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Search Results (433)

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16 pages, 7381 KiB  
Article
Cholecystokinin (CCK) Is a Mediator Between Nutritional Intake and Gonadal Development in Teleosts
by Hangyu Li, Hongwei Liang, Xiaowen Gao, Xiangtong Zeng, Shuo Zheng, Linlin Wang, Faming Yuan, Shaohua Xu, Zhan Yin and Guangfu Hu
Cells 2025, 14(2), 78; https://doi.org/10.3390/cells14020078 - 8 Jan 2025
Viewed by 260
Abstract
Nutritional intake is closely linked to gonadal development, although the mechanisms by which food intake affects gonadal development are not fully understood. Cholecystokinin (CCK) is a satiety neuropeptide derived from the hypothalamus, and the present study observed that hypothalamic CCK expression is significantly [...] Read more.
Nutritional intake is closely linked to gonadal development, although the mechanisms by which food intake affects gonadal development are not fully understood. Cholecystokinin (CCK) is a satiety neuropeptide derived from the hypothalamus, and the present study observed that hypothalamic CCK expression is significantly influenced by food intake, which is mediated through blood glucose levels. Interestingly, CCK and its receptors were observed to exhibit a high expression in the hypothalamus–pituitary–gonad (HPG) axis of grass carp (Ctenopharyngodon idellus), suggesting that CCK is potentially involved in regulating fish reproduction through the HPG axis. Further investigations revealed that CCK could significantly stimulate the expression of gonadotropin-releasing hormone-3 (GnRH3) in the hypothalamus. In addition, single-cell RNA sequencing showed that cckrb was highly enriched in pituitary follicle-stimulating hormone (FSH) cells. Further study confirmed that CCK can significantly induce FSH synthesis and secretion in primary cultured pituitary cells. Additionally, with primary cultured ovary cells as a model, the in vitro experiment demonstrated that CCK directly induces the expression of lhr, fshr, and cyp19a1a mRNA. This indicates that hypothalamic CCK may act as a nutrient sensor involved in regulating gonadal development in teleosts. Full article
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<p>Analysis of the aptitude of CCK and its receptor. (<b>A</b>) Amino acid sequence alignment of mature peptides among grass carp CCK1 and CCK2. (<b>B</b>) Tissue expression profile of carp CCKs and CCKRs. (<b>C</b>) Ligand selectivity of grass carp CCK-Rs for CCKs. To verify the affinity of grass carp CCKRa, CCKRb, and CCKRl to the two ligands (CCK1 and CCK2), the NFAT-Luc and CRE-Luc reporter genes were co-transfected with GFP into HEK293T, which can stably express grass carp CCKRa, CCKRb, and CCKRl. Then, the cells were treated with CCK1 or CCK2 for 24 h. Statistical significance is represented by different letters at <span class="html-italic">p</span> &lt; 0.05.</p>
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<p>Food intake induces CCK expression in the hypothalamus. (<b>A</b>) Postprandial changes in grass carp hypothalamus <span class="html-italic">cck1</span> and <span class="html-italic">cck2</span> mRNA expression were observed within 12 h. (<b>B</b>) Changes in reproduction-related hormones were observed in grass carp after a 7 day period of starvation stress. (<b>C</b>) Changes in blood glucose concentration were observed in postprandial grass carp as well as changes in CCK transcript levels in the hypothalamus after glucose injection. (<b>D</b>) Changes in cck in the hypothalamic cells of grass carp after 24 h of 2-DG treatment (40×). Different letters mean significant differences. * <span class="html-italic">p</span> &lt; 0.05. ** <span class="html-italic">p</span> &lt; 0.01. *** <span class="html-italic">p</span> &lt; 0.001.</p>
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<p>CCK induces the expression of GnRH3 in the hypothalamus. (<b>A</b>) Immunohistochemistry showing co-localization of CCK (red) and GnRH3 (green) in the hypothalamic tissues and cells. Black box shows immunohistochemistry area. (<b>B</b>) CCK1 and CCK2 induced GnRH3 (red) expression in the grass carp hypothalamic cells. * <span class="html-italic">p</span> &lt; 0.05. ** <span class="html-italic">p</span> &lt; 0.01. (<b>C</b>) Workflow of single-cell RNA-Seq of grass carp hypothalamus. (<b>D</b>) UMAP visualization shows the unsupervised clustering of the aggregate of scRNA-Seq experiments, revealing 17 major clusters of hypothalamic cells present in grass carp. (<b>E</b>) The dot plot displaying the percentage and average expression of genes related to glucose metabolism. (<b>F</b>) The UMAP visualization of <span class="html-italic">cckra</span>, <span class="html-italic">cckrb</span>, <span class="html-italic">cckrl</span>, and <span class="html-italic">gnrh3</span>. Purple arrow indicates area of expression.</p>
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<p>CCK induces FSH synthesis and secretion in the pituitary. (<b>A</b>) Immunofluorescence localization analysis of LH (red) and FSH (green) in the pituitary gland. (<b>B</b>) The UMAP visualization displays the unsupervised clustering of the aggregate of scRNA-Seq experiments, revealing 14 major clusters of pituitary cells. (<b>C</b>) Dot plot demonstrating the percentage and mean expression of the most prevalent genes in the pituitary gland. (<b>D</b>) UMAP visualization of <span class="html-italic">cckra</span>, <span class="html-italic">cckrb</span>, <span class="html-italic">cckrl</span>, and <span class="html-italic">gnrh3</span>. Purple arrow indicates area of expression. (<b>E</b>) Immunohistochemical analysis of CCK induced-FSH levels in pituitary cells (40×). (<b>F</b>) Time-dependent experiments of CCK1 and CCK2 on <span class="html-italic">fshβ</span> mRNA expression in the grass carp pituitary cells. (<b>G</b>) Dose-dependent experiments of CCK1 and CCK2 on the regulation of FSH protein secretion and <span class="html-italic">fshβ</span> mRNA expression in the grass carp pituitary cells. (<b>H</b>) Signal transduction of CCKs-regulated <span class="html-italic">fshβ</span> mRNA expression in the grass carp pituitary cells. Different letters mean significant differences.</p>
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<p>Functional studies of CCK in the grass carp gonads. (<b>A</b>) Immunofluorescence localization of CCK in the ovary. (<b>B</b>) Effect of CCK on <span class="html-italic">cyp11a</span>, <span class="html-italic">cyp17a1</span>, and <span class="html-italic">cyp19a1a</span> mRNA expression in the female and male gonads. (<b>C</b>) Effect of CCK on <span class="html-italic">lhr</span>, <span class="html-italic">fshr</span>, and <span class="html-italic">cyp19a1a</span> mRNA expression in oocytes. Different letters mean significant differences.</p>
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19 pages, 20606 KiB  
Article
Multi-Sensor Instrument for Aerosol In Situ Measurements
by Ilya Bruchkouski, Artur Szkop, Jakub Wink, Justyna Szymkowska and Aleksander Pietruczuk
Atmosphere 2025, 16(1), 42; https://doi.org/10.3390/atmos16010042 - 2 Jan 2025
Viewed by 298
Abstract
A short comparison campaign took place at the Racibórz measurement site in May 2024 to assess the consistency of the Integrated Aerosol Monitoring Unit (IAMU), which houses three PM aerosol sensors (SPS30, OPC-N3, and OPS 3330) within a single enclosure. This assessment was [...] Read more.
