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Search Results (4,351)

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13 pages, 1229 KiB  
Article
Evaluation of the Effects of Retro-Cavity Preconditioning with or Without Ethylenediaminetetraacetic Acid on Root Surface pH and Dislodgement Resistance of NeoMTA2 and Mineral Trioxide Aggregate Flow Retro-Fills: An Ex Vivo Investigation
by Sedigheh Khedmat, Seyyed Ali Abaee, Hadi Assadian, Antonio Signore and Stefano Benedicenti
J. Funct. Biomater. 2025, 16(1), 3; https://doi.org/10.3390/jfb16010003 - 24 Dec 2024
Abstract
Background: The aim of this study was to investigate the effects of retro-cavity preconditioning with or without 17% ethylenediaminetetraacetic acid (EDTA) solution on root surface pH as well as dislodgement resistance of NeoMTA2 and MTA Flow retro-fills. Methods: Forty-eight single-rooted human incisors were [...] Read more.
Background: The aim of this study was to investigate the effects of retro-cavity preconditioning with or without 17% ethylenediaminetetraacetic acid (EDTA) solution on root surface pH as well as dislodgement resistance of NeoMTA2 and MTA Flow retro-fills. Methods: Forty-eight single-rooted human incisors were selected. After completion of endodontic treatment, root-end resections were performed, and retro-cavities were prepared. The samples were randomly divided into two groups of A and B (n = 24 each). In group A, retro-cavities were preconditioned with 2.5% NaOCl, followed by 17% EDTA solution, whereas in group B, preconditioning was performed using 2.5% NaOCl before final irrigation with normal saline. Samples in each group were randomly subdivided into two subgroups of 1 and 2. Retro-fillings in the A1 and B1 subgroups were performed with MTA Flow, and in the A2 and B2 subgroups, they were performed with NeoMTA2. Root surface pH was measured in each sample at three different stages: before preparation of retro-cavities (pH0), after retro-cavity preconditioning (pH1), and three days after retro-filling (pH2). Subsequently, the push-out bond strength (PBS) of the retro-filling materials was measured by a universal testing machine, and their failure modes were visualized under 64× magnification. Results: Preconditioning with EDTA caused a significant increase in PBS for both NeoMTA2 and MTA Flow (p < 0.001). There was no significant difference between the average bond strength of MTA Flow and Neo MTA2 (p = 0.271). There was a significant increase in the average pH2 compared to pH1 and pH0 across all groups (p < 0.001). Specifically, the use of EDTA led to a notable increase in the average pH2 in the MTA Flow group compared to the Neo MTA2 group (p = 0.027). Groups preconditioned with EDTA more frequently indicated a cohesive failure mode. Conclusions: The use of EDTA significantly increased the push-out bond strength of retro-fill materials to dentin. However, it did not prevent the ultimate alkalinity of retro-filled cavities. Full article
(This article belongs to the Special Issue Advanced Materials for Clinical Endodontic Applications (2nd Edition))
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<p>Stereomicroscopic images of the types of bond failures: (<b>A</b>) adhesive failure, (<b>B</b>) cohesive failure, and (<b>C</b>) mixed failure.</p>
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<p>Push-out bond strength of experimental materials with 95% confidence interval, with or without preconditioning with EDTA (no: without preconditioning with EDTA; yes: conditioning with EDTA).</p>
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<p>Average pH1 and pH2 measurements before and after the use of retro-fill materials with or without preconditioning with EDTA.</p>
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<p>Percentage of failure types observed across various subgroups.</p>
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42 pages, 1364 KiB  
Systematic Review
The Theory of Complexity and Sustainable Urban Development: A Systematic Literature Review
by Walter Antonio Abujder Ochoa, Alfredo Iarozinski Neto, Paulo Cezar Vitorio Junior, Oriana Palma Calabokis and Vladimir Ballesteros-Ballesteros
Sustainability 2025, 17(1), 3; https://doi.org/10.3390/su17010003 - 24 Dec 2024
Abstract
Urbanization is a rapidly accelerating global phenomenon that challenges sustainable development, requiring innovative frameworks for understanding and managing urban complexity. This study explores the application of Complexity Theory in sustainable urban development, framing cities as Complex Adaptive Systems (CAS), where dynamic social, economic, [...] Read more.
Urbanization is a rapidly accelerating global phenomenon that challenges sustainable development, requiring innovative frameworks for understanding and managing urban complexity. This study explores the application of Complexity Theory in sustainable urban development, framing cities as Complex Adaptive Systems (CAS), where dynamic social, economic, environmental, and technological interactions generate emergent behaviors. A systematic literature review was conducted, analyzing 91 studies retrieved from Scopus that explicitly link Complexity Theory to urban sustainability. Key findings reveal trade-offs, such as balancing economic growth with ecological preservation and social equity, while emphasizing the role of self-organization and adaptive governance in enhancing urban resilience. Concrete examples include the application of fractal analysis in urban planning to predict sprawl and optimize infrastructure and the use of system dynamics models to align smart city initiatives with United Nations Sustainable Development Goals. Wider co-benefits identified include improved public health through integrated green infrastructure and the reinforcement of social cohesion via participatory urban planning. This research concludes that embracing Complexity Theory enables a holistic approach to urban sustainability, fostering adaptable, resilient systems that can better manage uncertainty. This study highlights the need for interdisciplinary collaboration and innovative policy frameworks to navigate the multifaceted challenges of modern urbanization. Full article
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<p>PRISMA 2020 flow diagram for systematic reviews.</p>
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<p>Documents by year extracted from Scopus.</p>
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<p>Documents by country or territory extracted from Scopus.</p>
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<p>Density visualization.</p>
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19 pages, 4816 KiB  
Article
Optimization of Enzymatic Hydrolysis and Fermentation Processing for Set-Type Oat Yogurt with Favorable Acidity and Coagulated Texture
by Wenjie Xu, Xinzhu Wu, Chen Xia, Zicong Guo, Zhengyuan Zhai, Yongqiang Cheng and Ju Qiu
Foods 2024, 13(24), 4180; https://doi.org/10.3390/foods13244180 - 23 Dec 2024
Abstract
The key role of enzymatic hydrolysis and fermentation in the sensory quality of set yogurt made from whole oats was demonstrated. The optimal process was established by the orthogonal and response surface methodology based on the acidity, textural, and rheological properties. The results [...] Read more.
