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16 pages, 1395 KiB  
Article
Effects of Rubber Plantation Restoration in National Parks on Plant Diversity and Soil Chemical Properties
by Chunyan Du, Donghai Li, Weifeng Wang, Xiaobo Yang, Zhixiang Wu, Chuan Yang, Yingying Zhang, Qingmao Fu and Dongling Qi
Diversity 2024, 16(11), 701; https://doi.org/10.3390/d16110701 - 18 Nov 2024
Viewed by 680
Abstract
Plantations left for natural succession play a significant role in Tropical Rainforest National Parks. Studying the succession and restoration of plantations is crucial for achieving a park’s authenticity and integrity, as well as for maximizing its ecological functions. However, the changes in vegetation [...] Read more.
Plantations left for natural succession play a significant role in Tropical Rainforest National Parks. Studying the succession and restoration of plantations is crucial for achieving a park’s authenticity and integrity, as well as for maximizing its ecological functions. However, the changes in vegetation and soil properties during the natural succession of these decommissioned plantations remain unclear. In this study, we examined rubber [(Hevea brasiliensis (Willd. Ex A. Juss.) Muell. Arg] plantations in the Yinggeling area of the National Park of Hainan Tropical Rainforest. We used community surveys, field sampling, and soil property analyses to investigate the species richness, diversity, and species composition of the aboveground plant communities during three succession periods of rubber plantations left for natural succession, including 0 years (ZY), 3 years (TY), and 7 years (SY). The soil pH, total organic carbon, total nitrogen, total phosphorus, available phosphorus, nitrate nitrogen, ammonium nitrogen, and total potassium contents in the three succession periods were analyzed. These results showed that there were 92 species of understory plants in the decommissioned rubber plantations, belonging to 72 genera in 39 families. The highest number of understory plant species was found in the plantations with 3 years of natural succession, totaling 66 species from 49 genera in 29 families. The number of families, genera, and species followed the pattern TY > SY > ZY. The Margalef richness index (F), Simpson index (D), and Shannon–Wiener index (H) of understory plants in the 0-year succession plantations were significantly lower than those in the 3-year and 7-year succession plantations. However, there was no significant difference in the Pielou (EH) index among the succession gradients. The soil pH, nitrate nitrogen (NO3--N), and available phosphorus (AP) in the 0-year succession plantations were significantly higher than those in the 3-year and 7-year succession plantations. There were no significant differences in soil total nitrogen (TN), total phosphorus (TP), total organic carbon (TOC), and ammonium nitrogen (NH4+-N) across the three succession gradients. The soil total potassium (TK) in the 3-year succession plantations was significantly higher than that in the 0-year and 7-year succession plantations. Soil available phosphorus and total phosphorus (TP) were positively correlated with the Margalef index, Simpson index, Shannon–Wiener index, and Pielou index. The recovery rate of understory vegetation in decommissioned rubber plantations was faster than that of the soil. This indicates that the construction of the National Park of Hainan Tropical Rainforest has significantly promoted the recovery of the number of plant species and plant species diversity that have been left from rubber plantation operations. These findings not only deepen our understanding of soil property changes during the vegetation succession of artificial forests, particularly rubber plantations, but they also hold significant implications for guiding tropical forest management and sustainable development. Full article
(This article belongs to the Special Issue Biodiversity Conservation Planning and Assessment)
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<p>Species diversity of understory plants in rubber plantations with different succession times. Note: “ZY” represents a rubber plantation with 0 years of natural succession; “TY” represents a rubber plantation with 3 years of natural succession; “SY” represents a rubber plantation with 7 years of natural succession. Different letters (a, b) indicated significant difference at 0.05 level.</p>
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<p>Analysis of soil chemical properties of rubber plantations at different successional times. Note: “ZY”, “TY”, and “SY are the variables, and soil properties as explanatory variables. “ZY” represents a rubber plantation with 0 years of natural succession; “TY” represents a rubber plantation with 3 years of natural succession; “SY” represents a rubber plantation with 7 years of natural succession. Different letters (a, b) indicated significant difference at 0.05 level.</p>
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<p>RDA ranking of plant diversity and soil physicochemical properties in rubber plantation understory at different succession times. Note: “Pielou”, “Shannon–Wiener”, “Simpson”, and “Marglef” are the variables, and soil properties as explanatory variables.</p>
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<p>Comparison of the recovery rate of understory plants and soil chemical properties of rubber plantation at different succession times. Note: “ZY” represents a rubber plantation with 0 years of natural succession; “TY” represents a rubber plantation with 3 years of natural succession; “SY” represents a rubber plantation with 7 years of natural succession.</p>
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17 pages, 9162 KiB  
Article
Estimating Cadmium Concentration in Agricultural Soils with ZY1-02D Hyperspectral Data: A Comparative Analysis of Spectral Transformations and Machine Learning Models
by Junwei Lv, Jing Geng, Xuanhong Xu, Yong Yu, Huajun Fang, Yifan Guo and Shulan Cheng
Agriculture 2024, 14(9), 1619; https://doi.org/10.3390/agriculture14091619 - 15 Sep 2024
Viewed by 985
Abstract
The accumulation of cadmium (Cd) in agricultural soils presents a significant threat to crop safety, emphasizing the critical necessity for effective monitoring and management of soil Cd levels. Despite technological advancements, accurately monitoring soil Cd concentrations using satellite hyperspectral technology remains challenging, particularly [...] Read more.
The accumulation of cadmium (Cd) in agricultural soils presents a significant threat to crop safety, emphasizing the critical necessity for effective monitoring and management of soil Cd levels. Despite technological advancements, accurately monitoring soil Cd concentrations using satellite hyperspectral technology remains challenging, particularly in efficiently extracting spectral information. In this study, a total of 304 soil samples were collected from agricultural soils surrounding a tungsten mine located in the Xiancha River basin, Jiangxi Province, Southern China. Leveraging hyperspectral data from the ZY1-02D satellite, this research developed a comprehensive framework that evaluates the predictive accuracy of nine spectral transformations across four modeling approaches to estimate soil Cd concentrations. The spectral transformation methods included four logarithmic and reciprocal transformations, two derivative transformations, and three baseline correction and normalization transformations. The four models utilized for predicting soil Cd were partial least squares regression (PLSR), support vector machine (SVM), bidirectional recurrent neural networks (BRNN), and random forest (RF). The results indicated that these spectral transformations markedly enhanced the absorption and reflection features of the spectral curves, accentuating key peaks and troughs. Compared to the original spectral curves, the correlation analysis between the transformed spectra and soil Cd content showed a notable improvement, particularly with derivative transformations. The combination of the first derivative (FD) transformation with the RF model yielded the highest accuracy (R2 = 0.61, RMSE = 0.37 mg/kg, MAE = 0.21 mg/kg). Furthermore, the RF model in multiple spectral transformations exhibited higher suitability for modeling soil Cd content compared to other models. Overall, this research highlights the substantial applicative potential of the ZY1-02D satellite hyperspectral data for detecting soil heavy metals and provides a framework that integrates optimal spectral transformations and modeling techniques to estimate soil Cd contents. Full article
(This article belongs to the Section Digital Agriculture)
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Graphical abstract

Graphical abstract
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<p>Distribution of soil sampling sites in the study area: (<b>a</b>) Jiangxi Province, China; (<b>b</b>) Geographic location of the study area; (<b>c</b>) Distribution of sampling points and elevation within the study area. The top-right image shows the coverage of the study area by the original ZY1-02D imagery.</p>
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<p>(<b>a</b>) Original spectral curves and (<b>b</b>) Savitzky–Golay (SG) smoothed spectral curves of soil samples from hyperspectral images. Note: Each color represents a sampling point.</p>
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<p>The correlation coefficients between soil Cd and original soil spectral data, and after Savitzky–Golay (SG) smoothed spectral data.</p>
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<p>Nine spectral transformation curves of soil samples from hyperspectral images. (<b>a</b>) logarithmic transformation (LT), (<b>b</b>) reciprocal transformation (RT), (<b>c</b>) first derivative (FD), (<b>d</b>) logarithm of reciprocal transformation (LR), (<b>e</b>) reciprocal of logarithmic transformation (RL), (<b>f</b>) reciprocal of logarithmic and first derivative (RLFD), (<b>g</b>) standard normal variate (SNV), (<b>h</b>) continuum removal (CR), and (<b>i</b>) multiplicative scatter correction (MSC). Note: Each color represents a sampling point.</p>
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<p>The correlation coefficient curves between the spectra derived from nine spectral transformation methods and the soil Cd content. (<b>a</b>) logarithmic transformation (LT), (<b>b</b>) reciprocal transformation (RT), (<b>c</b>) first derivative (FD), (<b>d</b>) logarithm of reciprocal transformation (LR), (<b>e</b>) reciprocal of logarithmic transformation (RL), (<b>f</b>) reciprocal of logarithmic and first derivative (RLFD), (<b>g</b>) standard normal variate (SNV), (<b>h</b>) continuum removal (CR), and (<b>i</b>) multiplicative scatter correction (MSC).</p>
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<p>Spatial distribution of soil Cd content in the study area driven by the RF model constructed with first derivative-transformed spectral data. Note that this Cd distribution map has been masked with a cropland layer derived from the GlobeLand30 dataset (<a href="http://www.globallandcover.com/" target="_blank">http://www.globallandcover.com/</a>, accessed on 20 December 2022).</p>
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<p>Relative proportional and spatial extents of three soil pollution categories based on soil Cd contents.</p>
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22 pages, 23123 KiB  
Article
Geological Study Based on Multispectral and Hyperspectral Remote Sensing: A Case Study of the Mahuaping Beryllium–Tungsten Deposit Area in Shangri-La
by Yunfei Hu, Zhifang Zhao, Xinle Zhang, Lunxin Feng, Yang Qin, Liu Ouyang and Ziqi Huang
Sustainability 2024, 16(15), 6387; https://doi.org/10.3390/su16156387 - 25 Jul 2024
Viewed by 1226
Abstract
This study applied Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) multispectral data and ZY1-02D hyperspectral data to map the structural distribution and hydrothermal alteration in the polymetallic ore district in southern Shangri-La City, Yunnan Province, China. The study area hosts several polymetallic [...] Read more.