A short comparison campaign took place at the Racibórz measurement site in May 2024 to assess the consistency of the Integrated Aerosol Monitoring Unit (IAMU), which houses three PM aerosol sensors (SPS30, OPC-N3, and OPS 3330) within a single enclosure. This assessment was supported by simultaneous measurements from two reference instruments (APS 3321 and SMP S3082), along with auxiliary observations from a ceilometer and meteorological station. To enhance particle transmission efficiency to the IAMU sensors, aerodynamic modeling of the inlet pipes was performed, accounting for particle density and diameter. The primary objective of this study was to evaluate the feasibility of using the IAMU, in conjunction with optimized inlet designs, for PM monitoring under varying ambient relative humidity and sensor temperature conditions. IAMU measurements have shown large absolute differences in PM values (exceeding one order of magnitude) with moderate (>0.54 for PM10) to high (>0.82 for PM2.5 and PM1) temporal correlations. A calibration method was proposed, using reference instrument data and incorporating sensor temperature and air sample humidity information. The IAMU, combined with the developed calibration methodology, enabled the estimation of the aerosol growth factor, deliquescence point (RH ≈ 65%), and PM1 hygroscopic parameter κ (0.27–0.56) for an industrial region in Poland. Full article
(This article belongs to the Section Aerosols)
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<p>Modeled air velocity distribution in the sampling head (<b>a</b>); main dimensions in mm (<b>b</b>); CAD model of inlet pipe configuration (<b>c</b>); modeled field of horizontal air velocity (<b>d</b>); and cross-sectional view (A-A) of horizontal velocity field near the inlet (<b>e</b>).</p>
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<p>IAMU sensors: (<b>a</b>) CAD model of SPS30 sensor with connection unit (transparent); (<b>b</b>) Common enclosure view: 1—OPC-N3, 2—SPS30, 3—OPS3330, 4—Raspberry Pi 3B; (<b>c</b>) SPS30 and OPC-N3: Connection schematic and data transmission.</p>
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<p>Integrated Aerosol Monitoring Unit (IAMU) during comparison campaign in Racibórz: (<b>a</b>) IAMU; (<b>b</b>) Common view of IAMU together with pipes for stationary instruments SMPS3082 and APS3321.</p>
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<p>Racibórz, 5 May 2024: The upper panel displays ceilometer data (Lufft CHM15k Nimbus), while the lower panel presents the aerosol differential volume distribution <math display="inline"><semantics> <mrow> <mstyle scriptlevel="0" displaystyle="true"> <mfrac> <mrow> <mi>d</mi> <mi>V</mi> </mrow> <mrow> <mi>d</mi> <mi>l</mi> <mi>o</mi> <mi>g</mi> <msub> <mi>D</mi> <mi>p</mi> </msub> </mrow> </mfrac> </mstyle> </mrow> </semantics></math> measured by stationary instruments. The SMPS 3082 was used for particle diameters in the range of 0.01–1 µm and the APS 3321 for diameters ranging from 1 to 10 µm.</p>
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<p>Transmission efficiency of the inlet pipe for eleven aerosol size fractions under varying horizontal wind velocities: (<b>a</b>) pump flow rate of 0.125 L/min; (<b>b</b>) pump flow rate of 0.5 L/min; (<b>c</b>) pump flow rate of 1.0 L/min.</p>
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<p>Series of in situ PM<sub>x</sub> measurements by IAMU sensors; aerosol differential volume distribution <math display="inline"><semantics> <mrow> <mstyle scriptlevel="0" displaystyle="true"> <mfrac> <mrow> <mi>d</mi> <mi>V</mi> </mrow> <mrow> <mi>d</mi> <mi>l</mi> <mi>o</mi> <mi>g</mi> <msub> <mi>D</mi> <mi>p</mi> </msub> </mrow> </mfrac> </mstyle> </mrow> </semantics></math>, measured by the stationary instruments SMPS 3082 and APS 3321; temperature from OPC-N3 sensor together with relative humidity (RH) data.</p>
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<p>PM<sub>x</sub> values measured by SPS30, OPC-N3, and OPS 3330 instruments, compared to values from reference size spectrometers (SMPS 3082 and APS 3321) for different RH values.</p>
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<p>GF values calculated for PM<sub>1</sub>, PM<sub>2.5</sub>, and PM<sub>10</sub>, measured by the SPS30, OPC-N3, and OPS 3330 sensors, are compared with values obtained from reference size spectrometers (SMPS 3082 and APS 3321) at different RH levels.</p>
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<p>GF values calculated for the OPS 3330, OPC-N3, and SPS30 sensors, including bi-linear fitting and the deliquescence relative humidity point (DRH).</p>
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<p>Comparison of GF in situ measurements for PM<sub>1</sub>, PM<sub>2.5</sub>, and PM<sub>10</sub>, by the SPS30, OPC-N3, and OPS 3330 sensors, with values obtained from reference instruments (SMPS 3082 and APS 3321) at different RH levels. Fitting is performed according to Equation (10).</p>
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14 pages, 2958 KiB  
Article
A Sustainable and Flexible Carbon Paper-Based Multifunctional Human–Machine Interface (HMI) Sensor
by Muhammad Muqeet Rehman, Maryam Khan, Hafiz Mohammad Mutee ur Rehman, Muhammad Saqib, Shahzad Iqbal, Sang Seop Lim, Kun Hyun Park and Woo Young Kim
Polymers 2025, 17(1), 98; https://doi.org/10.3390/polym17010098 - 1 Jan 2025
Viewed by 477
Abstract
We have executed a cost-effective approach to produce a high-performance multifunctional human–machine interface (HMI) humidity sensor. The designed sensors were ecofriendly, flexible, and highly sensitive to variability in relative humidity (%RH) in the surroundings. In this study, we have introduced a humidity sensor [...] Read more.
We have executed a cost-effective approach to produce a high-performance multifunctional human–machine interface (HMI) humidity sensor. The designed sensors were ecofriendly, flexible, and highly sensitive to variability in relative humidity (%RH) in the surroundings. In this study, we have introduced a humidity sensor by using carbon paper (as both a substrate and sensing material) and a silver (Ag) conductive ink pen. The carbon paper-based humidity sensor was developed by using a simple handwriting approach and the resulting devices exhibited excellent results including fast response/recovery times (12/24 s), a wide sensing range (30 to 85%), small hysteresis (1.1%), high stability (1 month), and repeatability. This high-performance humidity response could be attributed to the highly porous, hydrophilic, and permeable nature of carbon paper. Besides these features, the sensor offered high flexibility (100 bending cycles across different radii) and adaptability for uses like breath monitoring (through mouth and nose), proximity sensing (from multiple distances ranging from 1 to 10 cm), and depicting Morse code. This research work is a significant step forward in humidity sensing technology and the sustainable future of electronic devices by using a cost-effective, fast, and simple fabrication technique. Full article
(This article belongs to the Special Issue Nature-Inspired and Polymers-Based Flexible Electronics and Sensors)
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<p>(<b>a</b>) Schematic diagram of device fabrication. (<b>b</b>) Layered structure of a carbon paper-based humidity sensor, a detailed labeled diagram of the customized mask along with the optical images of a conductive Ag ink pen, and our developed sensor.</p>
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<p>Morphological analysis of carbon paper by using FESEM at (<b>a</b>) 200 µm and (<b>b</b>) 50 µm. (<b>c</b>) Elemental composition of carbon paper with wt% of each element present in it. (<b>d</b>) FTIR spectrum of carbon paper depicting the presence of important functional groups for sensing humidity.</p>
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<p>Electrical characterization of a carbon paper-based humidity sensor. (<b>a</b>) Impedance response at 1 kHz. (<b>b</b>) Impedance response at 10 kHz. (<b>c</b>) Repeatability of multiple humidity sensors. (<b>d</b>) Small hysteresis between the adsorption and desorption of a humidity sensor. (<b>e</b>) Response and recovery time obtained from the dynamic response of a humidity sensor. (<b>f</b>) Stable impedance response of a humidity sensor at multiple %RH.</p>
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<p>Mechanical robustness of a carbon paper-based humidity sensor (<b>a</b>) Stability against multiple bending radii at different %RH. (<b>b</b>) Stability against multiple bending cycles at different %RH. (<b>c</b>) Stability against multiple twisting cycles at different %RH.</p>
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<p>Multifunctional applications of carbon paper-based humidity sensor (<b>a</b>) Dynamic response of mouth breathing. (<b>b</b>) Stability of maximum/minimum impedance values during mouth breathing. (<b>c</b>) Dynamic response of nose breathing. (<b>d</b>) Stability of maximum/minimum impedance values during nose breathing. (<b>e</b>) Dynamic response of proximity sensing. (<b>f</b>) Impedance response of proximity sensing at different distance values. (<b>g</b>) Successful depiction of Morse Code and its standard table.</p>
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12 pages, 4039 KiB  
Article
Humidity-Activated Ammonia Sensor Based on Carboxylic Functionalized Cross-Linked Hydrogel
by Yaping Song, Yihan Xia, Wei Zhang, Yunlong Yu, Yanyu Cui, Lichao Liu, Tong Zhang, Sen Liu, Hongran Zhao and Teng Fei
Sensors 2024, 24(24), 8154; https://doi.org/10.3390/s24248154 - 20 Dec 2024
Viewed by 321
Abstract
Owing to its extensive use and intrinsic toxicity, NH3 detection is very crucial. Moisture can cause significant interference in the performance of sensors, and detecting NH3 in high humidity is still a challenge. In this work, a humidity-activated NH3 sensor [...] Read more.
