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Search Results (396)

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25 pages, 4118 KiB  
Article
Effect of COVID-19 Pandemic on Aircraft Emissions at Václav Havel Airport Prague in 2020
by Bo Stloukal, Jakub Hospodka and Ivan Nagy
Atmosphere 2025, 16(3), 296; https://doi.org/10.3390/atmos16030296 - 1 Mar 2025
Viewed by 210
Abstract
As a consequence of measures imposed during the COVID-19 pandemic, anthropogenic emissions worldwide decreased markedly in impacted sectors, including the aviation industry. The aim of this study is to investigate the effects of the pandemic on aircraft emissions below the mixing height (3000 [...] Read more.
As a consequence of measures imposed during the COVID-19 pandemic, anthropogenic emissions worldwide decreased markedly in impacted sectors, including the aviation industry. The aim of this study is to investigate the effects of the pandemic on aircraft emissions below the mixing height (3000 feet above ground) at Václav Havel Airport Prague during 2020. For this purpose, real aircraft emissions during 2020 were computed using provided surveillance data, while business-as-usual aircraft emissions that could have been expected at the airport that year under normal circumstances were estimated using traffic data from previous years and derived emission factors. We found that the median real emissions at the airport in 2020 were 220.859 t of NOX, 101.364 t of CO, 15.025 t of HC, 44,039.468 t of CO2, 17,201.825 t of H2O and 11.748 t of SO2. The median estimated reduction in emissions due to the pandemic in 2020 was −476.317 t of NOX, −203.998 t of CO, −28.388 t of HC, −95,957.278 t of CO2, −37,476.400 t of H2O and −25.595 t of SO2. Absolute differences between the real and business-as-usual emissions peaked in June 2020, while the relative differences peaked in April/May at −89.4% to −92.0%. Full article
(This article belongs to the Special Issue Transport Emissions and Their Environmental Impacts)
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<p>LKPR traffic in 2020 according to A-SMGCS data: (<b>a</b>) number of movements per month; (<b>b</b>) number of movements per week.</p>
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<p>Time series daily traffic model plotted against real data (absolute and smoothed values); time period 1 January 2018–31 January 2020.</p>
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<p>Total real LTO aircraft emissions at LKPR in 2020 of (<b>a</b>) NO<sub>X</sub>; (<b>b</b>) CO; (<b>c</b>) HC; (<b>d</b>) CO<sub>2</sub>; (<b>e</b>) H<sub>2</sub>O and (<b>f</b>) SO<sub>2</sub>.</p>
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<p>Evolution of monthly mean real LTO aircraft emissions at LKPR in 2020 of (<b>a</b>) CO<sub>2</sub> and H<sub>2</sub>O; (<b>b</b>) HC and SO<sub>2</sub>; (<b>c</b>) NO<sub>X</sub> and CO.</p>
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<p>(<b>a</b>) Estimated monthly business-as-usual numbers of aircraft movements and real monthly numbers of aircraft movements according to A-SMGCS and EUROCONTROL [<a href="#B43-atmosphere-16-00296" class="html-bibr">43</a>] at LKPR in 2020. (<b>b</b>) Real monthly numbers of aircraft movements according to EUROCONTROL [<a href="#B43-atmosphere-16-00296" class="html-bibr">43</a>] at LKPR in 2018 and 2019.</p>
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<p>Estimated weekly business-as-usual numbers of aircraft movements and weekly real numbers of aircraft movements at LKPR in 2018, 2019 and 2020 (according to A-SMGCS and EUROCONTROL [<a href="#B43-atmosphere-16-00296" class="html-bibr">43</a>]) (weeks 1–16).</p>
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<p>Comparison between the numbers of daily aircraft movements and total daily LTO aircraft emissions of (<b>a</b>) CO<sub>2</sub> and H<sub>2</sub>O; (<b>b</b>) HC and SO<sub>2</sub>; (<b>c</b>) NO<sub>X</sub> and CO.</p>
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<p>Total estimated business-as-usual LTO aircraft emissions at LKPR in 2020 of (<b>a</b>) NO<sub>X</sub>; (<b>b</b>) CO; (<b>c</b>) HC; (<b>d</b>) CO<sub>2</sub>; (<b>e</b>) H<sub>2</sub>O and (<b>f</b>) SO<sub>2</sub>.</p>
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<p>Evolution of monthly mean estimated business-as-usual LTO aircraft emissions at LKPR in 2020 of (<b>a</b>) CO<sub>2</sub> and H<sub>2</sub>O; (<b>b</b>) HC and SO<sub>2</sub>; (<b>c</b>) NO<sub>X</sub> and CO.</p>
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<p>Monthly standard deviations including mean values per emission species: (<b>a</b>) CO<sub>2</sub> and H<sub>2</sub>O; (<b>b</b>) HC and SO<sub>2</sub>; (<b>c</b>) NO<sub>X</sub> and CO.</p>
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<p>Cumulative real and estimated business-as-usual (BAU) LTO aircraft emissions at LKPR in 2020 of (<b>a</b>) NO<sub>X</sub>; (<b>b</b>) CO; (<b>c</b>) HC; (<b>d</b>) CO<sub>2</sub>; (<b>e</b>) H<sub>2</sub>O and (<b>f</b>) SO<sub>2</sub>.</p>
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23 pages, 12551 KiB  
Article
Evaluation of Promising Areas for Biogas Production by Indirect Assessment of Raw Materials Using Satellite Monitoring
by Oleksiy Opryshko, Nikolay Kiktev, Sergey Shvorov, Fedir Hluhan, Roman Polishchuk, Maksym Murakhovskiy, Taras Hutsol, Szymon Glowacki, Tomasz Nurek and Mariusz Sojak
Sustainability 2025, 17(5), 2098; https://doi.org/10.3390/su17052098 - 28 Feb 2025
Viewed by 307
Abstract
An important issue in the sustainable development of agricultural engineering today is the use of biogas plants for the production of electricity and heat from the organic waste of agricultural products and other low-quality products, which also contributes to the improvement of environmental [...] Read more.
An important issue in the sustainable development of agricultural engineering today is the use of biogas plants for the production of electricity and heat from the organic waste of agricultural products and other low-quality products, which also contributes to the improvement of environmental safety. Traditional methods for assessing the apparent severity of the Roslynnytsia campaign based on statistics from the dominions proved to be ineffective. A hypothesis was proposed regarding the possibility of estimating the apparent biomass by averaging the indicators of depletion and assessing the CH4 and CO emissions based on satellite monitoring data. The aim of this work is to create a methodology for preparing a raw material base in united territorial communities to provide them with electrical and thermal energy using biogas plants. The achievement of this goal was based on solving the following tasks: monitoring biomethane emissions in the atmosphere as a result of rotting organic waste, and monitoring carbon monoxide emissions as a result of burning agricultural waste. Experimental studies were conducted using earth satellites on sites with geometric centers in the village of Gaishin in the Pereyaslav united territorial community, the city of Ovruch in the Zhytomyr region, the Oleshkovsky Sands National Park in the Kherson region (Ukraine), and the city of Jüterbog, which is located in the state of Brandenburg and is part of the Teltow-Fläming district (Germany). The most significant results of this research involve the methodology for the preparation of the raw material base in the united territorial communities for the production of biogas, based on indirect measurements of methane and carbon dioxide emissions using the process of remote sensing. Based on the use of the proposed scientific and methodological apparatus, it was found that the location of the territory with the center in the village of Gaishin has better prospects for collecting plant raw materials for biogas production than the location of the territorial district with the center in the city of Ovruch, the emissions in which are significantly lower. From March 2020–August 2023, a higher CO concentration was recorded on average by 0.0009 mol/m2, which is explained precisely by crop growing practices. In addition, as a result of the conducted studies, for the considered emissions of methane and carbon monoxide for monitoring promising raw materials, carbon monoxide has the best prospects, since methane emissions can also be caused by anthropogenic factors. Thus, in the desert (Oleshkivskie Pisky), large methane emissions were recorded throughout the year which could not be explained by crop growing practices or the livestock industry. Full article
(This article belongs to the Special Issue Agricultural Engineering for Sustainable Development)
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<p>Structural diagram of the study.</p>
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<p>Satellite image of the Pereyaslavsky district of the city council (red dotted line—border of the village of Gaishin) (source—Google maps).</p>
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<p>Satellite image of the Ovruch district (red dotted line—border of Ovruch city) (source—Google maps).</p>
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<p>Satellite image of the surroundings of the city of Jüterbog (city border is highlighted with a red dotted line) (source—Google maps).</p>
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<p>Satellite image of Oleshky Sands National Nature Park (image obtained from the Google maps internet service).</p>
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<p>Block diagram of the algorithm for calculating spatiotemporal changes in the content of CO and CH<sub>4</sub> in the atmosphere.</p>
