Carbon Emissions
by Vinod Kumar Sharma, Giulia Monteleone, Giacobbe Braccio, Cosmas N. Anyanwu and Nneoma N. Aneke
Processes 2025, 13(1), 69; https://doi.org/10.3390/pr13010069 - 31 Dec 2024
Viewed by 450
Abstract
The present paper seeks to showcase the significant potential of alternative energy technologies in driving clean energy transition. Renewable energy sources, including hydro, geothermal, biomass, solar, and wind energy, are developed and marketed as low- or non-carbon alternatives to conventional energy sources. However, [...] Read more.
The present paper seeks to showcase the significant potential of alternative energy technologies in driving clean energy transition. Renewable energy sources, including hydro, geothermal, biomass, solar, and wind energy, are developed and marketed as low- or non-carbon alternatives to conventional energy sources. However, the high upfront costs of these energy resources, coupled with their intermittency, are demerits that must be dealt with. Since certain nuclear technologies generate significantly less waste than coal and oil, nuclear energy is occasionally regarded as a green energy source, though the primary source of nuclear energy, namely uranium, is a finite resource. The main goal of developing green energy technologies is to provide energy in a sustainable manner while cutting down on waste and greenhouse gas emissions, thus reducing the overall carbon footprint of energy production. Full article
(This article belongs to the Special Issue Biomass to Renewable Energy Processes, 2nd Edition)
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<p>Nuclear Plants Operational in the World [<a href="#B16-processes-13-00069" class="html-bibr">16</a>].</p>
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<p>Nuclear power reactors under construction in the world [<a href="#B16-processes-13-00069" class="html-bibr">16</a>].</p>
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<p>Number of fusion devices under study in the world [<a href="#B17-processes-13-00069" class="html-bibr">17</a>].</p>
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<p>Cumulative installed wind power capacity (GW) worldwide from 2001 to 2023 [<a href="#B36-processes-13-00069" class="html-bibr">36</a>].</p>
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<p>Levelized cost of generating electricity (LCOE) by technology [<a href="#B39-processes-13-00069" class="html-bibr">39</a>].</p>
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<p>Evolution of Global RE Employment by Technology. Source: [<a href="#B43-processes-13-00069" class="html-bibr">43</a>].</p>
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<p>Energy production from renewables in 2023 [<a href="#B43-processes-13-00069" class="html-bibr">43</a>].</p>
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<p>Global installed CSP capacity (MW) distribution (This information was obtained from the National Renewable Energy Laboratory “NREL” official website) [<a href="#B45-processes-13-00069" class="html-bibr">45</a>].</p>
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<p>Cost of solar heating and cooling (USD/MWhth) [<a href="#B50-processes-13-00069" class="html-bibr">50</a>].</p>
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<p>Global Status of Solar District Heating in 2023. Source [<a href="#B51-processes-13-00069" class="html-bibr">51</a>].</p>
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<p>Novel Solar Thermal Electricity Generation Plant by ENEA.</p>
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<p>Deployment of Solar PV by Continent [<a href="#B56-processes-13-00069" class="html-bibr">56</a>].</p>
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<p>Biomass Processing Technologies. Source [<a href="#B64-processes-13-00069" class="html-bibr">64</a>].</p>
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<p>Continuous steam explosion pilot plant designed by Stake Technology Ltd., Ontario, Canada, installed at the ENEA Trisaia Centre in Southern Italy.</p>
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<p>Primary risks associated with key clean electrification technologies [<a href="#B95-processes-13-00069" class="html-bibr">95</a>].</p>
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<p>Type of hydrogen based on the energy that produced it.</p>
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15 pages, 2860 KiB  
Article
Eight Weeks of Resistance Training Is Not a Sufficient Stimulus to Improve Body Composition in Post-COVID-19 Elderly Adults
by Katarzyna Kaczmarczyk, Kamila Płoszczyca, Karol Jaskulski and Miłosz Czuba
J. Clin. Med. 2025, 14(1), 174; https://doi.org/10.3390/jcm14010174 - 31 Dec 2024
Viewed by 310
Abstract
Background: This study sought to assess how body mass (BM) and body composition in post-COVID-19 elderly adults were affected by 8 weeks of resistance training. An additional goal was to determine the agreement between Bioelectrical Impedance Analysis (BIA) and Dual Energy X-Ray [...] Read more.