This study applied Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) multispectral data and ZY1-02D hyperspectral data to map the structural distribution and hydrothermal alteration in the polymetallic ore district in southern Shangri-La City, Yunnan Province, China. The study area hosts several polymetallic deposits, including the Mahuaping tungsten–beryllium deposit, which has significant mineral exploration potential. The deposit type is mainly magmatic–hydrothermal, with average grades of 0.41% WO3 and 0.22% BeO, and substantial reserves, prominently controlled by faults. Based on this, this study employed ASTER data for the visual interpretation of structures through false-color composites combined with DEM data. Additionally, ASTER and ZY1-02D data were processed using the principal component analysis and spectral angle mapper methods to extract anomalies related to tungsten mineralization such as carbonate alteration, sericitization, chloritization, and hematization of the hydrothermal origin. The results indicated that the structural trends in the study area predominantly align in north–south and northeast directions, with alteration anomalies concentrated in the central and fold areas. Our analysis of typical deposits revealed their close association with north–south faults and east–west joints, as well as the enrichment level of alteration anomalies, identifying five high-potential target areas for mineral exploration. Further evaluation involved field validation through the spectral scanning of samples, field verification, and a comparison with known lithology. These assessments confirmed that the spectral curves matched those in the USGS database, the structural interpretations aligned with the field observations (84% accuracy from 25 sampling points, with 21 matching extracted alteration types), and the alteration results corresponded well with the lithological units, indicating high accuracy in alteration extraction. Finally, a comparative discussion highlighted that the results derived from ZY1-02D data were more applicable to the local area. The outcomes of this study can support subsequent mineral exploration efforts, enhancing the sustainability of important mineral resources. Full article
(This article belongs to the Special Issue Sustainability in Mineral Potential Mapping of Key Mineral Resources)
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<p>Regional geology and tectonics of the study area: (<b>a</b>) Shangri-La region tectonics [<a href="#B29-sustainability-16-06387" class="html-bibr">29</a>]. (<b>b</b>) Mahuaping region tectonics [<a href="#B30-sustainability-16-06387" class="html-bibr">30</a>].</p>
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<p>Geological sketch map of Mahuaping area. (<b>a</b>) Location of the northwestern part of Yunnan Province, China; (<b>b</b>) Location of the study area; (<b>c</b>) Geological sketch map of Mahuaping area.</p>
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<p>Technical roadmap.</p>
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<p>Preprocessed remote sensing images: (<b>a</b>) ASTER Image 321. (<b>b</b>) ZY1-02D Image 29-19-10.</p>
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<p>Structural interpretation map of linear and circular structures in the study area.</p>
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<p>Spectral curves: (<b>a</b>) measured spectral curve; (<b>b</b>) measured spectral curve resampled to ASTER; (<b>c</b>) measured spectral curve resampled to ZY1-02D; (<b>d</b>) resampled spectral curve from 500 nm to 900 nm; (<b>e</b>) resampled spectral curve from 2100 nm to 2400 nm.</p>
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<p>Extraction results of mineral alteration anomalies in Mahuaping mining area: (<b>a</b>) sericite alteration; (<b>b</b>) carbonate alteration; (<b>c</b>) chlorite alteration; (<b>d</b>) iron staining.</p>
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<p>Extraction of alteration anomalies using spectral angle method. (<b>a</b>) Sericite; (<b>b</b>) calcite; (<b>c</b>) chlorite; (<b>d</b>) limonite.</p>
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<p>Distribution map of prospective areas for mineralization prediction.</p>
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<p>(<b>a</b>) Measured spectral curves of alteration characteristic minerals; (<b>b</b>) USGS spectral curves of alteration characteristic minerals; (<b>c</b>) measured spectral curves in the 2100~2300 nm range; (<b>d</b>) USGS spectral curves in the 2100~2300 nm range; (<b>e</b>) measured spectral curves in the 2250~2450 nm range; (<b>f</b>) USGS spectral curves in the 2250~2450 nm range.</p>
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<p>Field survey route map.</p>
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<p>Field collection sample photos: (<b>a</b>) Sample 3—sericite feldspar schist; (<b>b</b>) Sample 6—carbonate-altered schist; (<b>c</b>) Sample 18—lazurite, scheelite; (<b>d</b>) scheelite fluorescence reaction; (<b>e</b>) Sample 27—marble; (<b>f</b>) Sample 37—sericite chlorite schist.</p>
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<p>Microscopic identification photos of field samples in the study area (<b>a</b>) Sample 16—Gn (galena) 2.5× (reflected light); (<b>b</b>) Sample 17—Hm (hematite), Py (pyrite) 2.5× (reflected light); (<b>c</b>) Sample 18—Wf (scheelite) 2.5× (reflected light); (<b>d</b>) Sample 21—Ber (beryl) 2.5× (single polarization); (<b>e</b>) Sample 28—Qtz (quartz) 2.5× (cross-polarized light); (<b>f</b>) Sample 28—Cal (calcite) 2.5× (single polarization); (<b>g</b>) Sample 33—Bit (biotite) 2.5× (single polarization); (<b>h</b>) Sample 38—Ser (sericite) 5× (cross-polarized light).</p>
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<p>Comparison of alteration results and stratigraphy.</p>
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22 pages, 8712 KiB  
Article
Deep Multi-Order Spatial–Spectral Residual Feature Extractor for Weak Information Mining in Remote Sensing Imagery
by Xizhen Zhang, Aiwu Zhang, Yuan Sun, Juan Wang, Haiyang Pang, Jinbang Peng, Yunsheng Chen, Jiaxin Zhang, Vincenzo Giannico, Tsegaye Gemechu Legesse, Changliang Shao and Xiaoping Xin
Remote Sens. 2024, 16(11), 1957; https://doi.org/10.3390/rs16111957 - 29 May 2024
Viewed by 769
Abstract
Remote sensing images (RSIs) are widely used in various fields due to their versatility, accuracy, and capacity for earth observation. Direct application of RSIs to harvest optimal results is generally difficult, especially for weak information features in the images. Thus, extracting the weak [...] Read more.
