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Entropy, Volume 27, Issue 1 (January 2025) – 96 articles

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21 pages, 2867 KiB  
Article
A Resource-Efficient Multi-Entropy Fusion Method and Its Application for EEG-Based Emotion Recognition
by Jiawen Li, Guanyuan Feng, Chen Ling, Ximing Ren, Xin Liu, Shuang Zhang, Leijun Wang, Yanmei Chen, Xianxian Zeng and Rongjun Chen
Entropy 2025, 27(1), 96; https://doi.org/10.3390/e27010096 (registering DOI) - 20 Jan 2025
Abstract
Emotion recognition is an advanced technology for understanding human behavior and psychological states, with extensive applications for mental health monitoring, human–computer interaction, and affective computing. Based on electroencephalography (EEG), the biomedical signals naturally generated by the brain, this work proposes a resource-efficient multi-entropy [...] Read more.
Emotion recognition is an advanced technology for understanding human behavior and psychological states, with extensive applications for mental health monitoring, human–computer interaction, and affective computing. Based on electroencephalography (EEG), the biomedical signals naturally generated by the brain, this work proposes a resource-efficient multi-entropy fusion method for classifying emotional states. First, Discrete Wavelet Transform (DWT) is applied to extract five brain rhythms, i.e., delta, theta, alpha, beta, and gamma, from EEG signals, followed by the acquisition of multi-entropy features, including Spectral Entropy (PSDE), Singular Spectrum Entropy (SSE), Sample Entropy (SE), Fuzzy Entropy (FE), Approximation Entropy (AE), and Permutation Entropy (PE). Then, such entropies are fused into a matrix to represent complex and dynamic characteristics of EEG, denoted as the Brain Rhythm Entropy Matrix (BREM). Next, Dynamic Time Warping (DTW), Mutual Information (MI), the Spearman Correlation Coefficient (SCC), and the Jaccard Similarity Coefficient (JSC) are applied to measure the similarity between the unknown testing BREM data and positive/negative emotional samples for classification. Experiments were conducted using the DEAP dataset, aiming to find a suitable scheme regarding similarity measures, time windows, and input numbers of channel data. The results reveal that DTW yields the best performance in similarity measures with a 5 s window. In addition, the single-channel input mode outperforms the single-region mode. The proposed method achieves 84.62% and 82.48% accuracy in arousal and valence classification tasks, respectively, indicating its effectiveness in reducing data dimensionality and computational complexity while maintaining an accuracy of over 80%. Such performances are remarkable when considering limited data resources as a concern, which opens possibilities for an innovative entropy fusion method that can help to design portable EEG-based emotion-aware devices for daily usage. Full article
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Figure 1

Figure 1
<p>The overall framework of the proposed resource-efficient multi-entropy fusion method for EEG-based emotion recognition.</p>
Full article ">Figure 2
<p>Channel and region locations in DEAP: (<b>a</b>) 32 EEG channels; (<b>b</b>) five brain regions.</p>
Full article ">Figure 3
<p>The 4-level DWT extracts five brain rhythms from emotional EEG signals.</p>
Full article ">Figure 4
<p>Two examples of ANOVA test box plots for the best entropy features that provide the highest accuracy from subject S1 in the DEAP dataset. (<b>a</b>) The alpha sample entropy (<span class="html-italic">α<sub>SE</sub></span>) in the P7 channel for arousal classification; (<b>b</b>) the beta singular-spectrum entropy (<span class="html-italic">β<sub>SSE</sub></span>) in the O2 channel for valence classification.</p>
Full article ">Figure 5
<p>Statistical frequency of the optimal time segment (s) for 32 subjects from the DEAP dataset: (<b>a</b>) arousal classification; (<b>b</b>) valence classification.</p>
Full article ">Figure 6
<p>Word clouds of the representative channels for 32 subjects from the DEAP dataset: (<b>a</b>) arousal classification; (<b>b</b>) valence classification.</p>
Full article ">
20 pages, 1226 KiB  
Article
Discontinuous Structural Transitions in Fluids with Competing Interactions
by Ana M. Montero, Santos B. Yuste, Andrés Santos and Mariano López de Haro
Entropy 2025, 27(1), 95; https://doi.org/10.3390/e27010095 (registering DOI) - 20 Jan 2025
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Abstract
This paper explores how competing interactions in the intermolecular potential of fluids affect their structural transitions. This study employs a versatile potential model with a hard core followed by two constant steps, representing wells or shoulders, analyzed in both one-dimensional (1D) and three-dimensional [...] Read more.
This paper explores how competing interactions in the intermolecular potential of fluids affect their structural transitions. This study employs a versatile potential model with a hard core followed by two constant steps, representing wells or shoulders, analyzed in both one-dimensional (1D) and three-dimensional (3D) systems. Comparing these dimensionalities highlights the effect of confinement on structural transitions. Exact results are derived for 1D systems, while the rational function approximation is used for unconfined 3D fluids. Both scenarios confirm that when the steps are repulsive, the wavelength of the oscillatory decay of the total correlation function evolves with temperature either continuously or discontinuously. In the latter case, a discontinuous oscillation crossover line emerges in the temperature–density plane. For an attractive first step and a repulsive second step, a Fisher–Widom line appears. Although the 1D and 3D results share common features, dimensionality introduces differences: these behaviors occur in distinct temperature ranges, require deeper wells, or become attenuated in 3D. Certain features observed in 1D may vanish in 3D. We conclude that fluids with competing interactions exhibit a rich and intricate pattern of structural transitions, demonstrating the significant influence of dimensionality and interaction features. Full article
(This article belongs to the Special Issue Dimensional Crossover in Classical and Quantum Systems)
Show Figures

Figure 1

Figure 1
<p>DOC lines on the <math display="inline"><semantics> <msup> <mi>T</mi> <mo>*</mo> </msup> </semantics></math> vs. <math display="inline"><semantics> <msup> <mi>ρ</mi> <mo>*</mo> </msup> </semantics></math> plane for the 1D case with <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>=</mo> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> </mrow> </semantics></math>: (<b>a</b>) <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>2</mn> <mo>,</mo> <mn>1.9</mn> </mrow> </semantics></math>, (<b>b</b>) <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1.8</mn> <mo>,</mo> <mn>1.7</mn> </mrow> </semantics></math>, and (<b>c</b>) <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1.6</mn> <mo>,</mo> <mn>1.5</mn> </mrow> </semantics></math>. Insets display the angular frequency of the asymptotic oscillations of <math display="inline"><semantics> <mrow> <mi>h</mi> <mo>(</mo> <mi>r</mi> <mo>)</mo> </mrow> </semantics></math> as a function of <math display="inline"><semantics> <msup> <mi>T</mi> <mo>*</mo> </msup> </semantics></math> for (<b>a</b>) <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1.9</mn> </mrow> </semantics></math> at <math display="inline"><semantics> <mrow> <msup> <mi>ρ</mi> <mo>*</mo> </msup> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math>, (<b>b</b>) <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1.7</mn> </mrow> </semantics></math> at <math display="inline"><semantics> <mrow> <msup> <mi>ρ</mi> <mo>*</mo> </msup> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math>, and (<b>c</b>) <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1.6</mn> </mrow> </semantics></math> at <math display="inline"><semantics> <mrow> <msup> <mi>ρ</mi> <mo>*</mo> </msup> <mo>=</mo> <mn>0.8</mn> </mrow> </semantics></math>. The circles in panel (<b>b</b>) represent the four states examined in <a href="#entropy-27-00095-f002" class="html-fig">Figure 2</a> for <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1.7</mn> </mrow> </semantics></math>.</p>
Full article ">Figure 2
<p>A logarithmic plot of <math display="inline"><semantics> <mrow> <mo stretchy="false">|</mo> <mi>h</mi> <mo>(</mo> <mi>r</mi> <mo>)</mo> <mo stretchy="false">|</mo> </mrow> </semantics></math> for large <span class="html-italic">r</span> in the 1D case <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>=</mo> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1.7</mn> </mrow> </semantics></math>, for the following states: (<b>a</b>) <math display="inline"><semantics> <mrow> <mrow> <mo>(</mo> <msup> <mi>ρ</mi> <mo>*</mo> </msup> <mo>,</mo> <msup> <mi>T</mi> <mo>*</mo> </msup> <mo>)</mo> </mrow> <mo>=</mo> <mrow> <mo>(</mo> <mn>0.55</mn> <mo>,</mo> <mn>1</mn> <mo>)</mo> </mrow> </mrow> </semantics></math>, (<b>b</b>) <math display="inline"><semantics> <mrow> <mrow> <mo>(</mo> <msup> <mi>ρ</mi> <mo>*</mo> </msup> <mo>,</mo> <msup> <mi>T</mi> <mo>*</mo> </msup> <mo>)</mo> </mrow> <mo>=</mo> <mrow> <mo>(</mo> <mn>0.55</mn> <mo>,</mo> <mn>3</mn> <mo>)</mo> </mrow> </mrow> </semantics></math>, (<b>c</b>) <math display="inline"><semantics> <mrow> <mrow> <mo>(</mo> <msup> <mi>ρ</mi> <mo>*</mo> </msup> <mo>,</mo> <msup> <mi>T</mi> <mo>*</mo> </msup> <mo>)</mo> </mrow> <mo>=</mo> <mrow> <mo>(</mo> <mn>0.55</mn> <mo>,</mo> <mn>5</mn> <mo>)</mo> </mrow> </mrow> </semantics></math>, and (<b>d</b>) <math display="inline"><semantics> <mrow> <mrow> <mo>(</mo> <msup> <mi>ρ</mi> <mo>*</mo> </msup> <mo>,</mo> <msup> <mi>T</mi> <mo>*</mo> </msup> <mo>)</mo> </mrow> <mo>=</mo> <mrow> <mo>(</mo> <mn>0.8</mn> <mo>,</mo> <mn>0.05</mn> <mo>)</mo> </mrow> </mrow> </semantics></math>. These states are labeled A–D in <a href="#entropy-27-00095-f001" class="html-fig">Figure 1</a>b, respectively.</p>
Full article ">Figure 3
<p>DOC lines on the <math display="inline"><semantics> <msup> <mi>T</mi> <mo>*</mo> </msup> </semantics></math> vs. <math display="inline"><semantics> <msup> <mi>ρ</mi> <mo>*</mo> </msup> </semantics></math> plane for the 1D case with <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>1</mn> </msub> <mo>=</mo> <mn>1.35</mn> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1.7</mn> </mrow> </semantics></math>: (<b>a</b>) <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>/</mo> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> <mn>0.5</mn> </mrow> </semantics></math>, (<b>b</b>) <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>=</mo> <mn>0</mn> </mrow> </semantics></math>, and (<b>c</b>) <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>/</mo> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> <mo>=</mo> <mo>−</mo> <mn>0.5</mn> <mo>,</mo> <mo>−</mo> <mn>1</mn> </mrow> </semantics></math>. Insets display the angular frequency of the asymptotic oscillations of <math display="inline"><semantics> <mrow> <mi>h</mi> <mo>(</mo> <mi>r</mi> <mo>)</mo> </mrow> </semantics></math> as a function of <math display="inline"><semantics> <msup> <mi>T</mi> <mo>*</mo> </msup> </semantics></math> for (<b>a</b>) <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>/</mo> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math> at <math display="inline"><semantics> <mrow> <msup> <mi>ρ</mi> <mo>*</mo> </msup> <mo>=</mo> <mn>0.45</mn> </mrow> </semantics></math>, (<b>b</b>) <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>=</mo> <mn>0</mn> </mrow> </semantics></math> at <math display="inline"><semantics> <mrow> <msup> <mi>ρ</mi> <mo>*</mo> </msup> <mo>=</mo> <mn>0.22</mn> </mrow> </semantics></math>, and (<b>c</b>) <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>/</mo> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> <mo>=</mo> <mo>−</mo> <mn>1</mn> </mrow> </semantics></math> at <math display="inline"><semantics> <mrow> <msup> <mi>ρ</mi> <mo>*</mo> </msup> <mo>=</mo> <mn>0.22</mn> </mrow> </semantics></math>.</p>
Full article ">Figure 4
<p>(<b>a</b>) FW lines on the <math display="inline"><semantics> <msup> <mi>T</mi> <mo>*</mo> </msup> </semantics></math> vs. <math display="inline"><semantics> <msup> <mi>ρ</mi> <mo>*</mo> </msup> </semantics></math> plane for the 1D case <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>1</mn> </msub> <mo>=</mo> <mn>1.35</mn> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1.7</mn> </mrow> </semantics></math> with, from the bottom to top, <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>/</mo> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> <mo>=</mo> <mo>−</mo> <mn>0.5</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mo>−</mo> <mn>1</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mo>−</mo> <mn>2</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mo>−</mo> <mn>4</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mo>−</mo> <mn>10</mn> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <mo>−</mo> <mn>100</mn> </mrow> </semantics></math>. (<b>b</b>) The same as in panel (<b>a</b>), except that now the vertical axis represents the scaled temperature <math display="inline"><semantics> <mrow> <msubsup> <mi>T</mi> <mn>1</mn> <mo>*</mo> </msubsup> <mo>=</mo> <msub> <mi>k</mi> <mi>B</mi> </msub> <mrow> <mi>T</mi> <mo>/</mo> <mo stretchy="false">|</mo> </mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mrow> <mo stretchy="false">|</mo> <mo>=</mo> </mrow> <msup> <mi>T</mi> <mo>*</mo> </msup> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> <mo>/</mo> <mrow> <mo stretchy="false">|</mo> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo stretchy="false">|</mo> </mrow> </mrow> </semantics></math>. The dotted curve is the FW line for a pure square-well fluid (<math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>0</mn> </mrow> </semantics></math>). Note that in panel (<b>b</b>) the curves corresponding to <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>/</mo> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> <mo>=</mo> <mo>−</mo> <mn>0.5</mn> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mo>−</mo> <mn>1</mn> </mrow> </semantics></math> are indistinguishable.</p>
Full article ">Figure 5
<p>(<b>a</b>) DOC lines on the <math display="inline"><semantics> <msup> <mi>T</mi> <mo>*</mo> </msup> </semantics></math> vs. <math display="inline"><semantics> <msup> <mi>ρ</mi> <mo>*</mo> </msup> </semantics></math> plane for the 3D case <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>=</mo> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> </mrow> </semantics></math> with <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1.55</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>1.6</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>1.65</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>1.7</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>1.75</mn> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <mn>1.8</mn> </mrow> </semantics></math>. The inset shows the loop corresponding to <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1.55</mn> </mrow> </semantics></math>. (<b>b</b>) The angular frequency of the asymptotic oscillations of <math display="inline"><semantics> <mrow> <mi>h</mi> <mo>(</mo> <mi>r</mi> <mo>)</mo> </mrow> </semantics></math> plotted as a function of <math display="inline"><semantics> <msup> <mi>T</mi> <mo>*</mo> </msup> </semantics></math> for <math display="inline"><semantics> <mrow> <msup> <mi>ρ</mi> <mo>*</mo> </msup> <mo>=</mo> <mn>0.05</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>0.1</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>0.15</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>0.2</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>0.25</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>0.3</mn> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <mn>0.4</mn> </mrow> </semantics></math>, with an interaction potential characterized by <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>=</mo> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1.7</mn> </mrow> </semantics></math>. The arrows indicate the direction of increasing (<b>a</b>) <math display="inline"><semantics> <msub> <mi>λ</mi> <mn>2</mn> </msub> </semantics></math> and (<b>b</b>) <math display="inline"><semantics> <msup> <mi>ρ</mi> <mo>*</mo> </msup> </semantics></math>.</p>
Full article ">Figure 6