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<p>Web application interface for assessing spatiotemporal changes in the content of CH<sub>4</sub> in the atmosphere for the settlement of Gaishin in 2021.</p>
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<p>Methane emissions during 2021 in the Kherson region over the Oleshky Sands research site.</p>
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<p>Satellite image of the location of the main and additional locations in the Kherson region, Oleshky Sands and Novokamenka, respectively.</p>
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<p>Remote sensing results—methane emissions at the research sites Gaishin 2022 and 2020 (<b>a</b>,<b>b</b>), Ovruch 2021 (<b>c</b>), and Jüterbog 2021 (<b>d</b>).</p>
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<p>Remote sensing results—methane emissions at the research sites Gaishin 2022 and 2020 (<b>a</b>,<b>b</b>), Ovruch 2021 (<b>c</b>), and Jüterbog 2021 (<b>d</b>).</p>
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<p>Remote sensing results—methane emissions at the research sites Gaishin 2022 and 2020 (<b>a</b>,<b>b</b>), Ovruch 2021 (<b>c</b>), and Jüterbog 2021 (<b>d</b>).</p>
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<p>Results of CO emissions analysis during 2022 for the locations Gaishin (<b>a</b>), Ovruch (<b>b</b>), Jüterbog (<b>c</b>), and Oleshky Sands (<b>d</b>).</p>
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<p>Results of CO emissions analysis during 2022 for the locations Gaishin (<b>a</b>), Ovruch (<b>b</b>), Jüterbog (<b>c</b>), and Oleshky Sands (<b>d</b>).</p>
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<p>Dependence of the averaged difference in methane emissions for 2020–2023 between the Oleshky Sands and Novokamenka sites.</p>
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<p>Dependence of the averaged 2020–2023 differences in CH<sub>4</sub> emissions between the Ovruch, Jüterbog, and Gaishin sites.</p>
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<p>Distribution of CO emissions over the territory of Ukraine and Poland in 2021.</p>
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<p>Averaged over the observation period, changes in CO emissions for the research sites during the year.</p>
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<p>Difference in average CO emissions between the base location Gaishin and Oleshky Sands, Ovruch, and Jüterbog, respectively.</p>
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<p>CO emissions in April 2020 due to a fire in the Chernobyl zone (<b>a</b>) and a test site to assess the impact of forest burning on an increase in CO content on the (<b>b</b>).</p>
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<p>Example of Working with Coding.</p>
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24 pages, 21665 KiB  
Article
Effects of Emission Variability on Atmospheric CO2 Concentrations in Mainland China
by Wenjing Lu, Xiaoying Li, Shenshen Li, Tianhai Cheng, Yuhang Guo and Weifang Fang
Remote Sens. 2025, 17(5), 814; https://doi.org/10.3390/rs17050814 - 26 Feb 2025
Viewed by 132
Abstract
Accurately assessing the impact of anthropogenic carbon dioxide (CO2) emissions on CO2 concentrations is essential for understanding regional climate change, particularly in high-emission countries like China. This study employed the GEOS-Chem chemical transport model to simulate and compare the spatiotemporal [...] Read more.
Accurately assessing the impact of anthropogenic carbon dioxide (CO2) emissions on CO2 concentrations is essential for understanding regional climate change, particularly in high-emission countries like China. This study employed the GEOS-Chem chemical transport model to simulate and compare the spatiotemporal distributions of XCO2 of three anthropogenic CO2 emission inventories in mainland China for the 2018–2020 period and analyzed the effects of emission variations on atmospheric CO2 concentrations. In eastern China, particularly in the Yangtze River Delta (YRD) and Beijing-Tianjin-Hebei (BTH) regions, column-averaged dry air mole fractions of CO2 (XCO2) can exceed 420 ppm during peak periods, with emissions from these areas contributing significantly to the national total. The simulation results were validated by comparing them with OCO-2 satellite observations and ground-based monitoring data, showing that more than 70% of the monitoring stations exhibited a correlation coefficient greater than 0.7 between simulated and observed data. The average bias relative to satellite observations was less than 1 ppm, with the Emissions Database for Global Atmospheric Research (EDGAR) showing the highest degree of agreement with both satellite and ground-based observations. During the study period, anthropogenic CO2 emissions resulted in an increase in XCO2 exceeding 10 ppm, particularly in the North China Plain and the YRD. In scenarios where emissions from either the BTH or YRD regions were reduced by 50%, a corresponding decrease of 1 ppm in XCO2 was observed in the study area and its surrounding regions. These findings underscore the critical role of emission control policies in mitigating the rise in atmospheric CO2 concentrations in densely populated and industrialized areas. This research elucidates the impacts of variations in anthropogenic emissions on the spatiotemporal distribution of atmospheric CO2 and emphasizes the need for improved accuracy of CO2 emission inventories. Full article
(This article belongs to the Section Atmospheric Remote Sensing)
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<p>Spatial distribution of emissions (gC/m<sup>2</sup>/d) in mainland China from three inventories in 2018–2020: (<b>a</b>) ODIAC, (<b>b</b>) MEIC and (<b>c</b>) EDGAR, with zoomed-in views of the BTH and YRD regions in the right panel.</p>
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<p>Time series of monthly anthropogenic CO<sub>2</sub> emissions over mainland China from 2018 to 2020 based on three emission inventories: ODIAC, MEIC, and EDGAR.</p>
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<p>Distribution of mean XCO<sub>2</sub> for three emission inventories (ODIAC, MEIC, and EDGAR) simulations (first column) and discrepancy between each of the three simulations and the mean (second to fourth columns) in 2018–2020 (ANN: annual; MAM: March–April-May; JJA: June–July–August; SON: September–October–November; DJF: December–February).</p>
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<p>Bias (XCO<sub>2</sub>_OCO minus XCO<sub>2</sub>_Sim) distributions of satellite XCO<sub>2</sub> observations and model simulations for ANN, MAM, JJA, SON and DJF in 2020, with the first, second, and third columns showing the differences between observations and simulations based on the ODIAC, MEIC, and EDGAR inventories ((<b>a</b>) Obs minus Sim_ODIAC, (<b>b</b>) Obs minus Sim_MEIC, and (<b>c</b>) Obs minus Sim_EDGAR).</p>
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<p>Geophysical locations of the selected sites.</p>
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<p>The Taylor diagram comparing the XCO<sub>2</sub> simulated by the three anthropogenic emission inventories based on GEOS-Chem with the Ground-based CO<sub>2</sub> observations in the 2018–2020 period. The radial coordinates represent the standard deviation ratio between the simulated CO<sub>2</sub> and the observed CO<sub>2</sub> in each stie, while the angular coordinates indicate the correlation coefficient. The gray dashed lines denote the centered root mean square error (RMSE-c).</p>
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<p>Spatial distribution of average differences between simulations from inventories and no_fossil simulations ((<b>a</b>) Sim_ODIAC minus Sim_no_fossil, (<b>b</b>) Sim_MEIC minus Sim_no_fossil and (<b>c</b>) Sim_EDGAR minus Sim_no_fossil) in 2018–2020.</p>
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<p>The distribution of average XCO<sub>2</sub> discrepancy between the adjusted emission scenarios ((<b>a</b>) +20%, (<b>b</b>) −20%, (<b>c</b>) +50%, (<b>d</b>) −50%, (<b>e</b>) +100%, and (<b>f</b>) −100% scenarios) and the baseline experiment (Sim_EDGAR) for 2020.</p>
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<p>The distribution of XCO<sub>2</sub> average discrepancy between the adjusted emission scenarios (solely on the BTH region or YRD region, (<b>a</b>) +20%, (<b>b</b>) −20%, (<b>c</b>) +50%, (<b>d</b>) −50%, (<b>e</b>) +100%, and (<b>f</b>) −100% scenarios) and the baseline experiment (Sim_EDGAR) in 2020.</p>
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<p>Scatter plots of the OCO-2 XCO<sub>2</sub> and GEOS-Chem simulated XCO<sub>2</sub> for the year 2020.</p>
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<p>Heatmap of Spearman’s correlation coefficients between anthropogenic CO<sub>2</sub> emissions (using the EDGAR inventory) and simulated XCO<sub>2</sub> concentrations for 2018–2020. Blank regions over mainland China indicate areas where the correlation did not meet statistical significance.</p>
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22 pages, 3268 KiB  
Review
Advances in Primary Air Pollutant Emissions of Industrial Boilers in China: Emission Characteristics, Emission Inventories, and Mitigation Potentials
by Yali Tong, Xudong Guo, Fenghui Guo and Tao Yue
Sustainability 2025, 17(5), 1987; https://doi.org/10.3390/su17051987 - 26 Feb 2025
Viewed by 164
Abstract
Industrial boilers are one of the important anthropogenic emission sources of primary air pollutants including particulate matter (PM), sulfur dioxide (SO2), and nitric oxide (NOx). China possesses the largest number of industrial boilers in the world, characterized by a [...] Read more.