The key role of enzymatic hydrolysis and fermentation in the sensory quality of set yogurt made from whole oats was demonstrated. The optimal process was established by the orthogonal and response surface methodology based on the acidity, textural, and rheological properties. The results indicated that the enzymatic hydrolysis appropriately consisted of liquefaction with 12 U/mL α-amylase at 70 °C and pH 6.5 for 60 min, followed by saccharification with 400 U/mL α-1,4-glucan glucohydrolase at 60 °C and pH 4.5 for 60 min. The Streptococcus thermophilus ST15 and Lactobacillus bulgaricus 20249 strains were the most efficacious strains, with a 0.1% inoculation for the fermentation at 42 °C for 16 h. So, a soft semisolid oat yogurt formed with an 8% solid–liquid ratio, which exhibited an acidity of 73.17 °T, a cohesiveness ratio of 0.51, and a maximum apparent viscosity of 1902.67 Pa·s. The coagulated texture of the oat yogurt was closely associated with the exopolysaccharide (EPS) yield up to 304.99 mg/L. These findings supported the optimal processing of oat yogurt, especially its correlation with the high capacity of EPS production by strains. It is an innovative and feasible way to improve the properties of set-type oat yogurt, especially the utilization of the whole oat. Full article
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<p>Changes in dextrose equivalent (DE) value of enzymatic hydrolysate under different liquefaction ((<b>A</b>) enzyme concentration; (<b>B</b>) temperature; (<b>C</b>) time; (<b>D</b>) pH) or saccharification conditions ((<b>E</b>) enzyme concentration; (<b>F</b>) temperature; (<b>G</b>) time; (<b>H</b>) pH). Lowercase letters expressed the statistical significance among different yogurt groups at <span class="html-italic">p</span> &lt; 0.05.</p>
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<p>Water-holding capacity (<b>A</b>), cohesiveness (<b>B</b>), and viscosity (<b>C</b>) of fermented oat hydrolysate (<b>D</b>), oat paste (<b>E</b>), and set-type oat yogurt (<b>F</b>). For the fermented oat hydrolysate, the enzymatic hydrolysate of oats was fermented directly; for the oat paste, the enzymatic hydrolysate and flour mixture was heated; for the set-type oat yogurt, oat paste was fermented. Lowercase letters in the column express the statistical significance among different yogurt groups at <span class="html-italic">p</span> &lt; 0.05.</p>
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<p>Acidity (<b>A</b>), cohesiveness (<b>B</b>), and viable bacterial count (<b>C</b>) of set-type oat yogurt fermented by different strain combinations, as well as the ability of these combinations to produce exopolysaccharides (EPSs) (<b>D</b>). <span class="html-italic">ST15</span>, <span class="html-italic">Streptococcus thermophilus15</span>; <span class="html-italic">ST20370</span>, <span class="html-italic">Streptococcus thermophilus 20370</span>; <span class="html-italic">LB20247</span>, <span class="html-italic">Lactobacillus bulgaricus 20247</span>; <span class="html-italic">LB20249</span>, <span class="html-italic">Lactobacillus bulgaricus 20249</span>; <span class="html-italic">LB20271</span>, <span class="html-italic">Lactobacillus bulgaricus 20271</span>. Lowercase letters in the column express the statistical significance among different yogurt groups at <span class="html-italic">p</span> &lt; 0.05.</p>
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<p>Changes in acidity (<b>A</b>), pH (<b>B</b>), and cohesiveness (<b>C</b>) of set-type oat yogurt at different temperatures, times, solid–liquid ratios, and inoculation volumes. The x-axis labels A, B, C, D, and E correspond to the variable conditions defined in the legend, in the specified order.</p>
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<p>Rheological properties of set-type oat yogurt. Plots of steady shear analysis (<b>A</b>), storage modulus and loss modulus (<b>B</b>), and tan δ (G″/G′ ratio) (<b>C</b>) for set-type oat yogurt with different temperatures (1), times (2), solid–liquid ratios (3), and inoculation volumes (4).</p>
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<p>Response surface and contour plots for acidity (<b>A</b>), pH (<b>B</b>), cohesiveness (<b>C</b>), and apparent viscosity (<b>D</b>). 1, inoculation volume and solid–liquid ratio; 2, inoculation volume and temperature; 3, solid–liquid ratio and temperature. Red color means the higher response value (acidity, pH, cohesiveness, and apparent viscosity), while green/blue color means the lower response value (acidity, pH, cohesiveness, and apparent viscosity).</p>
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<p>Spider plot for electronic tongue sensory score of fermented oat hydrolysate, oat paste, and set-type oat yogurt (<b>A</b>). Correlation analysis of EPS and set-type oat yogurt cohesiveness, apparent viscosity, acidity, pH, and viable bacterial count (<b>B</b>). Principal component analysis (PCA) of EPS and set-type oat yogurt cohesiveness, apparent viscosity, acidity, pH, and viable bacterial count (<b>C</b>).</p>
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16 pages, 545 KiB  
Article
Fuzzy Rough Set Models Based on Fuzzy Similarity Relation and Information Granularity in Multi-Source Mixed Information Systems
by Pengfei Zhang, Yuxin Zhao, Dexian Wang, Yujie Zhang and Zheng Yu
Mathematics 2024, 12(24), 4039; https://doi.org/10.3390/math12244039 - 23 Dec 2024
Abstract
As a pivotal research method in the field of granular computing (GrC), fuzzy rough sets (FRSs) have garnered significant attention due to their successful overcoming of the limitations of traditional rough sets in handling continuous data. This paper is dedicated to exploring the [...] Read more.