<p>(<b>a</b>) DOC lines on the <math display="inline"><semantics> <msup> <mi>T</mi> <mo>*</mo> </msup> </semantics></math> vs. <math display="inline"><semantics> <msup> <mi>ρ</mi> <mo>*</mo> </msup> </semantics></math> plane for the 3D case <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>1</mn> </msub> <mo>=</mo> <mn>1.35</mn> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1.7</mn> </mrow> </semantics></math> with, from right to left, <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>/</mo> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>2.5</mn> </mrow> </semantics></math>, 2, 1, <math display="inline"><semantics> <mrow> <mn>0.5</mn> </mrow> </semantics></math>, 0, <math display="inline"><semantics> <mrow> <mo>−</mo> <mn>0.5</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mo>−</mo> <mn>0.75</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mo>−</mo> <mn>1</mn> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <mo>−</mo> <mn>2</mn> </mrow> </semantics></math>. The inset shows the loop corresponding to <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>/</mo> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> <mo>=</mo> <mo>−</mo> <mn>0.75</mn> </mrow> </semantics></math>. (<b>b</b>) The angular frequency of the asymptotic oscillations of <math display="inline"><semantics> <mrow> <mi>h</mi> <mo>(</mo> <mi>r</mi> <mo>)</mo> </mrow> </semantics></math> plotted as a function of <math display="inline"><semantics> <msup> <mi>T</mi> <mo>*</mo> </msup> </semantics></math> for <math display="inline"><semantics> <mrow> <msup> <mi>ρ</mi> <mo>*</mo> </msup> <mo>=</mo> <mn>0.04</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>0.13</mn> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <mn>0.14</mn> </mrow> </semantics></math>, with an interaction potential characterized by <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>/</mo> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> <mo>=</mo> <mo>−</mo> <mn>0.75</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>1</mn> </msub> <mo>=</mo> <mn>1.35</mn> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1.7</mn> </mrow> </semantics></math>. The circles in panel (<b>a</b>) represent the two states examined in <a href="#entropy-27-00095-f007" class="html-fig">Figure 7</a> for <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>/</mo> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> <mo>=</mo> <mo>−</mo> <mn>0.5</mn> </mrow> </semantics></math>.</p>
Full article ">Figure 7
<p>A logarithmic plot of <math display="inline"><semantics> <mrow> <mi>r</mi> <mo stretchy="false">|</mo> <mi>h</mi> <mo>(</mo> <mi>r</mi> <mo>)</mo> <mo stretchy="false">|</mo> </mrow> </semantics></math> in the 3D case <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>/</mo> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> <mo>=</mo> <mo>−</mo> <mn>0.5</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>1</mn> </msub> <mo>=</mo> <mn>1.35</mn> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1.7</mn> </mrow> </semantics></math>, for the following states: (<b>a</b>) <math display="inline"><semantics> <mrow> <mrow> <mo>(</mo> <msup> <mi>ρ</mi> <mo>*</mo> </msup> <mo>,</mo> <msup> <mi>T</mi> <mo>*</mo> </msup> <mo>)</mo> </mrow> <mo>=</mo> <mrow> <mo>(</mo> <mn>0.05</mn> <mo>,</mo> <mn>0.6</mn> <mo>)</mo> </mrow> </mrow> </semantics></math> and (<b>b</b>) <math display="inline"><semantics> <mrow> <mrow> <mo>(</mo> <msup> <mi>ρ</mi> <mo>*</mo> </msup> <mo>,</mo> <msup> <mi>T</mi> <mo>*</mo> </msup> <mo>)</mo> </mrow> <mo>=</mo> <mrow> <mo>(</mo> <mn>0.25</mn> <mo>,</mo> <mn>0.6</mn> <mo>)</mo> </mrow> </mrow> </semantics></math>. These states are labeled A and B in <a href="#entropy-27-00095-f006" class="html-fig">Figure 6</a>a, respectively. The solid lines illustrate the values derived from numerical Laplace inversion, whereas the dashed lines depict the asymptotic expression <math display="inline"><semantics> <mrow> <mrow> <mi>r</mi> <mo stretchy="false">|</mo> <mi>h</mi> <mrow> <mo>(</mo> <mi>r</mi> <mo>)</mo> </mrow> <mo stretchy="false">|</mo> </mrow> <mo>=</mo> <mn>2</mn> <msup> <mi>e</mi> <mrow> <mo>−</mo> <mi>ζ</mi> <mi>r</mi> </mrow> </msup> <mrow> <mo stretchy="false">|</mo> <msub> <mi>A</mi> <mi>ζ</mi> </msub> <mo form="prefix">cos</mo> <mrow> <mo>(</mo> <mi>ω</mi> <mi>r</mi> <mo>+</mo> <mi>δ</mi> <mo>)</mo> </mrow> <mo stretchy="false">|</mo> </mrow> </mrow> </semantics></math>, where <math display="inline"><semantics> <mrow> <mi>s</mi> <mo>=</mo> <mo>−</mo> <mi>ζ</mi> <mo>±</mo> <mo>ı</mo> <mi>ω</mi> </mrow> </semantics></math> denotes the leading pole of <math display="inline"><semantics> <mrow> <mi>G</mi> <mo>(</mo> <mi>s</mi> <mo>)</mo> </mrow> </semantics></math>.</p>
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<p>(<b>a</b>) FW lines on the <math display="inline"><semantics> <msup> <mi>T</mi> <mo>*</mo> </msup> </semantics></math> vs. <math display="inline"><semantics> <msup> <mi>ρ</mi> <mo>*</mo> </msup> </semantics></math> plane for the 3D case <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>1</mn> </msub> <mo>=</mo> <mn>1.35</mn> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1.7</mn> </mrow> </semantics></math> with, from the bottom to top, <math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo>/</mo> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> <mo>=</mo> <mo>−</mo> <mn>4</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mo>−</mo> <mn>8</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mo>−</mo> <mn>20</mn> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <mo>−</mo> <mn>50</mn> </mrow> </semantics></math>. (<b>b</b>) The same as in panel (<b>a</b>), except that now the vertical axis represents the scaled temperature <math display="inline"><semantics> <mrow> <msubsup> <mi>T</mi> <mn>1</mn> <mo>*</mo> </msubsup> <mo>=</mo> <msub> <mi>k</mi> <mi>B</mi> </msub> <mrow> <mi>T</mi> <mo>/</mo> <mo stretchy="false">|</mo> </mrow> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mrow> <mo stretchy="false">|</mo> <mo>=</mo> </mrow> <msup> <mi>T</mi> <mo>*</mo> </msup> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> <mo>/</mo> <mrow> <mo stretchy="false">|</mo> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo stretchy="false">|</mo> </mrow> </mrow> </semantics></math>. The dotted line is the FW line for a pure square-well fluid (<math display="inline"><semantics> <mrow> <msub> <mi>ϵ</mi> <mn>2</mn> </msub> <mo>/</mo> <mrow> <mo stretchy="false">|</mo> <msub> <mi>ϵ</mi> <mn>1</mn> </msub> <mo stretchy="false">|</mo> </mrow> <mo>=</mo> <mn>0</mn> </mrow> </semantics></math>).</p>
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<p>Density dependence of (<b>a</b>) <math display="inline"><semantics> <mrow> <msub> <mi>ζ</mi> <mi>HR</mi> </msub> <mrow> <mo>(</mo> <msup> <mi>ρ</mi> <mo>*</mo> </msup> <mo>)</mo> </mrow> </mrow> </semantics></math> and (<b>b</b>) <math display="inline"><semantics> <mrow> <msub> <mi>ω</mi> <mi>HR</mi> </msub> <mrow> <mo>(</mo> <msup> <mi>ρ</mi> <mo>*</mo> </msup> <mo>)</mo> </mrow> </mrow> </semantics></math>.</p>
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23 pages, 2995 KiB  
Article
Novel Ensemble Approach with Incremental Information Level and Improved Evidence Theory for Attribute Reduction
by Peng Yu, Yifeng Zheng, Ziwen Liu, Baoya Wei, Wenjie Zhang, Ziqiong Lin and Zhehan Li
Entropy 2025, 27(1), 94; https://doi.org/10.3390/e27010094 (registering DOI) - 20 Jan 2025
Viewed by 35
Abstract
With the development of intelligent technology, data in practical applications show exponential growth in quantity and scale. Extracting the most distinguished attributes from complex datasets becomes a crucial problem. The existing attribute reduction approaches focus on the correlation between attributes and labels without [...] Read more.
With the development of intelligent technology, data in practical applications show exponential growth in quantity and scale. Extracting the most distinguished attributes from complex datasets becomes a crucial problem. The existing attribute reduction approaches focus on the correlation between attributes and labels without considering the redundancy. To address the above problem, we propose an ensemble approach based on an incremental information level and improved evidence theory for attribute reduction (IILE). Firstly, the incremental information level reduction measure comprehensively assesses attributes based on reduction capability and redundancy level. Then, an improved evidence theory and approximate reduction methods are employed to fuse multiple reduction results, thereby obtaining an approximately globally optimal and a most representative subset of attributes. Eventually, using different metrics, experimental comparisons are performed on eight datasets to confirm that our proposal achieved better than other methods. The results show that our proposal can obtain more relevant attribute sets by using the incremental information level and improved evidence theory. Full article
(This article belongs to the Section Information Theory, Probability and Statistics)
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Figure 1
<p>Flow chart of IILE.</p>
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<p>Comparison of accuracy between IILE and IIL on KNN.</p>
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<p>Comparison of accuracy between IILE and IIL on SVM.</p>
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<p>Comparison of accuracy between IILE and IIL on CART.</p>
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<p>Comparison of reduced rate between IILE and IIL.</p>
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<p>KNN critical difference graph.</p>
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<p>SVM critical difference graph.</p>
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<p>CART critical difference graph.</p>
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<p>Average critical difference graph.</p>
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5 pages, 166 KiB  
Editorial
Nonadditive Entropies and Nonextensive Statistical Mechanics
by Ugur Tirnakli
Entropy 2025, 27(1), 93; https://doi.org/10.3390/e27010093 (registering DOI) - 20 Jan 2025
Viewed by 135
Abstract
The centennial Boltzmann–Gibbs statistical mechanics [...] Full article
26 pages, 27819 KiB  
Article
Spatiotemporal Evolution of the Water System’s Structure and Its Relationship with Urban System Based on Fractal Dimension: A Case Study of the Huaihe River Basin, China
by Hailong Yu, Bin Yu, Xiangmin Zhang, Yong Fan, Sai Wen and Shanshan Jiao
Entropy 2025, 27(1), 92; https://doi.org/10.3390/e27010092 (registering DOI) - 20 Jan 2025
Viewed by 168
Abstract
The formation and development of cities are inseparable from a certain scale of water resources. The information contained in the morphological structures of cities and water systems is often overlooked. Exploring the spatiotemporal evolution of water system structures (WSS) and urban system structures [...] Read more.
The formation and development of cities are inseparable from a certain scale of water resources. The information contained in the morphological structures of cities and water systems is often overlooked. Exploring the spatiotemporal evolution of water system structures (WSS) and urban system structures (USS) can reveal the “urban–water” relationship from a new perspective. The Huaihe River Basin (HRB) was selected as the case area, based on the theory of fractal dimensions, grid dimension and multifractal spectrum methods were used to depict the structural evolutionary characteristics of water systems and urban systems from different dimensions. Then, through a comparative analysis of fractal parameters and spectral lines, the characteristics and changing patterns of the “urban-water” relationship in the HRB from 1980 to 2019 were revealed. The results indicate the following: (1) The water system structure in the HRB is complex and exhibits distinct scale characteristics, showing improvement overall and at larger scales while continuously degrading at smaller scales. (2) Both the water system and urban system exhibit increasingly complex spatial development characteristics; however, the USS continues to optimize over time, while the WSS experiences degradation. (3) The development patterns of the water system and urban system are significant differences in the HRB. Urban development mainly relies on outward expansion, whereas the water system is primarily characterized by intensive enhancement. (4) Because of the rapid development of urban areas, water scarcity may occur in densely populated urban areas or larger cities in the future. The research results can serve as a scientific reference for urban planning and water resource management in the HRB. Full article
(This article belongs to the Special Issue Entropy in Landscape Ecology, 4th Edition)
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Figure 1
<p>Location of the Huaihe River Basin. The water systems and urban settlements data came from the National Geographic Information Resource Directory Service System (<a href="http://www.ngcc.cn/" target="_blank">http://www.ngcc.cn/</a>, accessed on 20 April 2021). The classification of urban levels refers to the “Notice on Adjusting the Standards for Classifying Urban Sizes” issued by China. The difference is that small cities (type II) are divided into the following two levels, represented by superscript format of numbers 1 and 2: small cities (type II) <sup>1</sup> with populations of 100,000–200,000 and small cities (type II) <sup>2</sup> with populations fewer than 100,000.</p>
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<p>Flowchart of the research design. The CNLUCC dataset refers to the “China Multiperiod Land Use Remote Sensing Monitoring Dataset”. The WSS and USS refer to water system structures and urban system structures, respectively.</p>
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<p>Grid division map of the water system and urban construction land in the Huaihe River Basin.</p>
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<p>Spatial distribution maps of surface water bodies and urban construction land in the Huaihe River Basin from 1985 to 2019: (<b>a1</b>–<b>a5</b>) urban built-up areas in 1980, 1990, 2000, 2010, and 2018, respectively; (<b>b1</b>–<b>b4</b>) water systems in the 1980s, 1990s, 2000s, and 2010s, respectively.</p>
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<p>Fitting diagram of fractal logarithmic relationship of the water system in the Huaihe River Basin from 1980 to 2019: (<b>a</b>–<b>d</b>) refer to the 1980s, 1990s, 2000s, and 2010s, respectively. The solid line represents the whole, and <span class="html-italic">D</span> is the overall grid dimension. The dashed line represents segments, where <span class="html-italic">D</span><sub>1</sub> and <span class="html-italic">D</span><sub>2</sub> are the first-order scale zone grid dimension (the last 6 points, white squares) and the second-order scale zone grid dimension (the first 3 points, red squares).</p>
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<p>The <span class="html-italic">q</span>-<span class="html-italic">D<sub>q</sub></span> spectrum and <span class="html-italic">a</span>-<span class="html-italic">f</span>(<span class="html-italic">a</span>) spectrum of the water system in the Huaihe River Basin from 1980 to 2019.</p>
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<p>Fitting diagram of the fractal logarithmic relationship of the urban system in the HRB from 1980 to 2018. The solid line represents the whole, with <span class="html-italic">D</span> representing the overall grid dimension. The dashed line represents segments, where <span class="html-italic">D</span><sub>1</sub>, <span class="html-italic">D</span><sub>2</sub>, and <span class="html-italic">D</span><sub>3</sub> correspond to the first-order scale grid dimension (the last 3 points, white squares), the second-order scale grid dimension (the middle 3 points, yellow squares), and the third-order scale grid dimension (the first 3 points, red squares), respectively.</p>
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<p>The <span class="html-italic">q</span>-<span class="html-italic">D<sub>q</sub></span> spectrum and <span class="html-italic">a</span>-<span class="html-italic">f</span>(<span class="html-italic">a</span>) spectrum of the urban system in the Huaihe River Basin from 1980 to 2018.</p>
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<p>Comparison of the grid dimensions between the water system and urban system in the Huaihe River Basin. The water systems in 1990, 2000, 2010, and 2018 correspond to those in the 1980s, 1990s, 2000s, and 2010s, respectively. (<b>a</b>) The overall grid dimensions; (<b>b</b>,<b>c</b>) the grid dimensions of the sub-scale regions; (<b>d</b>) the differences in the grid dimensions among each scale region. Among them, (<b>b</b>) includes the grid dimensions of the first-order scale zone of the water system and the first- and second-order scale zones of the urban system; (<b>c</b>) includes the grid dimensions of the second-order scale zone of the water system and the third-order scale zone of the urban system. (<b>d</b>) The difference in the grid dimensions of the urban system is the average of that across the three scale zones. The lines represent fitted line that varies over time, where the dashed line represents the fitted curve that includes the grid dimensions of the water system in the 1980s, and the solid line does not include that period. The green squares represent water system without 1980s, red and purple squares represent urban system, and white squares represent water system in 1980s.</p>
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<p>Comparison of the multifractal spectrum between the water system and urban system in the Huaihe River Basin. The water systems in 2000, 2010, and 2018 correspond to those in the 1990s, 2000s, and 2010s, respectively.</p>
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16 pages, 1260 KiB  
Article
Maximizing Free Energy Gain
by Artemy Kolchinsky, Iman Marvian, Can Gokler, Zi-Wen Liu, Peter Shor, Oles Shtanko, Kevin Thompson, David Wolpert and Seth Lloyd
Entropy 2025, 27(1), 91; https://doi.org/10.3390/e27010091 (registering DOI) - 20 Jan 2025
Viewed by 194
Abstract
Maximizing the amount of work harvested from an environment is important for a wide variety of biological and technological processes, from energy-harvesting processes such as photosynthesis to energy storage systems such as fuels and batteries. Here, we consider the maximization of free energy—and [...] Read more.