Remote sensing images (RSIs) are widely used in various fields due to their versatility, accuracy, and capacity for earth observation. Direct application of RSIs to harvest optimal results is generally difficult, especially for weak information features in the images. Thus, extracting the weak information in RSIs is reasonable to promote further applications. However, the current techniques for weak information extraction mainly focus on spectral features in hyperspectral images (HSIs), and a universal weak information extraction technology for RSI is lacking. Therefore, this study focused on mining the weak information from RSIs and proposed the deep multi-order spatial–spectral residual feature extractor (DMSRE). The DMSRE considers the global information and three-dimensional cube structures by combining low-rank representation, high-order residual quantization, and multi-granularity spectral segmentation theories. This extractor obtains spatial–spectral features from two derived sequences (deep spatial–spectral residual feature (DMSR) and deep spatial–spectral coding feature (DMSC)), and three RSI datasets (i.e., Chikusei, ZY1-02D, and Pasture datasets) were employed to validate the DMSRE method. Comparative results of the weak information extraction-based classifications (including DMSR and DMSC) and the raw image-based classifications showed the following: (i) the DMSRs can improve the classification accuracy of individual classes in fine classification applications (e.g., Asphalt class in the Chikusei dataset, from 89.12% to 95.99%); (ii) the DMSC improved the overall accuracy in rough classification applications (from 92.07% to 92.78%); and (iii) the DMSC improved the overall accuracy in RGB classification applications (from 63.25% to 63.6%), whereas DMSR improved the classification accuracy of individual classes on the RGB image (e.g., Plantain classes in the Pasture dataset, from 32.49% to 39.86%). This study demonstrates the practicality and capability of the DMSRE method to promote target recognition on RSIs and presents an alternative technique for weak information mining on RSIs, indicating the potential to extend weak information-based applications of RSIs. Full article
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<p>Flowchart of LRR for RSI.</p>
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<p>Color image sample of (<b>a</b>) CK dataset, (<b>b</b>) ZY dataset, (<b>c</b>) PT dataset; corresponding GT of (<b>d</b>) CK dataset, (<b>e</b>) ZY dataset, (<b>f</b>) PT dataset; and corresponding legend of (<b>g</b>) CK dataset, (<b>h</b>) ZY dataset, and (<b>i</b>) PT dataset.</p>
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<p>Color image sample of (<b>a</b>) CK dataset, (<b>b</b>) ZY dataset, (<b>c</b>) PT dataset; corresponding GT of (<b>d</b>) CK dataset, (<b>e</b>) ZY dataset, (<b>f</b>) PT dataset; and corresponding legend of (<b>g</b>) CK dataset, (<b>h</b>) ZY dataset, and (<b>i</b>) PT dataset.</p>
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<p>Flowchart of the proposed method. (DMSR: deep spatial–spectral residual feature; DMSC: deep spatial–spectral coding feature).</p>
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<p>Schematic of this study.</p>
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<p>SSIM (<b>a</b>) and MSA (<b>b</b>) values between the CK dataset and its DMSC.</p>
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<p>Color image of (<b>a</b>–<b>h</b>) first- to eighth-order DMSR of the CK dataset.</p>
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<p>Color images of (<b>a</b>–<b>h</b>) first- to eighth-order DMSC for the CK dataset.</p>
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<p>Image of (<b>a</b>) detailed image 1, (<b>b</b>–<b>i</b>) first-order to eighth-order of DMSC of detailed image 1, (<b>j</b>) detailed image 2, and (<b>k</b>–<b>r</b>) first-order to eighth-order DMSR of detailed image 2.</p>
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<p>Spectral (vegetation) features of (<b>a</b>–<b>h</b>) the spectral curves of the first-order to eighth-order DMSC and DMSR.</p>
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<p>Classification results of (<b>a</b>–<b>h</b>) first-order to eighth-order DMSR of the CK dataset.</p>
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<p>Classification results of (<b>a</b>–<b>h</b>) the first-order to eighth-order DMSC of the CK dataset.</p>
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<p>Classification results of (<b>a</b>–<b>h</b>) the first-order to eighth-order DMSC of the CK dataset.</p>
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<p>Classification results of (<b>a</b>–<b>h</b>) first-order to eighth-order DMSR of the ZY dataset.</p>
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<p>Classification results of (<b>a</b>–<b>h</b>) first-order to eighth-order DMSR of the ZY dataset.</p>
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<p>Classification results of (<b>a</b>–<b>h</b>) first-order to eighth-order DMSC of the ZY dataset.</p>
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<p>Color image of (<b>a</b>–<b>h</b>) first-order to eighth-order DMSR of the PT dataset.</p>
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<p>Color image of (<b>a</b>–<b>h</b>) first-order to eighth-order DMSC of the PT dataset.</p>
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<p>Color image of (<b>a</b>–<b>h</b>) first-order to eighth-order DMSC of the PT dataset.</p>
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22 pages, 6306 KiB  
Article
Validation of Red-Edge Vegetation Indices in Vegetation Classification in Tropical Monsoon Region—A Case Study in Wenchang, Hainan, China
by Miao Liu, Yulin Zhan, Juan Li, Yupeng Kang, Xiuling Sun, Xingfa Gu, Xiangqin Wei, Chunmei Wang, Lingling Li, Hailiang Gao and Jian Yang
Remote Sens. 2024, 16(11), 1865; https://doi.org/10.3390/rs16111865 - 23 May 2024
Viewed by 1113
Abstract
Vegetation classification has always been the focus of remote sensing applications, especially for tropical regions with fragmented terrain, cloudy and rainy climates, and dense vegetation. How to effectively classify vegetation in tropical regions by using multi-spectral remote sensing with high resolution and red-edge [...] Read more.
Vegetation classification has always been the focus of remote sensing applications, especially for tropical regions with fragmented terrain, cloudy and rainy climates, and dense vegetation. How to effectively classify vegetation in tropical regions by using multi-spectral remote sensing with high resolution and red-edge spectrum needs to be further verified. Based on the experiment in Wenchang, Hainan, China, which is located in the tropical monsoon region, and combined with the ZY-1 02D 2.5 m fused images in January, March, July, and August, this paper discusses whether NDVI and four red-edge vegetation indices (VIs), CIre, NDVIre, MCARI, and TCARI, can promote vegetation classification and reduce the saturation. The results show that the schemes with the highest classification accuracies in all phases are those in which the red-edge VIs are involved, which suggests that the red-edge VIs can effectively contribute to the classification of vegetation. The maximum accuracy of the single phase is 86%, and the combined accuracy of the four phases can be improved to 92%. It has also been found that CIre and NDVIre do not reach saturation as easily as NDVI and MCARI in July and August, and their ability to enhance the separability between different vegetation types is superior to that of TCARI. In general, red-edge VIs can effectively promote vegetation classification in tropical monsoon regions, and red-edge VIs, such as CIre and NDVIre, have an anti-saturation performance, which can slow down the confusion between different vegetation types due to saturation. Full article
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<p>Geographic location and sample distribution of the study area.</p>
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<p>Technical route of the study.</p>
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<p>J<sub>Bh</sub> distance for two spectral analysis schemes at 4-band and 5-band in different phases of remote sensing images. The <span class="html-italic">Y</span>-axis is the J<sub>bh</sub> distance value, indicating the separability of vegetation types. A total of 43,104 samples in 5 categories are used to calculate the J<sub>bh</sub> distance.</p>
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<p>Importance evaluation results of the spectra and VIs for each phase. The results of VIs are marked in orange and spectral results in blue. (<b>a</b>) January; (<b>b</b>) March; (<b>c</b>) July; (<b>d</b>) August.</p>
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<p>Local image segmentation results at different scales. The boundaries of the segmentation objects are marked with blue lines. (<b>a</b>) Segmentation scale: 25; (<b>b</b>) segmentation scale: 50; (<b>c</b>) segmentation scale: 100; and (<b>d</b>) the legend.</p>
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<p>Vegetation classification accuracies of different schemes in four phases. The classification schemes are shown in <a href="#remotesensing-16-01865-t004" class="html-table">Table 4</a> with A representing 4-band, AB representing 4-band + NDVI, AC representing 4-band + CIre, AD representing 4-band + NDVIre, AE representing 4-band + MCARI, AF representing 4-band + TCARI. (<b>a</b>) OA; (<b>b</b>) Kappa.</p>
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<p>The vegetation classification result map of multi-temporal Cire-assisted scheme.</p>
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<p>Variation curves of different VIs in January, March, July, and August. The types of dry land, woodland, garden, and paddy field are marked with different colors. (<b>a</b>) NDVI; (<b>b</b>) CIre; (<b>c</b>) NDVIre; (<b>d</b>) MCARI; (<b>e</b>) TCARI.</p>
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<p>Scatter plots of the relationship between normalized red-edge VIs and NDVI for different vegetation types in January, March, July, and August. Dry land, woodland, and garden are marked with blue, orange, and grey dots, respectively. (<b>a</b>) CIre (January); (<b>b</b>) CIre (March); (<b>c</b>) CIre (July); (<b>d</b>) CIre (August); (<b>e</b>) NDVIre (January); (<b>f</b>) NDVIre (March); (<b>g</b>) NDVIre (July); (<b>h</b>) NDVIre (August); (<b>i</b>) MCARI (January); (<b>j</b>) MCARI (March); (<b>k</b>) MCARI (July); (<b>l</b>) MCARI (August); (<b>m</b>) TCARI (January); (<b>n</b>) TCARI (March); (<b>o</b>) TCARI (July); and (<b>p</b>) TCARI (August).</p>
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12 pages, 3670 KiB  
Article
Breeding Soft Durum Wheat through Introgression of the T5AL·5VS Translocated Chromosome
by Wen Li, Yi Wei, Yinyu Jin, Heyu Chen, Lingna Kong, Xiaoxue Liu, Liping Xing, Aizhong Cao and Ruiqi Zhang
Agronomy 2024, 14(4), 848; https://doi.org/10.3390/agronomy14040848 - 18 Apr 2024
Cited by 1 | Viewed by 1194
Abstract
The limited culinary utilizations of durum wheat (Triticum turgidum ssp. durum) are partly related to its very hard kernel texture, which is due to the softness genes Puroindoline a (Pina) and Puroindoline b (Pinb) on the Hardness [...] Read more.