As a pivotal research method in the field of granular computing (GrC), fuzzy rough sets (FRSs) have garnered significant attention due to their successful overcoming of the limitations of traditional rough sets in handling continuous data. This paper is dedicated to exploring the application potential of FRS models within the framework of multi-source complex information systems, which undoubtedly holds profound research significance. Firstly, a novel multi-source mixed information system (MsMIS), encompassing five distinct data types, is introduced, thereby enriching the dimensions of data processing. Subsequently, a similarity function, designed based on the unique attributes of the data, is utilized to accurately quantify the similarity relations among objects. Building on this foundation, fuzzy T-norm operators are employed to integrate the similarity matrices derived from different data types into a cohesive whole. This integration not only lays a solid foundation for subsequent model construction but also highlights the value of multi-source information fusion in the analysis of the MsMIS. The integrated results are subsequently utilized to develop FRS models. Through rigorous examination from the perspective of information granularity, the rationality of the FRS model is proven, and its mathematical properties are explored. This paper contributes to the theoretical advancement of FRS models in GrC and offers promising prospects for their practical implementation. Full article
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<p>The calculation process of multi-source mixed data fusion.</p>
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19 pages, 445 KiB  
Article
A Qualitative Exploration of the Process and Experience of Change in Moving on in My Recovery: An Acceptance and Commitment Therapy Based Recovery Group for Substance Use Disorder
by Emma L. Shepley, Mike C. Jackson and Lee M. Hogan
Behav. Sci. 2024, 14(12), 1237; https://doi.org/10.3390/bs14121237 - 23 Dec 2024
Abstract
Moving on in my recovery (MOIMR) is a new, acceptance and commitment therapy (ACT) based group intervention to support recovery from substance use disorder. It was co-developed by, and is co-facilitated with, people in recovery. This study used a grounded theory model to [...] Read more.
Moving on in my recovery (MOIMR) is a new, acceptance and commitment therapy (ACT) based group intervention to support recovery from substance use disorder. It was co-developed by, and is co-facilitated with, people in recovery. This study used a grounded theory model to understand the process of change experienced by individuals who completed the group programme. Ten individuals who were abstinent from substances following their participation in MOIMR were interviewed. The model that emerged depicted a chronological series of processes that centred around a core category of gains derived from approaching their emotional vulnerability by leaning in to discomfort (e.g., difficult internal experiences like thoughts, emotions, and physical sensations) whilst pursuing activities that aligned to what mattered to them. Initial key processes indicated that participants experienced a degree of suffering from substance use prior to engagement. Group safety was a key element in fostering connection, normalisation, and cohesion, combined with psychological understanding being significantly derived from those with a lived experience of substance misuse and addiction. Later processes reflecting core ACT mechanisms such as letting go, value-guided action, and acceptance of difficult internal experiences took time to develop; many participants reported completing MOIMR more than once as a means of understanding these components. Limitations, along with implications for clinical practice and future research are discussed. Full article
(This article belongs to the Special Issue Promoting Behavioral Change to Improve Health Outcomes)
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<p>Model of the process of change through MOIMR.</p>
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15 pages, 6531 KiB  
Article
Preparation and Performance Study of Novel Foam Vegetation Concrete
by Teng Zhang, Tianbin Li, Hua Xu, Mengyun Wang and Lingling Lu
Materials 2024, 17(24), 6295; https://doi.org/10.3390/ma17246295 - 23 Dec 2024
Abstract
Vegetation concrete is one of the most widely used substrates in ecological slope protection, but its practical application often limits the growth and nutrient uptake of plant roots due to consolidation problems, which affects the effectiveness of slope protection. This paper proposed the [...] Read more.
Vegetation concrete is one of the most widely used substrates in ecological slope protection, but its practical application often limits the growth and nutrient uptake of plant roots due to consolidation problems, which affects the effectiveness of slope protection. This paper proposed the use of a plant protein foaming agent as a porous modifier to create a porous, lightweight treatment for vegetation concrete. Physical performance tests, direct shear tests, plant growth tests, and scanning electron microscopy experiments were conducted to compare and analyze the physical, mechanical, microscopic characteristics, and phyto-capabilities of differently treated vegetation concrete. The results showed that the higher the foam content, the more significant the porous and lightweight properties of the vegetation concrete. When the foam volume was 50%, the porosity increased by 106.05% compared to the untreated sample, while the volume weight decreased by 20.53%. The shear strength, cohesion, and internal friction angle of vegetation concrete all showed a decreasing trend with increasing foaming agent content. Festuca arundinacea grew best under the 30% foaming agent treatment, with germinative energy, germinative percentage, plant height, root length, and underground biomass increasing by 6.31%, 13.22%, 8.57%, 18.71%, and 34.62%, respectively, compared to the untreated sample. The scanning electron microscope observation showed that the pore structure of vegetation concrete was optimized after foam incorporation. Adding plant protein foaming agents to modify the pore structure of vegetation concrete is appropriate, with an optimal foam volume ratio of 20–30%. This study provides new insights and references for slope ecological restoration engineering. Full article
(This article belongs to the Special Issue Functional Cement-Based Composites for Civil Engineering (Volume II))
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<p>Vegetation concrete: (<b>a</b>) Vegetation concrete, (<b>b</b>) Consolidation of Vegetation concrete (Magnified view).</p>