Maximizing the amount of work harvested from an environment is important for a wide variety of biological and technological processes, from energy-harvesting processes such as photosynthesis to energy storage systems such as fuels and batteries. Here, we consider the maximization of free energy—and by extension, the maximum extractable work—that can be gained by a classical or quantum system that undergoes driving by its environment. We consider how the free energy gain depends on the initial state of the system while also accounting for the cost of preparing the system. We provide simple necessary and sufficient conditions for increasing the gain of free energy by varying the initial state. We also derive simple formulae that relate the free energy gained using the optimal initial state rather than another suboptimal initial state. Finally, we demonstrate that the problem of finding the optimal initial state may have two distinct regimes, one easy and one difficult, depending on the temperatures used for preparation and work extraction. We illustrate our results on a simple model of an information engine. Full article
(This article belongs to the Section Statistical Physics)
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Figure 1
<p>Four-stage protocol used to harvest free energy from the environment. During the Preparation stage, the system is coupled to the internal work reservoir and a heat bath at temperature <math display="inline"><semantics> <msub> <mi>T</mi> <mn>0</mn> </msub> </semantics></math>. During Interaction, the system harvests free energy from the external environment. During Work Extraction, the system is coupled to the internal work reservoir and a heat bath at temperature <math display="inline"><semantics> <msub> <mi>T</mi> <mn>1</mn> </msub> </semantics></math>. During Reset, the system is again coupled to the external environment.</p>
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<p>Availability gain <math display="inline"><semantics> <mrow> <mi mathvariant="script">G</mi> <mo>(</mo> <mi>p</mi> <mo>)</mo> </mrow> </semantics></math> as a function of the engine initial distribution <math display="inline"><semantics> <mrow> <mo>(</mo> <mi>p</mi> <mo>(</mo> <mn>0</mn> <mo>)</mo> <mo>,</mo> <mn>1</mn> <mo>−</mo> <mi>p</mi> <mo>(</mo> <mn>0</mn> <mo>)</mo> <mo>)</mo> </mrow> </semantics></math>. (<b>a</b>–<b>d</b>) correspond to four different environment initial distributions <math display="inline"><semantics> <msub> <mi>p</mi> <mi>env</mi> </msub> </semantics></math>. Black lines show <math display="inline"><semantics> <mrow> <mi mathvariant="script">G</mi> <mo>(</mo> <mi>p</mi> <mo>)</mo> </mrow> </semantics></math> computed using Equation (<a href="#FD17-entropy-27-00091" class="html-disp-formula">17</a>); green dots indicate predictions made using our information-theoretic expression (<a href="#FD18-entropy-27-00091" class="html-disp-formula">18</a>) (using shorthand <math display="inline"><semantics> <mrow> <mi mathvariant="script">G</mi> <mo>(</mo> <mi>q</mi> <mo>)</mo> <mo>+</mo> <mo>Δ</mo> <mi>D</mi> </mrow> </semantics></math> in legend). Optimal initial distribution <span class="html-italic">q</span> and equilibrium initial distribution <math display="inline"><semantics> <mi>π</mi> </semantics></math> are indicated using vertical lines. Dashed curve indicates reduction in the engine’s Shannon entropy as a function of initial distribution, <math display="inline"><semantics> <mrow> <mo>−</mo> <mo>Δ</mo> <mi mathvariant="script">H</mi> </mrow> </semantics></math> from Equation (<a href="#FD22-entropy-27-00091" class="html-disp-formula">22</a>). Vertical axes have the same scale. Other parameters: <math display="inline"><semantics> <mrow> <msub> <mi>T</mi> <mn>0</mn> </msub> <mo>=</mo> <msub> <mi>T</mi> <mn>1</mn> </msub> <mo>=</mo> <mi>T</mi> <mo>=</mo> <mn>1</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mi>ϵ</mi> <mo>=</mo> <mn>1</mn> </mrow> </semantics></math>.</p>
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<p>Same as in <a href="#entropy-27-00091-f002" class="html-fig">Figure 2</a>, but where the temperature of Work Extraction is higher than of Preparation, <math display="inline"><semantics> <mrow> <msub> <mi>T</mi> <mn>1</mn> </msub> <mo>=</mo> <mn>3</mn> <mo>&gt;</mo> <msub> <mi>T</mi> <mn>0</mn> </msub> <mo>=</mo> <mn>1</mn> </mrow> </semantics></math>. Black lines show <math display="inline"><semantics> <mrow> <mi mathvariant="script">G</mi> <mo>(</mo> <mi>p</mi> <mo>)</mo> </mrow> </semantics></math> computed using Equation (<a href="#FD17-entropy-27-00091" class="html-disp-formula">17</a>); green dots indicate predictions made using information-theoretic expression (<a href="#FD18-entropy-27-00091" class="html-disp-formula">18</a>). (<b>a</b>–<b>d</b>) correspond to different initial states of the environment. Observe that in some cases, the function <math display="inline"><semantics> <mi mathvariant="script">G</mi> </semantics></math> is non-concave and may have multiple local maxima. In (<b>d</b>), the optimal distribution <span class="html-italic">q</span> does not have full support, so the equivalence between Equations (<a href="#FD17-entropy-27-00091" class="html-disp-formula">17</a>) and (<a href="#FD18-entropy-27-00091" class="html-disp-formula">18</a>) does not hold.</p>
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<p>Gain of availability <math display="inline"><semantics> <mrow> <mi mathvariant="script">G</mi> <mo>(</mo> <mi>ρ</mi> <mo>)</mo> </mrow> </semantics></math> in a quantum system for different amounts of coherence (parameterized by <math display="inline"><semantics> <mi>θ</mi> </semantics></math>). Solid black line shows <math display="inline"><semantics> <mi mathvariant="script">G</mi> </semantics></math> for states diagonal in the reference basis, dashed black line shows <math display="inline"><semantics> <mi mathvariant="script">G</mi> </semantics></math> for states diagonal in the basis of the optimizer <math display="inline"><semantics> <mi>σ</mi> </semantics></math>, both calculated using Equation (<a href="#FD25-entropy-27-00091" class="html-disp-formula">25</a>). Markers indicate predicted values of <math display="inline"><semantics> <mi mathvariant="script">G</mi> </semantics></math> from information-theoretic expression (<a href="#FD26-entropy-27-00091" class="html-disp-formula">26</a>). (<b>a</b>) For <math display="inline"><semantics> <mrow> <mi>θ</mi> <mo>=</mo> <mn>0</mn> </mrow> </semantics></math> (no coherence), we recover the classical result shown in <a href="#entropy-27-00091-f003" class="html-fig">Figure 3</a>b. (<b>b</b>–<b>d</b>) Advantage of selecting initial state in the optimal basis increases with increased coherence. Vertical axes have the same scale. See text for details.</p>
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55 pages, 18951 KiB  
Article
Structured Dynamics in the Algorithmic Agent
by Giulio Ruffini, Francesca Castaldo and Jakub Vohryzek
Entropy 2025, 27(1), 90; https://doi.org/10.3390/e27010090 (registering DOI) - 19 Jan 2025
Viewed by 168
Abstract
In the Kolmogorov Theory of Consciousness, algorithmic agents utilize inferred compressive models to track coarse-grained data produced by simplified world models, capturing regularities that structure subjective experience and guide action planning. Here, we study the dynamical aspects of this framework by examining how [...] Read more.
In the Kolmogorov Theory of Consciousness, algorithmic agents utilize inferred compressive models to track coarse-grained data produced by simplified world models, capturing regularities that structure subjective experience and guide action planning. Here, we study the dynamical aspects of this framework by examining how the requirement of tracking natural data drives the structural and dynamical properties of the agent. We first formalize the notion of a generative model using the language of symmetry from group theory, specifically employing Lie pseudogroups to describe the continuous transformations that characterize invariance in natural data. Then, adopting a generic neural network as a proxy for the agent dynamical system and drawing parallels to Noether’s theorem in physics, we demonstrate that data tracking forces the agent to mirror the symmetry properties of the generative world model. This dual constraint on the agent’s constitutive parameters and dynamical repertoire enforces a hierarchical organization consistent with the manifold hypothesis in the neural network. Our findings bridge perspectives from algorithmic information theory (Kolmogorov complexity, compressive modeling), symmetry (group theory), and dynamics (conservation laws, reduced manifolds), offering insights into the neural correlates of agenthood and structured experience in natural systems, as well as the design of artificial intelligence and computational models of the brain. Full article
27 pages, 1556 KiB  
Article
Environmental Performance, Financial Constraints, and Tax Avoidance Practices: Insights from FTSE All-Share Companies
by Probowo Erawan Sastroredjo, Marcel Ausloos and Polina Khrennikova
Entropy 2025, 27(1), 89; https://doi.org/10.3390/e27010089 (registering DOI) - 18 Jan 2025
Viewed by 417
Abstract
Through its initiative known as the Climate Change Act (2008), the Government of the United Kingdom encourages corporations to enhance their environmental performance with the significant aim of reducing targeted greenhouse gas emissions by the year 2050. Previous research has predominantly assessed this [...] Read more.
Through its initiative known as the Climate Change Act (2008), the Government of the United Kingdom encourages corporations to enhance their environmental performance with the significant aim of reducing targeted greenhouse gas emissions by the year 2050. Previous research has predominantly assessed this encouragement favourably, suggesting that improved environmental performance bolsters governmental efforts to protect the environment and fosters commendable corporate governance practices among companies. Studies indicate that organisations exhibiting strong corporate social responsibility (CSR), environmental, social, and governance (ESG) criteria, or high levels of environmental performance often engage in lower occurrences of tax avoidance. However, our findings suggest that an increase in environmental performance may paradoxically lead to a rise in tax avoidance activities. Using a sample of 567 firms listed on the FTSE All Share from 2014 to 2022, our study finds that firms associated with higher environmental performance are more likely to avoid taxation. The study further documents that the effect is more pronounced for firms facing financial constraints. Entropy balancing, propensity score matching analysis, the instrumental variable method, and the Heckman test are employed in our study to address potential endogeneity concerns. Collectively, the findings of our study suggest that better environmental performance helps explain the variation in firms’ tax avoidance practices. Full article
(This article belongs to the Special Issue Entropy, Econophysics, and Complexity)
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<p>The distribution of <span class="html-italic">EPILLAR</span> is characterised by a data range extending from 0 to 0.1. It is evident that each bin—we here arbitrarily utilise ten bins to delineate the distribution of <span class="html-italic">EPILLAR</span>—exhibits a value (denoted as <span class="html-italic">N<sub>x</sub></span>). Furthermore, the cumulative value of all bins corresponds to the total number of observations (<span class="html-italic">N</span> = 1004).</p>
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<p>The distribution of (<span class="html-italic">p<sub>x</sub></span>)(ln(<span class="html-italic">p<sub>x</sub></span>)). The variable denoted by <span class="html-italic">x</span> represents the number of bins, ranging from 1 to 10. It is pertinent to emphasise that there exists no “entropy” within a bin designated as “<span class="html-italic">x</span>”; rather, the “entropy” is quantified as the (negative) summation of <span class="html-italic">p<sub>x</sub></span> ln(<span class="html-italic">p<sub>x</sub></span>).</p>
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27 pages, 3968 KiB  
Article
Dissipation Alters Modes of Information Encoding in Small Quantum Reservoirs Near Criticality
by Krai Cheamsawat and Thiparat Chotibut
Entropy 2025, 27(1), 88; https://doi.org/10.3390/e27010088 (registering DOI) - 18 Jan 2025
Viewed by 395
Abstract
Quantum reservoir computing (QRC) has emerged as a promising paradigm for harnessing near-term quantum devices to tackle temporal machine learning tasks. Yet, identifying the mechanisms that underlie enhanced performance remains challenging, particularly in many-body open systems where nonlinear interactions and dissipation intertwine in [...] Read more.
Quantum reservoir computing (QRC) has emerged as a promising paradigm for harnessing near-term quantum devices to tackle temporal machine learning tasks. Yet, identifying the mechanisms that underlie enhanced performance remains challenging, particularly in many-body open systems where nonlinear interactions and dissipation intertwine in complex ways. Here, we investigate a minimal model of a driven-dissipative quantum reservoir described by two coupled Kerr-nonlinear oscillators, an experimentally realizable platform that features controllable coupling, intrinsic nonlinearity, and tunable photon loss. Using Partial Information Decomposition (PID), we examine how different dynamical regimes encode input drive signals in terms of redundancy (information shared by each oscillator) and synergy (information accessible only through their joint observation). Our key results show that, near a critical point marking a dynamical bifurcation, the system transitions from predominantly redundant to synergistic encoding. We further demonstrate that synergy amplifies short-term responsiveness, thereby enhancing immediate memory retention, whereas strong dissipation leads to more redundant encoding that supports long-term memory retention. These findings elucidate how the interplay of instability and dissipation shapes information processing in small quantum systems, providing a fine-grained, information-theoretic perspective for analyzing and designing QRC platforms. Full article
(This article belongs to the Special Issue Quantum Computing in the NISQ Era)
18 pages, 276 KiB  
Article
Fitting Copulas with Maximal Entropy
by Milan Bubák and Mirko Navara
Entropy 2025, 27(1), 87; https://doi.org/10.3390/e27010087 (registering DOI) - 18 Jan 2025
Viewed by 179
Abstract
We deal with two-dimensional copulas from the perspective of their differential entropy. We formulate a problem of finding a copula with maximum differential entropy when some copula values are given. As expected, the solution is a copula with a piecewise constant density (a [...] Read more.
We deal with two-dimensional copulas from the perspective of their differential entropy. We formulate a problem of finding a copula with maximum differential entropy when some copula values are given. As expected, the solution is a copula with a piecewise constant density (a checkerboard copula). This allows us to simplify the optimization of the continuous objective function, the differential entropy, to an optimization of finitely many density values. We present several ideas to simplify this problem . It has a feasible numerical solution. We also present several instances that admit closed-form solutions. Full article
(This article belongs to the Special Issue Quantum Probability and Randomness V)
14 pages, 369 KiB  
Article
Statistical Mechanics of Directed Networks
by Marián Boguñá and M. Ángeles Serrano
Entropy 2025, 27(1), 86; https://doi.org/10.3390/e27010086 (registering DOI) - 18 Jan 2025
Viewed by 208
Abstract
Directed networks are essential for representing complex systems, capturing the asymmetry of interactions in fields such as neuroscience, transportation, and social networks. Directionality reveals how influence, information, or resources flow within a network, fundamentally shaping the behavior of dynamical processes and distinguishing directed [...] Read more.
Directed networks are essential for representing complex systems, capturing the asymmetry of interactions in fields such as neuroscience, transportation, and social networks. Directionality reveals how influence, information, or resources flow within a network, fundamentally shaping the behavior of dynamical processes and distinguishing directed networks from their undirected counterparts. Robust null models are crucial for identifying meaningful patterns in these representations, yet designing models that preserve key features remains a significant challenge. One such critical feature is reciprocity, which reflects the balance of bidirectional interactions in directed networks and provides insights into the underlying structural and dynamical principles that shape their connectivity. This paper introduces a statistical mechanics framework for directed networks, modeling them as ensembles of interacting fermions. By controlling the reciprocity and other network properties, our formalism offers a principled approach to analyzing directed network structures and dynamics, introducing new perspectives and models and analytical tools for empirical studies. Full article
(This article belongs to the Special Issue 180th Anniversary of Ludwig Boltzmann)
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<p>Possible fermionic states between a pair of nodes <span class="html-italic">i</span> and <span class="html-italic">j</span>, and their associated energies. The solid arrow indicates the presence of a directed link and the dashed arrow an empty state. When the two fermions simultaneously occupy the two states, <math display="inline"><semantics> <mrow> <mi>i</mi> <mo>→</mo> <mi>j</mi> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>j</mi> <mo>→</mo> <mi>i</mi> </mrow> </semantics></math>, the total energy includes a correction <math display="inline"><semantics> <mrow> <mo>Δ</mo> <msub> <mi>ε</mi> <mrow> <mi>i</mi> <mi>j</mi> </mrow> </msub> </mrow> </semantics></math> added to the sum of the energies of the partially occupied states.</p>
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<p>Reciprocity of the interacting directed <math display="inline"><semantics> <msup> <mi mathvariant="double-struck">S</mi> <mi>d</mi> </msup> </semantics></math> model for fully correlated in- and out-energies, as a function of <math display="inline"><semantics> <mrow> <mo>Δ</mo> <mi>ε</mi> </mrow> </semantics></math>. Different curves correspond to different temperatures <math display="inline"><semantics> <msup> <mi>β</mi> <mrow> <mo>−</mo> <mn>1</mn> </mrow> </msup> </semantics></math>.</p>
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22 pages, 444 KiB  
Article
Some New Constructions of q-ary Codes for Correcting a Burst of at Most t Deletions
by Wentu Song, Kui Cai and Tony Q. S. Quek
Entropy 2025, 27(1), 85; https://doi.org/10.3390/e27010085 (registering DOI) - 18 Jan 2025
Viewed by 205
Abstract
In this paper, we construct q-ary codes for correcting a burst of at most t deletions, where t,q2 are arbitrarily fixed positive integers. We consider two scenarios of error correction: the classical error correcting codes, which recover each [...] Read more.