The limited culinary utilizations of durum wheat (Triticum turgidum ssp. durum) are partly related to its very hard kernel texture, which is due to the softness genes Puroindoline a (Pina) and Puroindoline b (Pinb) on the Hardness (Ha) locus eliminated during allopolyploid formation. A previous study has reported that the softness genes Dina/Dinb, homologous to Pina/Pinb, were located on the chromosome arm 5VS of wild species Dasypyrum villosum. In the present study, we describe the process of transferring the soft grain texture from D. villosum into durum wheat through homoeologous recombination to develop a Robertsonian translocation. A durum wheat–D. villosum T5AL·5V#5S translocation line, S1286, was developed and characterized by molecular cytogenetic analysis from BC4F2 progeny of durum cv. ZY1286/D. villosum 01I140. The translocation line S1286 exhibited a soft grain texture as evidenced by observation through an electron microscope and a Single Kernel Characterization System (SKCS) hardness value of 5.5. Additionally, a newly developed 5VS/5AS co-dominant InDel marker, LW5VS-1, facilitated the transfer of the T5AL·5V#5S translocated chromosome into diverse durum wheat backgrounds. Subsequently, the T5AL·5V#5S translocated chromosome was transferred into five high-yielding durum wheat backgrounds by backcrossing and traced using marker LW5VS-1. Compared with each recurrent parent, T5AL·5V#5S lines showed good viability, similar development, and no yield penalty. Meanwhile, a significant decrease in plant height of about 6.0% was observed when comparing T5AL·5V#5S translocation lines with their recurrent parents. Accordingly, our results provide an efficient strategy for developing soft kernel durum wheat through the combination of T5AL·5V#5S translocation and the co-dominant marker LW5VS-1, which will be crucial for meeting the future challenges of sustainable agriculture and food security. Full article
(This article belongs to the Section Crop Breeding and Genetics)
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<p>Flow chart for transferring soft grain texture from <span class="html-italic">D. villosum</span> into durum wheat.</p>
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<p>Identification of the durum wheat–<span class="html-italic">D. villosum</span> 5V#5S introgression lines through genomic in situ (GISH) and fluorescent in situ (FISH) hybridization. <span class="html-italic">D. villosum</span> genomic DNA labeled with fluorescein-12-dUTP (<span class="html-italic">green</span>) as probes was used for GISH. Probes for FISH were <span class="html-italic">Oligo-pSc119.2-1</span> and <span class="html-italic">Oligo-AFA-1,2</span>, labeled with TAM (<span class="html-italic">red</span>). Wheat chromosomes were counterstained with DAPI (<span class="html-italic">blue</span>). (<b>a</b>) GISH/FISH patterns of plant T20-3-26, containing a single TW·5V#5S translocation chromosome (arrow indicate). (<b>b</b>) GISH patterns of S1286 (2n = 28), containing a pair of TW·5V#5S translocated chromosomes. (<b>c</b>) GISH patterns of metaphase I in S1286 showing the translocated chromosome pair forming a ring bivalent. (<b>d</b>) GISH/FISH patterns of S1286, showing that the opposite arm of the 5V#5S translocated chromosome in S1286 was chromosome arm 5AL, which was a homozygous T5AL·5V#5S translocation line. Bars, 10 μm.</p>
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<p>PCR amplification patterns of 5VS-specific marker CINAU5V-237. The line S1286 has both 5VS- and 5BS-specific bands but lacks the bands of wheat 5AS and 5DS.</p>
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<p>Stereo-scanned electron microscopy of freeze-fractured grains of ZY1286 and S1286. The matrix protein adhered to the surfaces of the starch granules in ZY1286 (<b>a</b>,<b>b</b>) but separated in line S1286 (<b>c</b>,<b>d</b>). Magnification 1000× (<b>a</b>,<b>c</b>) and 2000× (<b>b</b>,<b>d</b>).</p>
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<p>PCR amplification patterns of 5VS/5AS co-dominant marker <span class="html-italic">LW5VS-1</span> in ZY1286/S1286 F<sub>2</sub> individuals.</p>
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<p>Plant and seed morphology of T5AL·5V#5S translocation line and the recurrent parents. (<b>a</b>) The plants of S1286 and ZY1286, showing similar developmental stages. (<b>b</b>) Comparison of seeds between ZY1286 and T5AL·5V#5S translocation line S1286. Scale bar = 0.5 cm. (<b>c</b>) The transverse sections of seeds of different T5AL·5V#5S translocation lines and their recurrent parents. Scale bar = 0.5 cm.</p>
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23 pages, 3279 KiB  
Review
DNA Vaccines: Their Formulations, Engineering and Delivery
by Michael Kozak and Jiafen Hu
Vaccines 2024, 12(1), 71; https://doi.org/10.3390/vaccines12010071 - 11 Jan 2024
Cited by 15 | Viewed by 5974
Abstract
The concept of DNA vaccination was introduced in the early 1990s. Since then, advancements in the augmentation of the immunogenicity of DNA vaccines have brought this technology to the market, especially in veterinary medicine, to prevent many diseases. Along with the successful COVID [...] Read more.
The concept of DNA vaccination was introduced in the early 1990s. Since then, advancements in the augmentation of the immunogenicity of DNA vaccines have brought this technology to the market, especially in veterinary medicine, to prevent many diseases. Along with the successful COVID mRNA vaccines, the first DNA vaccine for human use, the Indian ZyCovD vaccine against SARS-CoV-2, was approved in 2021. In the current review, we first give an overview of the DNA vaccine focusing on the science, including adjuvants and delivery methods. We then cover some of the emerging science in the field of DNA vaccines, notably efforts to optimize delivery systems, better engineer delivery apparatuses, identify optimal delivery sites, personalize cancer immunotherapy through DNA vaccination, enhance adjuvant science through gene adjuvants, enhance off-target and heritable immunity through epigenetic modification, and predict epitopes with bioinformatic approaches. We also discuss the major limitations of DNA vaccines and we aim to address many theoretical concerns. Full article
(This article belongs to the Special Issue Feature Papers of DNA and mRNA Vaccines)
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<p>Some of the components of DNA vaccine technology. Many factors including delivery route, vector design, adjuvant choice and promotor/gene design all play important roles in the outcome of DNA vaccinations. Combinations of these different components make the DNA vaccine one of the most versatile yet challenging vaccine formats. Created with BioRender.com.</p>
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<p>Conventional vaccine mechanism and DNA vaccine mechanism. Conventional vaccines (<b>on the left</b>) including peptide, subunit, live and attenuated viruses and toxins require endocytosis and intracellular processing of the pathogen. Because the pathogen is exogenous to the presenting cell, it is processed through the MHC II pathway, which preferentially engages CD4+ cells. DNA vaccine (<b>on the right</b>) can be endocytosed or can be engineered to passively cross the phospholipid membrane. The nucleic acid then locates to the nucleus and transcription and translation occur as if the DNA were native, which leads to presentation of the peptide through the MHC I pathway, preferentially activating CD8+ cells, additionally, the same peptide is exocytosed and then taken up by nearby cells, which then present the peptide via the MHC II pathway. Adapted from “COVID-19 DNA-Based Vaccine”, by BioRender.com (2023). Retrieved from <a href="https://app.biorender.com/biorender-templates" target="_blank">https://app.biorender.com/biorender-templates</a> accessed on 10 December 2023</p>
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<p>Neoantigen mechanism, a DNA vaccine immunotherapy target. Neopeptides occur when DNA mutation results in a novel transcriptional template leading to a novel polypeptide. Neoantigens occur when the neopeptide is presented on MHC, with the new portion of the polypeptide oriented for exposure to immune cells as a novel epitope. Adapted from “Neoantigen Presentation”, by BioRender.com (2023). Retrieved from <a href="https://app.biorender.com/biorender-templates" target="_blank">https://app.biorender.com/biorender-templates</a> accessed on 10 December 2023.</p>
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<p>DNA Vaccine transport across the plasma membrane. For DNA vaccines to have the intended effect, the DNA must be transported across the plasma membrane and the DNA must then enter the nucleus. Nuclear localization signals are often intrinsic to DNA viruses but can be engineered in to plasmids. Plasmid transport across the plasma membrane can be facilitated in many ways, some of which are represented here. Clockwise from viral capsid. Viral capsid (most often as viral vector) protects and facilitates delivery of nucleic acid cargo to cytosol of cells by harnessing viral properties for cellular engagement and cargo routing. Nanoparticles can be engineered to small sizes with lipophilicity and non-polarity to facilitate transportation of plasmid across the plasma membrane. Cationic conjugates can be attached to negatively charged nucleic acids of plasmids to facilitate transport across plasma membrane. Coated gold beads are used as carrier molecules similar to engineered nanoparticles and can easily cross the phospholipid membrane to reach the cytosol. Liposomal covering allows for passive diffusion across lipid bilayers including the nuclear envelope. Empty bacterial capsules contain intrinsic immunostimulatory properties and can prevent extracellular breakdown of naked nucleic acid. Created with BioRender.com.</p>
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<p>Common adjuvants and proposed mechanisms. (<b>A</b>) The CpG motifs stimulate TLRs, which activate signal transduction cascades, leading to nuclear upregulation of cytokines which stimulate immune cell response; most famously, the STING pathway. (<b>B</b>) Oil emulsions stimulate endoplasmic reticulum (ER) stress signaling pathway, which upregulates inflammatory cytokines, like interleukin-6 (IL-6), which activate and potentiate immune cells. (<b>C</b>) DNA stimulates signal transduction cascade, which upregulates transcription of inflammatory genes. (<b>D</b>) Aluminum causes inflammation and stimulates a release of ATP and DNA from injured cells, which activate DCs and macrophages. (<b>E</b>) Aluminum also stimulates inflammasomes. (<b>F</b>) Gene Adjuvants are immunostimulatory genes added to the plasmid for transcription within the cell (or can be delivered as separate plasmids alongside the vaccine), which are transcribed with the antigenic gene and work to potentiate immune cell response. Created with BioRender.com.</p>
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<p>Mechanism of vaccine delivery and intended site of vaccine delivery. All vaccines ultimately stimulate antigen presenting cells (APCs) which drain to lymph nodes to further activate the adaptive immune response. Epidermal, intradermal and intramuscular (IM) delivery routes rely on different, but related, populations of macrophages for adaptive immune system activation (<b>on the left</b>). Mucosal delivery is enhanced with specific M-cell stimulatory molecules (<b>on the right</b>). Created with BioRender.com.</p>
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12 pages, 2693 KiB  
Article
Lanthanide Contraction in LnF3 (Ln = Ce-Lu) and Its Chemical and Structural Consequences: Part 1: Location of YF3 in the LnF3 Series According to Its Chemical and Structural Characteristics
by Boris P. Sobolev and Elena A. Sulyanova
Int. J. Mol. Sci. 2023, 24(23), 17013; https://doi.org/10.3390/ijms242317013 - 30 Nov 2023
Cited by 2 | Viewed by 1049
Abstract
A lanthanide contraction(LC) of 14 lanthanides (Ln) from 58Ce to 71Lu consists of the interaction of Ln nucleus with 4f-electrons. Rare earth elements (REEs—R) include Sc, Y, La, and 14 Ln. They are located [...] Read more.