Industrial boilers are one of the important anthropogenic emission sources of primary air pollutants including particulate matter (PM), sulfur dioxide (SO2), and nitric oxide (NOx). China possesses the largest number of industrial boilers in the world, characterized by a wide spatial and industrial distribution, and a small scale of individual capacity. The study of air pollutant emissions of industrial boilers in China is an essential field for realizing the green and sustainable development of Chinese industrial sectors in terms of air pollution and CO2 reduction. Therefore, this study comprehensively summarized the research progress of industrial boilers in terms of primary air pollutant emissions. Currently, significant progress has been made in the study of air pollutant emissions from industrial boilers in China, including the following aspects: (1) the characterization of air pollutant emissions based on field data, (2) the development of multi-scale air pollutant emission inventories, and (3) the scenario analysis of emission reduction potentials and control strategies. In addition, this study further clarified the evolution of air pollution control technologies, based on the analysis of the development of air pollutant emission standards for industrial boilers. Further, the shortcomings of the research on air pollutant emissions of industrial boilers were elucidated, and the perspectives were proposed in view of the development requirements of air pollution control in China. This is expected to provide important contributions to the development of pollution-carbon reduction policies and formulation of green sustainable development strategies related to industrial boilers. Full article
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<p>Endogenous technological change with carbon constraints and other uncertainties [<a href="#B40-sustainability-17-01987" class="html-bibr">40</a>].</p>
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<p>Progress of air pollutant emission control policies for CFIBs in China from 2013 to 2025.</p>
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<p>Distribution of the phase-out scale of CFIBs in China from 2014 to 2017.</p>
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<p>Evolution of PM and SO<sub>2</sub> emission standard limits of CFIBs.</p>
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<p>Comparison of PM, NO<span class="html-italic">x</span>, and SO<sub>2</sub> emission limits of industrial boilers.</p>
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<p>Development of air pollutant emission limits and air pollution control technologies for CFIBs.</p>
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<p>Development of air pollutant emission limits and air pollution control technologies for CFIBs.</p>
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13 pages, 6247 KiB  
Article
Study on the Pollution Characteristics of Characteristic Elements in Atmospheric PM2.5 in a Special Region and Their Deposition Patterns in the Upper Respiratory System
by Siqi Liu, Yilin Jiang, Mamatrishat Mamat and Guangwen Feng
Atmosphere 2025, 16(3), 257; https://doi.org/10.3390/atmos16030257 - 24 Feb 2025
Viewed by 177
Abstract
The impact of PM2.5 on the environment and human health has garnered significant attention. While research on PM2.5 composition is increasing, fewer studies have focused on how dusty conditions in a special region affect the PM2.5 composition. This region’s unique [...] Read more.
The impact of PM2.5 on the environment and human health has garnered significant attention. While research on PM2.5 composition is increasing, fewer studies have focused on how dusty conditions in a special region affect the PM2.5 composition. This region’s unique environmental conditions, characterized by frequent dust events, complicate air quality management. The study investigates the seasonal distribution of inorganic elements in the PM2.5 under both dusty and non-dusty conditions through systematic sampling. Selective screening methods identified key pollutant elements, and a respiratory system model was developed to examine their diffusion and deposition patterns in the upper respiratory tract. Key findings reveal that inorganic element concentrations in the PM2.5 follow consistent seasonal trends, with significantly higher levels during dust events compared to non-dusty periods. Crustal elements are dominated in the PM2.5, but non-metallic elements (Cl, S) and metallic/quasi-metallic elements (Mn, Cd, Cr, As, Hg) are also prevalent, likely influenced by anthropogenic activities and industrial emissions. By PCA with human health assessments, six characteristic pollutants were identified: As, Co, Cd, Cr, V, and Mn. Simulations using COMSOL Multiphysics 6.2 software demonstrated distinct behaviors: As tends to concentrate in the posterior regions of the respiratory tract, while Co and Cd exhibit relatively uniform distributions, primarily affecting areas where airflow slows upstream. Cr, V, and Mn show dispersed and uniform patterns. Notably, even during dusty conditions, the concentration of the six pollutants remains relatively low in the different parts of the upper respiratory tract, suggesting minimal immediate health impacts. Our study provides valuable insights into the behavior of inorganic elements in the PM2.5 and their potential health implications, highlighting the need for further research on the effects of dusty conditions on air quality and public health. Full article
(This article belongs to the Section Air Quality and Health)
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<p>Schematic diagram of PM<sub>2.5</sub> sample collection site.</p>
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<p>Mass concentrations of 21 inorganic elements in PM<sub>2.5</sub> under different seasons and meteorological conditions ((<b>a</b>). spring, (<b>b</b>). summer, (<b>c</b>). autumn, (<b>d</b>). winter).</p>
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<p>Load diagram of PCA three-dimensional space.</p>
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<p>The 3D structural diagram of upper respiratory tract model.</p>
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<p>Entrance (<b>left</b>) and exit (<b>right</b>) of respiratory model.</p>
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<p>Overall schematic diagram (<b>left</b>) and local enlarged view (<b>right</b>) of respiratory model mesh division.</p>
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<p>Concentration distribution of As (<b>left</b>), Co (<b>middle</b>), and Cd (<b>right</b>) in PM<sub>2.5</sub> at T = 1 s.</p>
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<p>Concentration distribution of Cr (<b>left</b>), V (<b>middle</b>), and Mn (<b>right</b>) in PM<sub>2.5</sub> at T = 1 s.</p>
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24 pages, 25124 KiB  
Article
Co-Response of Atmospheric NO2 and CO2 Concentrations from Satellites Observations of Anthropogenic CO2 Emissions for Assessing the Synergistic Effects of Pollution and Carbon Reduction
by Kaiyuan Guo, Liping Lei, Hao Song, Zhanghui Ji and Liangyun Liu
Remote Sens. 2025, 17(5), 739; https://doi.org/10.3390/rs17050739 - 20 Feb 2025
Viewed by 191
Abstract
Anthropogenic CO2 emissions are one of the primary drivers of the increase in atmospheric CO2 concentrations. It has been indicated that reducing emitted pollution gases can simultaneously bring out anthropogenic CO2 reduction, known as the synergistic effects of pollution and [...] Read more.