In this paper, we construct q-ary codes for correcting a burst of at most t deletions, where t,q2 are arbitrarily fixed positive integers. We consider two scenarios of error correction: the classical error correcting codes, which recover each codeword from one read (channel output), and the reconstruction codes, which allow to recover each codeword from multiple channel reads. For the first scenario, our construction has redundancy logn+8loglogn+o(loglogn) bits, encoding complexity O(q7tn(logn)3) and decoding complexity O(nlogn). For the reconstruction scenario, our construction can recover the codewords with two reads and has redundancy 8loglogn+o(loglogn) bits. The encoding complexity of this construction is Oq7tn(logn)3, and decoding complexity is Oq9t(nlogn)3. Both of our constructions have lower redundancy than the best known existing works. We also give explicit encoding functions for both constructions that are simpler than previous works. Full article
(This article belongs to the Special Issue Coding Theory and Its Applications)
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<p>Illustration examples: each dot in the upper row represents a symbol of <math display="inline"><semantics> <mi mathvariant="bold-italic">x</mi> </semantics></math>, and each dot in the lower row represents a symbol of <math display="inline"><semantics> <msup> <mrow> <mi mathvariant="bold-italic">x</mi> </mrow> <mo>′</mo> </msup> </semantics></math>, where two symbols with equal value are connected by a (solid or dashed) line segment. We can find that: (1) in (<b>a</b>), the substring <math display="inline"><semantics> <msub> <mi>x</mi> <mrow> <mo>[</mo> <mn>6</mn> <mo>,</mo> <mn>24</mn> <mo>]</mo> </mrow> </msub> </semantics></math> of <math display="inline"><semantics> <mi mathvariant="bold-italic">x</mi> </semantics></math> has period 2; (2) in (<b>b</b>), the substring <math display="inline"><semantics> <msub> <mi>x</mi> <mrow> <mo>[</mo> <mn>1</mn> <mo>,</mo> <mn>12</mn> <mo>]</mo> </mrow> </msub> </semantics></math> of <math display="inline"><semantics> <mi mathvariant="bold-italic">x</mi> </semantics></math> has period 4, so <math display="inline"><semantics> <mrow> <msub> <mi>x</mi> <mrow> <mo>[</mo> <mi>n</mi> <mo>]</mo> <mo>∖</mo> <mo>{</mo> <mn>1</mn> <mo>,</mo> <mn>2</mn> <mo>,</mo> <mn>3</mn> <mo>,</mo> <mn>4</mn> <mo>}</mo> </mrow> </msub> <mo>=</mo> <msub> <mi>x</mi> <mrow> <mo>[</mo> <mi>n</mi> <mo>]</mo> <mo>∖</mo> <mo>{</mo> <mn>9</mn> <mo>,</mo> <mn>10</mn> <mo>,</mo> <mn>11</mn> <mo>,</mo> <mn>12</mn> <mo>}</mo> </mrow> </msub> </mrow> </semantics></math>; and (3) in (<b>c</b>), the substring <math display="inline"><semantics> <msub> <mi>x</mi> <mrow> <mo>[</mo> <mn>7</mn> <mo>,</mo> <mn>26</mn> <mo>]</mo> </mrow> </msub> </semantics></math> of <math display="inline"><semantics> <mi mathvariant="bold-italic">x</mi> </semantics></math> has period 7.</p>
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24 pages, 14297 KiB  
Article
Image Encryption Method Based on Three-Dimensional Chaotic Systems and V-Shaped Scrambling
by Lei Wang, Wenjun Song, Jiali Di, Xuncai Zhang and Chengye Zou
Entropy 2025, 27(1), 84; https://doi.org/10.3390/e27010084 (registering DOI) - 17 Jan 2025
Viewed by 239
Abstract
With the increasing importance of securing images during network transmission, this paper introduces a novel image encryption algorithm that integrates a 3D chaotic system with V-shaped scrambling techniques. The proposed method begins by constructing a unique 3D chaotic system to generate chaotic sequences [...] Read more.
With the increasing importance of securing images during network transmission, this paper introduces a novel image encryption algorithm that integrates a 3D chaotic system with V-shaped scrambling techniques. The proposed method begins by constructing a unique 3D chaotic system to generate chaotic sequences for encryption. These sequences determine a random starting point for V-shaped scrambling, which facilitates the transformation of image pixels into quaternary numbers. Subsequently, four innovative bit-level scrambling strategies are employed to enhance encryption strength. To further improve randomness, DNA encoding is applied to both the image and chaotic sequences, with chaotic sequences directing crossover and DNA operations. Ciphertext feedback is then utilized to propagate changes across the image, ensuring increased complexity and security. Extensive simulation experiments validate the algorithm’s robust encryption performance for grayscale images, yielding uniformly distributed histograms, near-zero correlation values, and an information entropy value of 7.9975, approaching the ideal threshold. The algorithm also features a large key space, providing robust protection against brute force attacks while effectively resisting statistical, differential, noise, and cropping attacks. These results affirm the algorithm’s reliability and security for image communication and transmission. Full article
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<p>Phase diagrams of the chaotic system.</p>
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<p>Lyapunov exponent diagram of the chaotic system.</p>
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<p>Single-parameter Lyapunov exponent diagrams.</p>
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<p>Bifurcation diagrams.</p>
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<p>Sensitivity test of the initial values.</p>
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<p>Flowchart of the image encryption method.</p>
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<p>Schematic diagram of V-shaped scrambling.</p>
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<p>Quaternary number scrambling method.</p>
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<p>Schematic diagram of bit-level scrambling.</p>
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<p>Schematic diagram of DNA diffusion.</p>
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<p>Encryption and decryption results.</p>
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<p>Sensitivity analysis for the encryption process.</p>
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<p>Key sensitivity analysis for the decryption process.</p>
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<p>Image histogram analysis results.</p>
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<p>Correlations of adjacent pixels of the image before and after encryption. (<b>a</b>) Horizontal of the plain image; (<b>b</b>) vertical of the plain image; (<b>c</b>) diagonal of the plain image; (<b>d</b>) horizontal of the encrypted image; (<b>e</b>) vertical direction of the encrypted image; (<b>f</b>) diagonal of the encrypted image.</p>
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<p>Results of salt and pepper noise attack.</p>
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<p>Results of cropping attacks.</p>
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<p>Encryption results and histogram analysis of all-black and all-white images. (<b>a</b>) Encrypted all-black image; (<b>b</b>) histogram of encrypted all-black image; (<b>c</b>) encrypted all-white image; (<b>d</b>) histogram of encrypted all-white image.</p>
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<p>Correlation analysis of the encrypted all-black image.</p>
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27 pages, 1692 KiB  
Article
Optimizing Hydrogen Production in the Co-Gasification Process: Comparison of Explainable Regression Models Using Shapley Additive Explanations
by Thavavel Vaiyapuri
Entropy 2025, 27(1), 83; https://doi.org/10.3390/e27010083 (registering DOI) - 17 Jan 2025
Viewed by 311
Abstract
The co-gasification of biomass and plastic waste offers a promising solution for producing hydrogen-rich syngas, addressing the rising demand for cleaner energy. However, optimizing this complex process to maximize hydrogen yield remains challenging, particularly when balancing diverse feedstocks and improving process efficiency. While [...] Read more.
The co-gasification of biomass and plastic waste offers a promising solution for producing hydrogen-rich syngas, addressing the rising demand for cleaner energy. However, optimizing this complex process to maximize hydrogen yield remains challenging, particularly when balancing diverse feedstocks and improving process efficiency. While machine learning (ML) has shown significant potential in simulating and optimizing such processes, there is no clear consensus on the most effective regression models for co-gasification, especially with limited experimental data. Additionally, the interpretability of these models is a key concern. This study aims to bridge these gaps through two primary objectives: (1) modeling the co-gasification process using seven different ML algorithms, and (2) developing a framework for evaluating model interpretability, ultimately identifying the most suitable model for process optimization. A comprehensive set of experiments was conducted across three key dimensions, generalization ability, predictive accuracy, and interpretability, to thoroughly assess the models. Support Vector Regression (SVR) exhibited superior performance, achieving the highest coefficient of determination (R2) of 0.86. SVR outperformed other models in capturing non-linear dependencies and demonstrated effective overfitting mitigation. This study further highlights the limitations of other ML models, emphasizing the importance of regularization and hyperparameter tuning in improving model stability. By integrating Shapley Additive Explanations (SHAP) into model evaluation, this work is the first to provide detailed insights into feature importance and demonstrate the operational feasibility of ML models for industrial-scale hydrogen production in the co-gasification process. The findings contribute to the development of a robust framework for optimizing co-gasification, supporting the advancement of sustainable energy technologies and the reduction of greenhouse gas (GHG) emissions. Full article
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<p>Evaluation framework for explainable ML models in hydrogen yield prediction.</p>
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<p>Box plot for outlier analysis.</p>
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<p>Heat map for correlation analysis.</p>
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<p>Learning curve analysis of all explainable ML models with optimized hyperparameters. (<b>a</b>) LR, (<b>b</b>) KNN, (<b>c</b>) DTR, (<b>d</b>) SVR, (<b>e</b>) GBR, (<b>f</b>) RFR, (<b>g</b>) MLP.</p>
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<p>Learning curve analysis of all explainable ML models with default hyperparameters. (<b>a</b>) LR, (<b>b</b>) KNN, (<b>c</b>) DTR, (<b>d</b>) SVR, (<b>e</b>) GBR, (<b>f</b>) RFR, (<b>g</b>) MLP.</p>
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<p>Box Plot of 5-CV results for all explainable ML models in hydrogen yield prediction. (<b>a</b>) Default hyperparameters, (<b>b</b>) Optimized hyperparameters.</p>
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<p>Line graph illustrating the statistical performance metrics for all explainable ML models. (<b>a</b>) Default hyperparameters, (<b>b</b>) Optimized hyperparameters.</p>
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<p>Scatter plots of all explainable ML models with default hyperparameters for hydrogen yield prediction analysis. (<b>a</b>) LR, (<b>b</b>) KNN, (<b>c</b>) DTR, (<b>d</b>) SVR, (<b>e</b>) GBR, (<b>f</b>) RFR, (<b>g</b>) MLP.</p>
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<p>Scatter plots of all explainable ML models with optimized hyperparameters for hydrogen yield prediction analysis. (<b>a</b>) LR, (<b>b</b>) KNN, (<b>c</b>) DTR, (<b>d</b>) SVR, (<b>e</b>) GBR, (<b>f</b>) RFR, (<b>g</b>) MLP.</p>
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<p>SHAP summary plots of all explainable ML models in hydrogen yield prediction. (<b>a</b>) LR, (<b>b</b>) KNN, (<b>c</b>) DTR, (<b>d</b>) SVR, (<b>e</b>) GBR, (<b>f</b>) RFR, (<b>g</b>) MLP.</p>
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<p>SHAP force plots of all explainable ML models for an instance yielding low hydrogen.</p>
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<p>SHAP force plots of all explainable ML models for an instance yielding high hydrogen.</p>
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21 pages, 1162 KiB  
Article
Forecasting Stock Market Indices Using Integration of Encoder, Decoder, and Attention Mechanism
by Tien Thanh Thach
Entropy 2025, 27(1), 82; https://doi.org/10.3390/e27010082 (registering DOI) - 17 Jan 2025
Viewed by 356
Abstract
Accurate forecasting of stock market indices is crucial for investors, financial analysts, and policymakers. The integration of encoder and decoder architectures, coupled with an attention mechanism, has emerged as a powerful approach to enhance prediction accuracy. This paper presents a novel framework that [...] Read more.
Accurate forecasting of stock market indices is crucial for investors, financial analysts, and policymakers. The integration of encoder and decoder architectures, coupled with an attention mechanism, has emerged as a powerful approach to enhance prediction accuracy. This paper presents a novel framework that leverages these components to capture complex temporal dependencies and patterns within stock price data. The encoder effectively transforms an input sequence into a dense representation, which the decoder then uses to reconstruct future values. The attention mechanism provides an additional layer of sophistication, allowing the model to selectively focus on relevant parts of the input sequence for making predictions. Furthermore, Bayesian optimization is employed to fine-tune hyperparameters, further improving forecast precision. Our results demonstrate a significant improvement in forecast precision over traditional recurrent neural networks. This indicates the potential of our integrated approach to effectively handle the complex patterns and dependencies in stock price data. Full article
(This article belongs to the Collection Advances in Applied Statistical Mechanics)
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<p>RNN architecture.</p>
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<p>Illustration of an RNN architecture for forecasting the next trading day’s stock price index.</p>
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<p>LSTM architecture.</p>
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<p>Illustration of an LSTM architecture for forecasting the next trading day’s stock price index.</p>
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<p>GRU architecture.</p>
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<p>Illustration of a GRU architecture for forecasting the next trading day’s stock price index.</p>
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<p>Encoder–decoder architecture for forecasting the next trading day’s stock price index. In this architecture, the encoder’s final hidden state is used as the initial hidden state for the decoder, and the decoder’s input value is the last value of the input sequence.</p>
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<p>Encoder–decoder architecture with a single-head attention mechanism for forecasting the next trading day’s stock price index. In this architecture, the encoder’s final hidden state is used as the initial hidden state for the decoder, and the decoder’s input value is the last value of the input sequence.</p>
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<p>Time series plots for VN-Index and HNX-Index data.</p>
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<p>A sliding window is used to generate the input and target output from the observed time series.</p>
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<p>Training loss curves of the five models for VN-Index (<b>a</b>) and HNX-Index (<b>b</b>) using schedulers to decrease the learning rate.</p>
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<p>Boxplots for the MAE of the models across 10 separate experiments on the VN-Index (<b>a</b>) and HNX-Index (<b>b</b>) test sets.</p>
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<p>Boxplots for the RMSE of the models across 10 separate experiments on the VN-Index (<b>a</b>) and HNX-Index (<b>b</b>) test sets.</p>
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<p>Boxplots for the MAPE of the models across 10 separate experiments on the VN-Index (<b>a</b>) and HNX-Index (<b>b</b>) test sets.</p>
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<p>The predicted curves, along with the training and test data plots for the VN-Index (<b>a</b>) and HNX-Index (<b>b</b>), were generated using the RNN architecture.</p>
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<p>The predicted curves, along with the training and test data plots for the VN-Index (<b>a</b>) and HNX-Index (<b>b</b>), were generated using the LSTM architecture.</p>
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<p>The predicted curves, along with the training and test data plots for the VN-Index (<b>a</b>) and HNX-Index (<b>b</b>), were generated using the GRU architecture.</p>
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<p>The predicted curves, along with the training and test data plots for the VN-Index (<b>a</b>) and HNX-Index (<b>b</b>), were generated using the encoder–decoder architecture.</p>
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<p>The predicted curves, along with the training and test data plots for the VN-Index (<b>a</b>) and HNX-Index (<b>b</b>), were generated using the encoder–decoder architecture with an attention mechanism.</p>
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<p>The attention score matrices for the first ten predictions on the test set, made by the encoder–decoder architecture with an attention mechanism, are shown for both the VN-Index (<b>a</b>) and the HNX-Index (<b>b</b>). For each row, the attention scores indicate how the decoder’s hidden state focuses on each of the five hidden states of the encoder.</p>
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17 pages, 821 KiB  
Article
Measuring the Risk Spillover Effect of RCEP Stock Markets: Evidence from the TVP-VAR Model and Transfer Entropy
by Yijiang Zou, Qinghua Chen, Jihui Han and Mingzhong Xiao
Entropy 2025, 27(1), 81; https://doi.org/10.3390/e27010081 (registering DOI) - 17 Jan 2025
Viewed by 262
Abstract
This paper selects daily stock market trading data of RCEP member countries from 3 December 2007 to 9 December 2024 and employs the Time-Varying Parameter Vector Autoregression (TVP-VAR) model and transfer entropy to measure the time-varying volatility spillover effects among the stock markets [...] Read more.