Background: This study sought to assess how body mass (BM) and body composition in post-COVID-19 elderly adults were affected by 8 weeks of resistance training. An additional goal was to determine the agreement between Bioelectrical Impedance Analysis (BIA) and Dual Energy X-Ray Absorptiometry (DXA) in elderly people. Methods: Participants were randomly assigned to an intervention Group, which engaged in 8 weeks of resistance training, and a Control Group, which was advised to maintain their usual activity levels. Before and after the intervention, the body composition was analyzed via the BIA and DXA methods. Results: We found no statistically significant changes in BM or body composition following resistance training. BIA was found to overestimate the participants’ baseline BM and fat-free mass (FFM) and to underestimate the fat mass (FM), compared to the DXA method. There were no significant differences in intervention-induced changes in FM and FFM measured by BIA and DXA. Conclusions: Moderate intensity resistance training lasting 8 weeks was not found to be a sufficient stimulus to improve BM and body composition in post-COVID-19 elderly adults. We also conclude that BIA may serve as a viable alternative to DXA for measuring longitudinal changes in body composition in elderly people. Full article
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<p>CONSORT flow diagram. F—females; M—males.</p>
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<p>Bland–Altman plots comparing body mass (BM) (<b>A</b>), fat mass (FM) (<b>B</b>), and fat-free mass (FFM) (<b>C</b>) determined by DXA and BIA methods at baseline. The solid line represents the bias, and the dashed lines represent upper and lower limits of agreement (LOA = Bias ± 1.96 × SD). BIA—Bioelectrical Impedance Analysis; DXA—Dual Energy X-Ray Absorptiometry.</p>
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17 pages, 803 KiB  
Review
What Veterinarians Need to Know About the Newly-Emerging Field of Insects-as-Food-and-Feed
by Kimberly L. Boykin and Mark A. Mitchell
Vet. Sci. 2025, 12(1), 12; https://doi.org/10.3390/vetsci12010012 - 31 Dec 2024
Viewed by 434
Abstract
Over the last two decades, the insects-as-food-and-feed industry has rapidly emerged. Its growth is largely because insects require substantially less resources (water, food, and energy) to produce than traditional sources of animal protein, making it a sustainable alternative food option. As this industry [...] Read more.
Over the last two decades, the insects-as-food-and-feed industry has rapidly emerged. Its growth is largely because insects require substantially less resources (water, food, and energy) to produce than traditional sources of animal protein, making it a sustainable alternative food option. As this industry continues to grow, veterinarians will likely be called upon to assist in identifying food safety concerns, assessing animal health, implementing biosecurity measures, and formulating/prescribing treatment protocols comparable to what we have seen with the honeybee industry and the institution of veterinary feed directives (VFDs). Similar to other agricultural markets, high animal densities and management practices put insects at high risk for infectious diseases. Veterinarians interested in working with these species will need to become knowledgeable regarding the diseases afflicting the feeder insect industry and how best to diagnose and treat pathogens of concern. Using the edible cricket industry as an example, this review will highlight health and production issues while drawing similarities to other traditional livestock operations. If the insects-as-feed-and-food industry is going to be viable, veterinary involvement will be essential to ensure that insects can be used as a safe source of food for all. Full article
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<p>Visual representations of the top three cricket species used in the feeder insect industry, (<b>A</b>) <span class="html-italic">Acheta domesticus</span> cricket, adult female [<a href="#B40-vetsci-12-00012" class="html-bibr">40</a>]; (<b>B</b>) <span class="html-italic">Gryllodes sigillatus</span> cricket, subadult female [<a href="#B41-vetsci-12-00012" class="html-bibr">41</a>]; (<b>C</b>) <span class="html-italic">Gryllus assimilis</span> cricket, adult male [<a href="#B42-vetsci-12-00012" class="html-bibr">42</a>].</p>
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20 pages, 830 KiB  
Review
Sustainable Nutritional Strategies for Gut Health in Weaned Pigs: The Role of Reduced Dietary Crude Protein, Organic Acids and Butyrate Production
by Kathryn Ruth Connolly, Torres Sweeney and John V. O’Doherty
Animals 2025, 15(1), 66; https://doi.org/10.3390/ani15010066 - 30 Dec 2024
Viewed by 381
Abstract
Weaning in piglets presents significant physiological and immunological challenges, including gut dysbiosis and increased susceptibility to post-weaning diarrhoea (PWD). Abrupt dietary, environmental, and social changes during this period disrupt the intestinal barrier and microbiota, often necessitating antimicrobial use. Sustainable dietary strategies are critical [...] Read more.
Weaning in piglets presents significant physiological and immunological challenges, including gut dysbiosis and increased susceptibility to post-weaning diarrhoea (PWD). Abrupt dietary, environmental, and social changes during this period disrupt the intestinal barrier and microbiota, often necessitating antimicrobial use. Sustainable dietary strategies are critical to addressing these issues while reducing reliance on antimicrobials. Reducing dietary crude protein mitigates the availability of undigested proteins for pathogenic bacteria, lowering harmful by-products like ammonia and branched-chain fatty acids, which exacerbate dysbiosis. Organic acid supplementation improves gastric acidification, nutrient absorption, and microbial balance, while also serving as an energy-efficient alternative to traditional grain preservation methods. Increasing intestinal butyrate, a key short-chain fatty acid with anti-inflammatory and gut-protective properties, is particularly promising. Butyrate strengthens intestinal barrier integrity by upregulating tight junction proteins, reduces inflammation by modulating cytokine responses, and promotes anaerobic microbial stability. Exogenous butyrate supplementation via salts provides immediate benefits, while endogenous stimulation through prebiotics (e.g., resistant starch) and probiotics promotes sustained butyrate production. These interventions selectively enhance butyrate-producing bacteria such as Roseburia and Faecalibacterium prausnitzii, further stabilising the gut microbiota. Integrating these strategies can enhance gut integrity, microbial resilience, and immune responses in weaned piglets. Their combination offers a sustainable, antimicrobial-free approach to improving health and productivity in modern pig production systems. Full article
(This article belongs to the Special Issue Impact of Genetics and Feeding on Growth Performance of Pigs)
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<p>The proposed synergistic effects of reduced dietary crude protein, organic acid and butyrate on post-weaned pig growth and health.</p>
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21 pages, 1609 KiB  
Article
Exploring Feed Digestibility and Broiler Performance in Response to Dietary Supplementation of Chlorella vulgaris
by Sofie Van Nerom, Kobe Buyse, Filip Van Immerseel, Johan Robbens and Evelyne Delezie
Animals 2025, 15(1), 65; https://doi.org/10.3390/ani15010065 - 30 Dec 2024
Viewed by 332
Abstract
This study evaluated the feed digestibility of diets including autotrophic Chlorella (C.) vulgaris in 252 male broilers (Ross 308), comparing unprocessed biomass (trial 1) and pulsed electric field (PEF) processed biomass (trial 2) at inclusion levels up to 20%. In trial 2, performance [...] Read more.