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<p>Foam made by high-speed mixer: (<b>a</b>) High-speed mixer, (<b>b</b>) Foam.</p>
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<p>Sample preparation: (<b>a</b>) Add powdered components and stir; (<b>b</b>) Add water and stir; (<b>c</b>) Add foam. (<b>d</b>) Stirring, (<b>e</b>) Add larger granular components and stir; (<b>f</b>) Foam vegetation concrete.</p>
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<p>Vegetation concrete samples with different foam volumes: (<b>a</b>) 0%, (<b>b</b>) 10%, (<b>c</b>) 20%, (<b>d</b>) 30%, (<b>e</b>) 40%, (<b>f</b>) 50%.</p>
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<p>Change in volume weight and porosity of vegetation concrete with added foam volume.</p>
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<p>Shear strength of vegetation concrete at different ages.</p>
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<p>Influence of foam volume on cohesion and angle of internal friction of vegetated concrete.</p>
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<p>The growth conditions of <span class="html-italic">Festuca arundinacea</span> on vegetation concrete with different treatments: (<b>a</b>) 0%, (<b>b</b>) 10%, (<b>c</b>) 20%, (<b>d</b>) 30%, (<b>e</b>) 40%, (<b>f</b>) 50%.</p>
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<p>Influence of foam volume on the biomass of <span class="html-italic">Festuca arundinacea</span>.</p>
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<p>SEM images of vegetation concrete samples at ×2000 magnification: (<b>a</b>) 0%, (<b>b</b>) 10%, (<b>c</b>) 20%, (<b>d</b>) 30%, (<b>e</b>) 40%, (<b>f</b>) 50%.</p>
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<p>SEM images of vegetation concrete with 0% and 50% foam volume at ×5000 magnification: (<b>a</b>) 0%, (<b>b</b>) 50%.</p>
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16 pages, 1705 KiB  
Review
Examining South Tyrol’s Experience: Digital Health Adoption and Workforce Issues in Implementing Italy’s Primary Care Reform Under Ministerial Decree No. 77/2022
by Christian J. Wiedermann, Angelika Mahlknecht, Verena Barbieri, Dietmar Ausserhofer, Barbara Plagg, Carla Felderer, Pasqualina Marino, Adolf Engl and Giuliano Piccoliori
Epidemiologia 2024, 5(4), 838-853; https://doi.org/10.3390/epidemiologia5040057 - 23 Dec 2024
Abstract
Background: Ministerial Decree (D.M.) 77/2022 aims to reform Italy’s primary care system by establishing community health centres and integrating digital tools to address healthcare access disparities and workforce shortages. This review focuses on frailty assessment tools, digital health innovations, and workforce challenges in [...] Read more.
Background: Ministerial Decree (D.M.) 77/2022 aims to reform Italy’s primary care system by establishing community health centres and integrating digital tools to address healthcare access disparities and workforce shortages. This review focuses on frailty assessment tools, digital health innovations, and workforce challenges in the Autonomous Province of Bolzano, South Tyrol, emphasising interprofessional trust and collaboration issues. Methods: Using a narrative custom review approach guided by the SANRA checklist, this study synthesised findings from PubMed, official health websites, and regional surveys on frailty, workforce dynamics, interprofessional collaboration, and digital infrastructure in South Tyrol. Results: General practitioners (GPs) exhibited high professional motivation but expressed concerns about autonomy and administrative burdens in collaborative care models. Trust issues between GPs and specialists hinder workforce cohesion and care coordination, highlighting the need for structured inter-professional communication. Frailty assessments, such as the PRISMA-7 tool, identify over 33% of community-dwelling individuals aged 75 years and older as frail, necessitating targeted interventions. Digital health adoption, particularly electronic health records and telemedicine, is slow because of workforce shortages and infrastructure limitations. Conclusions: The successful implementation of D.M. 77/2022 in South Tyrol requires addressing workforce challenges, improving interprofessional trust, expanding digital infrastructure, and integrating frailty assessment findings into care strategies. These measures are critical for achieving a more resilient, equitable, and effective primary healthcare system. Full article
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<p>Structural organisation of territorial primary healthcare services introduced by D.M. 77/2022 in Italy. The reform emphasises the decentralisation of services into community-based primary care centres, community hospitals, and home care services coordinated by the Territorial Operations Center at the district level. Patient stratification defines various levels of care needs, from low-intensity services for healthy individuals to high-intensity services for terminally ill patients, and the integration of digital tools, such as Electronic Health Records and Telemedicine. Abbreviations: COT, territorial operations center (Centrale Operativa Territoriale); CDCs, community-based primary care centers (Case della Comunità); ODC, community hospital (Ospedale di Comunità); UCP, palliative care unit (Unità di Cure Palliative); EHRs, electronic health records.</p>
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<p>Framework for integrating frailty assessments, digital health tools, and workforce challenges under D.M. 77/2022 in South Tyrol. Abbreviations: AI, artificial intelligence; EHRs, electronic health records; D.M., ministerial decree (“Decreto Ministeriale”), PRISMA-7, Program on Research for Integrating Services for the Maintenance of Autonomy-7; SANRA, Scale for the Assessment of Narrative Review Articles.</p>
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29 pages, 16899 KiB  
Article
Exploring Design Interventions to Enhance Intergenerational Sharing: An Importance–Performance Analysis of Public Spaces in Changsha, China
by Zhuolin Li, Zhe Li and Jinbiao Ma
Sustainability 2024, 16(24), 11228; https://doi.org/10.3390/su162411228 - 21 Dec 2024
Viewed by 338
Abstract
Intergenerational sharing promotes social cohesion within communities by encouraging dialogue and understanding across different age groups. Nevertheless, existing research has inadequately delved into the human experiences and meaning-making processes that underpin intergenerational sharing, leading to a limited grasp of effective design intervention strategies [...] Read more.