This paper selects daily stock market trading data of RCEP member countries from 3 December 2007 to 9 December 2024 and employs the Time-Varying Parameter Vector Autoregression (TVP-VAR) model and transfer entropy to measure the time-varying volatility spillover effects among the stock markets of the sampled countries. The results indicate that the signing of the RCEP has strengthened the interconnectedness of member countries’ stock markets, with an overall upward trend in volatility spillover effects, which become even more pronounced during periods of financial turbulence. Within the structure of RCEP member stock markets, China is identified as a net risk receiver, while countries like Japan and South Korea act as net risk spillover contributors. This highlights the current “fragility” of China’s stock market, making it susceptible to risk shocks from the stock markets of economically developed RCEP member countries. This analysis suggests that significant changes in bidirectional risk spillover relationships between China’s stock market and those of other RCEP members coincided with the signing and implementation of the RCEP agreement. Full article
(This article belongs to the Special Issue Risk Spillover and Transfer Entropy in Complex Financial Networks)
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<p>Dynamic total connectedness. Note: This figure shows the time-varying total dependency across RCEP stock markets using TVP-VAR model.</p>
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<p>Net pairwise directional connectedness. Note: This figure only shows the directional spillover effect between China and other countries’ stock markets.</p>
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<p>Risk spillover network of RCEP member countries’ stock markets. Note: In this figure, blue nodes represent the main risk-exporting countries, and yellow nodes represent the risk-receiving countries, and the thickness of the links represents the intensity of risk spillovers. (<b>a</b>) Before the signing of the RCEP. (<b>b</b>) After the signing of the RCEP.</p>
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<p>Heat maps of transfer entropy between different sectors (<b>a</b>) before the singing of the RCEP and (<b>b</b>) after the signing of the RCEP. Note: 1–10 in this figure represent the stock markets of the following 10 countries: China, Vietnam, Singapore, Indonesia, Malaysia, South Korea, Japan, New Zealand, Thailand, and Australia (arranged in order).</p>
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<p>The stock market network constructed based on the transfer entropy matrix. This figure shows a directed network, and the arrows on the edges indicate the direction of information flow. (<b>a</b>) Before the singing of the RCEP. (<b>b</b>) After the signing of the RCEP.</p>
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17 pages, 887 KiB  
Article
Bidimensional Increment Entropy for Texture Analysis: Theoretical Validation and Application to Colon Cancer Images
by Muqaddas Abid, Muhammad Suzuri Hitam, Rozniza Ali, Hamed Azami and Anne Humeau-Heurtier
Entropy 2025, 27(1), 80; https://doi.org/10.3390/e27010080 - 17 Jan 2025
Viewed by 285
Abstract
Entropy algorithms are widely applied in signal analysis to quantify the irregularity of data. In the realm of two-dimensional data, their two-dimensional forms play a crucial role in analyzing images. Previous works have demonstrated the effectiveness of one-dimensional increment entropy in detecting abrupt [...] Read more.
Entropy algorithms are widely applied in signal analysis to quantify the irregularity of data. In the realm of two-dimensional data, their two-dimensional forms play a crucial role in analyzing images. Previous works have demonstrated the effectiveness of one-dimensional increment entropy in detecting abrupt changes in signals. Leveraging these advantages, we introduce a novel concept, two-dimensional increment entropy (IncrEn2D), tailored for analyzing image textures. In our proposed method, increments are translated into two-letter words, encoding both the size (magnitude) and direction (sign) of the increments calculated from an image. We validate the effectiveness of this new entropy measure by applying it to MIX2D(p) processes and synthetic textures. Experimental validation spans diverse datasets, including the Kylberg dataset for real textures and medical images featuring colon cancer characteristics. To further validate our results, we employ a support vector machine model, utilizing multiscale entropy values as feature inputs. A comparative analysis with well-known bidimensional sample entropy (SampEn2D) and bidimensional dispersion entropy (DispEn2D) reveals that IncrEn2D achieves an average classification accuracy surpassing that of other methods. In summary, IncrEn2D emerges as an innovative and potent tool for image analysis and texture characterization, offering superior performance compared to existing bidimensional entropy measures. Full article
(This article belongs to the Special Issue Entropy in Biomedical Engineering, 3rd Edition)
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Figure 1

Figure 1
<p>Illustration of the two possible methods for constructing the increment image <b>V</b>(<b>I</b>).</p>
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<p>Illustration of steps 1 and 2 of IncrEn<sub>2<span class="html-italic">D</span></sub>, using the row-wise method to compute the increment image.</p>
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<p>Template vectors illustrating the steps to obtain words.</p>
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<p>MIX<sub>2<span class="html-italic">D</span></sub>(<span class="html-italic">p</span>) family of images with varying noise levels, <math display="inline"><semantics> <mrow> <mi>p</mi> </mrow> </semantics></math>.</p>
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<p>Simulated images of size 256 × 256 pixels with vertical stripes (patterns 1–10) and horizontal stripes (patterns 11–20).</p>
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<p>One image (576 × 576 pixels) of each of the six selected categories from the Kylberg dataset.</p>
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<p>A few sample images (768 × 768 pixels) from the LC25000 dataset: (<b>a</b>–<b>d</b>) colon cancer tissues and (<b>e</b>–<b>h</b>) normal tissues.</p>
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<p>IncrEn<sub>2<span class="html-italic">D</span></sub> for MIX<sub>2<span class="html-italic">D</span></sub>(<span class="html-italic">p</span>) images of size 256 × 256 pixels for <span class="html-italic">R</span>=4 and <math display="inline"><semantics> <mrow> <mi>m</mi> <mo>=</mo> <mn>2</mn> <mo>,</mo> <mn>3</mn> </mrow> </semantics></math>, and 4.</p>
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<p>IncrEn<sub>2<span class="html-italic">D</span></sub> for MIX<sub>2<span class="html-italic">D</span></sub>(<span class="html-italic">p</span>) images of size 256 × 256 pixels for <math display="inline"><semantics> <mrow> <mi>m</mi> <mo>=</mo> <mn>2</mn> </mrow> </semantics></math> and varying <span class="html-italic">R</span> values from 2 to 6.</p>
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<p>IncrEn<sub>2<span class="html-italic">D</span></sub> for MIX<sub>2<span class="html-italic">D</span></sub>(<span class="html-italic">p</span>) images of different sizes for <math display="inline"><semantics> <mrow> <mi>m</mi> <mo>=</mo> <mn>2</mn> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>R</mi> <mo>=</mo> <mn>4</mn> </mrow> </semantics></math>.</p>
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<p>Effect of different standard deviations on IncrEn<sub>2<span class="html-italic">D</span></sub> values with <math display="inline"><semantics> <mrow> <mi>m</mi> <mo>=</mo> <mn>2</mn> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>R</mi> <mo>=</mo> <mn>4</mn> </mrow> </semantics></math>.</p>
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<p>IncrEn<sub>2<span class="html-italic">D</span></sub> values with row-wise and column-wise increment images for MIX<sub>2<span class="html-italic">D</span></sub>(<span class="html-italic">p</span>) of size 256 × 256 pixels with <math display="inline"><semantics> <mrow> <mi>m</mi> <mo>=</mo> <mn>2</mn> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>R</mi> <mo>=</mo> <mn>4</mn> </mrow> </semantics></math>.</p>
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<p>Multiscale IncrEn<sub>2<span class="html-italic">D</span></sub> values with <math display="inline"><semantics> <mrow> <mi>m</mi> <mo>=</mo> <mn>2</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mi>R</mi> <mo>=</mo> <mn>4</mn> </mrow> </semantics></math>, and scale factors from 1 to 4 for cancerous and normal tissues.</p>
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18 pages, 504 KiB  
Article
Multi-Condition Remaining Useful Life Prediction Based on Mixture of Encoders
by Yang Liu, Bihe Xu and Yangli-ao Geng
Entropy 2025, 27(1), 79; https://doi.org/10.3390/e27010079 - 17 Jan 2025
Viewed by 285
Abstract
Accurate Remaining Useful Life (RUL) prediction is vital for effective prognostics in and the health management of industrial equipment, particularly under varying operational conditions. Existing approaches to multi-condition RUL prediction often treat each working condition independently, failing to effectively exploit cross-condition knowledge. To [...] Read more.
Accurate Remaining Useful Life (RUL) prediction is vital for effective prognostics in and the health management of industrial equipment, particularly under varying operational conditions. Existing approaches to multi-condition RUL prediction often treat each working condition independently, failing to effectively exploit cross-condition knowledge. To address this limitation, this paper introduces MoEFormer, a novel framework that combines a Mixture of Encoders (MoE) with a Transformer-based architecture to achieve precise multi-condition RUL prediction. The core innovation lies in the MoE architecture, where each encoder is designed to specialize in feature extraction for a specific operational condition. These features are then dynamically integrated through a gated mixture module, enabling the model to effectively leverage cross-condition knowledge. A Transformer layer is subsequently employed to capture temporal dependencies within the input sequence, followed by a fully connected layer to produce the final prediction. Additionally, we provide a theoretical performance guarantee for MoEFormer by deriving a lower bound for its error rate. Extensive experiments on the widely used C-MAPSS dataset demonstrate that MoEFormer outperforms several state-of-the-art methods for multi-condition RUL prediction. Full article
(This article belongs to the Section Multidisciplinary Applications)
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Figure 1

Figure 1
<p>Framework of the proposed MoEFormer. The model comprises three key components: distribution alignment, Mixture of Encoders (MoE), and Transformer predictor. The distribution alignment step aims to mitigate distribution drift in sensor features collected under varying operating conditions. The MoE component is designed to extract complementary knowledge from different working conditions. Lastly, the Transformer predictor captures temporal dependencies within the features, ultimately producing the final RUL prediction.</p>
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<p>Comparison of MoEFormer’s predicted RUL values against the ground truth for FD002 and FD004.</p>
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<p>The sample-wise distribution of MoEFormer’s predicted RUL values against the actual RUL values for FD002 and FD004.</p>
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<p>(<b>a</b>) RMSE and (<b>b</b>) Score of MoEFormer as a function of window size.</p>
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<p>(<b>a</b>) RMSE and (<b>b</b>) Score of MoEFormer as a function of <math display="inline"><semantics> <mi>λ</mi> </semantics></math> (refer to (<a href="#FD17-entropy-27-00079" class="html-disp-formula">17</a>)).</p>
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17 pages, 1273 KiB  
Article
Anomalous Behavior of the Non-Hermitian Topological System with an Asymmetric Coupling Impurity
by Junjie Wang, Fude Li and Weijun Cheng
Entropy 2025, 27(1), 78; https://doi.org/10.3390/e27010078 - 17 Jan 2025
Viewed by 339
Abstract
A notable feature of systems with non-Hermitian skin effects is the sensitivity to boundary conditions. In this work, we introduce one type of boundary condition provided by a coupling impurity. We consider a system where a two-level system as an impurity couples to [...] Read more.
A notable feature of systems with non-Hermitian skin effects is the sensitivity to boundary conditions. In this work, we introduce one type of boundary condition provided by a coupling impurity. We consider a system where a two-level system as an impurity couples to a nonreciprocal Su–Schrieffer–Heeger chain under periodic boundary conditions at two points with asymmetric couplings. We first study the spectrum of the system and find that asymmetric couplings lead to topological phase transitions. Meanwhile, a striking feature is that the coupling impurity can act as an effective boundary, and asymmetric couplings can also induce a flexibly adjusted zero mode. It is localized at one of the two effective boundaries or both of them by tuning coupling strengths. Moreover, we uncover three types of localization behaviors of eigenstates for this non-Hermitian impurity system with on-site disorder. These results corroborate the potential for control of a class of non-Hermitian systems with coupling impurities. Full article
(This article belongs to the Special Issue Entropy: From Atoms to Complex Systems)
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Figure 1

Figure 1
<p>Schematicsof the nonreciprocal SSH chain coupled to an impurity via either <math display="inline"><semantics> <mrow> <mi>A</mi> <mo>−</mo> <mi>B</mi> </mrow> </semantics></math> coupling (<b>a</b>) or <math display="inline"><semantics> <mrow> <mi>A</mi> <mo>−</mo> <mi>A</mi> </mrow> </semantics></math> coupling (<b>b</b>) with asymmetric coupling strengths (<math display="inline"><semantics> <mrow> <msub> <mi>g</mi> <mi>m</mi> </msub> <mo>≠</mo> <msub> <mi>g</mi> <mi>n</mi> </msub> </mrow> </semantics></math>).</p>
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<p>(<b>a</b>) Spectrum of pure SSH chain (<a href="#FD1-entropy-27-00078" class="html-disp-formula">1</a>) in complex plane. (<b>b</b>) Spectrum of the system with <math display="inline"><semantics> <mrow> <mi>A</mi> <mo>−</mo> <mi>B</mi> </mrow> </semantics></math> couplings (<a href="#FD3a-entropy-27-00078" class="html-disp-formula">3a</a>) in complex plane. (<b>c</b>) Spectrum of the system with <math display="inline"><semantics> <mrow> <mi>A</mi> <mo>−</mo> <mi>A</mi> </mrow> </semantics></math> couplings (<a href="#FD3b-entropy-27-00078" class="html-disp-formula">3b</a>) in complex plane. The results were obtained by numerically solving the Schödinger equation. The parameters were set as <math display="inline"><semantics> <mrow> <mi>L</mi> <mo>=</mo> <mn>50</mn> <mo>,</mo> <mi>m</mi> <mo>=</mo> <mn>26</mn> <mo>,</mo> <mi>n</mi> <mo>=</mo> <mn>25</mn> <mo>,</mo> <msub> <mi>g</mi> <mi>n</mi> </msub> <mo>=</mo> <mn>0.5</mn> <mo>,</mo> <msub> <mi>g</mi> <mi>m</mi> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> <msub> <mi>t</mi> <mn>1</mn> </msub> <mo>=</mo> <mn>0.2</mn> <mo>,</mo> <msub> <mi>t</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>γ</mi> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math>.</p>
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<p>Absolute value of the spectrum as a function of <math display="inline"><semantics> <msub> <mi>t</mi> <mn>1</mn> </msub> </semantics></math> with <math display="inline"><semantics> <mrow> <mi>A</mi> <mo>−</mo> <mi>B</mi> </mrow> </semantics></math> coupling. The results are obtained by numerically solve the Schödinger equation. <math display="inline"><semantics> <mrow> <msub> <mi>g</mi> <mi>n</mi> </msub> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>0.1</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>0.01</mn> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <mn>0.001</mn> </mrow> </semantics></math> for (<b>a</b>), (<b>b</b>), (<b>c</b>), and (<b>d</b>), respectively. The other parameters were set as <math display="inline"><semantics> <mrow> <mi>L</mi> <mo>=</mo> <mn>50</mn> <mo>,</mo> <mi>m</mi> <mo>=</mo> <mn>26</mn> <mo>,</mo> <mi>n</mi> <mo>=</mo> <mn>25</mn> <mo>,</mo> <msub> <mi>g</mi> <mi>m</mi> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> <msub> <mi>t</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>γ</mi> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math>.</p>
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<p>Absolute value of the spectrum as a function of <math display="inline"><semantics> <msub> <mi>t</mi> <mn>1</mn> </msub> </semantics></math> with <math display="inline"><semantics> <mrow> <mi>A</mi> <mo>−</mo> <mi>A</mi> </mrow> </semantics></math> coupling. The results were obtained by numerically solving the Schödinger equation. <math display="inline"><semantics> <mrow> <msub> <mi>g</mi> <mi>n</mi> </msub> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>0.1</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>0.01</mn> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <mn>0.001</mn> </mrow> </semantics></math> for (<b>a</b>), (<b>b</b>), (<b>c</b>), and (<b>d</b>), respectively. The other parameters were set as <math display="inline"><semantics> <mrow> <mi>L</mi> <mo>=</mo> <mn>50</mn> <mo>,</mo> <mi>m</mi> <mo>=</mo> <mn>26</mn> <mo>,</mo> <mi>n</mi> <mo>=</mo> <mn>25</mn> <mo>,</mo> <msub> <mi>g</mi> <mi>m</mi> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> <msub> <mi>t</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>γ</mi> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math>.</p>