Owing to its extensive use and intrinsic toxicity, NH3 detection is very crucial. Moisture can cause significant interference in the performance of sensors, and detecting NH3 in high humidity is still a challenge. In this work, a humidity-activated NH3 sensor was prepared by urocanic acid (URA) modifying poly (ethylene glycol) diacrylate (PEGDA) via a thiol-ene click cross-linking reaction. The optimized sensor achieved a response of 70% to 50 ppm NH3 at 80% RH, with a response time of 105.6 s and a recovery time of 346.8 s. The sensor was improved for response and recovery speed. In addition, the prepared sensor showed excellent selectivity to NH3 in high-humidity environments, making it suitable for use in some areas with high humidity all the year round or in high-humidity areas such as the detection of respiratory gas. A detailed investigation of the humidity-activated NH3-sensing mechanism was conducted using complex impedance plot (CIP) measurements. Full article
(This article belongs to the Section Chemical Sensors)
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<p>Schematic diagram for the preparation of NH<sub>3</sub> sensors and the structure of monomers.</p>
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<p>Response and recovery curves of the (<b>a</b>) S1 sensor, (<b>b</b>) S2 sensor and (<b>c</b>) S3 sensor to NH<sub>3</sub> with concentrations of 3 ppm, 5 ppm, 10 ppm, 20 ppm, 30 ppm, 40 ppm, and 50 ppm at 80% RH; the relationship between the impedance modulus and ammonia concentration of the (<b>d</b>) S1 sensor, (<b>e</b>) S2 sensor, and (<b>f</b>) S3 sensor (the red line is the fitted curve of the relationship between impedance modulus and ammonia concentration).</p>
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<p>(<b>a</b>) The impedance modulus of the S2 sensor at with and without 50 ppm NH<sub>3</sub> in 10–80% RH. (<b>b</b>) The response of the S2 sensor to 50 ppm NH<sub>3</sub> in 10–80% RH. (<b>c</b>) The dynamic response curve of the S2 sensor to 50 ppm NH<sub>3</sub> at 20% RH, 50% RH, and 80% RH.</p>
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<p>Response and recovery curve of S2 sensor upon exposure to 50 ppm NH<sub>3</sub> at 80% RH.</p>
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<p>Complex impedance plots of S2 sensor without NH<sub>3</sub> (gray) or 50 ppm NH<sub>3</sub> (red) at (<b>a</b>) 20% RH, (<b>b</b>) 50% RH, and (<b>c</b>) 80% RH.</p>
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<p>Proposed conduction mechanisms in the S2 sensor in the presence of humidity and NH<sub>3</sub>: (<b>a</b>) at low relative humidity (RH), (<b>b</b>) at moderate RH, and (<b>c</b>) at high RH.</p>
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<p>(<b>a</b>) The response of the S2 sensor to 10 ppm NH<sub>3</sub>, CH<sub>3</sub>OH, CH<sub>3</sub>COCH<sub>3</sub>, and C<sub>2</sub>H<sub>4</sub> at 25 °C at 80% RH. (<b>b</b>) The impedance modulus (black) of the S2 sensor at 80% RH and the response (red) of the S2 sensor to 50 ppm NH<sub>3</sub> at 80% RH over 15 days.</p>
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14 pages, 7499 KiB  
Article
Smart Concrete Using Optical Sensors Based on Bragg Gratings Embedded in a Cementitious Mixture: Cure Monitoring and Beam Test
by Edson Souza, Pâmela Pinheiro, Felipe Coutinho, João Dias, Ronaldo Pilar, Maria José Pontes and Arnaldo Leal-Junior
Sensors 2024, 24(24), 7998; https://doi.org/10.3390/s24247998 - 14 Dec 2024
Viewed by 395
Abstract
Smart concrete is a structural element that can combine both sensing and structural capabilities. In addition, smart concrete can monitor the curing of concrete, positively impacting design and construction approaches. In concrete, if the curing process is not well developed, the structural element [...] Read more.
Smart concrete is a structural element that can combine both sensing and structural capabilities. In addition, smart concrete can monitor the curing of concrete, positively impacting design and construction approaches. In concrete, if the curing process is not well developed, the structural element may develop cracks in this early stage due to shrinkage, decreasing structural mechanical strength. In this paper, a system of measurement using fiber Bragg grating (FBG) sensors for monitoring the curing of concrete was developed to evaluate autogenous shrinkage strain, temperature, and relative humidity (RH) in a single system. Furthermore, K-type thermocouples were used as reference temperature sensors. The results presented maximum autogenous shrinkage strains of 213.64 με, 125.44 με, and 173.33 με for FBG4, FBG5, and FBG6, respectively. Regarding humidity, the measured maximum relative humidity was 98.20 %RH, which was reached before 10 h. In this case, the recorded maximum temperature was 63.65 °C and 61.85 °C by FBG2 and the thermocouple, respectively. Subsequently, the concrete specimen with the FBG strain sensor embedded underwent a bend test simulating beam behavior. The measurement system can transform a simple structure like a beam into a smart concrete structure, in which the FBG sensors’ signal was maintained by the entire applied load cycles and compared with FBG strain sensors superficially positioned. In this test, the maximum strain measurements were 85.65 με, 123.71 με, and 56.38 με on FBG7, FBG8, and FBG3, respectively, with FBG3 also monitoring autogenous shrinkage strain. Therefore, the results confirm that the proposed system of measurement can monitor the cited parameters throughout the entire process of curing concrete. Full article
(This article belongs to the Section Optical Sensors)
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<p>FBG Hygrometer Sensor. The zoomed-in view shows details of the FBGs.</p>
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<p>The curing concrete setup photo is presented in (<b>A</b>). The experimental components are identified in the schematic drawing (<b>B</b>).</p>
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<p>The photo (<b>A</b>) presents the shrinkage bench, where the autogenous shrinkage strain was measured. The distribution of the FBG strain sensors is identified in the schematic drawing (<b>B</b>).</p>
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<p>The bend test using three-point bending. (<b>A</b>) presents a photo of the positioning of smart concrete and (<b>B</b>) presents a schematic representation using two supports and one loading point, highlighted in red.</p>
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<p>Temperature sensitivity calibration for FBG2 for relative humidities of 60 %RH, 70 %RH, 80 %RH, 90 %RH, and 95 %RH.</p>
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<p>Temperature sensitivity calibration for FBG1 for relative humidities of 60 %RH, 70 %RH, 80 %RH, 90 %RH, and 95 %RH.</p>
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<p>Relative humidity sensitivity calibration for FBG1 for temperatures of 30 °C, 40 °C, and 45 °C.</p>
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<p>Comparison between the temperature curves obtained by the thermocouple and FBG2.</p>
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<p>Relative humidity variation versus the test time, monitored by FBG1.</p>
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<p>Monitored temperature by thermocouple versus time in the concrete specimen of shrinkage bench.</p>
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<p>Monitored strain by the FBG4, FBG5, and FBG6 strain sensors versus time. For FBG3, the Bragg wavelength shift during the test is presented.</p>
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<p>Monitored autogenous shrinkage strain by FBG4, FBG5, and FBG6 versus test time.</p>
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<p>FBG7, FBG8, and FBG3 strain responses to applied bend load cycles.</p>
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14 pages, 4193 KiB  
Article
Simultaneous Temperature and Relative Humidity Measurement Using Machine Learning in Rayleigh-Based Optical Frequency Domain Reflectometry
by Mateusz Mądry, Bogusław Szczupak, Mateusz Śmigielski and Bartosz Matysiak
Sensors 2024, 24(24), 7913; https://doi.org/10.3390/s24247913 - 11 Dec 2024
Viewed by 520
Abstract
This paper presents, for the first time to the best of our knowledge, simultaneous temperature and relative humidity (RH) measurement using a machine learning (ML) model in Rayleigh-based Optical Frequency Domain Reflectometry (OFDR). The sensor unit consists of two segments: bare and polyimide-coated [...] Read more.