A lanthanide contraction(LC) of 14 lanthanides (Ln) from 58Ce to 71Lu consists of the interaction of Ln nucleus with 4f-electrons. Rare earth elements (REEs—R) include Sc, Y, La, and 14 Ln. They are located in 4–6th periods of the subgroup of group III. The electronic structure divides R into short (d- Sc, Y, La) and long (14 f-elements Ce-Lu) homologous series. The most important chemical consequence of LC is the creation of a new conglomerate of 16 RF3 by mixing fluorides of d- (Y, La) and f-elements. This determines the location of YF3 among LnF3. The location of YF3 depends on the structural (formula volumesVform) and thermochemical (temperatures and heats of phase transformations, phase diagrams) properties. The location of YF3 between HoF3 and ErF3 was determined by Vform at a standard pressure (Pst) and temperature (Tst). The location of YF3 according to heats of phase transformations ΔHfus and ΔHtrans is in a dimorphic structural subgroup (SSGr) D (Ln = Er-Lu), but without the exact “pseudo ZY”. According to the temperatures of phase transformations (Ttrans) in LnF3 (Ln = Dy-Lu), YF3 is located in the SSGr D between ErF3 and TmF3. The ErF3-YF3 and YF3-TmF3 phase diagrams show it to be between ErF3 and TmF3. The crystals of five β-LnF3 (Ln = Ho-Lu) and β-YF3 were obtained in identical conditions and their crystal structures were studied. Vform (at Pst and Tst) with “pseudoatomic number ZY = 67.42 was calculated from the unit cell parameters, which were defined with ±5 × 10−4 Å accuracy. It determines the location of YF3 between HoF3 and ErF3. Full article
(This article belongs to the Special Issue Recent Advances on Fluorine Chemistry)
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<p>The location of YF<sub>3</sub> in the <span class="html-italic">Ln</span>F<sub>3</sub> series based on the average <b><span class="html-italic">T</span></b><sub>fus</sub> (1), <b><span class="html-italic">T</span></b><sub>trans</sub> (2) of <span class="html-italic">Ln</span>F<sub>3</sub> with <span class="html-italic">Ln</span> = Dy-Lu and YF<sub>3</sub> (3, 4). Curve 1—<b><span class="html-italic">T</span></b><sub>fus</sub> of <span class="html-italic">Ln</span>F<sub>3</sub> with <span class="html-italic">Ln</span> = Dy-Lu (blue solid circles), curve 2—<b><span class="html-italic">T</span></b><sub>trans</sub> of <span class="html-italic">Ln</span>F<sub>3</sub> with <span class="html-italic">Ln</span> = Er-Lu (red open rectangles). The <b><span class="html-italic">T</span></b><sub>fus</sub> (3) and <b><span class="html-italic">T</span></b><sub>trans</sub> (4) of YF<sub>3</sub> are shown by green semi-open icons. Vertical I is the boundary between structural subgroups <b><span class="html-italic">C</span></b> (<span class="html-italic">Ln</span> = Tb-Ho) and <b><span class="html-italic">D</span></b> (<span class="html-italic">Ln</span> = Er-Lu). Vertical II separates <sub>39</sub>Y from the Z-scale for <span class="html-italic">Ln</span>.</p>
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<p>Δ<b><span class="html-italic">H</span></b><sub>fus</sub> and Δ<b><span class="html-italic">H</span></b><sub>trans</sub> for <span class="html-italic">Ln</span>F<sub>3</sub> (<span class="html-italic">Ln</span> = Tb-Yb) and YF<sub>3</sub>. Curve 1—Δ<b><span class="html-italic">H</span></b><sub>fus</sub> for <span class="html-italic">Ln</span>F<sub>3</sub> with <span class="html-italic">Ln</span>=Tb-Ho (grey semi-open rectangles), curve 2—Δ<b><span class="html-italic">H</span></b><sub>fus</sub> for <span class="html-italic">Ln</span>F<sub>3</sub> with <span class="html-italic">Ln</span> = Er-Yb (blue solid circles), curve 3—Δ<b><span class="html-italic">H</span></b><sub>trans</sub> for <span class="html-italic">Ln</span>F<sub>3</sub> with <span class="html-italic">Ln</span> = Er-Yb (red semi-open rhombs). Δ<b><span class="html-italic">H</span></b><sub>fus</sub> and Δ<b><span class="html-italic">H</span></b><sub>trans</sub> of YF<sub>3</sub> are shown by green icons. Vertical I is the boundary between structural subgroups <b><span class="html-italic">C</span></b> (<span class="html-italic">Ln</span> = Tb-Ho) and <b><span class="html-italic">D</span></b> (<span class="html-italic">Ln</span> = Er-Lu). Vertical II separates <sub>39</sub>Y from the Z-scale for <span class="html-italic">Ln</span>.</p>
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<p>The phase diagram of the short composite “HoF<sub>3</sub>-YF<sub>3</sub>-ErF<sub>3</sub>” QS (<b><span class="html-italic">P</span></b> = <b><span class="html-italic">P</span></b><sub>st</sub>; <b><span class="html-italic">T</span></b> &gt; <b><span class="html-italic">T</span></b><sub>st</sub>). Black solid circles correspond to experimental data.</p>
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<p>The phase diagram of the short composite “ErF<sub>3</sub>-YF<sub>3</sub>-TmF<sub>3</sub>” QS (<b><span class="html-italic">P</span></b> = <b><span class="html-italic">P</span></b><sub>st</sub>, <b><span class="html-italic">T</span></b> &gt; <b><span class="html-italic">T</span></b><sub>st</sub>). Black solid circles correspond to experimental data.</p>
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<p>The location of YF<sub>3</sub> in the <span class="html-italic">Ln</span>F<sub>3</sub> (<span class="html-italic">Ln</span> = Ho-Lu) series based on V<sub>form</sub>. Open blue rectangles—V<sub>form</sub>s of <b><span class="html-italic">β</span></b>-<span class="html-italic">Ln</span>F<sub>3</sub> (<span class="html-italic">Ln</span> = Ho-Lu), the solid blue rectangles correspond to V<sub>form</sub> of <b><span class="html-italic">β</span></b>-YF<sub>3</sub>.</p>
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14 pages, 3569 KiB  
Article
An Enhanced Atmospheric Pre-Corrected Differential Absorption (APDA) Algorithm by Extending LUTs Applied to Analyze ZY1-02D Hyperspectral Images
by Hongwei Zhang, Hao Zhang, Xiaobo Zhu, Shuning Zhang, Zhonghui Ma and Xuetao Hao
Atmosphere 2023, 14(10), 1560; https://doi.org/10.3390/atmos14101560 - 13 Oct 2023
Viewed by 1220
Abstract
Water vapor is a crucial component of the atmosphere. Its absorption significantly influences remote sensing by impacting radiation signals transmitted through the atmosphere. Determining columnar water vapor (CWV) from hyperspectral remote sensing data is essential during the imagery atmospheric correction process. Over the [...] Read more.
Water vapor is a crucial component of the atmosphere. Its absorption significantly influences remote sensing by impacting radiation signals transmitted through the atmosphere. Determining columnar water vapor (CWV) from hyperspectral remote sensing data is essential during the imagery atmospheric correction process. Over the past 40 years, numerous CWV inversion algorithms have been developed, with refinements to enhance retrieval accuracy and reliability. In this study, we proposed an enhanced atmospheric pre-corrected differential absorption (APDA) algorithm. This enhancement was achieved by thoroughly analyzing water vapor absorption in relation to elevation and aerosol optical depth and extending look up tables (LUTs). The enhanced method utilizes a pre-built MODTRAN lookup table and is applied to ZY1-02D hyperspectral data from a satellite launched in 2020. We compared the inversion results of 10 ZY1-02D scenes obtained using the improved method with AERONET measurements and inversion results from commonly used atmospheric correction software, namely, FLAASH and ATCOR. The updated algorithm demonstrated a lower average error (0.0568 g·cm−2) and relative average error (10.49%) compared to the ATCOR software (0.17 g·cm−2 and 40.78%, respectively) and the FLAASH module (0.13 g·cm−2 and 30.82%, respectively). Consequently, the enhanced method outperforms traditional CWV inversion algorithms, especially at high altitudes. Full article
(This article belongs to the Special Issue New Insights in Atmospheric Water Vapor Retrieval)
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<p>Influence of different absorption bands on water vapor transmittance at (<b>a</b>) 940 nm and (<b>b</b>) 1130 nm. CWV, columnar water vapor.</p>
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<p>Influence of different absorption bands on water vapor transmittance at (<b>a</b>) 940 nm and (<b>b</b>) 1130 nm. CWV, columnar water vapor.</p>
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<p>Comparison of the sensitivities of different absorption regions.</p>
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<p>Transmittance simulated at different AODs at 550 nm.</p>
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<p>Influence of different ground elevation on transmittance.</p>
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<p>Flow chart of water vapor inversion.</p>
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<p>Relative and absolute errors of APDA, APDA-enhanced, and FLAASH.</p>
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<p>Statistic of inversion results.</p>
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<p>Absolute error distribution diagram under different conditions. (<b>a</b>) Absolute error as a function of ground elevation. (<b>b</b>) Absolute error as a function of AOD.</p>
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<p>Comparison of inversion results of water vapor at high altitude stations: (<b>a</b>) NAM_CO-true color image; (<b>b</b>) NAM_CO-FLAASH; (<b>c</b>) NAM_CO-APDA; (<b>d</b>) NAM_CO-enhanced APDA; (<b>e</b>) QOMS_CAS-true color image; (<b>f</b>) QOMS_CAS-FLAASH; (<b>g</b>) QOMS_CAS-APDA; and (<b>h</b>) QOMS_CAS-enhanced APDA.</p>
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22 pages, 14476 KiB  
Article
Estimation and Mapping of Soil Organic Matter Content Using a Stacking Ensemble Learning Model Based on Hyperspectral Images
by Menghong Wu, Sen Dou, Nan Lin, Ranzhe Jiang and Bingxue Zhu
Remote Sens. 2023, 15(19), 4713; https://doi.org/10.3390/rs15194713 - 26 Sep 2023
Cited by 9 | Viewed by 2488
Abstract
Fast and accurate SOM estimation and spatial mapping are significant for cultivated land planning and management, crop growth monitoring, and soil carbon pool estimation. It is a key problem to construct a fast and efficient estimation model based on hyperspectral remote sensing image [...] Read more.