This study evaluated the feed digestibility of diets including autotrophic Chlorella (C.) vulgaris in 252 male broilers (Ross 308), comparing unprocessed biomass (trial 1) and pulsed electric field (PEF) processed biomass (trial 2) at inclusion levels up to 20%. In trial 2, performance and meat color were also evaluated. Each trial included seven treatments (0%, 1%, 2%, 5%, 10%, 15%, and 20% (%w/w on dry matter (DM)) C. vulgaris) with six replicates (three birds per replicate) per treatment. Data were analyzed using linear, quadratic, and broken-line models. Control feeds without microalgae inclusion achieved a crude protein digestibility of 82.04 ± 1.42% (trial 1) and 81.63 ± 1.90% (trial 2), while feed with 20% non-processed microalgae inclusion only had a protein digestibility of 66.96 ± 1.16% (trial 1) and feed with PEF processed microalgae at 20% had a protein digestibility of 72.75 ± 0.34% (trial 2). In general, increasing inclusion levels of C. vulgaris impaired nutrient digestibility, significantly reducing crude protein, crude fat, gross energy, and crude ash digestibility (p < 0.001). Broken-line models identified critical inclusion thresholds beyond which digestibility declined significantly, i.e., at 10% for crude protein, 12.53% for crude fat, and 9.26% for gross energy in unprocessed microalgae feeds (trial 1). For PEF-processed microalgae, only a broken line fit was obtained for gross energy, with a breakpoint at 5% (trial 2). Furthermore, a significant linear decrease in body weight (BW) (p < 0.001), average daily gain (ADG) (p < 0.001), average daily feed intake (ADFI) (p = 0.006), and relative and absolute breast filet weight was observed as microalgae inclusion level increased (trial 2). Color parameters also changed significantly with increasing microalgae inclusion level: L* showed a significant linear decrease (p = 0.029), b* and a* showed a significant linear increase (p < 0.001) (trial 2). This research advances the exploration of sustainable protein alternatives, highlighting the potential of microalgae in broiler feed and the benefits of processing methods such as PEF to enhance nutrient utilization. Full article
(This article belongs to the Section Poultry)
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<p>Relation between microalgae inclusion level in the feed and crude protein digestibility. Broken-line model (segmented) (blue, solid line, breakpoint: 10.00% [CI: 7.25%, 12.75%] slope before breakpoint: −0.32 [CI: −0.43, −0.22], slope after breakpoint: −1.12 [CI: −1.38, −0.87], Davies-test: <span class="html-italic">p</span>-value: 0.148), linear model (red, dotted line, slope: −0.69 [CI: −0.77, −0.61], <span class="html-italic">p</span> &lt; 0.001), and quadratic (black, dashed line, <span class="html-italic">p</span> &lt; 0.001) model describing the relationship between crude protein digestibility of the feed (%<span class="html-italic">w/w</span> on DM) and inclusion level of unprocessed autotrophic microalgae (A) (left figure, trial 1, n = 6). Linear model (red, dotted line, slope: −0.49 [CI: −0.55, −0.43], <span class="html-italic">p</span> &lt; 0.001) and quadratic model (black, dashed line) (<span class="html-italic">p</span> &lt; 0.001) describing the relationship between crude protein digestibility of the feed (%<span class="html-italic">w/w</span> on DM) and inclusion level of PEF-processed autotrophic microalgae (APEF) (right figure, trial 2, n = 6). Black dots indicate measured data points. PEF: pulsed electric field. CI: confidence interval.</p>
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<p>Relation between microalgae inclusion level in the feed and crude fat digestibility. Broken-line model (segmented) (blue, solid line, breakpoint: 12.53% [CI: 10.41%; 14.65%], slope before breakpoint: −0.56 [CI: −0.88, −0.23], slope after breakpoint: −3.13 [CI: −3.91, −2.35], Davies-test: <span class="html-italic">p</span>-value: 0.930), linear model (red, dotted line, slope: −1.39 [CI: −1.61, −1.17], <span class="html-italic">p</span> &lt; 0.001), and quadratic model (black, dashed line) (<span class="html-italic">p</span> &lt; 0.001) describing the relationship between crude fat digestibility of the feed (%<span class="html-italic">w</span>/<span class="html-italic">w</span> on DM) and inclusion level of unprocessed autotrophic microalgae (A) (left figure, trial 1, n = 6). Linear model (red, dotted line, slope: −0.65 [CI: −0.77, −0.53], <span class="html-italic">p</span> &lt; 0.001) and quadratic model (black, dashed line, <span class="html-italic">p</span> &lt; 0.001) describing the relationship between crude fat digestibility of the feed (%<span class="html-italic">w</span>/<span class="html-italic">w</span> on DM) and inclusion level of PEF-processed autotrophic microalgae (APEF) (right figure, trial 2, n = 6). Black dots indicate measured data points. PEF: pulsed electric field. CI: confidence interval.</p>