This paper presents, for the first time to the best of our knowledge, simultaneous temperature and relative humidity (RH) measurement using a machine learning (ML) model in Rayleigh-based Optical Frequency Domain Reflectometry (OFDR). The sensor unit consists of two segments: bare and polyimide-coated fibers, each with different sensitivities to temperature. The polyimide-coated fiber is RH-sensitive, unlike the bare fiber. We propose the ML approach to avoid manual post-processing data and maintain relatively high accuracy of the sensor. The root mean square error (RMSE) values for the 3 cm length of the sensor unit were 0.36 °C and 1.73% RH for temperature and RH, respectively. Furthermore, we investigated the impact of sensor unit lengths and number of data points on RMSE values. This approach eliminates the need for manual data processing, reduces analysis time, and enables accurate, simultaneous measurement of temperature and RH in Rayleigh-based OFDR. Full article
(This article belongs to the Section Optical Sensors)
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<p>The scheme of the experimental setup consisted of LUNA OBR 4600 as Rayleigh-based OFDR, a PC (Personal Computer) with dedicated software, SMF-28, bare fiber—SM1500(7.8/125), PI-coated fiber—SM1500(7.8/125P), and the climate chamber. The sensor unit consists of bare and PI-coated fibers.</p>
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<p>The backscattered trace from LUNA OBR 4600 to the end of the fiber line.</p>
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<p>The algorithm for measurement data processing in this study.</p>
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<p>(<b>a</b>) The exemplary spectral shift as a function of fiber length (limited to the investigated section) for different RH values at a constant temperature of 40 °C. (<b>b</b>) Spectral shift values as a function of RH changes.</p>
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<p>The exemplary spectral shift as a function of fiber length (limited to the investigated section) for different temperature values at constant 50% RH.</p>
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<p>The spectral shift as a function of ascending and descending RH for PI-coated fiber.</p>
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<p>The spectral shift for ascending and descending temperatures in a range of 30–80 °C for (<b>a</b>) bare fiber and (<b>b</b>) PI-coated fiber.</p>
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<p>The spectral shift as a function of strain for bare and PI-coated fibers.</p>
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<p>The RMSE values for different sensor lengths (3–10 cm) for temperature and RH, respectively.</p>
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<p>The RMSE values for different numbers of measurement points with constant value of sensor length (10 cm) for temperature and RH, respectively.</p>
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<p>The RMSE values for different numbers of measurement points with constant values of sensor length (3 cm) for temperature and RH, respectively.</p>
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19 pages, 8894 KiB  
Article
The Effect of Doping rGO with Nanosized MnO2 on Its Gas Sensing Properties
by Mohamed Ayoub Alouani, Juan Casanova-Chafer, Santiago de Bernardi-Martín, Alejandra García-Gómez, Foad Salehnia, José Carlos Santos-Ceballos, Alejandro Santos-Betancourt, Xavier Vilanova and Eduard Llobet
Chemosensors 2024, 12(12), 256; https://doi.org/10.3390/chemosensors12120256 - 6 Dec 2024
Viewed by 687
Abstract
Manganese dioxide (MnO2) has drawn attention as a sensitiser to be incorporated in graphene-based chemoresistive sensors thanks to its promising properties. In this regard, a rGO@MnO2 sensing material was prepared and deposited on two different substrates (silicon and Kapton). The [...] Read more.
Manganese dioxide (MnO2) has drawn attention as a sensitiser to be incorporated in graphene-based chemoresistive sensors thanks to its promising properties. In this regard, a rGO@MnO2 sensing material was prepared and deposited on two different substrates (silicon and Kapton). The effect of the substrate nature on the morphology and sensing behaviour of the rGO@MnO2 material was thoroughly analysed and reported. These sensors were exposed to different dilutions of NO2 ranging from 200 ppb to 1000 ppb under dry and humid conditions (25% RH and 70% RH) at room temperature. rGO@MnO2 deposited on Kapton showed the highest response of 6.6% towards 1 ppm of NO2 under dry conditions at RT. Other gases or vapours such as NH3, CO, ethanol, H2 and benzene were also tested. FESEM, HRTEM, Raman, XRD and ATR-IR were used to characterise the prepared sensors. The experimental results showed that the incorporation of nanosized MnO2 in the rGO material enhanced its response towards NO2. Moreover, this material also showed very good responses toward NH3 both under dry and humid conditions, with the rGO@MnO2 sensor on silicon showing the highest response of 18.5% towards 50 ppm of NH3 under 50% RH at RT. Finally, the synthetised layers showed no cross-responsiveness towards other toxic gases. Full article
(This article belongs to the Special Issue Advanced Chemical Sensors for Gas Detection)
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<p>Pictures of the prepared sensors on the (<b>a</b>) silicon substrate and (<b>b</b>) Kapton substrate.</p>
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<p>Schematic representation of the gas detection process and used equipment.</p>
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<p>(<b>a</b>) Raman spectra of rGO and (<b>b</b>) Raman spectra of rGO@MnO<sub>2</sub>.</p>
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<p>FESEM images of (<b>a</b>) the surface of the graphene doped with MnO<sub>2</sub> deposited on the silicon substrate and (<b>b</b>) the surface of the graphene doped with MnO<sub>2</sub> deposited on the Kapton substrate.</p>
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<p>(<b>a</b>) HRTEM image of layered graphene doped with nanosized MnO<sub>2</sub>; (<b>b</b>) a zoomed HRTEM image of a scale of 50 nm of the same material; (<b>c</b>) EDS mapping showing Mn concentration on the area of analysis; (<b>d</b>) EDS map of O element in the mapped area; (<b>e</b>) EDS map of C element in the same mapped area; (<b>f</b>) overlay image of all the maps of the elements C (green), O (red) and Mn (blue); (<b>g</b>) EDS map spectrum of the studied area.</p>
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<p>(<b>a</b>) HRTEM image of layered graphene doped with nanosized MnO<sub>2</sub>; (<b>b</b>) a zoomed HRTEM image of a scale of 50 nm of the same material; (<b>c</b>) EDS mapping showing Mn concentration on the area of analysis; (<b>d</b>) EDS map of O element in the mapped area; (<b>e</b>) EDS map of C element in the same mapped area; (<b>f</b>) overlay image of all the maps of the elements C (green), O (red) and Mn (blue); (<b>g</b>) EDS map spectrum of the studied area.</p>
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<p>ATR-IR spectra of (<b>a</b>) rGO@MnO<sub>2</sub> on silicon substrate and (<b>b</b>) rGO@MnO<sub>2</sub> on Kapton substrate.</p>
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<p>(<b>a</b>) Calibration curve of the responses of the fabricated sensors towards different concentrations of NO<sub>2</sub> at room temperature and under dry conditions; (<b>b</b>) resistance changes of the rGO@MnO<sub>2</sub> on silicon substrate for 600 ppb of NO<sub>2</sub> at 25% RH; (<b>c</b>) resistance changes of the rGO@MnO<sub>2</sub> on Kapton substrate for 600 ppb of NO<sub>2</sub> at 25% RH.</p>
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<p>(<b>a</b>) calibration curves of the different sensors under 25% relative humidity at room temperature and (<b>b</b>) calibration curves under 70% relative humidity at room temperature.</p>
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<p>Comparison of the responses of the different sensors towards different gases at dry conditions to study the selectivity of the sensitive layer.</p>
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<p>(<b>a</b>) Calibration curve of the responses of the fabricated sensors towards different test conditions (Dry, 25% RH and 50% RH); (<b>b</b>) resistance changes of the sensor pristine rGO on Kapton when exposed to NH<sub>3</sub> at 25% RH; (<b>c</b>) hydrogen bonding of water and ammonia molecules.</p>
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13 pages, 3122 KiB  
Article
Fabrication of a Portable Magnetic Microcantilever Using Fe40Ni38Mo4B18 Amorphous Ribbon and Its Application as a Humidity Sensor by Coating with TiO2 Nanotubes
by Selçuk Atalay, Sema Erdemoglu, Hatice Çağlar Yılmaz, Emine Mete, Orhan Orcun Inan and Veli Serkan Kolat
Magnetochemistry 2024, 10(12), 98; https://doi.org/10.3390/magnetochemistry10120098 - 5 Dec 2024
Viewed by 499
Abstract
Microcantilevers (MCs) are highly sensitive sensors capable of detecting mass changes on the surface at the nanogram and even picogram scale. In this study, microcantilevers were fabricated for the first time using the Sodick AP250L Wire electrical discharge machining (EDM) from amorphous 2826MB [...] Read more.