Intergenerational sharing promotes social cohesion within communities by encouraging dialogue and understanding across different age groups. Nevertheless, existing research has inadequately delved into the human experiences and meaning-making processes that underpin intergenerational sharing, leading to a limited grasp of effective design intervention strategies in community spaces. This study aimed to explore the environmental and social factors influencing intergenerational interactions in community public spaces in Changsha, China, addressing two primary questions: (1) What environmental factors shape intergenerational sharing behaviors? (2) What design strategies can enhance intergenerational sharing in community public spaces? This research employed a mixed-methods approach, including qualitative observation and quantitative importance–performance analysis (IPA) through a survey of 212 residents, to investigate the intergenerational sharing needs of residents. To begin with, the study conducted a detailed analysis of the characteristics and variations in Changsha’s community public spaces. The finding revealed notable disparities in intergenerational sharing behaviors among three types of community spaces: traditional, commercial housing, and integrated neighborhoods. Through environmental behavior observation and IPA, key environmental factors influencing intergenerational sharing behaviors were identified, emphasizing areas for improvement. Based on these findings, the study proposed a design framework consisting of community planning and design, spatial layout and facility construction, and community management, with nine targeted strategies to optimize environmental factors for intergenerational sharing to cater to the unique characteristics of different community types. These findings can deepen our understanding of intergenerational sharing mechanisms and offer practical recommendations for fostering stronger interactions, providing valuable insights for future community public space design. Full article
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<p>Importance–performance analysis (IPA) [<a href="#B8-sustainability-16-11228" class="html-bibr">8</a>].</p>
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<p>Distribution of public spaces (created by the author).</p>
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<p>Community public space layout types (created by the author).</p>
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<p>Intergenerational activities in Shouxing Street community.</p>
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<p>Intergenerational activities in Sunshine community.</p>
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<p>Intergenerational activities in Wangyue Lake community.</p>
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<p>General information.</p>
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<p>Data related to intergenerational communication.</p>
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<p>Specific intergenerational activities.</p>
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<p>Satisfaction scree plot.</p>
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<p>Four quadrant chart of overall satisfaction–importance.</p>
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<p>Quadrant chart of satisfaction–importance of questionnaire items (factors).</p>
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13 pages, 5875 KiB  
Article
Propagation Law of Hydraulic Fractures in Continental Shale Reservoirs with Sandstone–Shale Interaction
by Yuan Gao, Qiuping Qin, Xiaobing Bian, Xiaoyang Wang, Wenjun Xu and Yanxin Zhao
Processes 2024, 12(12), 2931; https://doi.org/10.3390/pr12122931 - 21 Dec 2024
Viewed by 299
Abstract
There are significant lithological and stress differences between continental shale layers, posing challenges for hydraulic fractures (HFs) to propagate through the formations, leading to weak fracture effects. To address this, this article adopts the finite element and cohesive force element methods to formulate [...] Read more.
There are significant lithological and stress differences between continental shale layers, posing challenges for hydraulic fractures (HFs) to propagate through the formations, leading to weak fracture effects. To address this, this article adopts the finite element and cohesive force element methods to formulate a three-dimensional numerical model for hydraulic fracture (HF) propagation through layers, considering interlayer lithology and stress variations. The accuracy of the model was verified by physical experiments, and the one-factor analysis method was used to creatively reveal the complex mechanism of the effect of geological and engineering variables on the diffusion of HFs in continental shale reservoirs. The results show that high interlayer stress difference, high interlayer tensile strength difference, low interlayer Young’s modulus difference and large interlayer thickness are not conducive to the penetration of HFs, but increasing the injection rate and the viscosity of fracturing fluid can effectively improve the penetration of HFs. The influence ranking of each factor was determined using the grey relational degree analysis method: interlayer stress difference > interlayer Young’s modulus difference > interlayer tensile strength difference > interlayer thickness > injection rate > fracturing fluid viscosity. Full article
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<p>The traction-separation law of cohesive elements [<a href="#B17-processes-12-02931" class="html-bibr">17</a>].</p>
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<p>Schematic of fluid flow within a damaged unit [<a href="#B17-processes-12-02931" class="html-bibr">17</a>].</p>
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<p>Comparison of indoor experiments and numerical simulation results.</p>
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<p>Numerical simulation diagram.</p>
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<p>Comparison of simulation results of different spacer thicknesses.</p>
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<p>Comparison of simulation results of stress difference between different layers.</p>
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<p>Comparison of simulation results of different tensile strength differences.</p>
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<p>Comparison of simulation results of different Young’s modulus differences.</p>
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<p>Comparison of simulation results of different injection rates.</p>
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<p>Comparison of simulation results of viscosity of different fracturing fluids.</p>
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<p>Calculation results of correlation degree of different influencing factors.</p>
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41 pages, 5642 KiB  
Article
Smart Campus Performance Assessment: Framework Consolidation and Validation Through a Delphi Study
by Ken Polin, Tan Yigitcanlar, Mark Limb and Tracy Washington
Buildings 2024, 14(12), 4057; https://doi.org/10.3390/buildings14124057 - 20 Dec 2024
Viewed by 295
Abstract
The concept of a smart campus is rapidly gaining traction worldwide, driven by the growth of artificial intelligence (AI) and the Internet of Things (IoT), along with the digital transformation of higher education institutions. While numerous initiatives have been undertaken to enhance the [...] Read more.
The concept of a smart campus is rapidly gaining traction worldwide, driven by the growth of artificial intelligence (AI) and the Internet of Things (IoT), along with the digital transformation of higher education institutions. While numerous initiatives have been undertaken to enhance the capability of smart campus systems to keep pace with AI advancements, there have been few attempts to develop a cohesive conceptual framework for the smart campus, and to date, there has been limited empirical research conducted to validate the framework. This study bridges this gap by providing the first in-depth assessment of a holistic smart campus conceptual framework. The paper uses a Delphi study approach to validate and consolidate a framework for assessing the robustness of the smart campus assessment framework for application in university settings. The framework consists of four domains, 16 categories, and 48 indicators, comprising a total of 68 items that were validated by experts across the globe. Two rounds of structured questionnaires were conducted to achieve consensus on the framework. The first round involved 34 experts from diverse geographic and professional backgrounds in the smart campus field. The second round included 21 of the earlier participants, which was sufficient to determine consensus. In total, seven of the forty-eight indicators were agreed upon after Round 1, increasing to forty-three after Round 2. The results indicate strong agreement among the experts, affirming the framework’s robustness. This study offers an expert-based, interpretive assessment of the development of the smart campus concept, with a particular focus on validating the smart campus framework. Full article
(This article belongs to the Collection Cities and Infrastructure)
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<p>Smart campus framework, adopted from [<a href="#B14-buildings-14-04057" class="html-bibr">14</a>].</p>
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<p>Sample questions of the survey.</p>
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<p>Delphi study diagram.</p>
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<p>Round 1 Delphi experts by region.</p>
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<p>Round 1 Delphi experts by sector.</p>
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<p>Round 1 frequency of choices on dimensions.</p>
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<p>Round 1 frequency of choices on categories.</p>
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<p>Round 1 frequency of choices on indicators.</p>
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<p>Round 2 frequency of choices on dimensions.</p>
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<p>Round 2 frequency of choices on categories.</p>
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<p>Round 2 frequency of choices on indicators.</p>
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<p>Mean score of 68 items.</p>
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<p>Standard deviation of 68 items.</p>
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<p>Overall agreement consensus level.</p>
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<p>Specific agreement consensus level.</p>
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16 pages, 4704 KiB  
Article
Natural Fiber Reinforcement of Ceramic Slurry Compacts
by Simona Elena Avram, Lucian Barbu Tudoran, Stanca Cuc, Gheorghe Borodi, Bianca Violeta Birle and Ioan Petean
J. Compos. Sci. 2024, 8(12), 542; https://doi.org/10.3390/jcs8120542 - 20 Dec 2024
Viewed by 218
Abstract
Background: ceramic tile wastewater slurry contains a large amount of fine kaolinite particles acting as a matrix for mineral filler particles of quartz and mullite. Reinforcing it with natural fibers increases its compression strength. A novel approach is using Stipa pennata fibers because [...] Read more.