Anthropogenic CO2 emissions are one of the primary drivers of the increase in atmospheric CO2 concentrations. It has been indicated that reducing emitted pollution gases can simultaneously bring out anthropogenic CO2 reduction, known as the synergistic effects of pollution and carbon reduction for controlling increases in CO2 and pollution gas concentrations. This study aims to assess these synergistic effects, which are still not clearly understood, by analyzing the mechanisms of atmospheric CO2 and NO2 concentration variability in response to human emission reduction activities. We utilize satellite-observed NO2, which is a short-lived anthropogenic pollution gas with the same emission sources as CO2, along with CO2 concentration data to detect their simultaneous response to anthropogenic CO2 emissions, thereby assessing and comparing the synergistic effects of pollution and carbon reduction in the two study areas of China and the United States, as well as in a special scenario of abrupt reductions in anthropogenic CO2 emissions. The results show that the synergistic effects of pollution and carbon reduction in the United States are likely better than those in China, as the United States demonstrates a stronger response (R2 = 0.53) between atmospheric NO2 and anthropogenic CO2 emission compared with China (R2 = 0.36). This difference is attributable to the CO2 emissions from coal-fired power generation in China are much more than those in the United States, where oil and natural gas dominate. Furthermore, the analysis of special scenarios during the COVID-19 pandemic (2020–2022) in China demonstrates that the types of anthropogenic emission sources are the main factors influencing the synergistic effects of pollution and carbon reduction. Specifically, the megacity regions, where fossil fuel power plants and transportation are the main emission sources, presented stronger synergistic effects of pollution and carbon reduction than those regions dominated by coal-based metallurgical and chemical plants. Full article
(This article belongs to the Special Issue Using Remote Sensing Technology to Quantify Greenhouse Gas Emissions)
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<p>Response of NO<sub>2</sub> and XCO<sub>2</sub> to anthropogenic CO<sub>2</sub> emissions in China (<b>a</b>) annual average of NO<sub>2</sub> (<b>b</b>) correlation between NO<sub>2</sub> and ODIAC in grids (<b>c</b>) annual average of XCO<sub>2</sub> (<b>d</b>) correlation between XCO<sub>2</sub> and ODIAC in grids (<b>e</b>) annual average of ODIAC, and (<b>f</b>) correlation between NO<sub>2</sub> and XCO<sub>2</sub> in grids.</p>
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<p>Response of NO<sub>2</sub> and XCO<sub>2</sub> to anthropogenic CO<sub>2</sub> emissions in China (<b>a</b>) annual average of NO<sub>2</sub> (<b>b</b>) correlation between NO<sub>2</sub> and ODIAC in grids (<b>c</b>) annual average of XCO<sub>2</sub> (<b>d</b>) correlation between XCO<sub>2</sub> and ODIAC in grids (<b>e</b>) annual average of ODIAC, and (<b>f</b>) correlation between NO<sub>2</sub> and XCO<sub>2</sub> in grids.</p>
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<p>Response of NO<sub>2</sub> and XCO<sub>2</sub> to anthropogenic CO<sub>2</sub> emissions in the United States (<b>a</b>) annual average of NO<sub>2</sub> (<b>b</b>) correlation between NO<sub>2</sub> and ODIAC in grids (<b>c</b>) annual average of XCO<sub>2</sub> (<b>d</b>) correlation between XCO<sub>2</sub> and ODIAC in grids (<b>e</b>) annual average of ODIAC, and (<b>f</b>) correlation between NO<sub>2</sub> and XCO<sub>2</sub> in grids.</p>
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<p>Clustering of NO<sub>2</sub> spatiotemporal variations based on satellite-observed monthly NO<sub>2</sub> data (2019–2022) (<b>a</b>) China and (<b>b</b>) the United States.</p>
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<p>Correlation of NO<sub>2</sub> to anthropogenic CO<sub>2</sub> emissions and XCO<sub>2</sub> in clustered areas (<b>a</b>) China and (<b>b</b>) the United States.</p>
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<p>Types of power plants in the study areas: (<b>a</b>) China and (<b>b</b>) the United States.</p>
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<p>Time variation in monthly averaged NO<sub>2</sub> and ODIAC emissions (<b>lower</b>), and the relative variation (<b>upper</b>) calculated as the year-on-year difference in the same month divided by the value of the same month in the previous year, in China from 2019 to 2022.</p>
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<p>Time variation in monthly averaged NO<sub>2</sub> and ODIAC emissions (<b>lower</b>), and the relative variation (<b>upper</b>) calculated as the year-on-year difference in the same month divided by the value of the same month in the previous year, in the United States from 2019 to 2022.</p>
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<p>Annual incremental response relationship between NO<sub>2</sub> and anthropogenic CO<sub>2</sub> emission in high-pollution areas in China and the United States (<b>a</b>) China and (<b>b</b>) United States.</p>
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<p>High-pollution emission clustered areas in China (<b>a</b>) and the year-on-year differences in NO<sub>2</sub> and anthropogenic CO<sub>2</sub> emissions in the same month from 2020 to 2022 (<b>b</b>).</p>
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<p>The YRD and BTH study areas and the year-on-year differences in XCO<sub>2</sub> (<b>b</b>) and NO<sub>2</sub> (<b>c</b>) in the same month from 2020 to 2022 in both areas. The base map in (<b>a</b>) is the four-year mean concentration of NO<sub>2</sub> from 2019 to 2022, with black dots indicating the locations of prefecture-level cities in China.</p>
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<p>Spatial distribution of NO<sub>2</sub> differences between April and May 2022 and the same period in 2021 for (<b>a</b>) YRD and (<b>b</b>) BTH.</p>
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<p>Response of the changes in the mean NO<sub>2</sub> concentrations and ODIAC emissions for (<b>a</b>) YRD and (<b>b</b>) BTH between January and February 2020 and the same period in 2019 (<b>c</b>) YRD and (<b>d</b>) BTH, between April and May 2022 and the same period in 2021.</p>
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<p>Response of the changes in the mean NO<sub>2</sub> concentrations and ODIAC emissions for (<b>a</b>) YRD and (<b>b</b>) BTH between January and February 2020 and the same period in 2019 (<b>c</b>) YRD and (<b>d</b>) BTH, between April and May 2022 and the same period in 2021.</p>
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<p>Correlation of NO<sub>2</sub> differences to CO<sub>2</sub> differences, which is the values in April–May in the year 2022 minus the values in April–May in the year 2021 for (<b>a</b>) YRD (<b>b</b>) BTH.</p>
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<p>Response of NO<sub>2</sub> to EDGAR emissions in China and the United States (<b>a</b>,<b>b</b>) the spatial distribution of annual mean EDGAR emissions (2019–2022) in China and the United States (<b>c</b>,<b>d</b>) the grid-based response of NO<sub>2</sub> to EDGAR in China and the United States (<b>e</b>,<b>f</b>) the cluster-based response of NO<sub>2</sub> to EDGAR in China and the United States.</p>
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<p>Response of NO<sub>2</sub> to EDGAR emissions in China and the United States (<b>a</b>,<b>b</b>) the spatial distribution of annual mean EDGAR emissions (2019–2022) in China and the United States (<b>c</b>,<b>d</b>) the grid-based response of NO<sub>2</sub> to EDGAR in China and the United States (<b>e</b>,<b>f</b>) the cluster-based response of NO<sub>2</sub> to EDGAR in China and the United States.</p>
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<p>Interannual response of NO<sub>2</sub> increments to EDGAR emission increments in high-pollution areas of China and the United States (<b>a</b>) China and (<b>b</b>) the United States.</p>
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<p>Mean XCO<sub>2</sub> concentration simulated by the CAMAS model in China and the United States for the period 2019–2020. (<b>a</b>) China and (<b>b</b>) the United States.</p>
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17 pages, 1132 KiB  
Article
Planning Amidst Uncertainty: Identifying Core CCS Infrastructure Robust to Storage Uncertainty
by Daniel Olson and Sean Yaw
Energies 2025, 18(4), 926; https://doi.org/10.3390/en18040926 - 14 Feb 2025
Viewed by 252
Abstract
Carbon Capture and Storage (CCS) is a critical technology for reducing anthropogenic CO2 emissions, but its large-scale deployment is complicated by uncertainties in geological storage performance. These uncertainties pose significant financial and operational risks, as underperforming storage sites can lead to costly [...] Read more.
Carbon Capture and Storage (CCS) is a critical technology for reducing anthropogenic CO2 emissions, but its large-scale deployment is complicated by uncertainties in geological storage performance. These uncertainties pose significant financial and operational risks, as underperforming storage sites can lead to costly infrastructure modifications, inefficient pipeline routing, and economic shortfalls. To address this challenge, we propose a novel optimization workflow that is based on mixed-integer linear programming and explicitly integrates probabilistic modeling of storage uncertainty into CCS infrastructure design. This workflow generates multiple infrastructure scenarios by sampling storage capacity distributions, optimally solving each scenario using a mixed-integer linear programming model, and aggregating results into a heatmap to identify core infrastructure components that have a low likelihood of underperforming. A risk index parameter is introduced to balance trade-offs between cost, CO2 processing capacity, and risk of underperformance, allowing stakeholders to quantify and mitigate uncertainty in CCS planning. Applying this workflow to a CCS dataset from the US Department of Energy’s Carbon Utilization and Storage Partnership project reveals key insights into infrastructure resilience. Reducing the risk index from 15% to 0% is observed to lead to an 83.7% reduction in CO2 processing capacity and a 77.1% decrease in project profit, quantifying the trade-off between risk tolerance and project performance. Furthermore, our results highlight critical breakpoints, where small adjustments in the risk index produce disproportionate shifts in infrastructure performance, providing actionable guidance for decision-makers. Unlike prior approaches that aimed to cheaply repair underperforming infrastructure, our workflow constructs robust CCS networks from the ground up, ensuring cost-effective infrastructure under storage uncertainty. These findings demonstrate the practical relevance of incorporating uncertainty-aware optimization into CCS planning, equipping decision-makers with a tool to make informed project planning decisions. Full article
(This article belongs to the Section B3: Carbon Emission and Utilization)
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<p>Proposed process for identifying core infrastructure that is resistant to storage capacity uncertainty. Red circles are CO<sub>2</sub> sources, blue circles are storage sites. In step 1, multiple scenarios are generated to reflect a range of possible values for uncertain storage capacities. In step 2, each scenario is individually solved optimally using the MILP model. A heatmap is constructed in step 3 by calculating the number of times each infrastructure component is used. In step 4, the heatmap is filtered to only include a subset of all used infrastructure. Finally, the largest feasible infrastructure is calculated in step 5.</p>
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<p>CCS infrastructure dataset from the US State of California. The study area is bounded by <math display="inline"><semantics> <mrow> <mo>(</mo> <mn>40.960</mn> <mo>,</mo> <mo>−</mo> <mn>123.659</mn> <mo>)</mo> </mrow> </semantics></math> in the top left corner and <math display="inline"><semantics> <mrow> <mo>(</mo> <mn>33.636</mn> <mo>,</mo> <mo>−</mo> <mn>116.042</mn> <mo>)</mo> </mrow> </semantics></math> in the bottom right. Red circles are CO<sub>2</sub> sources, blue circles are storage sites, and purple edges are candidate pipeline locations.</p>
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<p>Aggregated heatmap of solutions from 57 scenarios with different storage capacities. Infrastructure is colored on a red–yellow–green color gradient, where red corresponds to less commonly used infrastructure and green corresponds to more commonly used infrastructure.</p>
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<p>Core CCS infrastructure found by the proposed method for a subregion of the dataset using various risk indices. Infrastructure is colored on a red–yellow–green color gradient, where red corresponds to less commonly used infrastructure and green corresponds to more commonly used infrastructure. (<b>a</b>) Risk index = <math display="inline"><semantics> <mrow> <mn>100</mn> <mo>%</mo> </mrow> </semantics></math>. (<b>b</b>) Risk index = <math display="inline"><semantics> <mrow> <mn>43</mn> <mo>%</mo> </mrow> </semantics></math>. (<b>c</b>) Risk index = <math display="inline"><semantics> <mrow> <mn>30</mn> <mo>%</mo> </mrow> </semantics></math>. (<b>d</b>) Risk index = <math display="inline"><semantics> <mrow> <mn>15</mn> <mo>%</mo> </mrow> </semantics></math>.</p>
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<p>Annual amount of CO<sub>2</sub> processed versus risk index for a range of risk index values.</p>
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<p>Annual infrastructure cost versus risk index for a range of risk index values. Note that the infrastructure cost is negative due to LCFS and <math display="inline"><semantics> <mrow> <mn>45</mn> <mi>Q</mi> </mrow> </semantics></math> tax credits.</p>
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11 pages, 375 KiB  
Article
Response of Soil Chemical and Biological Properties to Cement Dust Emissions: Insights for Sustainable Soil Management
by Serdar Bilen, Murat Bilen, Mudahir Ozgul, Ekrem Ozlu and Ugur Simsek
Sustainability 2025, 17(4), 1409; https://doi.org/10.3390/su17041409 - 9 Feb 2025
Viewed by 564
Abstract
Land use change is associated with both higher fossil fuel usage and global cement production, significantly impacting environmental sustainability. Cement dust emission is the third-largest source of anthropogenic CO2 emissions, right behind fossil fuel usage due to intense agricultural practices like aggressive [...] Read more.