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<p>Relation between microalgae inclusion level in the feed and gross energy digestibility. Broken-line model (segmented) (blue, solid line, breakpoint: 9.26% [CI: 4.98%, 13.54%], slope before breakpoint: −0.1 [CI: −0.59, 0.39], slope after breakpoint: −1.07 [CI: −1.34, −0.79], Davies-test: <span class="html-italic">p</span>-value: 0.125), linear model (red, dotted line, slope: −0.58 [CI: −0.70, −0.45], <span class="html-italic">p</span> &lt; 0.001), and quadratic model (black, dashed line, <span class="html-italic">p</span> &lt; 0.001) describing the relationship between gross energy digestibility of the feed (%w/w on DM) and inclusion level of unprocessed autotrophic microalgae (A) (left figure, trial 1, n = 6). Broken-line model (segmented) (blue, solid line, breakpoint: 5 [CI: −6.11, 16.11], slope before breakpoint: −0.09 [CI: −0.74, 0.57], slope after breakpoint: −0.34 [CI: −0.42, −0.25], Davies-test: <span class="html-italic">p</span>-value: 0.641), linear model (red, dotted line, slope: −0.28 [CI: −0.33, −0.28], <span class="html-italic">p</span> &lt; 0.001), and quadratic model (black, dashed line, <span class="html-italic">p</span> &lt; 0.001) describing the relationship between gross energy digestibility of the feed (%w/w on DM) and inclusion level of PEF-processed autotrophic microalgae (APEF) in the feed (%) (right figure, trial 2, n = 6). Black dots indicate measured data points. PEF: pulsed electric field. CI: confidence interval.</p>
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<p>Relation between microalgae inclusion level in the feed and crude ash digestibility. Linear model (red, dotted line, slope: −0.53 [CI: −0.61, −0.45], <span class="html-italic">p</span> &lt; 0.001) and quadratic model (black, dashed line, <span class="html-italic">p</span> &lt; 0.001) describing the relationship between crude ash digestibility of the feed (%w/w on DM) and inclusion level of autotrophic microalgae (A) (left figure, trial 1, n = 6). Linear model (red, dotted line, slope: −0.44 [CI: −0.55, −0.34], <span class="html-italic">p</span> &lt; 0.001) and quadratic model (black, dashed line) (<span class="html-italic">p</span> &lt; 0.001) describing the relationship between crude ash digestibility of the feed (%w/w on DM) and inclusion level of PEF-processed autotrophic microalgae (APEF) (right figure, trial 2, n = 6). Black dots indicate measured data points. PEF: pulsed electric field. CI: confidence interval.</p>
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<p>Essential amino acids levels relative to lysine (%) of <span class="html-italic">C. vulgaris</span> used in the current study and of soybean meal 48 reported by CVB, (2018).</p>
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16 pages, 3272 KiB  
Article
Innovative Use of Wood Ash for Fluoride Removal from Water: Comprehensive Experiments and Mechanism Insight
by Jae-In Lee, Jin-Kyu Kang, Sanghyun Jeong, Chang-Gu Lee, Joon-Weon Choi and Seong-Jik Park
Appl. Sci. 2025, 15(1), 245; https://doi.org/10.3390/app15010245 - 30 Dec 2024
Viewed by 310
Abstract
This study investigates the potential of wood ash (WA), a by-product of wood-based energy production, as an eco-friendly alternative for removing fluoride from water. Kinetic analysis revealed that WA enables rapid fluoride removal, reaching equilibrium within 1 h (112.09 ± 3.9 mg/g). Equilibrium [...] Read more.
This study investigates the potential of wood ash (WA), a by-product of wood-based energy production, as an eco-friendly alternative for removing fluoride from water. Kinetic analysis revealed that WA enables rapid fluoride removal, reaching equilibrium within 1 h (112.09 ± 3.9 mg/g). Equilibrium analysis demonstrated that WA exhibits a Langmuir maximum capacity of 157.34 mg/g, indicating a high adsorption capacity that ranks within the top 10% of reported adsorbents (34th out of 328). According to thermodynamic analysis, the adsorption process appears to be both endothermic and spontaneous at elevated temperatures. pH dependence studies showed that while the fluoride adsorption capacity of WA peaked under acidic conditions, it remained relatively stable (116.01 ± 0.8 mg/g) over a wide range of pH levels (5 to 11). An optimal dosage of 6.67 g/L achieved a greater than 98% fluoride removal rate. Coexisting anions affected the fluoride adsorption capacity of WA, with the order of influence being PO43− > CO32− >> SO42− > NO3 ≈ Cl. Mechanistic analyses confirmed the surface precipitation of CaF2 as the primary mechanism responsible for fluoride removal. With a Ca content of over 66 wt.%, WA facilitates enhanced fluoride removal. Overall, this study highlights the efficacy of WA as a sustainable adsorbent for the removal of fluoride from water, contributing to the valorization of WA in wastewater treatment applications. Full article
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<p>Fluorine adsorption by wood ash (WA) over time and its comparison with kinetic model fittings. (<b>a</b>) pseudo-first-order (PFO), pseudo-second-order (PSO), and Elovich model; (<b>b</b>) intra-particle diffusion (IPD) model.</p>
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<p>Fluoride adsorption capacity of WA at equilibrium and its comparison with adsorption isotherm fittings.</p>
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<p>Influence of (<b>a</b>) initial pH of the fluoride solution, (<b>b</b>) dose of WA, and (<b>c</b>) presence of coexisting anions on fluoride removal. The different letters (a, b, c, d, e, and f) indicate statistically significant differences among treatments, as determined by Duncan’s multiple range test at a 5% probability level.</p>
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<p>Field emission scanning electron microscopy images of (<b>a</b>) WA and (<b>b</b>) fluoride-adsorbed WA (F-WA). Accelerating voltage: 15.0 kV; magnification: ×10,000; scale bar: 5.00 μm.</p>