Microcantilevers (MCs) are highly sensitive sensors capable of detecting mass changes on the surface at the nanogram and even picogram scale. In this study, microcantilevers were fabricated for the first time using the Sodick AP250L Wire electrical discharge machining (EDM) from amorphous 2826MB (Fe40Ni38Mo4B18) ferromagnetic ribbons. This method is advantageous because it allows for the simultaneous production of a large number of microcantilevers, with about 100 MCs being produced in a single manufacturing process. Additionally, a straightforward and cost-effective measurement system was developed to measure the resonance frequency and frequency shift of the MC entirely through magnetic means, a technique not previously reported in the literature. To evaluate the performance of the MC, we employed it as a humidity sensor. For the TiO2-NT-coated MC, a frequency shift of approximately 202 Hz was observed when the humidity level changed from 5% to 95% relative humidity (RH). Full article
(This article belongs to the Section Applications of Magnetism and Magnetic Materials)
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<p>XRD spectrum of amorphous ribbon.</p>
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<p>SEM pictures of some MCs. The dimensions of the MCs vary across the figures as follows: in Figure (<b>A</b>), it is 1000 µm long and 400 µm wide; in Figure (<b>B</b>), it is 2000 µm long and 400 µm wide; in Figure (<b>C</b>), it is 1200 µm long and 400 µm wide; and in Figure (<b>D</b>), it is 2000 µm long and 160 µm wide.</p>
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<p>MC resonance frequency measurement system. The system also measures the effect of the applied external magnetic field and humidity on the resonance frequency. Inset shows the humidity cabin magnified.</p>
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<p>Design drawings of the MC unit and images of the MC unit produced according to this design.</p>
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<p>Resonance curves when the MC sensor is inside and outside the pickup coil.</p>
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<p>Resonance frequency curves of the 1000 µm long MC and the change in resonance frequency with the magnetic field.</p>
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<p>(<b>a</b>) Resonance frequency curves of the 1500 µm long MC and their variation with the magnetic field. (<b>b</b>) Resonance frequency as a function of the applied magnetic field.</p>
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<p>Measurement of the sample’s resonance frequency using phase angle. The resonance frequency was measured at different magnetic field values between 100 and 1200 A/m.</p>
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<p>Variation in MC resonance frequency with 1/L<sup>2</sup>. The red line is generated using Equation (1) and the black squares are experimental data.</p>
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<p>SEM picture of TiO<sub>2</sub> NTs.</p>
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<p>SEM pictures of the MCs coated with TiO<sub>2</sub> NT.</p>
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<p>The frequency response of the TiO<sub>2</sub>-based NT-coated MC sensor across humidity cycles ranging from 5% RH to 95% RH.</p>
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<p>Variation in the resonance frequency of the MC at 5%, 86%, and 81% RH values.</p>
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<p>Changes in the resonance frequency of the MC at varying RH% levels. The inset illustrates the time-dependent shifts in resonance frequency corresponding to different RH% values.</p>
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19 pages, 12883 KiB  
Article
A Flexible Wearable Sensor for In Situ Non-Destructive Detection of Plant Leaf Transpiration Information
by Zhikang Li, Hanping Mao, Lizhi Li, Yazhou Wei, Yongsheng Yu, Mingxue Zhao and Ze Liu
Agriculture 2024, 14(12), 2174; https://doi.org/10.3390/agriculture14122174 - 28 Nov 2024
Viewed by 539
Abstract
This paper investigates an in situ, non-destructive detection sensor based on flexible wearable technology that can reflect the intensity of plant transpiration. The sensor integrates four components: a flexible substrate, a humidity-sensing element, a temperature-sensing element, and a self-adhesive film. It is capable [...] Read more.
This paper investigates an in situ, non-destructive detection sensor based on flexible wearable technology that can reflect the intensity of plant transpiration. The sensor integrates four components: a flexible substrate, a humidity-sensing element, a temperature-sensing element, and a self-adhesive film. It is capable of accurately and continuously measuring the temperature, humidity, and vapor pressure deficit (VPD) on the leaf surface, thus providing information on plant transpiration. We combined the humidity-sensitive material graphene oxide (GO) with a PDMS-GO-SDS flexible substrate as the humidity-sensing element of the sensor. This element exhibits high sensitivity, fast response, and excellent biocompatibility with plant interfaces. The humidity monitoring sensitivity of the sensor reaches 4456 pF/% RH, while the temperature sensing element has a sensitivity of approximately 3.93 Ω/°C. Additionally, tracking tests were conducted on tomato plants in a natural environment, and the experimental results were consistent with related research findings. This sensor can be used to monitor plant growth during agricultural production and facilitate precise crop management, helping to advance smart agriculture in the Internet of Things (IoT) for plants. Full article
(This article belongs to the Section Digital Agriculture)
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<p>(<b>a</b>) Schematic diagram of the flexible substrate preparation process. (<b>b</b>) Schematic diagram of the flexible substrate after curing. (<b>c</b>) Printing process of the interdigitated electrode.</p>
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<p>Schematic diagram of the flexible wearable sensor.</p>
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<p>Schematic of deformation of flexible substrate under different degrees of bending.</p>
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<p>(<b>a</b>) XRD characterization image of the PDMS-GO composite material. (<b>b</b>) FTIR characterization image of the composite material. (<b>c</b>) XPS characterization image of pure PDMS and the composite material.</p>
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<p>(<b>a</b>) SEM image of the cross-section of the composite material. (<b>b</b>) Silicon mapping image of the composite material. (<b>c</b>) Oxygen mapping image of the composite material. (<b>d</b>) Carbon mapping image of the composite material.</p>
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<p>(<b>a</b>) SEM image of the cross-section of the composite material. (<b>b</b>) Silicon mapping image of the composite material. (<b>c</b>) Oxygen mapping image of the composite material. (<b>d</b>) Carbon mapping image of the composite material.</p>
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<p>(<b>a</b>) Permeability testing of the adhesive film. (<b>b</b>) UV transmittance of the PDMS-GO-SDS flexible substrate.</p>
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<p>Influence of humidity on the resistance information of the temperature sensing element at (<b>a</b>) 10 °C, (<b>b</b>) 25 °C, and (<b>c</b>) 40 °C; influence of light intensity on the resistance information of the temperature sensing element at (<b>d</b>) 10 °C, (<b>e</b>) 25 °C, and (<b>f</b>) 40 °C.</p>
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<p>(<b>a</b>) Relationship between the resistance value of the temperature sensing element and temperature. (<b>b</b>) Response curve of the temperature sensing element during rapid temperature changes from 10 °C to 40 °C. (<b>c</b>) Temperature response graph of the temperature sensing element over a long period. (<b>d</b>) Fitting of the resistance value R of the temperature sensing element with temperature T.</p>
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<p>Capacitance response of the humidity-sensing element at 40% RH (normal relative humidity) under different frequencies.</p>
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<p>Capacitive response of the humidity-sensing element under the influence of temperature at (<b>a</b>) 30% RH, (<b>b</b>) 60% RH, and (<b>c</b>) 90% RH; capacitive response of the humidity-sensing element under the influence of light intensity at (<b>d</b>) 30% RH, (<b>e</b>) 60% RH, and (<b>f</b>) 90% RH.</p>
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<p>Capacitive response of the humidity-sensing element under the influence of temperature at (<b>a</b>) 30% RH, (<b>b</b>) 60% RH, and (<b>c</b>) 90% RH; capacitive response of the humidity-sensing element under the influence of light intensity at (<b>d</b>) 30% RH, (<b>e</b>) 60% RH, and (<b>f</b>) 90% RH.</p>
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<p>The capacitance values of humidity-sensing elements using PDMS-GO-SDS and pure PDMS as flexible substrates vary with relative humidity.</p>
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<p>(<b>a</b>) Response curve of the humidity-sensing element during rapid changes from 20% RH to 80% RH. (<b>b</b>) Detection stability of the humidity-sensing element under long-term storage conditions. (<b>c</b>) Fitting of capacitance value C of the humidity-sensing element with relative humidity RH.</p>
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<p>(<b>a</b>) Leaf temperature curves measured by the wearable sensor and the commercial sensor. (<b>b</b>) Leaf surface relative humidity curves measured by the wearable sensor and the commercial sensor. (<b>c</b>) Leaf small environmental air temperature curves measured by the wearable sensor and the commercial sensor. (<b>d</b>) The wearable sensor detecting tomatoes in a real scene.</p>
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<p>(<b>a</b>) Leaf temperature curves measured by the wearable sensor and the commercial sensor. (<b>b</b>) Leaf surface relative humidity curves measured by the wearable sensor and the commercial sensor. (<b>c</b>) Leaf small environmental air temperature curves measured by the wearable sensor and the commercial sensor. (<b>d</b>) The wearable sensor detecting tomatoes in a real scene.</p>
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<p>(<b>a</b>) Detection of leaf and surrounding microenvironment temperature by the wearable sensor. (<b>b</b>) Detection of surface relative humidity of the leaf by the wearable sensor. (<b>c</b>) Detection of leaf <span class="html-italic">VPD<sub>L</sub></span>.</p>
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14 pages, 3964 KiB  
Article
A High-Sensitivity Fiber Optic Soil Moisture Sensor Based on D-Shaped Fiber and Tin Oxide Thin Film Coatings
by Chuen-Lin Tien, Hsi-Fu Shih, Jia-Kai Tien and Ching-Chiun Wang
Sensors 2024, 24(23), 7474; https://doi.org/10.3390/s24237474 - 23 Nov 2024
Viewed by 716
Abstract
We present a high-sensitivity fiber optic soil moisture sensor based on side-polished multimode fibers and lossy mode resonance (LMR). The multimode fibers (MMFs), after side-polishing to form a D-shaped structure, are coated with a single-layer SnO2 thin film by electron beam evaporation [...] Read more.