Land use change is associated with both higher fossil fuel usage and global cement production, significantly impacting environmental sustainability. Cement dust emission is the third-largest source of anthropogenic CO2 emissions, right behind fossil fuel usage due to intense agricultural practices like aggressive tillage management. This study’s aim is to determine cement dust emissions impacts on various tillage management methods and the formation of cement dust-affected CO2 emissions, soil pH, soil organic matter content, total nitrogen content, available phosphorus, CaCO3 content, bacteria and fungi populations, and enzyme activities. The target of this study is to evaluate how cement dust emissions impact the soil properties and sustainability of different tillage practices. Composite soils from wheat–sugar beet (potato)–fallow cropping sequences under conventional tillage (CT) and no-till (NT) management were collected (0–30 cm depth) with three replications at varying distances from a cement factory (1, 2, 4, 6, 8, and 10 km). To find differences among individual treatments and distances, a two-way ANOVA was employed along with Duncan’s LSD test comparing the various effects of tillage techniques. The associations between soil chemical and biological properties and CO2 fluxes under the impact of cement dust were examined using Pearson’s correlation analysis. There were notable relationships between soil microbial population, enzyme activities, pH, CaCO3, and CO2 fluxes. The sampling distance from the cement plant had a substantial correlation with soil organic carbon, urease activity, pH, CaCO3, and bacterial populations. According to the study, different tillage methods (CT and NT) affected the diversity and abundance of microorganisms within the soil ecosystem. CT was more beneficial for the microbial population and for sustainable management. Full article
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<p>Pearson’s correlation analysis of soil health indicators and CO<sub>2</sub> fluxes under cement dust accumulation at 0–30 cm depth in Gümüşhane district. The color and size of the circle denotes the magnitude and direction of the relationship. (SOM, soil organic matter; TN, total nitrogen content; PAv, available phosphorus content; Bpop, bacteria population; Fpop, fungi population; BFr, bacteria/fungi ratio; PAcd, acid phosphatase activity; PAlk, alkaline phosphatase activity; UAc, urease activity; DAc, dehydrogenase activity; CO<sub>2</sub>, CO<sub>2</sub> fluxes).</p>
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25 pages, 11358 KiB  
Article
A New Regional Background Atmospheric Station in the Yangtze River Delta Region for Carbon Monoxide: Assessment of Spatiotemporal Characteristics and Regional Significance
by Yi Lin, Shan Li, Yan Yu, Meijing Lu, Bingjiang Chen, Yuanyuan Chen, Kunpeng Zang, Shuo Liu, Bing Qi and Shuangxi Fang
Atmosphere 2025, 16(1), 101; https://doi.org/10.3390/atmos16010101 - 17 Jan 2025
Viewed by 478
Abstract
A new meteorological station (DMS) was established at the Morning Glory summit in Zhejiang Province to provide regional background information on atmospheric composition in the Yangtze River Delta (YRD) region, China. This study investigated the first carbon monoxide (CO) records at DMS from [...] Read more.
A new meteorological station (DMS) was established at the Morning Glory summit in Zhejiang Province to provide regional background information on atmospheric composition in the Yangtze River Delta (YRD) region, China. This study investigated the first carbon monoxide (CO) records at DMS from September 2020 to January 2022. The annual average concentration of CO was 233.4 ± 3.8 ppb, which exceeded the measurements recorded at the other Asian background sites. The winter CO concentration remained elevated but peaked in March in the early spring due to the combined effect of regional emissions within the YRD and transportation impacts of North China and Southeast Asia sources. The diurnal cycle had a nocturnal peak and a morning valley but with a distinct afternoon climb, as the metropolis in the YRD contributed to a local concentration enhancement. The back trajectory analysis and the Weighted Potential Sources Contribution Function (WPSCF) maps highlighted emissions from Anhui, Jiangxi, Zhejiang, and Jiangsu provinces as significant sources. Due to well-mixed air conditions and fewer anthropogenic influences, DMS records closely aligned with the CO averages derived from the Copernicus Atmospheric Monitoring Service (CAMS) covering the YRD, confirming its representativeness for regional CO levels. This study underscored DMS as a valuable station for monitoring and understanding CO spatiotemporal characteristics in the YRD region. Full article
(This article belongs to the Section Air Quality)
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<p>Research flowchart of this study.</p>
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<p><b>Left</b>: The location of the YRD region in China. <b>Right</b>: The distribution of metropolises and the location of DMS and LAN in YRD. The base map on the right was from the Open-source Data Inventory for Anthropogenic CO<sub>2</sub> (ODIAC) data in 2019, downloaded via <a href="https://db.cger.nies.go.jp/dataset/ODIAC/" target="_blank">https://db.cger.nies.go.jp/dataset/ODIAC/</a> accessed on 14 August 2024.</p>
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<p>Schematic of the measurement system at DMS.</p>
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<p>DMS at the hilltop flat. (<b>a</b>): Experimental square cabin on the summit of DMS; (<b>b</b>): a 10 mm O.D. sampling line outside the experimental square cabin at the top of a 10 m tower.</p>
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<p>Hourly CO data series at DMS station during the study period.</p>
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<p>Monthly statistics of CO concentrations at DMS during the study period. The lines in the box are the median CO concentrations; the bottom and the top of the box represent the 25th and the 75th percentile; the bottom whisker reaches the minimum, and the top whisker extends 1.5 times the Interquartile Range (IQR); the crosses are the average monthly CO concentrations; the blue dots are the outliers.</p>
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<p>Anomaly diurnal circle of CO concentrations at DMS during the study period. Spring: March to May; summer: June-August; autumn: September-November; winter: December-February.</p>
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<p><b>Left</b>: Cluster analysis of 1-day back trajectories for the most significant concentration enhancement period of the whole day (14:00–19:00 LT in spring, 16:00–22:00 LT in summer, 16:00–20:00 LT in autumn, 14:00–19:00 LT in winter) at DMS. <b>Right</b>: The average pressure changes corresponding to each cluster. The colorful lines on the map are cluster analysis results with base maps of average column CO concentration retrieval from TROPOMI products.</p>
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<p><b>Left</b>: Cluster analysis of 1-day back trajectories encompassing all seasons from 2020 to 2022 at DMS. The colorful lines on the map are cluster analysis results with base maps of average column CO concentration retrieval from TROPOMI products. <b>Right</b>: The average pressure change corresponds to each cluster.</p>
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<p><b>Left</b>: Cluster analysis of 3-day back trajectories encompassing all seasons from 2020 to 2022 at DMS. The colorful lines on the map are cluster analysis results with base maps of average column CO concentration retrieval from TROPOMI products. <b>Right</b>: The average pressure change corresponds to each cluster.</p>
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<p>Geographical distributions of seasonal weighted potential sources of CO from 2020 to 2022 at DMS. The higher WPSCF represented the higher contribution from the areas to the CO concentration at DMS. The WPSCF were reclassified by Natural Break as low (&lt;0.2), Medium (0.2–0.4), Relative-High (0.4–0.6), and High (&gt;0.6) for better performance.</p>
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<p>Comparison of wind-rose maps between (<b>a</b>) LAN and (<b>b</b>) DMS. The average CO concentrations were divided into 16 horizontal wind directions. Error bars in each direction indicate 95% confidence intervals. The maps of LAN were adapted from Liu’s work [<a href="#B17-atmosphere-16-00101" class="html-bibr">17</a>].</p>
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<p>Non-parametric regression between wind direction, wind speed, and CO concentration at DMS. The percentage represented the wind frequency of the different wind directions.</p>
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<p>Annual CLCD in 2021 within a 20 km radius of DMS (<b>a</b>) and LAN (<b>b</b>) and NTL data in 2022 within a 20 km radius of DMS (<b>c</b>) and LAN (<b>d</b>).</p>
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<p>Centered on DMS, the buffer range with radii of 3.75°, 4.50°, and 5.25°.</p>
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27 pages, 6768 KiB  
Article
Complex Study of Settlements Dating from the Paleolithic to Medieval Period in the Ural Mountains on the Border of Europe and Asia
by Valentina Prikhodko, Nikita Savelev, Vyacheslav Kotov, Sergey Nikolaev, Evgeny Ruslanov, Mikhail Rumyantsev and Elena Manakhova
Geosciences 2025, 15(1), 31; https://doi.org/10.3390/geosciences15010031 - 16 Jan 2025
Viewed by 648
Abstract
Soil, geochemical, microbiological, and archeological studies were conducted at eight settlements dating from the Paleolithic to Late Medieval and Modern Ages near the southern Trans-Urals Mountains, Russia. The forest-steppe landscapes, rivers, and abundant mineral resources have attracted people to the region since ancient [...] Read more.