Fast and accurate SOM estimation and spatial mapping are significant for cultivated land planning and management, crop growth monitoring, and soil carbon pool estimation. It is a key problem to construct a fast and efficient estimation model based on hyperspectral remote sensing image data to realize the inversion mapping of SOM in large areas. In order to solve the problem that the estimation accuracy is not high due to the influence of hyperspectral image quality and soil sample quantity during the estimation model construction, this study explored a method for constructing an estimation model of SOM contents based on a new stacking ensemble learning algorithm and hyperspectral images. Surface soil samples in Huangzhong County of Qinghai Province were collected, and their ZY1-02D hyperspectral remote sensing images were investigated. As input data, a feature band dataset was constructed using the Pearson correlation coefficient and successive projections algorithm. Based on the dataset, a new SOM estimation model under the stacking ensemble learning framework combined with heterogeneous models was developed by optimizing the combination of base and meta-learners. Finally, the spatial distribution map of SOM was plotted based on the result of the model over the study area. The result suggested that the input data quality of the estimation model is improved by constructing a feature band dataset. The multi-class ensemble learning estimation model with the combination strategy of the base and meta-learners has better predictive effects and stability than the single-algorithm and single-level ensemble models with homogeneous learners. The coefficient of determination is 0.829, the residual prediction deviation is 2.85, and the predictive set root mean square error is 1.953. The results can provide new ideas for estimating SOM content using hyperspectral images and ensemble learning algorithms, and serve as a reference for mapping large-scale SOM spatial distribution using space-borne hyperspectral images. Full article
(This article belongs to the Special Issue Application of Hyperspectral Imagery in Precision Agriculture)
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<p>Flowchart of this study.</p>
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<p>(<b>left</b>) Location of the study area and (<b>right</b>) the spatial distribution of soil samples.</p>
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<p>Image spectrum, measured spectrum, and correlation coefficients.</p>
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<p>Original and transformation spectral reflectance curves : (<b>a</b>) original spectral curves (R); (<b>b</b>) spectral first-order differential transformation curves (FD-R); (<b>c</b>) spectral second-order differential transformation curves (SD−R); (<b>d</b>) spectral Savitzky-Golay filter transformation curves (SG); (<b>e</b>) spectral continuum removal first-order differential transformation curves (FD-SG); (<b>f</b>) spectral continuum removal second-order differential transformation curves (SD-SG); (<b>g</b>) spectral continuum removal transformation curves (CR); (<b>h</b>) spectral fractional-order transformation curves (FOD).</p>
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<p>(<b>a</b>) The threshold value for extracting bare soil pixel; (<b>b</b>) bare soil pixel extraction results. The yellow part is bare soil and the rest is non-bare soil.</p>
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<p>Flowchart of the stacking ensemble learning model.</p>
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<p>Sensitive band distribution after different spectral pre-processing methods.</p>
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<p>Feature band distribution based on SPA selection result: (<b>a</b>) the calculation results of <span class="html-italic">RMSE</span> with the different variables; (<b>b</b>) feature band distribution map.</p>
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<p>The correlation between the prediction results of each individual model.</p>
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<p>Scatter plots of the estimated values against the measured values of different inversion models (RF, GBDT, SVM, ELM, RR, GPR, and stacking).</p>
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<p>Spatial distribution results of SOM based on the stacking model.</p>
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15 pages, 7945 KiB  
Article
The Development and Application of Two-Color Pressure-Sensitive Paint in Jet Impingement Experiments
by Wei-Chieh Chen, Chih-Yung Huang, Kui-Thong Tan and Hirotaka Sakaue
Aerospace 2023, 10(9), 805; https://doi.org/10.3390/aerospace10090805 - 15 Sep 2023
Cited by 1 | Viewed by 1306
Abstract
This study aimed to develop a two-color pressure-sensitive paint (PSP) that has both high pressure sensitivity and high temperature sensitivity. Different nitrobenzoxadiazole (NBD) derivatives were used as the temperature probe. Among them, NBD-ZY37 demonstrated favorable stability against photodegradation, and its temperature sensitivity in [...] Read more.
This study aimed to develop a two-color pressure-sensitive paint (PSP) that has both high pressure sensitivity and high temperature sensitivity. Different nitrobenzoxadiazole (NBD) derivatives were used as the temperature probe. Among them, NBD-ZY37 demonstrated favorable stability against photodegradation, and its temperature sensitivity in an RTV118-based two-color PSP was −1.4%/°C. Moreover, temperature sensitivity was independent of pressure in the tested temperature range. PtTFPP was used, and its pressure sensitivity was measured to be 0.5% per kPa. The two-color PSP paint underwent further examination in jet impingement experiments. The experimental results indicated that the pressure fluctuation introduced by the shock waves occurred earlier at higher impingement angles. Specifically, when the pressure ratio was 2.38, increasing the impinging angle from 15° to 30° caused the location of the pressure wave to move from s/D at 0.8 to the exit of the nozzle. Simultaneously, the shape of the maximum pressure zone changed from a fan shape to a round shape. Additionally, the jet region expanded when the pressure ratio was increased. Full article
(This article belongs to the Section Aeronautics)
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<p>Pressure calibration setup.</p>
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<p>Temperature calibration setup.</p>
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<p>Jet impingement setup.</p>
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<p>Geometry of the impinging jet.</p>
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<p>Pressure calibration in the spectrum.</p>
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<p>Emission spectra of two-color PSP at different temperatures.</p>
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<p>Calibration results from the spectrometer calibration system. (<b>a</b>) Pressure calibration and (<b>b</b>) temperature calibration.</p>
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<p>(<b>a</b>) Pressure calibration of a single luminophore PSP and (<b>b</b>) temperature calibration of a single luminophore PSP from monochrome and color CCD camera for comparison.</p>
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<p>(<b>a</b>) Pressure calibration of a single luminophore TSP and (<b>b</b>) temperature calibration of a single luminophore TSP from monochrome and color CCD camera for comparison.</p>
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<p>Description of pressure distribution on the surface and pressure along the centerline at α = 20° and Φ = 3.40.</p>
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<p>Temperature distribution on the surface and temperature along the centerline at α = 20° and Φ = 3.40.</p>
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<p>Calibration curves of two-color PSP from color CCD camera. (<b>a</b>) Pressure calibration and (<b>b</b>) temperature calibration.</p>
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<p>Pressures along the jet centerline corrected and not corrected at α = 20° and Φ = 3.40.</p>
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<p>Pressure distribution on the surface at α = 15°.</p>
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<p>Pressure distribution on the surface at α = 20°.</p>
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<p>Pressure distribution on the surface at α = 30°.</p>
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<p>Pressure distribution along the centerline at α = 15°.</p>
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<p>Pressure distribution along the centerline at α = 20°.</p>
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<p>Pressure distribution along the centerline at α = 30°.</p>
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20 pages, 80951 KiB  
Article
Lithium-Rich Pegmatite Detection Integrating High-Resolution and Hyperspectral Satellite Data in Zhawulong Area, Western Sichuan, China
by Wenqing Ding, Lin Ding, Qingting Li, Jinxiang Li and Liyun Zhang
Remote Sens. 2023, 15(16), 3969; https://doi.org/10.3390/rs15163969 - 10 Aug 2023
Cited by 6 | Viewed by 4917
Abstract
Lithium (Li) has grown to be a strategic key metal due to the enormous demand for the development of new energy industries over the world. As one of the most significant sources of Li resources, pegmatite-type Li deposits hold a large share of [...] Read more.