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<p>XPS spectra of WA and fluoride-adsorbed WA (F-WA): (<b>a</b>) C1s spectrum of WA, (<b>b</b>) C1s spectrum of F-WA, (<b>c</b>) Ca2p spectrum of WA, (<b>d</b>) Ca2p spectrum of F-WA, and (<b>e</b>) F1s spectrum of F-WA.</p>
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<p>Schematic diagram of fluoride removal using wood ash (WA).</p>
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25 pages, 3570 KiB  
Review
Contemporary Trends in Pulsed Field Ablation for Cardiac Arrhythmias
by Hagai Yavin, Mark Prasad, Jonathan Gordon, Tolga Aksu and Henry D. Huang
J. Cardiovasc. Dev. Dis. 2025, 12(1), 10; https://doi.org/10.3390/jcdd12010010 - 30 Dec 2024
Viewed by 303
Abstract
Pulsed field ablation (PFA) is a catheter-based procedure that utilizes short high voltage and short-duration electrical field pulses to induce tissue injury. The last decade has yielded significant scientific progress and quickened interest in PFA as an energy modality leading to the emergence [...] Read more.
Pulsed field ablation (PFA) is a catheter-based procedure that utilizes short high voltage and short-duration electrical field pulses to induce tissue injury. The last decade has yielded significant scientific progress and quickened interest in PFA as an energy modality leading to the emergence of the clinical use of PFA technologies for the treatment of atrial fibrillation. It is generally agreed that more research is needed to improve our biophysical understanding of PFA for clinical cardiac applications as well as its potential as a potential alternative energy source to thermal ablation modalities for the treatment of other arrhythmias. In this review, we discuss the available preclinical and clinical evidence for PFA for atrial fibrillation, developments for ventricular arrhythmia (VA) ablation, and future perspectives. Full article
(This article belongs to the Special Issue Heart Rhythm Disorders: Diagnosis, Treatment, and Management)
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<p>Conceptual figures showing an association between proximity of the electrode and relationship between strength of the electric field which may result in irreversible and reversible cellular electroporation. Theoretical differences between unipolar and bipolar configurations on biophysics of pulsed electric field delivery.</p>
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<p>Clinical and investigation catheter technologies for pulsed field ablation.</p>
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<p>(<b>A</b>) In four swine, direct ablation with PFA and RFA within the lumen of the esophagus were performed to assess the effect of PFA on esophagus tissue. <b>Left</b>, 3D anatomical map of the esophagus and RA. Red dots represent RFA while green dots, PFA. <b>Middle,</b> gross pathology demonstrates direct ablation to the esophageal lumen, interchangeably with PFA and RFA. <b>Right</b>, histological slides of PF and RF lesions show mild edema and focal superficial necrosis in PFA lesions, while RFA shows severe edema, necrosis, and hemorrhage spanning to the deep muscularis layers. (<b>B</b>) In six swine, 5.5 (1–8) PFA applications were placed on the endocardial RA, opposing the phrenic nerve. These did not result in phrenic nerve paralysis. Comparison RF ablation. <b>Left</b>, anatomical map with the course of the right phrenic nerve identified by pacing the lateral RA marked in light-blue tags. Green tags represent PFA and red represent RFA. <b>Middle</b>, gross pathology of the phrenic nerve with clear lesions at RFA sites opposed to the healthy-looking tissue at the PFA sites. <b>Right</b>, histological analysis at PFA application sites demonstrating PFA selectively affected cardiomyocytes but spared blood vessels and nervous tissue.</p>
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<p>(<b>A</b>) First pulsed field ablation (PFA) application from left atrium near right superior pulmonary vein induces a profound vagal response. (<b>B</b>) The red spherical tags show radiofrequency lesions given nearby the PFA lesion where acute vagal response was obtained which are indicated with blue and green spherical tags (from superior view). Although radiofrequency (RF) lesions did not induce further vagal response after PFA application, RF applications were performed to ensure long-term parasympathetic denervation. Image reproduced with permission from Sikiric et al. <span class="html-italic">J. Interv. Card Electrophysiol.</span> (2024).</p>
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<p>(<b>A</b>) shows penta-spline pulsed field ablation (PFA) catheter positioned at the right superior ganglionic plexus. (<b>B</b>) shows penta-spline PFA catheter position at the left superior and right inferior ganglionic plexuses.</p>
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33 pages, 17902 KiB  
Article
Modeling and Design of a Grid-Tied Renewable Energy System Exploiting Re-Lift Luo Converter and RNN Based Energy Management
by Kavitha Paulsamy and Subha Karuvelam
Sustainability 2025, 17(1), 187; https://doi.org/10.3390/su17010187 - 30 Dec 2024
Viewed by 328
Abstract
The significance of the Hybrid Renewable Energy System (HRES) is profound in the current scenario owing to the mounting energy requirements, pressing ecological concerns and the pursuit of transitioning to greener energy alternatives. Thereby, the modeling and design of HRES, encompassing PV–WECS–Battery, which [...] Read more.