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<p>Populations of the middle bound states for the system (<a href="#FD3a-entropy-27-00078" class="html-disp-formula">3a</a>) with <math display="inline"><semantics> <mrow> <mi>A</mi> <mo>−</mo> <mi>B</mi> </mrow> </semantics></math> coupling as a function of site <span class="html-italic">N</span>. Here <math display="inline"><semantics> <mrow> <msub> <mi>g</mi> <mi>n</mi> </msub> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>0.3</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>0.1</mn> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <mn>0.01</mn> </mrow> </semantics></math> for (<b>a</b>), (<b>b</b>), (<b>c</b>), and (<b>d</b>), respectively. The other parameters were chosen as <math display="inline"><semantics> <mrow> <mi>L</mi> <mo>=</mo> <mn>50</mn> <mo>,</mo> <mi>m</mi> <mo>=</mo> <mn>26</mn> <mo>,</mo> <mi>n</mi> <mo>=</mo> <mn>25</mn> <mo>,</mo> <msub> <mi>g</mi> <mi>m</mi> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> <msub> <mi>t</mi> <mn>1</mn> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> <msub> <mi>t</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>γ</mi> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math>. The site of impurity was set to <math display="inline"><semantics> <mrow> <mi>N</mi> <mo>=</mo> <mn>2</mn> <mi>L</mi> <mo>+</mo> <mn>1</mn> <mo>=</mo> <mn>101</mn> </mrow> </semantics></math>.</p>
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<p>Populations of zero mode for the system (<a href="#FD3a-entropy-27-00078" class="html-disp-formula">3a</a>) with <math display="inline"><semantics> <mrow> <mi>A</mi> <mo>−</mo> <mi>B</mi> </mrow> </semantics></math> coupling as a function of site <span class="html-italic">N</span>. <math display="inline"><semantics> <mrow> <msub> <mi>g</mi> <mi>n</mi> </msub> <mo>=</mo> <mn>1</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>0.5</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>0.1</mn> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <mn>0.01</mn> </mrow> </semantics></math> for (<b>a</b>), (<b>b</b>), (<b>c</b>), and (<b>d</b>), respectively. The other parameters were chosen as <math display="inline"><semantics> <mrow> <mi>L</mi> <mo>=</mo> <mn>50</mn> <mo>,</mo> <mi>m</mi> <mo>=</mo> <mn>40</mn> <mo>,</mo> <mi>n</mi> <mo>=</mo> <mn>20</mn> <mo>,</mo> <msub> <mi>g</mi> <mi>m</mi> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> <msub> <mi>t</mi> <mn>1</mn> </msub> <mo>=</mo> <mn>0.2</mn> <mo>,</mo> <msub> <mi>t</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>γ</mi> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math>. The site of impurity was set to <math display="inline"><semantics> <mrow> <mi>N</mi> <mo>=</mo> <mn>2</mn> <mi>L</mi> <mo>+</mo> <mn>1</mn> <mo>=</mo> <mn>101</mn> </mrow> </semantics></math>.</p>
Full article ">Figure 7
<p>Population of zero mode for the system (<a href="#FD3a-entropy-27-00078" class="html-disp-formula">3a</a>) with <math display="inline"><semantics> <mrow> <mi>A</mi> <mo>−</mo> <mi>A</mi> </mrow> </semantics></math> coupling as a function of site <span class="html-italic">N</span>. <math display="inline"><semantics> <mrow> <msub> <mi>g</mi> <mi>n</mi> </msub> <mo>=</mo> <mn>1</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>0.5</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>0.1</mn> </mrow> </semantics></math>, and <math display="inline"><semantics> <mrow> <mn>0.01</mn> </mrow> </semantics></math> for (<b>a</b>), (<b>b</b>), (<b>c</b>), and (<b>d</b>), respectively. The other parameters were chosen as <math display="inline"><semantics> <mrow> <mi>L</mi> <mo>=</mo> <mn>50</mn> <mo>,</mo> <mi>m</mi> <mo>=</mo> <mn>40</mn> <mo>,</mo> <mi>n</mi> <mo>=</mo> <mn>20</mn> <mo>,</mo> <msub> <mi>g</mi> <mi>m</mi> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> <msub> <mi>t</mi> <mn>1</mn> </msub> <mo>=</mo> <mn>0.2</mn> <mo>,</mo> <msub> <mi>t</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>γ</mi> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math>. The site of impurity was set to <math display="inline"><semantics> <mrow> <mi>N</mi> <mo>=</mo> <mn>2</mn> <mi>L</mi> <mo>+</mo> <mn>1</mn> <mo>=</mo> <mn>101</mn> </mrow> </semantics></math>.</p>
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<p>Mcom on the parameter space of coupling strengths <math display="inline"><semantics> <msub> <mi>g</mi> <mi>n</mi> </msub> </semantics></math> and disorder strengths <span class="html-italic">S</span> for the system with <math display="inline"><semantics> <mrow> <mi>A</mi> <mo>−</mo> <mi>A</mi> </mrow> </semantics></math> coupling. The results have been averaged for 50 disorder realizations. The parameters were chosen as <math display="inline"><semantics> <mrow> <mi>L</mi> <mo>=</mo> <mn>50</mn> <mo>,</mo> <mi>m</mi> <mo>=</mo> <mn>40</mn> <mo>,</mo> <mi>n</mi> <mo>=</mo> <mn>10</mn> <mo>,</mo> <msub> <mi>g</mi> <mi>m</mi> </msub> <mo>=</mo> <mn>100</mn> <mo>,</mo> <msub> <mi>t</mi> <mn>1</mn> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> <msub> <mi>t</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>γ</mi> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math>. The site of impurity was set to <math display="inline"><semantics> <mrow> <mi>N</mi> <mo>=</mo> <mn>2</mn> <mi>L</mi> <mo>+</mo> <mn>1</mn> <mo>=</mo> <mn>101</mn> </mrow> </semantics></math>.</p>
Full article ">Figure A1
<p>Populations of upper bound states in (<b>a</b>,<b>b</b>) with <math display="inline"><semantics> <mrow> <mi>A</mi> <mo>−</mo> <mi>B</mi> </mrow> </semantics></math> coupling and (<b>c</b>,<b>d</b>) with <math display="inline"><semantics> <mrow> <mi>A</mi> <mo>−</mo> <mi>A</mi> </mrow> </semantics></math> coupling as a function of site <span class="html-italic">N</span>. <math display="inline"><semantics> <mrow> <msub> <mi>g</mi> <mi>n</mi> </msub> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math> for (<b>a</b>,<b>c</b>), and <math display="inline"><semantics> <mrow> <msub> <mi>g</mi> <mi>n</mi> </msub> <mo>=</mo> <mn>0.3</mn> </mrow> </semantics></math> for (<b>b</b>,<b>d</b>). The other parameters were chosen as <math display="inline"><semantics> <mrow> <mi>L</mi> <mo>=</mo> <mn>50</mn> <mo>,</mo> <mi>m</mi> <mo>=</mo> <mn>40</mn> <mo>,</mo> <mi>n</mi> <mo>=</mo> <mn>20</mn> <mo>,</mo> <msub> <mi>g</mi> <mi>m</mi> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> <msub> <mi>t</mi> <mn>1</mn> </msub> <mo>=</mo> <mn>0.2</mn> <mo>,</mo> <msub> <mi>t</mi> <mn>2</mn> </msub> <mo>=</mo> <mn>1</mn> <mo>,</mo> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>γ</mi> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math>. The site of impurity was set to <math display="inline"><semantics> <mrow> <mi>N</mi> <mo>=</mo> <mn>2</mn> <mi>L</mi> <mo>+</mo> <mn>1</mn> <mo>=</mo> <mn>101</mn> </mrow> </semantics></math>.</p>
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17 pages, 1432 KiB  
Article
Distinguishing Ideal and Non-Ideal Chemical Systems Based on Kinetic Behavior
by Gregory Yablonsky and Vladislav Fedotov
Entropy 2025, 27(1), 77; https://doi.org/10.3390/e27010077 - 16 Jan 2025
Viewed by 306
Abstract
This paper focuses on differentiating between ideal and non-ideal chemical systems based on their kinetic behavior within a closed isothermal chemical environment. Non-ideality is examined using the non-ideal Marcelin–de Donde model. The analysis primarily addresses ‘soft’ non-ideality, where the equilibrium composition for a [...] Read more.
This paper focuses on differentiating between ideal and non-ideal chemical systems based on their kinetic behavior within a closed isothermal chemical environment. Non-ideality is examined using the non-ideal Marcelin–de Donde model. The analysis primarily addresses ‘soft’ non-ideality, where the equilibrium composition for a reversible non-ideal chemical system is identical to the corresponding composition for the ideal chemical system. Our approach in distinguishing the ideal and non-ideal systems is based on the properties of the special event, i.e., event, the time of which is well-defined. For the single-step first-order reaction in the ideal system, this event is the half-time-decay point, or the intersection point. For the two consecutive reversible reactions in the ideal system, A ↔ B ↔ C, this event is the extremum obtained within the conservatively perturbed equilibrium (CPE) procedure. For the non-ideal correspondent models, the times of chosen events significantly depend on the initial concentrations. The obtained difference in the behavior of the times of these events (intersection point and CPE-extremum point) between the ideal and non-ideal systems is proposed as the kinetic fingerprint for distinguishing these systems. Full article
(This article belongs to the Section Non-equilibrium Phenomena)
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Figure 1

Figure 1
<p>CPE effect in ideal two-step mechanism A ↔ B ↔ C. Dynamics of reactant concentrations at <span class="html-italic">A</span>(<span class="html-italic">t</span>) +<span class="html-italic"> B</span>(<span class="html-italic">t</span>) +<span class="html-italic"> C</span>(<span class="html-italic">t</span>) = 1 (conservation law); <span class="html-italic">B</span><sub>0</sub>, <span class="html-italic">B<sub>eq</sub></span>—initial and equilibrium concentrations of the reagent <span class="html-italic">B</span>.</p>
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<p>Relaxation time <span class="html-italic">t</span> from ln((<span class="html-italic">A</span><sub>0</sub> − <span class="html-italic">A<sub>eq</sub></span>)/(<span class="html-italic">A</span> − <span class="html-italic">A<sub>eq</sub></span>)) for different cases of the non-ideality: o—‘zeroth’; *—‘weak’; ×—non-ideality is ‘stronger’; and ☐—‘strong’.</p>
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<p>The ‘uniform’ non-ideality. Evolution of concentration of ideal (<span class="html-italic">A</span>, <span class="html-italic">B</span>) and non-ideal (<span class="html-italic">A</span>*, <span class="html-italic">B</span>*) components, respectively, at <span class="html-italic">a<sub>ij</sub></span> = <span class="html-italic">p</span>: (<b>a</b>) <span class="html-italic">A</span><sub>0</sub> = <span class="html-italic">A<sub>eq</sub></span>; <span class="html-italic">p = +</span>1; (<b>b</b>) <span class="html-italic">B</span><sub>0</sub> = <span class="html-italic">B<sub>eq</sub></span>; <span class="html-italic">p = +</span>1; (<b>c</b>) <span class="html-italic">A</span><sub>0</sub> = <span class="html-italic">A<sub>eq</sub></span>; <span class="html-italic">p = −</span>1; and (<b>d</b>) <span class="html-italic">B</span><sub>0</sub> = <span class="html-italic">B<sub>eq</sub></span>; <span class="html-italic">p = −</span>1.</p>
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<p>The ‘non-uniform’ non-ideality. Kinetic dependencies for ideal and non-ideal cases at <span class="html-italic">a</span><sub>11</sub> = <span class="html-italic">a</span><sub>21</sub> = <span class="html-italic">a</span><sub>31</sub> = 1, <span class="html-italic">a</span><sub>12</sub> = <span class="html-italic">a</span><sub>22</sub> = <span class="html-italic">a</span><sub>32</sub> = 2, <span class="html-italic">a</span><sub>13</sub> = <span class="html-italic">a</span><sub>23</sub> = <span class="html-italic">a</span><sub>33</sub> = 3: (<b>a</b>) <span class="html-italic">A</span><sub>0</sub> = <span class="html-italic">A<sub>eq</sub></span>; (<b>b</b>) <span class="html-italic">B</span><sub>0</sub> = <span class="html-italic">B<sub>eq</sub></span> and at <span class="html-italic">a</span><sub>11</sub> = −2, <span class="html-italic">a</span><sub>12</sub> = 1, <span class="html-italic">a</span><sub>13</sub> = −4, <span class="html-italic">a</span><sub>21</sub> = −2, <span class="html-italic">a</span><sub>22</sub> = 1, <span class="html-italic">a</span><sub>23</sub> = −4, <span class="html-italic">a</span><sub>31</sub> = −2, <span class="html-italic">a</span><sub>32</sub> = 1, <span class="html-italic">a</span><sub>33</sub> = −4; (<b>c</b>) <span class="html-italic">A</span><sub>0</sub> = <span class="html-italic">A<sub>eq</sub></span>; and (<b>d</b>) <span class="html-italic">B</span><sub>0</sub> = <span class="html-italic">B<sub>eq.</sub></span></p>
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<p>‘Non-uniform’ non-ideality. The time of CPE extremum, <span class="html-italic">t</span>*, at different initial conditions: <span class="html-italic">A</span><sub>0</sub> = <span class="html-italic">A<sub>eq</sub></span>, <span class="html-italic">B</span><sub>0</sub> = 0 (lower curve) and <span class="html-italic">A</span><sub>0</sub> = <span class="html-italic">A<sub>eq</sub></span>, <span class="html-italic">B</span><sub>0</sub> = 0.1 (upper curve): (<b>a</b>) <span class="html-italic">a</span><sub>11</sub> = 1, <span class="html-italic">a</span><sub>12</sub> = 2, <span class="html-italic">a</span><sub>13</sub> = 3, <span class="html-italic">a</span><sub>21</sub> = 1, <span class="html-italic">a</span><sub>22</sub> = 2, <span class="html-italic">a</span><sub>23</sub> = 3, <span class="html-italic">a</span><sub>31</sub> = 1, <span class="html-italic">a</span><sub>32</sub> = 2, <span class="html-italic">a</span><sub>33</sub> = 3, <span class="html-italic">t</span>* ≈ 0.018 → 0.013; and (<b>b</b>) <span class="html-italic">a</span><sub>11</sub> = 1/4, <span class="html-italic">a</span><sub>12</sub> = 2/4, <span class="html-italic">a</span><sub>13</sub> = 3/4, <span class="html-italic">a</span><sub>21</sub> = 1/4, <span class="html-italic">a</span><sub>22</sub> = 2/4, <span class="html-italic">a</span><sub>23</sub> = 3/4, <span class="html-italic">a</span><sub>31</sub> = 1/4, <span class="html-italic">a</span><sub>32</sub> = 2/4, <span class="html-italic">a</span><sub>33</sub> = 3/4, <span class="html-italic">t</span>* ≈ 0.050 → 0.033.</p>
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14 pages, 2466 KiB  
Article
Statistical Complexity Analysis of Sleep Stages
by Cristina D. Duarte, Marianela Pacheco, Francisco R. Iaconis, Osvaldo A. Rosso, Gustavo Gasaneo and Claudio A. Delrieux
Entropy 2025, 27(1), 76; https://doi.org/10.3390/e27010076 - 16 Jan 2025
Viewed by 286
Abstract
Studying sleep stages is crucial for understanding sleep architecture, which can help identify various health conditions, including insomnia, sleep apnea, and neurodegenerative diseases, allowing for better diagnosis and treatment interventions. In this paper, we explore the effectiveness of generalized weighted permutation entropy (GWPE) [...] Read more.
Studying sleep stages is crucial for understanding sleep architecture, which can help identify various health conditions, including insomnia, sleep apnea, and neurodegenerative diseases, allowing for better diagnosis and treatment interventions. In this paper, we explore the effectiveness of generalized weighted permutation entropy (GWPE) in distinguishing between different sleep stages from EEG signals. Using classification algorithms, we evaluate feature sets derived from both standard permutation entropy (PE) and GWPE to determine which set performs better in classifying sleep stages, demonstrating that GWPE significantly enhances sleep stage differentiation, particularly in identifying the transition between N1 and REM sleep. The results highlight the potential of GWPE as a valuable tool for understanding sleep neurophysiology and improving the diagnosis of sleep disorders. Full article
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Figure 1

Figure 1
<p>Normalized confusion matrix (%) for XGBoost algorithm classifier, with PE and C on the left and GWPE and GWPEC on the right as features. (<b>a</b>) XGBoost algorithm; PE and C as features, (<b>b</b>) XGBoost algorithm; GWPE and GWPEC as features.</p>
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<p>Normalized confusion matrix (%) for XGBoost algorithm classifier, with PDF on the left and GWPDF on the right as features. (<b>a</b>) XGBoost algorithm; PDF as features, (<b>b</b>) XGBoost algorithm; GWPDF as features.</p>
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<p>Median of values of generalized permutation entropy (<b>left</b>) and complexity (<b>right</b>) for <span class="html-italic">q</span> across all sleep stages.</p>
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<p>Median probabilities of the monotonic patterns <math display="inline"><semantics> <mrow> <mo>[</mo> <mn>0123</mn> <mo>]</mo> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mo>[</mo> <mn>3210</mn> <mo>]</mo> </mrow> </semantics></math> across all sleep stages for varying entropic index <span class="html-italic">q</span>.</p>
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<p>Normalized confusion matrix (%) for RF and SVM algorithms classifier, with PE and C on the left and, GWPE and GWPEC on the right as features. (<b>a</b>) RF algorithm; PE and C as features, (<b>b</b>) RF algorithm; GWPE and GWPEC as features, (<b>c</b>) SVM algorithm; PE and C as features, (<b>d</b>) SVM algorithm; GWPE and GWPEC as features.</p>
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<p>Normalized confusion matrix (%) for the RF and SVM algorithms classifier, with PDF on the left and GWPDF on the right as features. (<b>a</b>) RF algorithm; PDF as features, (<b>b</b>) RF algorithm; GWPDF as features, (<b>c</b>) SVM algorithm; PDF as features, (<b>d</b>) SVM algorithm; GWPDF as features.</p>
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15 pages, 2287 KiB  
Article
Transport Numbers and Electroosmosis in Cation-Exchange Membranes with Aqueous Electrolyte Solutions of HCl, LiCl, NaCl, KCl, MgCl2, CaCl2 and NH4Cl
by Simon B. B. Solberg, Zelalem B. Deress, Marte H. Hvamstad and Odne S. Burheim
Entropy 2025, 27(1), 75; https://doi.org/10.3390/e27010075 - 15 Jan 2025
Viewed by 341
Abstract
Electroosmosis reduces the available energy from ion transport arising due to concentration gradients across ion-exchange membranes. This work builds on previous efforts to describe the electroosmosis, the permselectivity and the apparent transport number of a membrane, and we show new measurements of concentration [...] Read more.