Lithium (Li) has grown to be a strategic key metal due to the enormous demand for the development of new energy industries over the world. As one of the most significant sources of Li resources, pegmatite-type Li deposits hold a large share of the mining market. In recent years, several large and super-large spodumene (Spd)-rich pegmatite deposits have been discovered successively in the Hoh-Xil–Songpan-Garzê (HXSG) orogenic belt of the northern Tibetan Plateau, indicative of the great Li prospecting potential of this belt. Hyperspectral remote sensing (HRS), as a rapidly developing exploration technology, is especially sensitive to the identification of alteration minerals, and has made important breakthroughs in porphyry copper deposit exploration. However, due to the small width of the pegmatite dykes and the lack of typical alteration zones, the ability of HRS in the exploration of Li-rich pegmatite deposits remains to be explored. In this study, Li-rich pegmatite anomalies were directly extracted from ZY1-02D hyperspectral imagery in the Zhawulong (ZWL) area of western Sichuan, China, using target detection techniques including Adaptive Cosine Estimator (ACE), Constrained Energy Minimization (CEM), Spectral Angle Mapper (SAM), and SAM with BandMax (SAMBM). Further, the Li-rich anomalies were superimposed with the distribution of pegmatite dykes delineated based on GF-2 high-resolution imagery. Our final results accurately identified the known range of Spd pegmatite dykes and further predicted two new exploration target areas. The approaches used in this study could be easily extended to other potential mineralization areas to discover new rare metal pegmatite deposits on the Tibetan Plateau. Full article
(This article belongs to the Special Issue New Trends on Remote Sensing Applications to Mineral Deposits-II)
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Graphical abstract

Graphical abstract
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<p>(<b>a</b>) Simplified tectonic map of the major pegmatite rare metal deposits in the Hoh-Xil-Songpan-Garzê-West Kunlun orogenic belt, modified after [<a href="#B48-remotesensing-15-03969" class="html-bibr">48</a>,<a href="#B57-remotesensing-15-03969" class="html-bibr">57</a>]. AKMS: Ayimaqin-Kunlun-Matztagh Suture, JS: Jinshajiang Suture, BNS: Bangong-Nujiang Suture, GLS: Garzê-Litang Suture, CL: Caolong, ZWL: Zhawulong, JJK: Jiajika, KEY: Ke’eryin, XBD: Xuebaoding, CKBS: Chakabeishan, XFL: Xuefengling, BLS: Bailongshan, DHLT: Dahongliutan, HSTS: Huoshitashi, and XEBL: Xiaoerbulong. (<b>b</b>) Simplified geological map of the ZWL ore field after [<a href="#B49-remotesensing-15-03969" class="html-bibr">49</a>].</p>
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<p>(<b>a</b>) Field outcrop of spodumene pegmatite in the Zhawulong deposit; (<b>b</b>,<b>c</b>) field pictures of spodumene (Spd) crystals.</p>
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<p>Schematic diagram of overall workflow.</p>
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<p>Comparison of image spatial features before (<b>left</b>) and after (<b>right</b>) panchromatic fusion.</p>
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<p>Distribution of pegmatite dykes delineated based on GF-2 imagery.</p>
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<p>(<b>a</b>) True-color composite image (B29-19-10) and (<b>b</b>) MNF-transformed image (MNF3-2-1) of ZY1-02D of the study area. The purple ellipse denotes the known Li deposit area. Mg: muscovite granite, Ms: metasediment, Lp: Li-rich pegmatite, and Qs: Quaternary sediment.</p>
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<p>(<b>a</b>) The average reflectance spectra and (<b>b</b>) MNF-transformed component curves for the endmembers extracted on the ZY1-02D imagery.</p>
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<p>Li-rich pegmatite anomaly detection results of the (<b>a</b>) ACE, (<b>b</b>) CEM, (<b>c</b>) SAM, and (<b>d</b>) SAMBM algorithms applied on MNF-transformed ZY1-02D imagery. The purple ellipse denotes the known Li ore field. Brighter levels of pixels indicate higher abundances of targets.</p>
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<p>Density slice results of (<b>a</b>) ACE, (<b>b</b>) CEM, (<b>c</b>) SAM, and (<b>d</b>) SAMBM superimposed with the distribution of pegmatite dykes, draped over B29 greyscale image of ZY1-02D.</p>
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<p>Prediction results of Li exploration target area integrating high-resolution (GF-2) and hyperspectral (ZY1-02D) imagery detected information. Area A denotes the known Zhawulong Li ore body [<a href="#B49-remotesensing-15-03969" class="html-bibr">49</a>,<a href="#B52-remotesensing-15-03969" class="html-bibr">52</a>], while B and C are newly discovered prospecting target areas.</p>
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<p>Comparison of detailed spectral anomalies and spatial features between (<b>a</b>,<b>a′</b>) the known Li-rich pegmatite [<a href="#B49-remotesensing-15-03969" class="html-bibr">49</a>,<a href="#B52-remotesensing-15-03969" class="html-bibr">52</a>] and (<b>b</b>,<b>b′</b>,<b>c</b>,<b>c′</b>) the newly predicted targets.</p>
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25 pages, 21973 KiB  
Article
Lithological Classification by Hyperspectral Images Based on a Two-Layer XGBoost Model, Combined with a Greedy Algorithm
by Nan Lin, Jiawei Fu, Ranzhe Jiang, Genjun Li and Qian Yang
Remote Sens. 2023, 15(15), 3764; https://doi.org/10.3390/rs15153764 - 28 Jul 2023
Cited by 16 | Viewed by 2216
Abstract
Lithology classification is important in mineral resource exploration, engineering geological exploration, and disaster monitoring. Traditional laboratory methods for the qualitative analysis of rocks are limited by sampling conditions and analytical techniques, resulting in high costs, low efficiency, and the inability to quickly obtain [...] Read more.
Lithology classification is important in mineral resource exploration, engineering geological exploration, and disaster monitoring. Traditional laboratory methods for the qualitative analysis of rocks are limited by sampling conditions and analytical techniques, resulting in high costs, low efficiency, and the inability to quickly obtain large-scale geological information. Hyperspectral remote sensing technology can classify and identify lithology using the spectral characteristics of rock, and is characterized by fast detection, large coverage area, and environmental friendliness, which provide the application potential for lithological mapping at a large regional scale. In this study, ZY1-02D hyperspectral images were used as data sources to construct a new two-layer extreme gradient boosting (XGBoost) lithology classification model based on the XGBoost decision tree and an improved greedy search algorithm. A total of 153 spectral bands of the preprocessed hyperspectral images were input into the first layer of the XGBoost model. Based on the tree traversal structural characteristics of the leaf nodes in the XGBoost model, three built-in XGBoost importance indexes were split and combined. The improved greedy search algorithm was used to extract the spectral band variables, which were imported into the second layer of the XGBoost model, and the bat algorithm was used to optimize the modeling parameters of XGBoost. The extraction model of rock classification information was constructed, and the classification map of regional surface rock types was drawn. Field verification was performed for the two-layer XGBoost rock classification model, and its accuracy and reliability were evaluated based on four indexes, namely, accuracy, precision, recall, and F1 score. The results showed that the two-layer XGBoost model had a good lithological classification effect, robustness, and adaptability to small sample datasets. Compared with the traditional machine learning model, the two-layer XGBoost model shows superior performance. The accuracy, precision, recall, and F1 score of the verification set were 0.8343, 0.8406, 0.8350, and 0.8157, respectively. The variable extraction ability of the constructed two-layer XGBoost model was significantly improved. Compared with traditional feature selection methods, the GREED-GFC method, when applied to the two-layer XGBoost model, contributes to more stable rock classification performance and higher lithology prediction accuracy, and the smallest number of extracted features. The lithological distribution information identified by the model was in good agreement with the lithology information verified in the field. Full article
(This article belongs to the Special Issue The Use of Hyperspectral Remote Sensing Data in Mineral Exploration)
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<p>(<b>a</b>) a map of Northwest China; (<b>b</b>) Qinghai Province, China; (<b>c</b>) Geological map of cold lake area in Qinghai Province.</p>
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<p>Flowchart of lithology classification method based on hyperspectral image.</p>
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<p>Hyperspectral image scene (R: 705.19 nm, G: 507.69 nm, B: 447.09 nm) of Qinghai Cold Lake in October 2021.</p>
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<p>Image spectrum, measured spectrum, and correlation coefficients of monzonitic granite (<b>a</b>) and marble (<b>b</b>).</p>
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<p>Greedy optimal substructure.</p>
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<p>Flowchart of the GREED-GFC method.</p>
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<p>Statistical diagram of spectral angle threshold of lithologic samples. (<b>a</b>) the optimum threshold of spectral Angle is determined by the partition cosine value; (<b>b</b>) the optimal threshold is used to determine the number of samples</p>
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<p>Feature extraction process before and after the XGBoost improvement. (<b>a</b>) FS method feature selection process; (<b>b</b>) AG method feature selection process; (<b>c</b>) AC method feature selection process; (<b>d</b>) GREED-GFC method feature selection process.</p>
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<p>Bat algorithm optimization process.</p>
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<p>Evaluation results of four optimal methods. (<b>a</b>) the training set evaluates the results; (<b>b</b>) the test set evaluates the results.</p>
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<p>Spatial distribution of lithologic information extracted by two-layer XGBoost model. (<b>a</b>) comparative analysis area one; (<b>b</b>) comparative analysis area two; (<b>c</b>) comparative analysis area three.</p>
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<p>Distribution of field verification points (<b>a</b>) and field investigation (<b>b</b>).</p>
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<p>Accuracy, precision, recall and F1 score (weighted average) of the two-layer XGBoost algorithm for the training set and test set (<b>a</b>) accuracy; (<b>b</b>) precision; (<b>c</b>) recall; (<b>d</b>) F1 score.</p>
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<p>Average accuracy of prediction of four feature selection methods.</p>
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19 pages, 4728 KiB  
Article
Mapping Alteration Minerals Using ZY-1 02D Hyperspectral Remote Sensing Data in Coalbed Methane Enrichment Areas
by Li Chen, Xinxin Sui, Rongyuan Liu, Hong Chen, Yu Li, Xian Zhang and Haomin Chen
Remote Sens. 2023, 15(14), 3590; https://doi.org/10.3390/rs15143590 - 18 Jul 2023
Cited by 7 | Viewed by 1983
Abstract
As a clean energy resource, coalbed methane (CBM) is an important industry in China’s dual-carbon strategic planning. Despite the immense potential of CBM resources in China, the current exploration level remains low due to outdated survey technology, impeding large-scale exploration and development. This [...] Read more.