Soil, geochemical, microbiological, and archeological studies were conducted at eight settlements dating from the Paleolithic to Late Medieval and Modern Ages near the southern Trans-Urals Mountains, Russia. The forest-steppe landscapes, rivers, and abundant mineral resources have attracted people to the region since ancient times. Cultural layers (CLs) are marked by finds of ceramics fragments, animal bones, stone, and metal tools. The properties of CLs include close-to-neutral pH, being well structured, the absence of salinity, enrichment with exchangeable calcium, and anthropogenic phosphorus (0.2–0.4%). The majority of CLs start at a depth of 3–25 cm, extend to 40–60 cm, and contain 6–10% organic carbon (Corg) in the 0–20 cm layer, reflecting carbon input from modern-day processes. At the Ishkulovo site (0.6–0.8 ka BP), Corg decreases to 1.3% because the CL is below 80 cm, and in the absence of fresh organic material input, carbon has been mineralized. The proximity of sites to deposits of copper, chromium, zinc, and manganese in the Ural Mountains creates natural high-content anomalies in the region, as indicated by their abundance in soils and parent rocks. In the past, these elements were also released into CLs from metal products, ceramic fragments, and raw materials used in their manufacture. The sites are quite far (18–60 km) from the Magnitogorsk Metallurgical plant, but industrial stockpiles of S (technogenic coefficient—Ct 30–87%), and, less often, Cr, Mn, and Sr (Ct 30–40%) accumulated in surface layers. These three factors have led to the concentration of pollutants of the first (arsenic, chromium, lead, and zinc) and second (cobalt, copper, and nickel) hazard classes at CLs, often in quantities 2–5 times higher than values for parent materials and geosphere average content (“Clarke” value), and, and less often, more than the allowable content for human health. This may have influenced their health and behavioral functions. Due to the above properties, chernozems have a high buffering capacity and a strong bond with heavy metals. Therefore, no inhibition of microbes was observed. The microbial biomass of the 0–10 cm layer is high, 520–680 µg C/g, and microbes cause the emission of 1.0 C-CO2 µg/g of soil per hour. During the ancient settlements’ development, a favorable paleoclimate was noted based on the data cited. This contributed to the spread of productive paleolandscapes, ensuring the development of domestic cattle breeding and agriculture. Full article
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<p>Study area location: (<b>A</b>)—Baskortostan Republic in Russia, (<b>B</b>)—Abzelilovskiy district within Bashkortostan, (<b>C</b>)—locations of the sites studied in the region around Magnitogorsk (<a href="https://opentopomap.org/#map=12/53.6136/58.6776" target="_blank">https://opentopomap.org/#map=12/53.6136/58.6776</a>, accessed on 3 January 2024).</p>
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<p>(<b>A</b>) Locations of Kusimovo-8, 6, and 7 sites. Quadcopter view. Photo by A.A. Khurmaev, 2021, (<b>B</b>) landscape near the Kusimovo and Sabakty-1a; sites. (<b>C</b>) three Paleolithic stone tools in different angles from the Kusimovo-8 site.—one stone tool in different angles.</p>
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<p>Soil and CLs at the sites of (<b>A</b>) Kusimovo-8, (<b>B</b>) Ishkulovo, (<b>C</b>) Elimbetovo-7, (<b>D</b>) Sabakty-1a.</p>
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<p>The granulometry of the sites.</p>
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<p>The granulometry of the sites.</p>
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<p>pH, iron, microbial biomass, and basal respiration of the sites. * In all figures, dashed line means the Clarke value, region—regional elements content accordion (8).</p>
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<p>Content of Corg, total nitrogen, and phosphorus; C/N ratio of the sites.</p>
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<p>(<b>a</b>) Content of some microelements of the sites. (<b>b</b>) Content of some microelements of the sites. (<b>c</b>) Content of potassium and manganese at the sites. Dashed line means the Clarke value, region—regional elements content accordion (8).</p>
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<p>(<b>a</b>) Content of some microelements of the sites. (<b>b</b>) Content of some microelements of the sites. (<b>c</b>) Content of potassium and manganese at the sites. Dashed line means the Clarke value, region—regional elements content accordion (8).</p>
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<p>(<b>a</b>) Content of some microelements of the sites. (<b>b</b>) Content of some microelements of the sites. (<b>c</b>) Content of potassium and manganese at the sites. Dashed line means the Clarke value, region—regional elements content accordion (8).</p>
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40 pages, 3051 KiB  
Review
Navigating the Challenges of Sustainability in the Food Processing Chain: Insights into Energy Interventions to Reduce Footprint
by Orlando Corigliano, Pietropaolo Morrone and Angelo Algieri
Energies 2025, 18(2), 296; https://doi.org/10.3390/en18020296 - 10 Jan 2025
Viewed by 1771
Abstract
This review paper examines the critical intersection of energy consumption and environmental impacts within the global food system, emphasizing the substantial footprint (including land usage, costs, food loss and waste, and carbon and water footprints) associated with current practices. The study delineates the [...] Read more.