Electroosmosis reduces the available energy from ion transport arising due to concentration gradients across ion-exchange membranes. This work builds on previous efforts to describe the electroosmosis, the permselectivity and the apparent transport number of a membrane, and we show new measurements of concentration cells with the Selemion CMVN cation-exchange membrane and single-salt solutions of HCl, LiCl, NaCl, MgCl2, CaCl2 and NH4Cl. Ionic transport numbers and electroosmotic water transport relative to the membrane are efficiently obtained from a relatively new permselectivity analysis method. We find that the membrane can be described as perfectly selective towards the migration of the cation, and that Cl does not contribute to the net electric current. For the investigated salts, we obtained water transference coefficients, tw, of 1.1 ± 0.8 for HCl, 9.2 ± 0.8 for LiCl, 4.9 ± 0.2 for NaCl, 3.7 ± 0.4 for KCl, 8.5 ± 0.5 for MgCl2, 6.2 ± 0.6 for CaCl2 and 3.8 ± 0.5 for NH4Cl. However, as the test compartment concentrations of LiCl, MgCl2 and CaCl2 increased past 3.5, 1.3 and 1.4 mol kg−1, respectively, the water transference coefficients appeared to decrease. The presented methods are generally useful for characterising concentration polarisation phenomena in electrochemistry, and may aid in the design of more efficient electrochemical cells. Full article
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Figure 1
<p>Sketch of the concentration cell used for the cation-exchange membrane (CEM) electric potential measurements, <math display="inline"><semantics> <mrow> <mo>Δ</mo> <mi>ϕ</mi> </mrow> </semantics></math>. The composition is described by the molality, <math display="inline"><semantics> <msub> <mi>m</mi> <mrow> <mi mathvariant="normal">M</mi> <mi mathvariant="normal">C</mi> <msub> <mi mathvariant="normal">l</mi> <mrow> <mi mathvariant="normal">z</mi> <mo>+</mo> </mrow> </msub> </mrow> </msub> </semantics></math>, and the superscript “ref” denotes the reference compartment which always has a salt concentration of <math display="inline"><semantics> <mrow> <msubsup> <mi>m</mi> <mrow> <mrow> <mi mathvariant="normal">M</mi> <mi mathvariant="normal">C</mi> <msub> <mi mathvariant="normal">l</mi> <mrow> <mi>z</mi> <mo>+</mo> </mrow> </msub> </mrow> </mrow> <mi>ref</mi> </msubsup> <mo>=</mo> <mn>0.1</mn> </mrow> </semantics></math>. Arrows show the ionic species transport directions that contribute to the electron direction displayed and the measured net electric potential.</p>
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<p>(<b>a</b>) Non-linear regression (solid lines) of the measured electric potential, <math display="inline"><semantics> <mrow> <mo>Δ</mo> <mi>ϕ</mi> </mrow> </semantics></math>, as a function of the chemical potential difference across the membrane, <math display="inline"><semantics> <mrow> <mo>Δ</mo> <msub> <mi>μ</mi> <mrow> <mi mathvariant="normal">M</mi> <mi mathvariant="normal">C</mi> <msub> <mi mathvariant="normal">l</mi> <mrow> <mi>z</mi> <mo>+</mo> </mrow> </msub> </mrow> </msub> </mrow> </semantics></math>, of the salts HCl (left-facing triangles), LiCl (circles), NaCl (squares) and MgCl<sub>2</sub> (right-facing triangles). Red shaded areas show the 95% confidence interval of the regression curves. (<b>b</b>) The regression residuals, <math display="inline"><semantics> <msub> <mi>ϵ</mi> <mi>ϕ</mi> </msub> </semantics></math>, of the non-linear curves of NaCl and MgCl<sub>2</sub> illustrating the difference in variance of the repeated measurements compared to between different measurements.</p>
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<p>The apparent transport numbers, <math display="inline"><semantics> <msubsup> <mi>t</mi> <mrow> <mrow> <mi mathvariant="normal">M</mi> <mi mathvariant="normal">C</mi> <msub> <mi mathvariant="normal">l</mi> <mrow> <mi>z</mi> <mo>+</mo> </mrow> </msub> </mrow> </mrow> <mi>app</mi> </msubsup> </semantics></math>, as a function of the chemical potential difference across the membrane, <math display="inline"><semantics> <mrow> <mo>Δ</mo> <msub> <mi>μ</mi> <mrow> <mi mathvariant="normal">M</mi> <mi mathvariant="normal">C</mi> <msub> <mi mathvariant="normal">l</mi> <mrow> <mi>z</mi> <mo>+</mo> </mrow> </msub> </mrow> </msub> </mrow> </semantics></math>, of the salts HCl (left-facing triangles), LiCl (circles), NaCl (squares) and MgCl<sub>2</sub> (right-facing triangles). Red shaded areas show the 95% confidence interval of the regression curves.</p>
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<p>Linear regression (solid lines) of the permselectivity, <math display="inline"><semantics> <mi>α</mi> </semantics></math>, as a function of the chemical potential ratio, <math display="inline"><semantics> <mrow> <mo>Δ</mo> <msub> <mi>μ</mi> <mi>w</mi> </msub> <mo>/</mo> <mo>Δ</mo> <msub> <mi>μ</mi> <mrow> <mi mathvariant="normal">M</mi> <mi mathvariant="normal">C</mi> <msub> <mi mathvariant="normal">l</mi> <mrow> <mi>z</mi> <mo>+</mo> </mrow> </msub> </mrow> </msub> </mrow> </semantics></math> in the linear (low-salt-concentration) region. Red shaded areas show the 95% confidence interval of the linear regressions, and non-linear curves (dotted lines) show the deviation from linearity at high salt concentrations for some salts.</p>
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<p>The membrane water transference coefficients, <math display="inline"><semantics> <msub> <mi>t</mi> <mi>w</mi> </msub> </semantics></math>, from the linear region of the curves of <a href="#entropy-27-00075-f004" class="html-fig">Figure 4</a>, compared to the hydrated cation radius in bulk solutions, <math display="inline"><semantics> <msub> <mi>r</mi> <mi>h</mi> </msub> </semantics></math>, communicated by Nightingale [<a href="#B42-entropy-27-00075" class="html-bibr">42</a>]. The filled symbols show the values for Nafion 117 [<a href="#B29-entropy-27-00075" class="html-bibr">29</a>,<a href="#B39-entropy-27-00075" class="html-bibr">39</a>], and the dotted lines show general trends.</p>
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<p>The estimated average cation molal concentration across the membrane, <math display="inline"><semantics> <msub> <mover accent="true"> <mi>m</mi> <mo stretchy="false">¯</mo> </mover> <msub> <mi mathvariant="normal">M</mi> <mrow> <mi>z</mi> <mo>+</mo> </mrow> </msub> </msub> </semantics></math>, compared to the average external test solution concentration, <math display="inline"><semantics> <msubsup> <mover accent="true"> <mi>m</mi> <mo stretchy="false">¯</mo> </mover> <mrow> <msub> <mi mathvariant="normal">M</mi> <mrow> <mi>z</mi> <mo>+</mo> </mrow> </msub> </mrow> <mi>ext</mi> </msubsup> </semantics></math>. Curves are generated using the apparent transport numbers of <a href="#entropy-27-00075-f003" class="html-fig">Figure 3</a> together with the ionic transport number and water transference coefficient from the linear region of curves from <a href="#entropy-27-00075-f004" class="html-fig">Figure 4</a>. A solid red line shows the arithmetic mean of the external concentrations.</p>
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6 pages, 181 KiB  
Article
The Gibbs Fundamental Relation as a Tool for Relativity
by Friedrich Herrmann and Michael Pohlig
Entropy 2025, 27(1), 74; https://doi.org/10.3390/e27010074 - 15 Jan 2025
Viewed by 218
Abstract
When relativistic physics is lectured on, interest is focused on the behavior of mechanical and electromagnetic quantities during a reference frame change. However, not only mechanical and electromagnetic quantities transform during a reference frame change; thermodynamic and chemical quantities do too. We will [...] Read more.
When relativistic physics is lectured on, interest is focused on the behavior of mechanical and electromagnetic quantities during a reference frame change. However, not only mechanical and electromagnetic quantities transform during a reference frame change; thermodynamic and chemical quantities do too. We will study the transformations of temperature and chemical potential, show how to obtain the corresponding transformation equations with little effort, and exploit the fact that the energy conjugate extensive quantities, namely entropy and amount of substance, are Lorentz-invariant. Full article
23 pages, 5323 KiB  
Article
Entropies in Electric Circuits
by Angel Cuadras, Victoria J. Ovejas and Herminio Martínez-García
Entropy 2025, 27(1), 73; https://doi.org/10.3390/e27010073 - 15 Jan 2025
Viewed by 260
Abstract
The present study examines the relationship between thermal and configurational entropy in two resistors in parallel and in series. The objective is to introduce entropy in electric circuit analysis by considering the impact of system geometry on energy conversion in the circuit. Thermal [...] Read more.
The present study examines the relationship between thermal and configurational entropy in two resistors in parallel and in series. The objective is to introduce entropy in electric circuit analysis by considering the impact of system geometry on energy conversion in the circuit. Thermal entropy is derived from thermodynamics, whereas configurational entropy is derived from network modelling. It is observed that the relationship between thermal entropy and configurational entropy varies depending on the configuration of the resistors. In parallel resistors, thermal entropy decreases with configurational entropy, while in series resistors, the opposite is true. The implications of the maximum power transfer theorem and constructal law are discussed. The entropy generation for resistors at different temperatures was evaluated, and it was found that the consideration of resistor configurational entropy change was necessary for consistency. Furthermore, for the sake of generalization, a similar behaviour was observed in time-dependent circuits, either for resistor–capacitor circuits or circuits involving degradation. Full article
(This article belongs to the Section Multidisciplinary Applications)
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Figure 1
<p>Current divider with two resistors in parallel. <span class="html-italic">E</span> describes a power source, either of voltage or current.</p>
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<p>Voltage divider with two resistors in series. <span class="html-italic">E</span> stands either for a voltage or current source.</p>
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<p>Equivalent series resistance and capacitor with a power source <span class="html-italic">E</span>.</p>
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<p>Configurational entropy (left) and thermal entropy (right) as a function of the normalized resistor ratio for a current source of 1 A and integration time of 1 s. <span class="html-italic">S</span><sub>config</sub> maximum is 0.68 for equal resistors and evolve to 0 when the difference between resistors increases. <span class="html-italic">S</span><sub>therm</sub> increases with <span class="html-italic">R</span><sub>2</sub>.</p>
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<p>Thermodynamic entropy vs. Configurational entropy from a normalized current source (1 A, in black) and normalized voltage source (1 V, in dashed red line) and integrated for 1 s.</p>
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<p>Current through <span class="html-italic">R</span><sub>2</sub> for reference case at constant temperature (black), temperature-dependent resistor with <span class="html-italic">α</span> = 0.0040 (red), temperature-dependent resistor with <span class="html-italic">α</span> = −0.0005 (green), and temperature-independent resistors (blue). All cases considered <span class="html-italic">T</span><sub>1</sub> = 300 K and <span class="html-italic">T</span><sub>2</sub> = 400 K. The difference between the blue curve and the reference curve indicates that it is not possible to modify the thermal dissipation without changing the structure of the material, i.e., the temperature coefficient term proportional to <span class="html-italic">α</span>.</p>
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<p><span class="html-italic">S</span><sub>config</sub> change due to resistance variation on temperature with <span class="html-italic">α</span> = 0.0040 (dashed red line) with respect to the reference configuration (black).</p>
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<p><span class="html-italic">S</span><sub>therm</sub> for reference case (black) and for temperature-dependent resistor with <span class="html-italic">α</span> = 0.0040 (in red) for a current source of 1 A.</p>
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<p><span class="html-italic">S</span><sub>therm</sub> as a function of <span class="html-italic">S</span><sub>config</sub> for reference configuration without temperature variation (black), thermal-dependent resistor with <span class="html-italic">α</span> = 0.0040 (dashed red line) and resistor with <span class="html-italic">α</span> = −0.0005 (dotted blue line) for a current source of 1 A. The difference between curves is related to the configurational entropy change of the resistor due to the heat injection with the consequent temperature variation.</p>
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<p><span class="html-italic">S</span><sub>therm</sub> as a function of <span class="html-italic">S</span><sub>config</sub> for current source (black) and voltage source (dashed red line) for series resistors. The red point of maximum <span class="html-italic">S</span><sub>config</sub> and maximum <span class="html-italic">S</span><sub>therm</sub> corresponds to <span class="html-italic">R</span><sub>1</sub> = <span class="html-italic">R</span><sub>2</sub> as described by the maximum power transfer theorem and pointed out with the arrow.</p>
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<p><span class="html-italic">S</span><sub>therm</sub> as a function of <span class="html-italic">S</span><sub>config</sub> for reference configuration (black) and thermal-dependent resistor (dashed red line) with <span class="html-italic">α</span> = 0.0040 for a voltage source. The difference between both curves is related to the entropy change of the resistor.</p>
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<p>(<b>a</b>) Tree shape network with three elements. (<b>b</b>) <span class="html-italic">S</span><sub>config</sub> for 3 resistor circuit. <span class="html-italic">R</span><sub>1</sub>= 1 Ω, <span class="html-italic">R</span><sub>2</sub> is the variable, <span class="html-italic">R</span><sub>3</sub> is studied for two cases: <span class="html-italic">R</span><sub>3</sub> = 1 Ω (black line), and <span class="html-italic">R</span><sub>3</sub> = 10 Ω (dashed red line). (<b>c</b>) S<sub>therm</sub> for the circuit with <span class="html-italic">R</span><sub>3</sub> = 1 Ω (black line) and <span class="html-italic">R</span><sub>3</sub> = 10 Ω (dashed red line) <span class="html-italic">E</span> = 1 V and (<b>d</b>) S<sub>config</sub> and S<sub>therm</sub> relationship with <span class="html-italic">R</span><sub>3</sub> = 1 Ω (black line) and <span class="html-italic">R</span><sub>3</sub> = 10 Ω (dashed red line), <span class="html-italic">R</span><sub>2</sub> as a variable and <span class="html-italic">E</span> = 1 V. <span class="html-italic">R</span> symmetry is lost when <span class="html-italic">R</span><sub>3</sub> and <span class="html-italic">R</span><sub>1</sub> are different. The arrows point at the maximum <span class="html-italic">S</span><sub>config</sub>.</p>
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<p>(<b>a</b>) Tree shape network with seven elements (<b>b</b>) <span class="html-italic">S</span><sub>config</sub> for 7 resistor circuit. <span class="html-italic">R</span><sub>2</sub> is variable and <span class="html-italic">R</span><sub>3</sub> = 1 Ω (black line) and <span class="html-italic">R</span><sub>3</sub> = 10 Ω (dashed red line). All other resistors are fixed to 1 Ω. (<b>c</b>) <span class="html-italic">S</span><sub>therm</sub> for the circuit with <span class="html-italic">R</span><sub>3</sub> = 1 Ω (black line) and <span class="html-italic">R</span><sub>3</sub> = 10 Ω (dashed red line) <span class="html-italic">E</span> = 1 V and (<b>d</b>) <span class="html-italic">S</span><sub>config</sub> and <span class="html-italic">S</span><sub>therm</sub> relationship with <span class="html-italic">R</span><sub>3</sub> = 1 Ω (black line) and <span class="html-italic">R</span><sub>3</sub> = 10 Ω (dashed red line), <span class="html-italic">R</span><sub>2</sub> as a variable and <span class="html-italic">E</span> = 1 V. Symmetry is lost when <span class="html-italic">R</span><sub>3</sub> and <span class="html-italic">R</span><sub>1</sub> are different.</p>
Full article ">Figure 14
<p>(<b>a</b>) Circuit with two voltage sources and two resistors. (<b>b</b>) S<sub>config</sub> − S<sub>therm</sub> relationship for <span class="html-italic">V</span><sub>1</sub> = 1 V, <span class="html-italic">V</span><sub>2</sub> = 2 V and <span class="html-italic">R</span><sub>1</sub> = 1 Ω or 10 Ω. <span class="html-italic">R</span><sub>2</sub> is the swept variable.</p>
Full article ">Figure 15
<p>Modulus of S<sub>config</sub> as a function of frequency for <span class="html-italic">C</span> = 1 F, <span class="html-italic">R</span> = 1 Ω (black), and <span class="html-italic">R</span>= 10 Ω (dashed red line).</p>
Full article ">Figure 16
<p>Nyquist plot for <span class="html-italic">S</span><sub>config</sub> for <span class="html-italic">R</span> = 1 Ω, <span class="html-italic">C</span> = 1 F, and 1 mHz &lt; <span class="html-italic">ω</span> &lt; 1 kHz.</p>
Full article ">Figure 17
<p>Relationship between S<sub>config</sub> and S<sub>therm</sub> for an <span class="html-italic">R-C</span> system (<span class="html-italic">R</span> = 1 Ω, <span class="html-italic">C</span> = 1 F, and <span class="html-italic">T</span> = 300 K). A similar behaviour to resistor circuits is found, showing the generality of the method for linear systems.</p>
Full article ">Figure 18
<p>Time dependent profiles for degradation in a parallel <span class="html-italic">R</span><sub>1</sub>//<span class="html-italic">R</span><sub>2</sub> circuit with <span class="html-italic">R</span><sub>1</sub> = 1 Ω, <span class="html-italic">T</span> = 300 K, and <span class="html-italic">I</span> = 1 A. (<b>a</b>) Time evolution of resistor degradation according to Equations (22)–(24). (<b>b</b>) Time dependent evolution of <span class="html-italic">S</span><sub>config</sub>. (<b>c</b>) Time dependent evolution of <span class="html-italic">S</span><sub>therm</sub>. (<b>d</b>) Relationship between <span class="html-italic">S</span><sub>config</sub> − <span class="html-italic">S</span><sub>therm</sub>. (<b>e</b>) Relationship between <span class="html-italic">S</span><sub>config</sub> and <math display="inline"><semantics> <mrow> <mover accent="true"> <mrow> <mi>S</mi> </mrow> <mo>˙</mo> </mover> </mrow> </semantics></math><sub>thermal</sub>.</p>
Full article ">Figure 18 Cont.