The significance of the Hybrid Renewable Energy System (HRES) is profound in the current scenario owing to the mounting energy requirements, pressing ecological concerns and the pursuit of transitioning to greener energy alternatives. Thereby, the modeling and design of HRES, encompassing PV–WECS–Battery, which mainly focuses on efficient power conversion and advanced control strategy, is proposed. The voltage gain of the PV system is improved using the Re-lift Luo converter, which offers high efficiency and power density with minimized ripples and power losses. Its voltage lift technique mitigates parasitic effects and delivers improved output voltage for grid synchronization. To control and stabilize the converter output, a Proportional–Integral (PI) controller tuned using a novel hybrid algorithm combining Grey Wolf Optimization (GWO) with Hermit Crab Optimization (HCO) is implemented. GWO follows the hunting and leadership characteristics of grey wolves for improved simplicity and robustness. By simulating the shell selection behavior of hermit crabs, the HCO adds diversity to exploitation. Due to these features, the hybrid GWO–HCO algorithm enhances the PI controller’s capability of handling dynamic non-linear systems, generating better control accuracy, and rapid convergence to optimal solutions. Considering the Wind Energy Conversion System (WECS), the PI controller assures improved stability despite fluctuations in wind. A Recurrent Neural Network (RNN)-based battery management system is also incorporated for accurate monitoring and control of the State of Charge (SoC) and the terminal voltage of battery storage. The simulation is conducted in MATLAB Simulink 2021a, and a lab-scale prototype is implemented for real-time validation. The Re-lift Luo converter achieves an efficiency of 97.5% and a voltage gain of 1:10 with reduced oscillations and faster settling time using a Hybrid GWO–HCO–PI controller. Moreover, the THD is reduced to 1.16%, which indicates high power quality and reduced harmonics. Full article
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<p>Configuration of the PV–WECS–Battery Integrated HRES.</p>
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<p>Circuit representation of the PV system.</p>
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<p>PV curve.</p>
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<p>Re-lift Luo converter.</p>
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<p>Modes of operation. (<b>a</b>) Mode 1. (<b>b</b>) Mode 2.</p>
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<p>Operational waveform.</p>
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<p>Efficiency comparison of converters.</p>
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<p>Flowchart of the Hybrid GWO–HCO.</p>
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<p>Structure of the Hybrid GWO–HCO optimized the PI controller system.</p>
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<p>RNN for the battery modeling.</p>
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<p>Grid voltage synchronization.</p>
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<p>Simulation setup of the proposed system.</p>
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<p>Waveforms representing (<b>a</b>) Temperature and (<b>b</b>) Irradiation.</p>
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<p>PV panel waveforms represent (<b>a</b>) voltage and (<b>b</b>) current.</p>
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<p>Waveforms for output voltage of the Re-lift Luo converter using (<b>a</b>) PI controller, (<b>b</b>) GWO–PI controller, (<b>c</b>) Hybrid GWO–HCO–PI controller, and (<b>d</b>) Combined representation of the converter outputs.</p>
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<p>Output current waveform of Re-lift Luo converter.</p>
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<p>Output voltage waveform of (<b>a</b>) DFIG and (<b>b</b>) PWM rectifier.</p>
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<p>Waveforms for battery parameters.</p>
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<p>Waveforms representing grid parameters.</p>
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<p>Single-phase of grid current and voltage.</p>
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<p>Waveforms of (<b>a</b>) real power, (<b>b</b>) reactive power.</p>
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<p>Power factor waveform.</p>
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<p>THD Waveform.</p>
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<p>Hardware setup.</p>
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<p>PV system output (<b>a</b>) Voltage (<b>b</b>) Current.</p>
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<p>Converter voltage waveform using (<b>a</b>) PI controller (<b>b</b>) GWO-PI controller (<b>c</b>) GWO-HCO-PI controller.</p>
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<p>(<b>a</b>) Output voltage of DFIG (<b>b</b>) Output of PWM rectifier.</p>
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<p>(<b>a</b>) Battery SoC (<b>b</b>) DC-link voltage.</p>
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<p>Grid-side (<b>a</b>) Voltage and (<b>b</b>) Current.</p>
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<p>Grid current THD in (<b>a</b>) R-phase (<b>b</b>) Y-phase and (<b>c</b>) B-phase.</p>
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<p>RMSE convergence of optimization algorithms.</p>
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<p>Voltage gain analysis of converters.</p>
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37 pages, 19268 KiB  
Review
From Waste to Worth: Upcycling Plastic into High-Value Carbon-Based Nanomaterials
by Ahmed M. Abdelfatah, Mohamed Hosny, Ahmed S. Elbay, Nourhan El-Maghrabi and Manal Fawzy
Polymers 2025, 17(1), 63; https://doi.org/10.3390/polym17010063 - 30 Dec 2024
Viewed by 631
Abstract
Plastic waste (PW) presents a significant environmental challenge due to its persistent accumulation and harmful effects on ecosystems. According to the United Nations Environment Program (UNEP), global plastic production in 2024 is estimated to reach approximately 500 million tons. Without effective intervention, most [...] Read more.