This review paper examines the critical intersection of energy consumption and environmental impacts within the global food system, emphasizing the substantial footprint (including land usage, costs, food loss and waste, and carbon and water footprints) associated with current practices. The study delineates the high energy demands and ecological burdens of food production, trade, and consumption through a comprehensive bibliographic analysis of high-impact research papers, authoritative reports, and databases. The paper systematically analyzes and synthesizes data to characterize the food industry’s current energy use patterns and environmental impacts. The results underscore a pressing need for strategic interventions to enhance food system efficiency and reduce the footprint. In light of the projected population growth and increasing food demand, the study advocates for a paradigm shift towards more sustainable and resilient food production practices, adopting energy-efficient technologies, promoting sustainable dietary habits, and strengthening global cooperation among stakeholders to achieve the Sustainable Development Goals. Investigations have revealed that the food system is highly energy-intensive, accounting for approximately 30% of total energy consumption (200 EJ per year). The sector remains heavily reliant on fossil fuels. Associated greenhouse gas (GHG) emissions, which constitute 26% of all anthropogenic emissions, have shown a linear growth trend, reaching 16.6 GtCO2eq in 2015 and projected to approach 18.6 GtCO2eq in the coming years. Notably, 6% of these emissions result from food never consumed. While the water footprint has slightly decreased recently, its demand is expected to increase by 20% to 30%, potentially reaching between 5500 and 6000 km3 annually by 2050. Energy efficiency interventions are estimated to save up to 20%, with a favorable payback period, as evidenced by several practical implementations. Full article
(This article belongs to the Collection Energy Efficiency and Environmental Issues)
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<p>Food imports and exports by main groups. Total values (<b>a</b>), food product share (<b>b</b>), including food groups (sugar and honey, meat and derivatives, fruits and vegetables, fish, fats and oils, dairy and eggs, cereals, and beverages).</p>
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<p>Share of dietary energy supply by continent and food aggregate (<b>a</b>); land use of foods (<b>b</b>).</p>
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<p>Food waste: waste per major contributors (<b>a</b>); food loss index (<b>b</b>); share of food loss by continent (<b>c</b>); GHG emissions linked to food waste (<b>d</b>).</p>
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<p>Food waste: waste per major contributors (<b>a</b>); food loss index (<b>b</b>); share of food loss by continent (<b>c</b>); GHG emissions linked to food waste (<b>d</b>).</p>
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<p>GHG food system emissions: year perspective (<b>a</b>); share of GHG per nation (<b>b</b>); GHC per sector and per gas source for USA (<b>c</b>); GHG production per food product (<b>d</b>).</p>
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<p>GHG food system emissions: year perspective (<b>a</b>); share of GHG per nation (<b>b</b>); GHC per sector and per gas source for USA (<b>c</b>); GHG production per food product (<b>d</b>).</p>
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<p>Potential path for food-related GHG reduction.</p>
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<p>Energy implications in food industry: energy employment in various food sectors categorized per source in the European Union (<b>a</b>); energy end use (EEU) share for different unit processes in Sweden (<b>b</b>) [<a href="#B43-energies-18-00296" class="html-bibr">43</a>].</p>
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<p>Water cycle focused on food supply chain.</p>
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<p>Water withdrawal worldwide: annual global value and population (<b>a</b>); continent distribution (<b>b</b>); sector share (<b>c</b>); continent and sector distribution (<b>d</b>).</p>
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<p>Water withdrawal worldwide: annual global value and population (<b>a</b>); continent distribution (<b>b</b>); sector share (<b>c</b>); continent and sector distribution (<b>d</b>).</p>
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<p>Water footprint in the food system: freshwater withdrawals per product (<b>a</b>); share of water usage per sector (<b>b</b>); water usage per component of the supply chain (<b>c</b>); water usage per food sector (<b>d</b>).</p>
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<p>Simplified block scheme of Food Industry 5.0.</p>
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18 pages, 4008 KiB  
Article
Source and Ecological Risk Assessment of Potentially Toxic Metals in Urban Riverine Sediments Using Multivariate Analytical and Statistical Tools
by Xiaojun Zheng, Abdul Rehman, Shan Zhong, Shah Faisal, Muhammad Mahroz Hussain, Syeda Urooj Fatima and Daolin Du
Land 2025, 14(1), 32; https://doi.org/10.3390/land14010032 - 27 Dec 2024
Viewed by 672
Abstract
Multivariate and statistical tool advancements help to assess potential pollution threats, their geochemical distribution, and the competition between natural and anthropogenic influences, particularly on sediment contamination with potentially toxic metals (PTMs). For this, riverine sediments from 25 locations along urban banksides of the [...] Read more.
Multivariate and statistical tool advancements help to assess potential pollution threats, their geochemical distribution, and the competition between natural and anthropogenic influences, particularly on sediment contamination with potentially toxic metals (PTMs). For this, riverine sediments from 25 locations along urban banksides of the River Ravi, Pakistan, were collected and analyzed to explore the distribution, pollution, ecological, and toxicity risk indices of PTMs like Al, As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Sn, Sr, V, and Zn using Inductively Coupled Plasma–Optical Emission Spectrometry (ICP-OES) technique. Additionally, techniques such as X-ray Diffraction (XRD) and Scanning Electron Microscopy–Energy Dispersive X-ray Spectroscopy (SEM-EDS) were employed to investigate the mineralogical and morphological aspects. The results indicated that mean concentrations (mg kg−1) of Cd (2.37), Cr (128), Hg (16.6), Pb (26.6), and Sb (2.44) were significantly higher than reference values given for upper continental crust (UCC) and world soil average (WSA), posing potential threats. Furthermore, the geochemical pollution indices showed that sediments were moderately polluted with Cd (Igeo = 2.37, EF = 12.1, and CF = 7.89) and extremely polluted with Hg (Igeo = 4.54, EF = 63.2, and CF = 41.41). Ecological and toxicity risks were calculated to be extremely high, using respective models, predominantly due to Hg (Eri = 1656 and ITRI = 91.6). SEM-EDS illustrated the small extent of anthropogenic particles having predominant concentrations of Zn, Fe, Pb, and Sr. Multivariate statistical analyses revealed significant associations between the concentrations of PTMs and the sampling locations, highlighting the anthropogenic contributions linked to local land-use characteristics. The present study concludes that River Ravi sediments exhibit moderate levels of Cd and extreme pollution by Hg, both of which contribute highly to extreme ecological and toxicity risks, influenced by both natural and anthropogenic contributions. Full article
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<p>Location of the sampling sites across the River Ravi. Details of the sampling area, geographical coordinates, and land-use type attributed to each location are provided in <a href="#app1-land-14-00032" class="html-app">Table S1</a>.</p>
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<p>The box plot shows the mean, median, and range of the geo-accumulation index (<span class="html-italic">I</span><sub>geo</sub>) for various PTMs.</p>
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<p>The box plots show the mean, median, and range of values for (<b>a</b>) enrichment factors (EFs) and (<b>b</b>) contamination factors (CFs) of various PTMs.</p>
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<p>Bar graph illustrations reveal the alarming values of the Nemerow pollution index (NPI), especially for chromium (Cr), antimony (Sb), cadmium (Cd) and mercury (Hg) in the sediments of River Ravi, Punjab, Pakistan.</p>
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<p>The box plots show the mean, median, and range of values for (<b>a</b>) the Ecological Risk Index (Eri) and (<b>b</b>) the Integrated Toxicity Risk Index (ITRI) of PTMs.</p>
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<p>X-ray diffraction analysis (XRD) spectra for representative sediment samples (SS4, SS12, SS18, SS22) showing corresponding peaks for a range of minerals, including Q = Quartz, K = Kaolinite, F = Feldspar, and C = Calcite.</p>
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<p>Scanning electron microscopy (SEM) images show the anthropogenic influence in the riverine sediments, by showing distinguished particles. EDS spectra indicated the quantitative proportion of various PTMs from corresponding particles.</p>
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<p>Results of multivariate statistical analysis illustrating the (<b>a</b>) corrplot of Pearson’s correlation coefficient (PCC) at <span class="html-italic">p</span> &lt; 0.05; (<b>b</b>) cluster analysis (CA) dendrogram; and (<b>c</b>) principal component analysis (PCA) using the rotation method (varimax with Kaiser normalization).</p>
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19 pages, 5204 KiB  
Article
Assessment of Heavy Metal Content and Identification of Their Sources in Bottom Sediments and Various Macrophyte Species of the Narew River (Poland)
by Mirosław Skorbiłowicz and Marcin Sidoruk
Minerals 2025, 15(1), 8; https://doi.org/10.3390/min15010008 - 25 Dec 2024
Viewed by 463
Abstract
The condition of the aquatic environment, particularly in protected areas of high ecological value such as the Narew River, requires detailed monitoring to identify and minimise the impact of anthropogenic factors on the ecosystem. This study focused on the content of heavy metals [...] Read more.
The condition of the aquatic environment, particularly in protected areas of high ecological value such as the Narew River, requires detailed monitoring to identify and minimise the impact of anthropogenic factors on the ecosystem. This study focused on the content of heavy metals in bottom sediments and macrophytes of the Narew River, emphasising the influence of human activities and natural factors on this ecologically valuable ecosystem. Pb, Cr, Zn, Cd, Fe, and Mn concentrations were analysed in sediment samples, and ten macrophyte species were collected at 11 sampling points along the river. A geochemical index (Igeo) and multivariate statistical analyses were employed to identify sources of contamination. The digested samples (sediments and plants) were analysed for Pb, Cr, Cu, Zn, Ni, Cd, Fe, and Mn using flame atomic absorption spectrometry (AAS) on an ICE 3500 Thermo Scientific spectrometer, with a measurement error below 5%, validated against certified reference materials. The study results indicated that most metals, including Ni, Cr, Co, Fe, and Mn, predominantly originate from natural geological processes. In contrast, Zn, Cd, Cu, and Pb were identified as being enriched due to anthropogenic activities. An analysis of macrophytes revealed varied patterns of metal accumulation, which correspond to the bioavailability of metals and their environmental concentrations. Comprehensive statistical analyses provided insights into the predominant sources of metal contamination, closely associated with industrial emissions, agricultural runoff, and transportation activities. The integration of sediment and macrophyte monitoring allowed for a thorough evaluation of the Narew River ecosystem, facilitating the identification of key pollution sources. These findings highlight the critical need for measures to mitigate anthropogenic contributions of heavy metals—particularly from industrial, agricultural, and transportation sectors—to safeguard the Narew River’s unique ecological and natural heritage. Full article
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<p>Locations of measurement points along the Narew River in Poland.</p>
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<p>Factor scores in points—bottom sediments.</p>
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<p>Factor scores in points—macrophytes.</p>
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<p>Hierarchical dendrograms for heavy metals in sediments obtained by Ward’s hierarchical clustering method.</p>
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<p>Hierarchical dendrograms for heavy metals in macrophytes were obtained by Ward’s hierarchical clustering method.</p>
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14 pages, 2492 KiB  
Article
Long-Term Variation Characteristics and Health Risks of Atmospheric Hg in the Largest City in Northwestern China
by Yuqi Pang, Hongmei Xu, Mengyun Yang, Bin Zhang, Liyan Liu, Sulin Chen, Jing Xue, Hui Zhang and Zhenxing Shen
Toxics 2024, 12(12), 935; https://doi.org/10.3390/toxics12120935 - 23 Dec 2024
Viewed by 584
Abstract
In this study, gaseous element mercury (GEM) and gaseous oxidized mercury (GOM) in the atmosphere were continuously observed at a minute resolution from 1 April 2019 to 31 December 2020 in urban Xi’an, the largest central city in Northwestern China. The concentrations of [...] Read more.