Background: ceramic tile wastewater slurry contains a large amount of fine kaolinite particles acting as a matrix for mineral filler particles of quartz and mullite. Reinforcing it with natural fibers increases its compression strength. A novel approach is using Stipa pennata fibers because of their local availability, good mechanical properties, and feathery aspect, making them able to reinforce ceramic slurry compacts. Preparation and investigation methods: Slurry conditioned at 33% humidity and milled at 6000 rpm for 5 min contains 39% quartz, 37% kaolinite, 16% mullite and 8% lepidocrocite (observed via XRD correlated with mineralogical microscopy). Kaolinite particles ensure optimal binding of the mineral filler and the Stipa pennata fibers into a dense composite structure, as observed via SEM. EDS maps reveal a local increase in C content, along with the natural fibers being associated with significant levels of Al and Si, indicating the microstructural compactness of the reinforcement layer. An additional compaction load enhances microstructural cohesion. Results: The sample without reinforcement has a compressive strength of 1.29 MPa. This increases to 2.89 MPa by adding a median reinforcing layer and reaches 3.13 MPa by adding a compaction load of 20 N. A median crossed fiber-reinforcing layer combined with the compaction load of 20 N ensures a compressive strength of 4.78 MPa. Introducing two reinforcing layers oriented perpendicular to one another ensures a compressive strength of 2.48 MPa. Lateral placement of the two reinforcing layers regarding the sample median plan causes a slight decrease in the compressive strength. SEM fractography reveals that the feather-like structure of Stipa pennata fiber acts as an anchor for the median site of the samples, slowing crack initiation under compressive efforts, creating a novel approach compared to natural fiber without lateral flakes. Conclusions: The optimal place for the reinforcement layer is the median site of the sample, and interlaced reinforcement ensures the best compressive resistance. Ceramic slurry reinforced with Stipa pennata is useful as an intermediary layer on the modular walls of ecologic buildings. Full article
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<p>Photographs of the walls of a century-old house in Romania: (<b>a</b>) break through the wall section and (<b>b</b>) wall surface plastering.</p>
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<p>General aspects of <span class="html-italic">Stipa pennata</span> fibers: reinforcing displacement and samples.</p>
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<p>XRD patterns for (<b>a</b>) raw <span class="html-italic">Stipa pennata</span> fibers, (<b>b</b>) ceramic slurry layer reinforced with <span class="html-italic">Stipa pennata</span>, and (<b>c</b>) ceramic slurry prior reinforcement.</p>
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<p>MOM images obtained for (<b>a</b>) <span class="html-italic">Stipa pennata</span> fibers, (<b>b</b>) reinforced ceramic slurry, and (<b>c</b>) ceramic slurry. Microstructural details of each image are marked with ’ (<b>a’</b>–<b>c’</b>).</p>
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<p>SEM images of the in-plane microstructure of <span class="html-italic">Stipa pennata</span> reinforcing layer: (<b>a</b>) <span class="html-italic">Stipa pennata</span> fibers, (<b>b</b>) reinforced ceramic slurry, and (<b>c</b>) ceramic slurry. Microstructural details of each image are marked with ’ (<b>a’</b>–<b>c’</b>).</p>
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<p>SEM microstructural aspects of the interlaced reinforcing layer: (<b>a</b>) the intersection of two <span class="html-italic">Stipa pennata</span> stems and (<b>b</b>) the intersection of the lateral flakes. Their aspect after slurry embedding is observed by MOM: (<b>a’</b>) the intersection of two <span class="html-italic">Stipa pennata</span> stems and (<b>b’</b>) the intersection of the lateral flakes.</p>
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<p>SEM images with the equivalent elemental map and EDS spectra for (<b>a</b>) overall reinforcing microstructure, (<b>b</b>) microstructural detail of the flakes reinforcement, and (<b>c</b>) microstructural detail of the slurry.</p>
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<p>The sample aspects after the compression test before removal from the testing machine: (<b>a</b>) S0, (<b>b</b>) S1, (<b>c</b>) S2, (<b>d</b>) S3, and (<b>e</b>) S4.</p>
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<p>The results of compression test: (<b>a</b>) compressive strength, and (<b>b</b>) compression Young modulus. Error bars represent the standard deviation.</p>
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<p>SEM fractography of the compressed, broken samples observed at magnification of ×200: (<b>a</b>–<b>a″</b>) S0, (<b>b</b>–<b>b″</b>) S1, (<b>c</b>–<b>c″</b>) S2, (<b>d</b>–<b>d″</b>) S3, and (<b>e</b>–<b>e″</b>) S4. Microstructural details were observed at a magnification of ×500 (′) and ×1000 (″).</p>
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19 pages, 13841 KiB  
Article
Spatial Prediction of Soil Water Content by Bayesian Optimization–Deep Forest Model with Landscape Index and Soil Texture Data
by Weihao Yang, Ruofan Zhen, Fanyue Meng, Xiaohang Yang, Miao Lu and Yingqiang Song
Agronomy 2024, 14(12), 3039; https://doi.org/10.3390/agronomy14123039 - 19 Dec 2024
Viewed by 552
Abstract
The accurate prediction of the spatial variability for soil water content (SWC) in farmland is essential for water resource management and sustainable agricultural development. However, natural factors introduce uncertainty and result in poor alignment when predicting farmland SWC, leading to low accuracy. To [...] Read more.