Plastic waste (PW) presents a significant environmental challenge due to its persistent accumulation and harmful effects on ecosystems. According to the United Nations Environment Program (UNEP), global plastic production in 2024 is estimated to reach approximately 500 million tons. Without effective intervention, most of this plastic is expected to become waste, potentially resulting in billions of tons of accumulated PW by 2060. This study explores innovative approaches to convert PW into high-value carbon nanomaterials (CNMs) such as graphene, carbon nanotubes (CNTs), and other advanced carbon structures. Various methods including pyrolysis, arc discharge, catalytic degradation, and laser ablation have been investigated in transforming PW into CNMs. However, four primary methodologies are discussed herein: thermal decomposition, chemical vapor deposition (CVD), flash joule heating (FJH), and stepwise conversion. The scalability of the pathways discussed for industrial applications varies significantly. Thermal decomposition, particularly pyrolysis, is highly scalable due to its straightforward setup and cost-effective operation, making it suitable for large-scale waste processing plants. It also produces fuel byproducts that can be used as an alternative energy source, promoting the concept of energy recovery and circular economy. CVD, while producing high-quality carbon materials, is less scalable due to the high cost and required complex equipment, catalyst, high temperature, and pressure, which limits its use to specialized applications. FJH offers rapid synthesis of high-quality graphene using an economically viable technique that can also generate valuable products such as green hydrogen, carbon oligomers, and light hydrocarbons. However, it still requires optimization for industrial throughput. Stepwise conversion, involving multiple stages, can be challenging to scale due to higher operational complexity and cost, but it offers precise control over material properties for niche applications. This research demonstrates the growing potential of upcycling PW into valuable materials that align with global sustainability goals including industry, innovation, and infrastructure (Goal 9), sustainable cities and communities (Goal 11), and responsible consumption and production (Goal 12). The findings underscore the need for enhanced recycling infrastructure and policy frameworks to support the shift toward a circular economy and mitigate the global plastic crisis. Full article
(This article belongs to the Section Circular and Green Polymer Science)
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<p>Total PW imports, total trade values, and average unit prices paid by the top 22 importers from 2013 to 2022. Reproduced from [<a href="#B7-polymers-17-00063" class="html-bibr">7</a>] under creative commons license CC BY 4.0.</p>
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<p>(<b>A</b>) Overview of the types and conditions of plastics utilized as feedstock for synthesizing carbon materials, including specifics on polymer types, physical state (e.g., unused, recycled), and any preprocessing methods applied. (<b>B</b>) Trend analysis shows the growth in the number of original research articles indexed in Scopus that focus on converting plastics into carbon materials over time, highlighting key milestones and shifts in research focus. a refers to the data collected by the authors of this publication on 29 June 2021 (<b>C</b>) Classification of the various carbon materials produced from plastics, detailing categories such as CNTs, graphene, and carbon black, along with their respective properties and characteristics. (<b>D</b>) Summary of the diverse fields of application for the carbon materials derived from plastics, including energy storage, electronics, environmental remediation, and composites, with examples of specific use cases in each sector. (<b>A</b>–<b>D</b>) are reproduced from [<a href="#B62-polymers-17-00063" class="html-bibr">62</a>] with permission from Elsevier, Copyright (2024).</p>
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<p>A comprehensive illustration depicting the lifecycle of PW, including its systematic fate from disposal to treatment practices. This includes an overview of different waste management techniques such as recycling, incineration, and landfilling, along with their environmental impacts and effectiveness in mitigating plastic pollution. Adapted from [<a href="#B69-polymers-17-00063" class="html-bibr">69</a>] under creative commons license CC BY 4.0.</p>
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<p>Sources and pathways of PW discharge, showing how waste from various origins (e.g., households, industry, aquaculture) reaches different environmental compartments (road, soil, wetlands, sea, reservoir tanks) via routes like atmospheric transport, landfills, sludge, and wastewater treatment. These lines refer to the different pathways of plastic discharge from various uses of plastic. Adapted from [<a href="#B70-polymers-17-00063" class="html-bibr">70</a>] under creative commons license CC BY 4.0.</p>
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<p>Possible routes for PW recycling, illustrating the four main pathways: Primary recycling, which involves mechanical reprocessing of scrap plastics into products with equivalent properties; secondary recycling, where used plastics are reprocessed into products with lower properties; tertiary recycling, focusing on the recovery of valuable chemical constituents such as monomers or additives; and quaternary recycling, which involves the recovery of energy from PW. These routes represent the key strategies in waste management and valorization of plastic materials. Adapted from [<a href="#B69-polymers-17-00063" class="html-bibr">69</a>] under creative commons license CC BY 4.0.</p>
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<p>Diverse applications of carbon-based nanomaterials derived from the conversion of PW.</p>
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<p>(<b>A</b>) Adsorption of MG (malachite green) dye on AC derived from polyurethane waste. Reprinted from [<a href="#B103-polymers-17-00063" class="html-bibr">103</a>] with permission from Elsevier, Copyright (2020). (<b>B</b>) Summarizing the adsorption removal of Cu (II), and Cr (VI) via PVC-derived hydrochar. Reprinted from [<a href="#B110-polymers-17-00063" class="html-bibr">110</a>] with permission from Elsevier, Copyright (2020).</p>