We present a high-sensitivity fiber optic soil moisture sensor based on side-polished multimode fibers and lossy mode resonance (LMR). The multimode fibers (MMFs), after side-polishing to form a D-shaped structure, are coated with a single-layer SnO2 thin film by electron beam evaporation with ion-assisted deposition technology. The LMR effect can be obtained when the refractive index of the thin film is positive and greater than its extinction coefficient and the real part of the external medium permittivity. The D-shaped fiber optic soil moisture sensor was placed in soil, allowing moisture to penetrate into the thin film microstructure, and it observed the resonance wavelength shift in LMR spectra to measure the relative humidity change in soil. Meanwhile, an Arduino electronic soil moisture sensing module was used as the experimental control group, with soil relative humidity ranging from 10%RH to 90%RH. We found that the D-shaped fiber with a residual thickness of 93 μm and SnO2 thin film thickness of 450 nm had a maximum sensitivity of 2.29 nm/%RH, with relative humidity varying from 10%RH to 90%RH. The D-shaped fiber also demonstrates a fast response time and good reproducibility. Full article
(This article belongs to the Special Issue Imaging and Sensing in Optics and Photonics)
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<p>Schematic diagram of D-shaped multimode fiber structure.</p>
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<p>Microscopy image of D-shaped multimode optical fiber after side-polishing.</p>
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<p>Schematic diagram of LMR phase-matching condition.</p>
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<p>The proposed D-shaped MMF coated with a SnO<sub>2</sub> thin film.</p>
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<p>Cross-sectional view of SEM image of SnO<sub>2</sub> thin film.</p>
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<p>Experimental setup of fiber soil moisture sensor.</p>
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<p>Spectra of soil moisture sensor with single-layer SnO<sub>2</sub> thin film.</p>
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<p>Linear fitting of sensitivity of single-layer SnO<sub>2</sub> film coated on D-shaped fiber.</p>
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<p>A plot of the resonant wavelength of the LMR sensor as a function of time as soil moisture changes from 10% to 90%RH. The pink line is the measured data and the grey line marks the response time.</p>
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<p>The response time of the LMR sensor to soil moisture switching from 10% RH to 50% RH under five soil moisture cycles. The red line is the measurement data, the purple line represents the 1150 nm scale, and the gray line represents the response time.</p>
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17 pages, 3996 KiB  
Article
The Influence of Relative Humidity and Pollution on the Meteorological Optical Range During Rainy and Dry Months in Mexico City
by Blanca Adilen Miranda-Claudes and Guillermo Montero-Martínez
Atmosphere 2024, 15(11), 1382; https://doi.org/10.3390/atmos15111382 - 16 Nov 2024
Viewed by 539
Abstract
The Meteorological Optical Range (MOR) is a measurement of atmospheric visibility. Visibility impairment has been linked to increased aerosol levels in the air. This study conducted statistical analyses using meteorological, air pollutant concentration, and MOR data collected in Mexico City from [...] Read more.
The Meteorological Optical Range (MOR) is a measurement of atmospheric visibility. Visibility impairment has been linked to increased aerosol levels in the air. This study conducted statistical analyses using meteorological, air pollutant concentration, and MOR data collected in Mexico City from August 2014 to December 2015 to determine the factors contributing to haze occurrence (periods when MOR < 10,000 m), defined using a light scatter sensor (PWS100). The outcomes revealed seasonal patterns in PM2.5 and relative humidity (RH) for haze occurrence along the year. PM2.5 levels during hazy periods in the dry season were higher compared to the wet season, aligning with periods of poor air quality (PM2.5 > 45 μg/m3). Pollutant-to-CO ratios suggested that secondary aerosols’ production, led by SO2 conversion to sulfate particles, mainly impacts haze occurrence during the dry season. Meanwhile, during the rainy season, the PWS100 registered haze events even with PM2.5 values close to 15 μg/m3 (considered good air quality). The broadened distribution of extinction efficiency during the wet period and its correlation with RH suggest that aerosol water vapor uptake significantly impacts visibility during this season. Therefore, attributing poor visibility strictly to poor air quality may not be appropriate for all times and locations. Full article
(This article belongs to the Section Meteorology)
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<p>The research methodology overview. Blue boxes represent the main phases/sections of the study, green boxes represent how the analysis was carried out, and the yellow box leads to the discussion of results.</p>
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<p>Time series for Meteorological Optical Range (<span class="html-italic">MOR</span>, black lines), meteorological, and pollutant (PM<sub>2.5</sub>, NO<sub>x</sub>, SO<sub>2</sub>, and CO) measurements from 22 to 23 November 2015. <span class="html-italic">MOR</span> data show a haze event on 23 November 2015. The upper panel (<b>a</b>) shows a comparison between PM<sub>2.5</sub>, NO<sub>x</sub>, and <span class="html-italic">RH</span> (red, blue, and yellow lines, respectively) measurements correlated with <span class="html-italic">MOR</span> data. The bottom panel (<b>b</b>) displays the SO<sub>2</sub>, CO, and <span class="html-italic">WS</span> (orange, blue, and green lines, respectively) estimates during the same period. It is observed that pollutant concentrations show higher levels during the haze occurrence. See more details in the text.</p>
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<p>The correlation matrix showing the relationship between <span class="html-italic">MOR</span> and meteorological and pollutants variables. Bold numbers in the green-colored cells indicate statistically significant results.</p>
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<p>The series of monthly averages of <span class="html-italic">MOR</span>, meteorological, and pollutant measurements obtained for haze (orange) and control (blue) periods. The information is displayed for the months when haze events occurred, so November 2014 and January, March, and October 2015 are missing. The open symbols indicate results obtained for the dry season. Each subfigure shows the comparison for the variables as: (<b>a</b>) <span class="html-italic">MOR</span>, (<b>b</b>) PM<sub>2.5</sub>, (<b>c</b>) <span class="html-italic">RH</span>, (<b>d</b>) NO<sub>x</sub>, (<b>e</b>) <span class="html-italic">WS</span>, (<b>f</b>) SO<sub>2</sub>, and (<b>g</b>) <span class="html-italic">WDIR</span>.</p>
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<p>The dispersion of <span class="html-italic">MOR</span> values, categorized into haze (<span class="html-italic">MOR</span> &lt; 10,000 m, blue points) and non-haze (<span class="html-italic">MOR</span> &gt; 10,000 m, orange points) classes, as a function of <span class="html-italic">RH</span> and PM<sub>2.5</sub> for the dry (<b>left panel</b>) and the precipitating (<b>right panel</b>) seasons.</p>
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<p>The contribution of particulate (PM<sub>2.5</sub>) pollution levels in four visibility ranges during the two chosen precipitation periods. The upper panel shows that bad air quality conditions contribute significantly (up to 60%) to haze occurrence during the low precipitation period.</p>
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<p>Estimates of (<b>a</b>) PM<sub>2.5</sub>/CO (μg/m<sup>3</sup>/ppmv), (<b>b</b>) SO<sub>2</sub>/CO (ppbv/ppmv), and (<b>c</b>) NO<sub>x</sub>/CO (ppbv/ppmv) ratios for two <span class="html-italic">MOR</span> ranges (shown in the <span class="html-italic">x</span>-axis of the bottom panel). Orange and blue bars show the mean values for each ratio during the representative periods of haze and good <span class="html-italic">MOR</span> estimates, respectively. The vertical bars correspond to the standard deviation of the mean values. Under different visibility conditions, these ratios are useful as a proxy for the contribution of gas–particle conversion processes. See details in the text.</p>
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<p>Frequency distributions of the extinction capacity of PM<sub>2.5</sub> per unit mass under diverse <span class="html-italic">RH</span> ranges: (<b>a</b>) 40 % &lt; <span class="html-italic">RH</span> &lt; 60 %, (<b>b</b>) 60 % &lt; <span class="html-italic">RH</span> &lt; 80 %, and (<b>c</b>) 80 % ≤ <span class="html-italic">RH.</span> The obtained distributions are displayed for the dry and rainy seasons.</p>
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<p>Cumulative curves of haze periods as a function of the PM<sub>2.5</sub> levels (<b>a</b>) and <span class="html-italic">RH</span> (<b>b</b>) during the two chosen seasons. The 50% frequency level was used to determine the particulate and moisture threshold values for haze incidence at the sampling site during the rainy and low precipitation seasons.</p>
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12 pages, 809 KiB  
Article
I3oT (Industrializable Industrial Internet of Things) Tool for Continuous Improvement in Production Line Efficiency by Means of Sub-Bottleneck Detection Method
by Javier Llopis, Antonio Lacasa, Nicolás Montés and Eduardo Garcia
Machines 2024, 12(11), 760; https://doi.org/10.3390/machines12110760 - 29 Oct 2024
Viewed by 591
Abstract
The present paper shows how to develop an I3oT (Industrializable Industrial Internet of Things) tool for continuous improvement in production line efficiency by means of the sub-bottleneck detection method. There is a large amount of scientific literature related to the detection of bottlenecks [...] Read more.