The accurate prediction of the spatial variability for soil water content (SWC) in farmland is essential for water resource management and sustainable agricultural development. However, natural factors introduce uncertainty and result in poor alignment when predicting farmland SWC, leading to low accuracy. To address this, this study introduced a novel indicator: landscape indices. These indices include the largest patch index (LPI), edge density (ED), aggregation index (AI), patch cohesion index (COH), contagion index (CON), landscape division index (DIV), percentage of like adjacencies (PLA), Shannon evenness index (SHEI), and Shannon diversity index (SHDI). A Bayesian optimization–deep forest (BO–DF) model was developed to leverage these indices for predicting the spatial variability of SWC. Statistical analysis revealed that landscape indices exhibited skewed distributions and weak linear correlations with SWC (r < 0.2). Despite this, incorporating landscape index variables into the BO–DF model significantly improved prediction accuracy, with R2 increasing by 35.85%. This model demonstrated a robust nonlinear fitting capability for the spatial variability of SWC. Spatial mapping of SWC using the BO–DF model indicated that high-value areas were predominantly located in the eastern and southern regions of the Yellow River Delta in China. Furthermore, the SHapley additive explanation (SHAP) analysis highlighted that landscape indices were key drivers in predicting SWC. These findings underscore the potential of landscape indices as valuable variables for spatial SWC prediction, supporting regional strategies for sustainable agricultural development. Full article
(This article belongs to the Special Issue Advanced Machine Learning in Agriculture)
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<p>The geographical location of the study area and the distribution of sampling points.</p>
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<p>The load values of the component matrix of soil texture feature data. The pie chart shows the cumulative contribution rate of the first three principal components (PCs) to the total variance.</p>
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<p>Schematic diagram of the structure of the BO–DF model for the SWC prediction. In this case, soil texture, landscape index, and SWC are used as input factors that ultimately act on SWC prediction. Each cascade level consists of two random forests (black) and two completely random woods (red) to ensure model diversity and generalization ability.</p>
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<p>The matrix scatter plot illustrates the relationship between soil water content (SWC) and various auxiliary variables derived from Sentinel-2 L2A imagery. The significance of the Pearson correlation coefficient (p) is included in the plot to assess the statistical relevance of these relationships. The environmental variables presented in the plot include largest patch index (LPI), edge density (ED), aggregation index (AI), patch cohesion index (COH), contagion index (CON), landscape division index (DIV), percentage of like adjacencies (PLA), Shannon evenness index (SHEI), Shannon diversity index (SHDI), and soil texture features (PC1, PC2, PC3, PC4, PC5).</p>
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<p>The iterative trend of RMSE during the BO algorithm. The horizontal axis is the sampling values of super hyper-parameters max_depth, n_trees, n_estimators, and min_samples_split, and the vertical axis is the sampling values of super hyper-parameters max_layers, min_samples_split, min_samples_leaf, and n_bins. The red circle is the optimal hyper-parameter range obtained after multiple iterations. The color band on the right side represents the value of RMSE.</p>
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<p>The scatter trend for the prediction of SWC by the BO–DF model in (a) only soil texture variables and (b) with the addition of the landscape index.</p>
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<p>Spatial mapping of the SWC in the study area.</p>
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<p>The driving importance of auxiliary variables for the SWC by SHAP analysis. The closer the color is to red, the larger the feature value is, and the closer the color is to blue, the smaller the feature value is.</p>
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16 pages, 828 KiB  
Review
Powering Indonesia’s Future: Reviewing the Road to Electric Vehicles Through Infrastructure, Policy, and Economic Growth
by Natalina Damanik, Ririen Clara Octavia and Dzikri Firmansyah Hakam
Energies 2024, 17(24), 6408; https://doi.org/10.3390/en17246408 - 19 Dec 2024
Viewed by 388
Abstract
Electric vehicles (EVs) emerged as a help for Indonesia as a pathway to address environmental challenges related to air pollution and greenhouse gas emissions from the transportation sector. Despite governmental efforts, including Presidential Regulation No. 55/2019, EV adoption rates in Indonesia remain low, [...] Read more.
Electric vehicles (EVs) emerged as a help for Indonesia as a pathway to address environmental challenges related to air pollution and greenhouse gas emissions from the transportation sector. Despite governmental efforts, including Presidential Regulation No. 55/2019, EV adoption rates in Indonesia remain low, although sales are increasing annually due to limited charging infrastructure, high upfront costs, and consumer perception. This study distinguishes itself from previous research by moving beyond a singular focus on policy, adoption factors, barriers, or economic opportunities. Instead, it integrates these dimensions into a cohesive analysis while placing particular emphasis on government policies. By adopting this multidimensional approach, the study presents a nuanced understanding of EV adoption in Indonesia, exploring not only the drivers, challenges, and economic potential but also the tangible benefits of EV manufacturing and usage for both producers and consumers within the current regulatory framework. It highlights the transformative impacts of EV adoption on key areas such as job creation, GDP expansion, and energy security, offering strategic insights for policymakers, industry leaders, and stakeholders. Future research could explore rural infrastructure development, local battery production impacts, and long-term economic implications of EV in Indonesia’s ecosystem. Full article
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<p>Global Passenger EV Sales by Market (Source: [<a href="#B56-energies-17-06408" class="html-bibr">56</a>]).</p>
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<p>Reasons for Consumers Considering EVs both Cars &amp; Motorcycles (Source: [<a href="#B1-energies-17-06408" class="html-bibr">1</a>], Processed by Author).</p>
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20 pages, 17223 KiB  
Article
Structural and Physicochemical Properties of Glycerol-Plasticized Edible Films Made from Pea Protein-Based Emulsions Containing Increasing Concentrations of Candelilla Wax or Oleic Acid
by Dariusz Kowalczyk, Waldemar Kazimierczak, Emil Zięba, Magdalena Lis and Monika Wawrzkiewicz
Molecules 2024, 29(24), 5998; https://doi.org/10.3390/molecules29245998 - 19 Dec 2024
Viewed by 283
Abstract
Hydrophobization could improve the moisture resistance of biopolymer-based materials, depending on the methods and materials used, providing benefits for packaging applications. The aim of this study was to compare the effect of increasing concentrations (0–2.0%) of candelilla wax (CW) and oleic acid (OA) [...] Read more.