In this study, gaseous element mercury (GEM) and gaseous oxidized mercury (GOM) in the atmosphere were continuously observed at a minute resolution from 1 April 2019 to 31 December 2020 in urban Xi’an, the largest central city in Northwestern China. The concentrations of GEM and GOM drastically fluctuated within the ranges of 0.022–297 ng/m3 and 0.092–381 pg/m3, showing average values of 5.78 ± 7.36 ng/m3 and 14.2 ± 20.8 pg/m3, respectively. GEM and GOM showed a decreasing trend of 0.121 ng/m3 and 0.472 pg/m3 per month, respectively, which we believe was mainly caused by anthropogenic sources, especially by a reduction in coal-fired emissions, rather than meteorological factors. The significant positive correlation between GEM and PM2.5, SO2, NO2, and CO, as well as Cr, As, and Pb in PM2.5 also proves that. GEM showed a higher concentration at nighttime than daytime, while an M-shaped diurnal trend was observed for GOM. The hazard quotient of GEM for both males and females decreased at a rate of 0.003 per month, and children aged 2–5 were more sensitive to non-carcinogenic health risks. The changing trends, controlling factors, and human health risks of Hg in the atmosphere are necessary and crucial to study for improving our understanding of the impacts of Hg in Northwestern China. Full article
(This article belongs to the Special Issue Atmospheric Emissions Characteristics and Its Impact on Human Health)
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<p>The location of the sampling site and Hg sampling system.</p>
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<p>The average monthly variation in GEM and GOM concentrations and Sen’s regression curves.</p>
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<p>Diurnal variation of GEM and GOM concentrations in 2019 and 2020.</p>
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<p>Seasonal variations in GEM and GOM concentrations from November 2019 to November 2020. The dotted gray lines represent the mean values, the solid gray lines within each box represent the median values, the boundaries of the boxes represent 25th and 75th percentiles, the whiskers indicate 10th and 90th percentiles, and the small dots represent outliers.</p>
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<p>Correlation between GEM, GOM, and other air pollutants (Cr, As, and Pb refer to their concentrations in PM<sub>2.5</sub>) and meteorological factors; ** indicates significant correlation at the 0.01 level (double tailed); * indicates significant correlation at the 0.05 level (double tailed).</p>
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<p>The hazard quotient (HQ) and Sen’s regression curves of GEM for different genders in Xi’an during the study period.</p>
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<p>Comparison of HQ of GEM at different age groups and different genders in April 2019 and December 2020 in Xi’an.</p>
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19 pages, 22817 KiB  
Article
Urban Single Precipitation Events: A Key for Characterizing Sources of Air Contaminants and the Dynamics of Atmospheric Chemistry Exchanges
by Maciej Górka, Aldona Pilarz, Magdalena Modelska, Anetta Drzeniecka-Osiadacz, Anna Potysz and David Widory
Water 2024, 16(24), 3701; https://doi.org/10.3390/w16243701 - 22 Dec 2024
Viewed by 1051
Abstract
The chemistry of atmospheric precipitation serves as an important proxy for discriminating the source(s) of air contaminants in urban environments as well as to discuss the dynamic of atmospheric chemistry exchanges. This approach can be undertaken at time scales varying from single events [...] Read more.
The chemistry of atmospheric precipitation serves as an important proxy for discriminating the source(s) of air contaminants in urban environments as well as to discuss the dynamic of atmospheric chemistry exchanges. This approach can be undertaken at time scales varying from single events to seasonal and yearly time frames. Here, we characterized the chemical composition of two single rain episodes (18 July 2018 and 21 February 2019) collected in Wrocław (SW Poland). Our results demonstrated inner variations and seasonality (within the rain event as well as between summer and winter), both in ion concentrations as well as in their potential relations with local air contaminants and scavenging processes. Coupling statistical analysis of chemical parameters with meteorological/synoptic conditions and HYSPLIT back trajectories allowed us to identify three main factors (i.e., principal components; PC) controlling the chemical composition of precipitation, and that these fluctuated during each event: (i) PC1 (40%) was interpreted as reflecting the long-range transport and/or anthropogenic influences of emission sources that included biomass burning, fossil fuel combustion, industrial processes, and inputs of crustal origin; (ii) PC2 (20%) represents the dissolution of atmospheric CO2 and HF into ionic forms; and (iii) PC3 (20%) originates from agricultural activities and/or biomass burning. Time variations during the rain events showed that each factor was more important at the start of the event. The study of both SO42− and Ca2+ concentrations showed that while sea spray inputs fluctuated during both rain events, their overall impact was relatively low. Finally, below-cloud particle scavenging processes were only observed for PM10 at the start of the winter rain episode, which was probably explained by the corresponding low rain intensity and an overlap from local aerosol emissions. Our study demonstrates the importance of multi-time scale approaches to explain the chemical variability in rainwater and both its relation to emission sources and the atmosphere operating processes. Full article
(This article belongs to the Section Urban Water Management)
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<p>Study sites in Wrocław (SW Poland): University of Wrocław (UWr), where precipitation was collected; IMWM and CIEP air quality monitoring stations.</p>
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<p>Time variations in the meteorological parameters and chemical composition for precipitation samples collected on 18 July 2018: (<b>A</b>) precipitation at IMWM station, wind velocity and air temperature at UWr station, wind rose (24 h); (<b>B</b>) SO<sub>2</sub>, NO<sub>x</sub>, PM<sub>10</sub>, PM<sub>2.5</sub>, O<sub>3</sub> concentrations at CIEP station; (<b>C</b>) anion concentrations in precipitation; (<b>D</b>) pH, EC, and cation concentrations in precipitation.</p>
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<p>Time variations in the meteorological parameters and chemical composition for precipitation samples collected during on 21 February 2019: (<b>A</b>) precipitation at IMWM and UWr stations, wind velocity and air temperature at UWr station, wind rose (24 h); (<b>B</b>) SO<sub>2</sub>, NO<sub>x</sub>, PM<sub>10</sub>, PM<sub>2.5</sub>, O<sub>3</sub> concentrations at CIEP station; (<b>C</b>) anion concentrations in precipitation; (<b>D</b>) pH, EC, and cation concentrations in precipitation.</p>
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<p>The 48 h NOAA HYSPLIT back trajectories showing air mass movement to Wrocław for the (<b>A</b>) summer (18 July 2018) and (<b>C</b>) winter (21 February 2019) precipitation episodes at 12:00 UTC. KNMI synoptic charts (<a href="https://www.knmi.nl" target="_blank">https://www.knmi.nl</a>, accessed on 29 March 2023) corresponding to the two SOM-based weather patterns at 12:00 UTC on (<b>B</b>) 18 July 2018 and (<b>D</b>) 21 February 2021. Prominent synoptic features: L—low-pressure system; H—high-pressure system; blue—cold front; red—warm front; magenta—occluded front.</p>
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<p>Time variations in the calculated concentrations of nSS and SS sulfates and nSS and SS calcium ions in rainwater for the (<b>A</b>,<b>B</b>) summer (18 July 2018) and (<b>C</b>,<b>D</b>) winter (21 February 2019) rain episodes. Equations used for calculations are detailed in the text.</p>
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<p>Time variations in the rainwater sample scores on each principal component analysis (PCA) principal component for (<b>A</b>) summer (18 July 2018) and (<b>B</b>) winter (21 February 2019) precipitation episodes. Results of the PCA for each precipitation event are also presented. Highlighted red values identify significant loadings.</p>
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