The present paper shows how to develop an I3oT (Industrializable Industrial Internet of Things) tool for continuous improvement in production line efficiency by means of the sub-bottleneck detection method. There is a large amount of scientific literature related to the detection of bottlenecks in production lines. However, there is no scientific literature that develops tools to improve production lines based on the bottlenecks that go beyond rebalancing tasks. This article explores the concept of a sub-bottleneck. In order to detect sub-bottlenecks in a massive way, the use of one of the I3oT (Industrializable Industrial Internet of Things) tools developed in our previous work, the mini-terms, is proposed. These mini-terms use the existing sensors for the normal operation of the production lines to measure the sub-cycle times and use them to predict the deterioration of the machine components found in the production lines. The sub-bottleneck algorithms proposed are used in two real twin lines at the Ford manufacturing plant in Almussafes (Valencia), the (3LH) and (3RH), to show how the lines can be continuously improved by means of sub-bottleneck detection. Full article
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<p>From the micro-term to the long-term data.</p>
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<p>Example of mini-term. Green area (without alarm). Red area (With alarm).</p>
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<p>From long-bottlenecks to sub-bottlenecks.</p>
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<p>Production line manufacturing line 3LH.</p>
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<p>Flowchart of lines 3LH and 3RH.</p>
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<p>Cycle time.</p>
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<p>Cycle times and sub-cycle times to detect the bottleneck and sub-bottlenecks, respectively. Numbers in red indicate the maximum time, the bottleneck.</p>
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15 pages, 5926 KiB  
Article
Sodium Alginate/MXene-Based Flexible Humidity Sensors with High-Humidity Durability and Application Potentials in Breath Monitoring and Non-Contact Human–Machine Interfaces
by Huizhen Chen, Xiaodong Huang, Yikai Yang and Yang Li
Nanomaterials 2024, 14(21), 1694; https://doi.org/10.3390/nano14211694 - 23 Oct 2024
Viewed by 916
Abstract
Flexible humidity sensors (FHSs) with fast response times and durability to high-humidity environments are highly desirable for practical applications. Herein, an FHS based on crosslinked sodium alginate (SA) and MXene was fabricated, which exhibited high sensitivity (impedance varied from 107 to 10 [...] Read more.
Flexible humidity sensors (FHSs) with fast response times and durability to high-humidity environments are highly desirable for practical applications. Herein, an FHS based on crosslinked sodium alginate (SA) and MXene was fabricated, which exhibited high sensitivity (impedance varied from 107 to 105 Ω between 10% and 90% RH), good selectivity, prompt response times (response/recover time of 4 s/11 s), high sensing linearity (R2 = 0.992) on a semi-logarithmic scale, relatively small hysteresis (~5% RH), good repeatability, and good resistance to highly humid environments (negligible changes in sensing properties after being placed in 98% RH over 24 h). It is proposed that the formation of the crosslinking structure of SA and the introduction of MXene with good conductivity and a high specific surface area contributed to the high performance of the composite FHS. Moreover, the FHS could promptly differentiate the respiration status, recognize speech, and measure fingertip movement, indicating potential in breath monitoring and non-contact human–machine interactions. This work provides guidance for developing advanced flexible sensors with a wide application scope in wearable electronics. Full article
(This article belongs to the Special Issue Advanced Nanomaterials in Gas and Humidity Sensors)
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<p>Schematic illustration for the preparation of (1) MXene and (2) c-SA/MXene FHS.</p>
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<p>Preparation of IDEs.</p>
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<p>Schematic diagram of humidity testing device.</p>
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<p>SEM images of (<b>a</b>) MAX phase (Ti<sub>3</sub>AlC<sub>2</sub>); (<b>b</b>) MXene; (<b>c</b>) SA; (<b>d</b>) SA/MXene0.5; (<b>e</b>) SA/MXene1; (<b>f</b>) SA/MXene2; (<b>g</b>) c-SA/MXene1-30; IDEs at (<b>h</b>) low magnification and (<b>i</b>) high magnification.</p>
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<p>SEM images of (<b>a</b>) cross section of c-SA/MXene1-30 FHS and (<b>b</b>) c-SA/MXene layer on IDEs at a high magnification scale.</p>
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<p>(<b>a</b>) FTIR spectrum of MXene; ATR-FTIR spectra of (<b>b</b>) SA, SA/MXene1, and c-SA/MXene1-30; (<b>c</b>) PI and PI-A; (<b>d</b>) Raman spectrum of IDEs in PI.</p>
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<p>Humidity sensitive curves of FHS prepared with (<b>a</b>) different concentration of MXene; (<b>b</b>) differ-ent crosslinking time; (<b>c</b>) hysteresis of FHS with different crosslinking time; (<b>d</b>) humidity sensitive curve of c-SA/MXene1-30 FHS; (<b>e</b>) humidity sensitive curve of c-SA/MXene1-30 FHS based on PI substrate without hydrophilic treatment; (<b>f</b>) response and recovery time of c-SA/MXene1-30 FHS.</p>
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<p>(<b>a</b>) Real-time response of the c-SA/MXene1-30 FHS placed in 98% RH for over 9 h; (<b>b</b>) humidity response of the c-SA/MXene1-30 FHS when the FHS was placed in 98% RH of 0 h and 24 h; (<b>c</b>) response of the c-SA/MXene1-30 FHS when exposed to 500 ppm vapors of different analytes: ethanol, ether, methanol, acetone, n-hexane; (<b>d</b>) response of the c-SA/MXene1-30 FHS during cyclic switching between high- and low-humidity environments.</p>
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<p>Nyquist plots of the c-SA/MXene1-30 FHS: (<b>a</b>) under 11 and 33% RH, (<b>b</b>) under 59% RH, (<b>c</b>) under 75 and 98% RH; (<b>d</b>) diagram of proposed sensing mechanism.</p>
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<p>Application of c-SA/MXene1-30 FHS: respiration monitoring under different states: (<b>a</b>) slow speed; (<b>b</b>) normal speed; (<b>c</b>) fast speed; (<b>d</b>) speech recognition; (<b>e</b>) real-time impedance response of distance change between sensor and fingertips.</p>
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13 pages, 3372 KiB  
Article
The Development of a Flexible Humidity Sensor Using MWCNT/PVA Thin Films
by Ana R. Santos and Júlio C. Viana
Nanomaterials 2024, 14(20), 1653; https://doi.org/10.3390/nano14201653 - 15 Oct 2024
Viewed by 1147
Abstract
The exponential demand for real-time monitoring applications has altered the course of sensor development, from sensor electronics miniaturization, e.g., resorting to printing techniques, to low-cost, flexible and functional wearable materials. Humidity sensing has been used in the prevention and diagnosis of medical conditions, [...] Read more.