Hydrophobization could improve the moisture resistance of biopolymer-based materials, depending on the methods and materials used, providing benefits for packaging applications. The aim of this study was to compare the effect of increasing concentrations (0–2.0%) of candelilla wax (CW) and oleic acid (OA) on the structural and physicochemical properties, including water affinity, of glycerol-plasticized pea protein isolate (PPI) films. OA acidified the film-forming solution and increased its viscosity more effectively than CW. At the highest concentration, OA prevented cohesive film formation, indicating a weakening of protein self-interaction. OA caused less yellowing, matting, and a smaller reduction in UV/VIS light transmittance compared to CW. Both lipids caused a slight reduction in the films’ water content. Phase separation (creaming) of CW enhanced surface hydrophobicity, resulting in a greater reduction in water vapor permeability than OA (~37–63% vs. 2–18%). The addition of lipids did not reduce film solubility or water absorption, and OA even increased these parameters. Increasing lipid content decreased the mechanical strength and stretchability of the films by 28–37% and 18–43%, respectively. The control film exhibited low heat-sealing strength (0.069 N/mm), which improved by 42% and 52% with the addition of CW and OA at optimal levels. Full article
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<p>pH (<b>A</b>) and viscosity (<b>B</b>) of pea protein isolate-based film-forming solutions containing increasing concentrations of candelilla wax (CW) and oleic acid (OA). Values with different superscript letters (a–f) are significantly different (<span class="html-italic">p</span> &lt; 0.05). The control refers to the lipid-free FFS.</p>
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<p>Effect of increasing concentrations of candelilla wax (CW) and oleic acid (OA) on the microtopography of pea protein isolate-based film-forming solutions (FFSs), visualized by differential interference contrast microscopy at 100× magnification. Red frames show 200× magnifications of FFSs obtained from lipids stained with Sudan Red III (<b>A</b>). Appearance of FFSs after storage at 25 °C (<b>B</b>). The control refers to the lipid-free FFS.</p>
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<p>Microtopography of the air side of glycerol-plasticized pea protein isolate-based films without (control) and with increasing additions of candelilla wax (CW) and oleic acid (OA), visualized by scanning electron microscopy (grayscale images) and differential interference contrast (DIC) microscopy (images in red frame) at magnifications of 1000× and 200×, respectively. Emulsion films for DIC microscopy were prepared using lipids stained with Sudan Red III.</p>
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<p>Cross-section of the glycerol-plasticized pea protein isolate-based films, without (control) and with additions of candelilla wax (CW) and oleic acid (OA), visualized by scanning electron microscopy at magnifications of (<b>A</b>) 1000× and (<b>B</b>) 5000×, as well as the films prepared with lipids stained with Sudan Red III, visualized by differential interference contrast (DIC) microscopy at a magnification of 200× (<b>C</b>).</p>
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<p>ATR/FT-IR spectra of the air side of glycerol-plasticized pea protein isolate-based films without (control) and with increasing additions of (<b>A</b>) candelilla wax (CW) and (<b>B</b>) oleic acid (OA).</p>
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<p>Effect of candelilla wax (CW) and oleic acid (OA) concentrations on the gloss (<b>A</b>), light transmittance (<b>B</b>), and opacity (<b>C</b>) of glycerol-plasticized pea protein isolate films. The control refers to the lipid-free film. Values with different superscript letters (a–f) are significantly different (<span class="html-italic">p</span> &lt; 0.05).</p>
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19 pages, 1141 KiB  
Article
Can Digital Activism Change Sustainable Supply Chain Practices in the Agricultural Bioeconomy? Evidence from #Buttergate
by Hamish van der Ven
Appl. Sci. 2024, 14(24), 11893; https://doi.org/10.3390/app142411893 - 19 Dec 2024
Viewed by 305
Abstract
Under what conditions will digital activism elicit a response from industry? What is the nature of that response and how does it impact sustainable supply chain practices? I develop three hypotheses in response to these questions by examining a recent case of digital [...] Read more.
Under what conditions will digital activism elicit a response from industry? What is the nature of that response and how does it impact sustainable supply chain practices? I develop three hypotheses in response to these questions by examining a recent case of digital activism targeted at the use of a controversial bioproduct in the Canadian dairy industry. Drawing on 14 key informant interviews as well as a novel Twitter dataset, I hypothesize that digital activism can elicit a response from industry when it originates with a small number of activists, provided that it also spreads to traditional media. I further hypothesize that industry’s response will be superficial and result in only token changes to sustainable supply chain practices due to the ephemerality and lack of cohesion inherent in some forms of digital activism. These hypotheses lay a foundation for broader cross-sectoral research on how industries respond to digital activism directed at their supply chains and add nuance to ongoing debates about the efficacy of digital activism as a means of changing industry practices. Full article
(This article belongs to the Special Issue Sustainability and Green Supply Chain Management in Industrial Fields)
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<p>Contributors to #buttergate by number of followers.</p>
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<p>Twitter activity and media coverage of #buttergate 12 February 2021–1 February 2022.</p>
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<p>Diversity of key terms mentioned in #buttergate.</p>
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