As a clean energy resource, coalbed methane (CBM) is an important industry in China’s dual-carbon strategic planning. Despite the immense potential of CBM resources in China, the current exploration level remains low due to outdated survey technology, impeding large-scale exploration and development. This study investigates the application of hyperspectral data in CBM enrichment areas, specifically focusing on the extraction of alteration minerals in the Hudi coal mine area of the Qinshui Basin using ZY-1 02D and Hyperion hyperspectral data. The hyperspectral alteration mineral identification methods are summarized and analyzed. A method that combines spectral feature matching and diagnostic characteristic parameters is proposed for mineral extraction based on the spectral characteristics of different minerals. The extraction results are verified through field samples using X-ray diffraction analysis. Results show that (1) both ZY-1 02D and Hyperion hyperspectral data yield favorable extraction results for clay and carbonate minerals; (2) the overall accuracy of clay and carbonate minerals extraction is higher using ZY-1 02D data compared with Hyperion data, with accuracies of 81.67% and 79.03%, respectively; (3) the proposed method effectively extracts alteration minerals in CBM enrichment areas using hyperspectral data, thereby providing valuable technical support for the application of hyperspectral data. Full article
(This article belongs to the Special Issue Remote Sensing for Geology and Mapping)
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<p>Location of the study area.</p>
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<p>Field spectra curves of rock and soil.</p>
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<p>Technical flowchart of the methodology in this research.</p>
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<p>Spectral characteristics of typical clay and carbonate minerals in the USGS_MIN spectral library. (<b>a</b>) Clay minerals; (<b>b</b>) Carbonate minerals.</p>
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<p>Preprocessed results. (<b>a</b>) Results of ZY-1 02D AHSI data, with a B29 (R), B19 (G), B10 (B) true color composite image. The red points represent field samples, and the green point indicates the position of the vegetation spectrum. (<b>b</b>) Results of Hyperion data, with a B29 (R), B20 (G), B12 (B) true color composite image. The green point indicates the position of the vegetation spectrum. (<b>c</b>) Vegetation spectrum of ZY-1 02D image at the green point. (<b>d</b>) Vegetation spectrum of Hyperion image at the green point.</p>
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<p>Local absorption feature. S1 and S2 are two reflection points and M is an absorption valley point. <span class="html-italic">λ</span><sub>S1</sub>, <span class="html-italic">R</span><sub>S1</sub>, <span class="html-italic">λ</span><sub>S2</sub>, <span class="html-italic">R</span><sub>S2</sub>, <span class="html-italic">λ</span><sub>M</sub>, and <span class="html-italic">R</span><sub>M</sub> are the wavelength and reflectivity of the points (S1, S2, and M), respectively. <span class="html-italic">W</span> is absorption width and <span class="html-italic">H</span> is absorption depth.</p>
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<p>Technical flowchart of integrated method in this research.</p>
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<p>Comparison of the endmember spectra of clay minerals extracted from the hyperspectral imagery and the standard spectra in USGS_MIN spectral library. (<b>a</b>) Endmember 1 and kaolinite; (<b>b</b>) Endmember 2 and montmorillonite.</p>
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<p>Comparison of the endmember spectra of carbonate minerals extracted from the hyperspectral imagery and the standard spectra in USGS_MIN spectral library. (<b>a</b>) Endmember 3 and siderite; (<b>b</b>) Endmember 4 and calcite.</p>
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<p>Comparison of the extraction results of clay minerals extracted from ZY-1 02D data and Hyperion data. The distributions of clay minerals are denoted in blue. (<b>a</b>) The extraction result of ZY-1 02D data; (<b>b</b>) The extraction result of Hyperion data; (<b>c</b>–<b>e</b>) The zoom-in detailed subfigures of region A, B, and C of ZY-1 02D data, respectively; (<b>f</b>–<b>h</b>) The zoom-in detailed subfigures of region A, B, and C of Hyperion data, respectively.</p>
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<p>Comparison of the extraction results of carbonate minerals extracted from ZY-1 02D and Hyperion data. The distributions of carbonate minerals are denoted in magenta (<b>a</b>) The extraction result of ZY-1 02D data; (<b>b</b>) The extraction result of Hyperion data; (<b>c</b>–<b>e</b>) The zoom-in detailed subfigures of region A, B, and C of ZY-1 02D data, respectively; (<b>f</b>–<b>h</b>) The zoom-in detailed subfigures of region A, B, and C of Hyperion data, respectively.</p>
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<p>Data quality comparison of the ZY-1 02D (<b>a</b>) and Hyperion (<b>b</b>) images.</p>
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22 pages, 6297 KiB  
Article
Estimation of the Total Soil Nitrogen Based on a Differential Evolution Algorithm from ZY1-02D Hyperspectral Satellite Imagery
by Rongrong Zhang, Jian Cui, Wenge Zhou, Dujuan Zhang, Wenhao Dai, Hengliang Guo and Shan Zhao
Agronomy 2023, 13(7), 1842; https://doi.org/10.3390/agronomy13071842 - 12 Jul 2023
Cited by 4 | Viewed by 1654
Abstract
Precise fertilizer application in agriculture requires accurate and dependable measurements of the soil total nitrogen (TN) concentration. Henan Province is one of the most important grain-producing areas in China. In order to promote the development of precision agriculture in Henan Province, this study [...] Read more.
Precise fertilizer application in agriculture requires accurate and dependable measurements of the soil total nitrogen (TN) concentration. Henan Province is one of the most important grain-producing areas in China. In order to promote the development of precision agriculture in Henan Province, this study took the high-standard basic farmland construction area in central Henan Province as the research area. Using single-phase images acquired from the ZY1-02D satellite hyperspectral sensor on 28 January 2021 (with a spatial resolution of 30 m × 30 m, a spectral range that covered 400–2500 nm, and a revisit period of 3 days) for spectral reflectance transformation and feature spectral band extraction. Based on multiple representation models, such as multiple linear regression, partial least squares regression, and support vector machine (SVM), all bands, feature bands, feature band combinations, and differential evolution (DE) algorithms were used to extract the secondary characteristic variables of the combination of characteristic bands, which were used as model inputs to estimate the content of TN in the study area. It was found that (1) the spectral reflectance transformation could help to improve the accuracy of prediction by reducing the interference from noise in the model, but the optimal spectral transformation method differed between different models and even between the training and test sets of the same model; (2) the estimation accuracy of the TN content model based on the minimum shrinkage and feature selection operator of the feature band was usually better than that of the full band, the feature combination band contained more effective information related to the TN content, and the combination of the DE algorithm and the SVM model achieved a better estimation accuracy for secondary feature extraction and TN content estimation of the feature combination band; and (3) ZY1-02D hyperspectral satellite data have the potential for the dynamic and non-destructive monitoring of regional TN content. Full article
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<p>Maps of the research site. (<b>a</b>) Map of China, where the blue area is Henan Province; (<b>b</b>) map of Henan Province; (<b>c</b>) hyperspectral ZY1-02D/AHSI image of the research area, together with the locations of the soil sampling sites (in this study, only the reflectance data of satellite images in cultivated areas were extracted for experimentation, excluding buildings and other areas).</p>
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<p>Flow chart of the experimental steps.</p>
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<p>DE algorithm’s flow chart.</p>
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<p>Spectral reflectance profiles for different TN contents: (<b>a</b>) original reflectance, (<b>b</b>) inverse reflectance, (<b>c</b>) natural logarithm of the reflectance, and (<b>d</b>) first-order derivative reflectance.</p>
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<p>LASSO algorithm TN feature band selection results: (<b>a</b>) OR–LASSO, (<b>b</b>) IR–LASSO, (<b>c</b>) NLR–LASSO, and (<b>d</b>) FDR–LASSO.</p>
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<p>Scatter plots of measured and predicted TN contents based on individual spectral reflectance conversions of the best estimation model for all bands: (<b>a</b>) OR–SVM training set model; (<b>b</b>) OR–SVM test set model.</p>
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<p>Scatter plots of the measured and predicted values of the best estimation model for TN content based on the LASSO feature selection: (<b>a</b>) OR–LASSO–SVM training set model; (<b>b</b>) OR–LASSO–SVM test set model.</p>
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<p>Scatter plots of the measured and predicted values of the best estimation model for TN content based on the LBC: (<b>a</b>) LBC–SVM training set model; (<b>b</b>) LBC–SVM test set model.</p>
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<p>Scatter plot of the measured and predicted values of the best estimation model for TN content based on LBC–DE: (<b>a</b>) LBC–DE–SVM training set model; (<b>b</b>) LBC–DE–SVM test set model.</p>
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<p>Comparison of the accuracy of the test set models: (<b>a</b>) R<sup>2</sup>, (<b>b</b>) MAE, and (<b>c</b>) RMSE.</p>
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<p>Map of the best model (LBC–DE–SVM) for estimating the TN content in the agricultural areas of the study area: (<b>a</b>) agricultural distribution in the study area and (<b>b</b>) spatial distribution of the TN content.</p>
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