The exponential demand for real-time monitoring applications has altered the course of sensor development, from sensor electronics miniaturization, e.g., resorting to printing techniques, to low-cost, flexible and functional wearable materials. Humidity sensing has been used in the prevention and diagnosis of medical conditions, as well as in the assessment of physical comfort. This paper presents a resistive flexible humidity sensor composed of silver interdigitated electrodes (IDTs) screen printed onto polyimide film and an active layer of multiwall carbon nanotubes (MWCNT) dispersed in a water-soluble polymer, polyvinyl alcohol (PVA). Different MWCNT/PVA sensor sizes and MWCNT percentages are tested to study their effect on the initial electrical resistance (Ri) values and sensor response at different humidity percentages. The results show that the Ri values decrease with the increase in % MWCNT. The sensor size did not influence the sensor response, while the % MWCNT affected the sensor behavior upon relative humidity (RH) increments. The 1% MWCNT/PVA sensor showed the best response, reaching a relative electrical resistance, ΔR/R0, of 509% at 99% RH. Comparable with other reported sensors, the produced MWCNT/PVA flexible sensor is simpler, greener and shows a good sensitivity to humidity, being easily incorporated in wearable monitoring applications, from sports to medical fields. Full article
(This article belongs to the Special Issue Advanced Nanomaterials for Soft and Wearable Electronics)
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<p>Schematics of the screen-printed interdigitated electrodes (IDTs) with different sizes: large, medium and small. Dimensions in millimeters (mm).</p>
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<p>Schematics of the MWCNT/PVA-based humidity sensor production process.</p>
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<p>(<b>a</b>) Initial electrical resistance of the MWCNT/PVA sensors with different sizes: small (♦), medium (●) and large (■); (<b>b</b>) area ratio for the three sensor sizes.</p>
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<p>Relative electrical resistance variation, ΔR/R<sub>0</sub>, of the 0.5% MWCNT/PVA samples (three sizes: large—●, medium—■ and small—♦) vs. relative humidity (RH). Inset shows the amplified ΔR/R<sub>0</sub> curves at lower RH% levels.</p>
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<p>SEM characterization of the MWCNT/PVA with different MWCNT percentages: (<b>a</b>,<b>a<sub>1</sub></b>) 1% MWCNT; (<b>b</b>,<b>b<sub>1</sub></b>) 0.5% MWCNT; (<b>c</b>,<b>c<sub>1</sub></b>) 0.4% MWCNT; (<b>d</b>,<b>d<sub>1</sub></b>) 0.25% MWCNT, with 5000× and 500,000× magnification, respectively.</p>
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<p>Variation in the initial electrical resistance of the MWCNT/PVA samples with % MWCNT.</p>
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<p>Electrical resistance behavior of PVA matrix, individual MWCNTs and the MWCNT/PVA upon RH increment.</p>
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<p>Relative electrical resistance, ΔR/R<sub>0</sub>, of MWCNT/PVA samples: 1% MWCNT (▲) and 0.5% MWCNT (●) vs. relative humidity (RH). Inset shows the amplified ΔR/R<sub>0</sub> curves at lower RH% levels.</p>
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<p>Influence of % MWCNT on the MWCNT/PVA sensor’s response upon an increase in RH: (<b>a</b>) relative electrical resistance, ΔR/R<sub>0</sub>, of high % MWCNT sensor; (<b>b</b>) relative electrical resistance, ΔR/R<sub>0</sub>, of low % MWCNT sensor and (<b>c</b>) comparison of electrical resistance behavior of MWCNT/PVA sensors.</p>
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<p>Relative electrical resistance, ΔR/R<sub>0</sub>, of MWCNT/PVA samples: 0.4% MWCNT (■) and 0.25% MWCNT (♦) vs. relative humidity (RH).</p>
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13 pages, 3334 KiB  
Article
Gelatin-Coated High-Sensitivity Microwave Sensor for Humidity-Sensing Applications
by Junho Yeo and Younghwan Kwon
Sensors 2024, 24(19), 6286; https://doi.org/10.3390/s24196286 - 28 Sep 2024
Cited by 1 | Viewed by 740
Abstract
In this paper, the humidity-sensing characteristics of gelatin were compared with those of poly(vinyl alcohol) (PVA) at L-band (1 ~ 2 GHz) microwave frequencies. A capacitive microwave sensor based on a defected ground structure with a modified interdigital capacitor (DGS-MIDC) in a microstrip [...] Read more.
In this paper, the humidity-sensing characteristics of gelatin were compared with those of poly(vinyl alcohol) (PVA) at L-band (1 ~ 2 GHz) microwave frequencies. A capacitive microwave sensor based on a defected ground structure with a modified interdigital capacitor (DGS-MIDC) in a microstrip transmission line operating at 1.5 GHz without any coating was used. Gelatin is a natural polymer based on protein sourced from animal collagen, whereas PVA is a high-sensitivity hydrophilic polymer that is widely used for humidity sensors and has a good film-forming property. Two DGS-MIDC-based microwave sensors coated with type A gelatin and PVA, respectively, with a thickness of 0.02 mm were fabricated. The percent relative frequency shift (PRFS) and percent relative magnitude shift (PRMS) based on the changes in the resonant frequency and magnitude level of the transmission coefficient for the microwave sensor were used to compare the humidity-sensing characteristics. The relative humidity (RH) was varied from 50% to 80% with a step of 10% at a fixed temperature of around 25 °C using a low-reflective temperature and humidity chamber manufactured with Styrofoam. The experiment’s results show that the capacitive humidity sensitivity of the gelatin-coated microwave sensor in terms of the PRFS and PRMS was higher compared to that of the PVA-coated one. In particular, the sensitivity of the gelatin-coated microwave sensor at a low RH from 50% to 60% was much greater compared to that of the PVA-coated one. In addition, the relative permittivity of the fabricated microwave sensors coated with PVA and gelatin was extracted by using the measured PRFS and the equation was derived by curve-fitting the simulated results. The change in the extracted relative permittivity for the gelatin-coated microwave sensor was larger than that of the PVA-coated one for varying the RH. Full article
(This article belongs to the Special Issue RF and IoT Sensors: Design, Optimization and Applications)
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<p>Chemical structures of (<b>a</b>) PVA and (<b>b</b>) gelatin.</p>
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<p>DGS-MIDC-based microwave sensor: (<b>a</b>) geometry, (<b>b</b>) electric-field distribution at 1.5 GHz, and (<b>c</b>) S-parameter characteristics and simplified equivalent circuit model.</p>
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<p>Performance characteristics of the DGS-MIDC-based microwave sensor for varying relative permittivity of the coated polymer with tan <span class="html-italic">δ</span> = 0: (<b>a</b>) S<sub>21</sub>, (<b>b</b>) <span class="html-italic">f</span><sub>r</sub>, and (<b>c</b>) PRFS.</p>
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<p>Extracted equivalent circuit parameters of the DGS-MIDC-based microwave sensor for varying relative permittivity of the coated polymer with tan <span class="html-italic">δ</span> = 0: (<b>a</b>) <span class="html-italic">C</span><sub>1</sub>; (<b>b</b>) <span class="html-italic">L</span><sub>1</sub>; (<b>c</b>) Δ<span class="html-italic">C</span><sub>1</sub>/<span class="html-italic">C</span><sub>1</sub>(%) and (<b>d</b>) Δ<span class="html-italic">L</span><sub>1</sub>/<span class="html-italic">L</span><sub>1</sub>(%).</p>
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<p>Photographs of the fabricated microwave sensors coated with (<b>a</b>) PVA and (<b>b</b>) gelatin.</p>
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<p>Block diagram and photographs of the experiment setup for the humidity-sensing measurements: (<b>a</b>) block diagram, (<b>b</b>) experiment setup with an open-top cover, and (<b>c</b>) experiment setup with closed-top cover.</p>
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<p>Measured S<sub>21</sub> characteristics of the fabricated microwave sensors coated with the polymers for varying RH. (<b>a</b>) PVA and (<b>b</b>) gelatin.</p>
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<p>Performance comparison of the fabricated microwave sensors coated with the polymers for varying RH. (<b>a</b>) <span class="html-italic">f</span><sub>r</sub>, (<b>b</b>) PRFS, (<b>c</b>) S<sub>21</sub> magnitude, and (<b>d</b>) PRMS.</p>
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<p>Comparison of the extracted relative permittivity from measured PRFSs of PVA- and gelatin-coated microwave sensors for varying RH.</p>
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