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<p>Schematic representation of the primary techniques employed for converting various types of PW into valuable graphene. This figure includes the following methods: (1) Thermal decomposition, illustrating the pyrolysis process and its parameters; (2) CVD, showing the setup and conditions necessary for graphene synthesis; (3) FJH, depicting the rapid heating mechanism and its advantages; and (4) stepwise conversion, outlining the multi-stage process involved in this method. Each technique draws attention to key features, potential benefits, and challenges associated with the conversion process.</p>
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<p>(<b>A</b>) Transmission electron microscopy (TEM) image and (<b>B</b>) high-resolution TEM (HR-TEM) image of graphene; (<b>C</b>) corresponding TEM image with an inset scanning electron microscopy (SEM) image of NG, illustrating its morphology; and (<b>D</b>) selected area electron diffraction (SAED) pattern of NG, providing insights into its crystallinity and structural integrity. Adapted from [<a href="#B148-polymers-17-00063" class="html-bibr">148</a>] under creative commons license CC BY 4.0.</p>
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<p>Overview of converting plastic packaging waste into carbon nanomaterials (CNMs) utilizing various catalyst materials. Reproduced from [<a href="#B149-polymers-17-00063" class="html-bibr">149</a>] with permission from American Chemical Society, Copyright (2022).</p>
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<p>Schematic representation of CVD setup showing main components and stages.</p>
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<p>From trash to treasure: converting PW into valuable graphene foil (GF). (<b>A</b>) Images of the raw waste plastic materials utilized in the experimental process, showcasing the types and conditions of the input materials. (<b>B</b>) Schematic representation of the fabrication process for the GF, outlining the key steps involved from PW to final product. (<b>C</b>) Photograph of the produced graphene foil, highlighting its physical characteristics. (<b>D</b>,<b>E</b>) Scanning electron microscopy (SEM) images of the graphene foil’s edge at different magnifications, with (<b>D</b>) showing a scale of 200 µm and (<b>E</b>) presenting a zoomed-in view at 500 nm, illustrating the structural details and surface morphology (<b>F</b>) Transmission electron microscopy (TEM) image depicting the few-layer graphene within the structure of the GF, providing insights into its layering and crystallinity. Reproduced from [<a href="#B156-polymers-17-00063" class="html-bibr">156</a>] with permission from Royal Society of Chemistry, Copyright (2017).</p>
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<p>Synthesis of high-quality graphene from solid waste plastic using CVD. (<b>A</b>) Schematic representation of the CVD process, illustrating the key components and steps involved in the synthesis. (<b>B</b>) PW is utilized as the carbon feedstock, highlighting its role in the conversion process. (<b>C</b>) Raman spectra confirm the quality and characteristics of the graphene crystal. Colors represents the Raman spectra of the round graphene crystal, taken randomly at different points (places) on the crystal. (<b>D</b>) Raman spectra of the few-layer graphene crystals, providing insights into their structural integrity and layer count. (<b>A</b>–<b>D</b>) are reproduced from [<a href="#B157-polymers-17-00063" class="html-bibr">157</a>] with permission from Elsevier, Copyright (2014).</p>
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<p>Synthesis of CNTs through sequential pyrolysis and combustion of PE. (<b>A</b>) Schematic representation of the three-stage stepwise CNT synthesis system, including Zone 1: pyrolysis, Zone 2: combustion, and Zone 3: synthesis stage. (*) the asterisk represents the flame that was present within the combustion stage only when oxygen was introduced to the venturi. (<b>B</b>,<b>C</b>) Scanning electron microscopy (SEM) images of CNTs generated from the combustion of HDPE at two different magnifications: 5 µm, illustrating overall morphology, and 1 µm, providing a closer view of the structural characteristics. (<b>A</b>–<b>C</b>) are reproduced from [<a href="#B158-polymers-17-00063" class="html-bibr">158</a>] with permission from Elsevier, Copyright (2010).</p>
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<p>Ultrafast and controllable phase evolution through FJH. (<b>A</b>) Schematic representation of the FJH setup, illustrating the key components involved in the process. (<b>B</b>) Schematic depiction of the flash products at various stages of the FJH process, highlighting the impact of energy input on phase transitions. (<b>C</b>) Schematic illustration of the formation of FND from polytetrafluoroethylene (PTFE), followed by the subsequent conversion of FND into polyhedral FCC, showcasing the transformation sequence. Reprinted from [<a href="#B160-polymers-17-00063" class="html-bibr">160</a>] with permission from American Chemical Society, Copyright (2021).</p>
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<p>Conversion of PW into FG. (<b>A</b>) Schematic representation of the alternating current flash graphene (AC-FG) synthesis process, illustrating the key steps involved. (<b>B</b>) Graph showing the yield of AC-FG derived from HDPE. (<b>C</b>) Analysis of the impact of the initial resistivity of the HDPE/carbon black (CB) blend on the yield of AC-FG, highlighting the relationship between resistivity and output. (<b>D</b>) Typical AC-FG yields are obtained from various plastic types when the initial resistance is set to 120 Ω, showcasing the versatility of the method. (<b>E</b>) Sequential images depicting the transformation process from post-consumer plastic received from a recycler to the final conversion into FG using AC-FJH. Reprinted from [<a href="#B20-polymers-17-00063" class="html-bibr">20</a>] with permission from the American Chemical Society, Copyright (2020).</p>
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