<p>Time dependent profiles for degradation in a parallel <span class="html-italic">R</span><sub>1</sub>//<span class="html-italic">R</span><sub>2</sub> circuit with <span class="html-italic">R</span><sub>1</sub> = 1 Ω, <span class="html-italic">T</span> = 300 K, and <span class="html-italic">I</span> = 1 A. (<b>a</b>) Time evolution of resistor degradation according to Equations (22)–(24). (<b>b</b>) Time dependent evolution of <span class="html-italic">S</span><sub>config</sub>. (<b>c</b>) Time dependent evolution of <span class="html-italic">S</span><sub>therm</sub>. (<b>d</b>) Relationship between <span class="html-italic">S</span><sub>config</sub> − <span class="html-italic">S</span><sub>therm</sub>. (<b>e</b>) Relationship between <span class="html-italic">S</span><sub>config</sub> and <math display="inline"><semantics> <mrow> <mover accent="true"> <mrow> <mi>S</mi> </mrow> <mo>˙</mo> </mover> </mrow> </semantics></math><sub>thermal</sub>.</p>
Full article ">Figure 19
<p>Relationship between <span class="html-italic">S</span><sub>therm</sub> − <span class="html-italic">S</span><sub>config.</sub> It is the same data from <a href="#entropy-27-00073-f018" class="html-fig">Figure 18</a>d with the axis exchanged.</p>
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24 pages, 18984 KiB  
Article
Maximum-Power Stirling-like Heat Engine with a Harmonically Confined Brownian Particle
by Irene Prieto-Rodríguez, Antonio Prados and Carlos A. Plata
Entropy 2025, 27(1), 72; https://doi.org/10.3390/e27010072 - 15 Jan 2025
Viewed by 355
Abstract
Heat engines transform thermal energy into useful work, operating in a cyclic manner. For centuries, they have played a key role in industrial and technological development. Historically, only gases and liquids have been used as working substances, but the technical advances achieved in [...] Read more.
Heat engines transform thermal energy into useful work, operating in a cyclic manner. For centuries, they have played a key role in industrial and technological development. Historically, only gases and liquids have been used as working substances, but the technical advances achieved in recent decades allow for expanding the experimental possibilities and designing engines operating with a single particle. In this case, the system of interest cannot be addressed at a macroscopic level and their study is framed in the field of stochastic thermodynamics. In the present work, we study mesoscopic heat engines built with a Brownian particle submitted to harmonic confinement and immersed in a fluid acting as a thermal bath. We design a Stirling-like heat engine, composed of two isothermal and two isochoric branches, by controlling both the stiffness of the harmonic trap and the temperature of the bath. Specifically, we focus on the irreversible, non-quasi-static case—whose finite duration enables the engine to deliver a non-zero output power. This is a crucial aspect, which enables the optimisation of the thermodynamic cycle by maximising the delivered power—thereby addressing a key goal at the practical level. The optimal driving protocols are obtained by using both variational calculus and optimal control theory tools. Furthermore, we numerically explore the dependence of the maximum output power and the corresponding efficiency on the system parameters. Full article
(This article belongs to the Special Issue Control of Driven Stochastic Systems: From Shortcuts to Optimality)
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<p>Scheme of the stochastic Stirling cycle. The harmonic confining potential at the operating points of the cycle, from (<b>A</b>–<b>D</b>), is represented by the purple curves. The filled red and blue areas correspond to the probability density functions at those state points, where red (blue) refers to the hot (cold) equilibrium temperatures. The representation of the heat engine in the <math display="inline"><semantics> <mrow> <mo>(</mo> <mi>κ</mi> <mo>,</mo> <mi>y</mi> <mo>)</mo> </mrow> </semantics></math> plane corresponds to the quasi-static version of the described cycle.</p>
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<p>Projection onto the <math display="inline"><semantics> <mrow> <mo>(</mo> <mi>κ</mi> <mo>,</mo> <mi>y</mi> <mo>)</mo> </mrow> </semantics></math> plane of the phase trajectory in the Stirling heat engine. The left (right) panel corresponds to the reversible (irreversible) cycle. In both panels, <math display="inline"><semantics> <mrow> <mi>ν</mi> <mo>=</mo> <mi>χ</mi> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math>; for the irreversible case, we consider ideal bounds for the temperature, i.e., <math display="inline"><semantics> <mrow> <msub> <mi>θ</mi> <mo movablelimits="true" form="prefix">min</mo> </msub> <mo>→</mo> <msup> <mn>0</mn> <mo>+</mo> </msup> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <msub> <mi>θ</mi> <mo movablelimits="true" form="prefix">max</mo> </msub> <mo>→</mo> <mo>∞</mo> </mrow> </semantics></math>.</p>
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<p>Density plots of the optimal power (<b>left</b>) and the corresponding efficiency (<b>right</b>) in the <math display="inline"><semantics> <mrow> <mo>(</mo> <mi>ν</mi> <mo>,</mo> <mi>χ</mi> <mo>)</mo> </mrow> </semantics></math> plane. We consider the loosest bounds for the temperature: <math display="inline"><semantics> <mrow> <msub> <mi>θ</mi> <mo movablelimits="true" form="prefix">min</mo> </msub> <mo>→</mo> <msup> <mn>0</mn> <mo>+</mo> </msup> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <msub> <mi>θ</mi> <mo movablelimits="true" form="prefix">max</mo> </msub> <mo>→</mo> <mo>∞</mo> </mrow> </semantics></math>.</p>
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<p>Density plot of the optimal power in the <math display="inline"><semantics> <mrow> <mo>(</mo> <mi>ν</mi> <mo>,</mo> <mi>χ</mi> <mo>)</mo> </mrow> </semantics></math> plane (<b>left</b>) and vertical sections for fixed values of the temperature ratio <math display="inline"><semantics> <mi>ν</mi> </semantics></math> (<b>right</b>). The curve <math display="inline"><semantics> <mrow> <mi>χ</mi> <mo>=</mo> <msup> <mi>χ</mi> <mo>∗</mo> </msup> <mrow> <mo>(</mo> <mi>ν</mi> <mo>)</mo> </mrow> </mrow> </semantics></math> (dotted line) gives the compression ratio yielding optimal power for every temperature ratio. On the right, the upper panel corresponds to <math display="inline"><semantics> <mrow> <mi>ν</mi> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math> and the bottom one to <math display="inline"><semantics> <mrow> <mi>ν</mi> <mo>=</mo> <msup> <mi>ν</mi> <mo>∗</mo> </msup> </mrow> </semantics></math>. The points at which maximum power is reached in each case are also displayed (squares).</p>
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<p>Efficiency at maximum power in our approach (black solid line), Carnot efficiency (red dotted line), Curzon–Ahlborn efficiency (blue dashed line) and <math display="inline"><semantics> <msub> <mi>η</mi> <mo>+</mo> </msub> </semantics></math> (green dash-dotted line), defined in Equation (<a href="#FD70-entropy-27-00072" class="html-disp-formula">70</a>), as a function of the temperature ratio <math display="inline"><semantics> <mi>ν</mi> </semantics></math>.</p>
Full article ">Figure 6
<p>Optimal compression ratio <math display="inline"><semantics> <msup> <mi>χ</mi> <mo>∗</mo> </msup> </semantics></math> as a function of the Carnot efficiency <math display="inline"><semantics> <mrow> <msub> <mi>η</mi> <mi>C</mi> </msub> <mo>=</mo> <mn>1</mn> <mo>−</mo> <mi>ν</mi> </mrow> </semantics></math>. We compare numerical results (black circles) with the theoretical expansion in <math display="inline"><semantics> <msub> <mi>η</mi> <mi>C</mi> </msub> </semantics></math> up to cubic order, as given by Equations (<a href="#FD71-entropy-27-00072" class="html-disp-formula">71</a>) and (<a href="#FD72-entropy-27-00072" class="html-disp-formula">72</a>) (blue solid line). The inset shows the difference between the numerical results and the first-order approximation <math display="inline"><semantics> <mrow> <mn>1</mn> <mo>+</mo> <msub> <mi>a</mi> <mn>1</mn> </msub> <msub> <mi>η</mi> <mi>C</mi> </msub> </mrow> </semantics></math>, which is very small, of the order of <math display="inline"><semantics> <msup> <mn>10</mn> <mrow> <mo>−</mo> <mn>3</mn> </mrow> </msup> </semantics></math>, up to <math display="inline"><semantics> <mrow> <msub> <mi>η</mi> <mi>C</mi> </msub> <mo>≃</mo> <mn>0.4</mn> </mrow> </semantics></math>.</p>
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<p>Optimal power <math display="inline"><semantics> <mover accent="true"> <mi mathvariant="script">P</mi> <mo>˜</mo> </mover> </semantics></math> as a function of the compression ratio <math display="inline"><semantics> <mi>χ</mi> </semantics></math> for fixed temperature ratio <math display="inline"><semantics> <mi>ν</mi> </semantics></math> and different values of the temperature bounds <math display="inline"><semantics> <mrow> <mo>(</mo> <msub> <mi>θ</mi> <mo movablelimits="true" form="prefix">min</mo> </msub> <mo>,</mo> <msub> <mi>θ</mi> <mo movablelimits="true" form="prefix">max</mo> </msub> <mo>)</mo> </mrow> </semantics></math>. In the four panels, we consider two values of <math display="inline"><semantics> <mi>ν</mi> </semantics></math>, <math display="inline"><semantics> <mrow> <mi>ν</mi> <mo>=</mo> <mn>0.5</mn> </mrow> </semantics></math> (<b>top</b>) and <math display="inline"><semantics> <mrow> <mi>ν</mi> <mo>=</mo> <msubsup> <mi>ν</mi> <mi>id</mi> <mo>∗</mo> </msubsup> </mrow> </semantics></math> (<b>bottom</b>) together with <math display="inline"><semantics> <mrow> <msub> <mi>θ</mi> <mo movablelimits="true" form="prefix">max</mo> </msub> <mo>→</mo> <mo>+</mo> <mo>∞</mo> </mrow> </semantics></math> (<b>left</b>) and <math display="inline"><semantics> <mrow> <msub> <mi>θ</mi> <mo movablelimits="true" form="prefix">min</mo> </msub> <mo>→</mo> <msup> <mn>0</mn> <mo>+</mo> </msup> </mrow> </semantics></math> (<b>right</b>). In this way, we have the ideal upper (lower) bound of the temperature in the left (right) panels, whereas several different values of the other, non-ideal, temperature bound are considered. The optimal power corresponding to the ideal limit of both bounds is also displayed in all the panels (dotted black line), which is reached when the non-ideal temperature bound approaches its ideal value.</p>
Full article ">Figure 8
<p>Density plots of the temperature and compression ratios (<b>top panels</b>) yielding optimal power (<b>bottom-left panel</b>), and the corresponding efficiency (<b>bottom-right panel</b>) in the <math display="inline"><semantics> <mfenced separators="" open="(" close=")"> <msub> <mi>θ</mi> <mo movablelimits="true" form="prefix">min</mo> </msub> <mo>,</mo> <msub> <mi>θ</mi> <mo movablelimits="true" form="prefix">max</mo> </msub> </mfenced> </semantics></math> plane. We consider the region defined by intervals <math display="inline"><semantics> <mrow> <mn>0</mn> <mo>&lt;</mo> <msub> <mi>θ</mi> <mo movablelimits="true" form="prefix">min</mo> </msub> <mo>&lt;</mo> <mn>0.4</mn> </mrow> </semantics></math>, <math display="inline"><semantics> <mrow> <mn>1.15</mn> <mo>&lt;</mo> <msub> <mi>θ</mi> <mo movablelimits="true" form="prefix">max</mo> </msub> <mo>&lt;</mo> <mn>2.50</mn> </mrow> </semantics></math>.</p>
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22 pages, 8302 KiB  
Article
Refraction of the Two-Photon Multimode Field via a Three-Level Atom
by Trever Harborth and Yuri Rostovtsev
Entropy 2025, 27(1), 71; https://doi.org/10.3390/e27010071 - 15 Jan 2025
Viewed by 374
Abstract
Classically, the refractive index of a medium is due to a response on said medium from an electromagnetic field. It has been shown that a single two-level atom interacting with a single photon undergoes dispersion. The following extends that analyses to a three-level [...] Read more.
Classically, the refractive index of a medium is due to a response on said medium from an electromagnetic field. It has been shown that a single two-level atom interacting with a single photon undergoes dispersion. The following extends that analyses to a three-level system interacting with two photons. Analysis of the system is completed both numerically for all photonic field modes, and analytically for an adiabatic solution of a single field mode. The findings are not only interesting for understanding additional physical phenomena due to the increased complexity of a three-level, two-photon system, but are also necessary for advancing applications such as quantum communications, quantum computation, and quantum information. Full article
(This article belongs to the Special Issue Entropy, Quantum Information and Entanglement)
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<p>Depiction of the electronic energy structure of a three-level ladder atom interacting with two photons, <span class="html-italic">k</span> and <span class="html-italic">q</span>.</p>
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<p>Depiction of the quantum four-port beam splitter. The beam splitter takes in two input states, <math display="inline"><semantics> <mrow> <mrow> <mo>|</mo> </mrow> <msub> <mi>α</mi> <mn>1</mn> </msub> <mrow> <mo>〉</mo> </mrow> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mrow> <mo>|</mo> </mrow> <msub> <mi>α</mi> <mn>2</mn> </msub> <mrow> <mo>〉</mo> </mrow> </mrow> </semantics></math>, and produces two output states <math display="inline"><semantics> <mrow> <mrow> <mo>|</mo> </mrow> <msub> <mi>β</mi> <mn>1</mn> </msub> <mrow> <mo>〉</mo> </mrow> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mrow> <mo>|</mo> </mrow> <msub> <mi>β</mi> <mn>2</mn> </msub> <mrow> <mo>〉</mo> </mrow> </mrow> </semantics></math>.</p>
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<p>Depiction of the Mach–Zehnder interferometer. In the upper arm resides a three-level atom, while in the lower arm is a variable phase changer.</p>
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<p>Demonstration of the phase of <math display="inline"><semantics> <mrow> <msubsup> <mi>A</mi> <mi>k</mi> <mi>q</mi> </msubsup> <mrow> <mo>(</mo> <mi>t</mi> <mo>)</mo> </mrow> </mrow> </semantics></math> for various modes of the <math display="inline"><semantics> <mrow> <mi>k</mi> </mrow> </semantics></math>-photon. The <span class="html-italic">q</span>-photon was chosen to be in the <math display="inline"><semantics> <mrow> <mi>q</mi> <mo>=</mo> <mn>1</mn> </mrow> </semantics></math> mode.</p>
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<p>Output configuration probabilities for the Mach–Zehnder interferometer with a <math display="inline"><semantics> <mi>χ</mi> </semantics></math>-phase changer in the lower arm.</p>
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<p>Probability for the electron to be in a given atomic level over the simulation time.</p>
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<p>Probability that the <span class="html-italic">k</span> and <span class="html-italic">q</span> photons exist.</p>
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<p>Demonstration of the <span class="html-italic">k</span>-photon with equal probability to be in any mode approaching and interacting with the three-level atom. Verification that atomic interaction changes the photon wave packet. The <span class="html-italic">q</span> photon is in the <math display="inline"><semantics> <mrow> <mi>q</mi> <mo>=</mo> <mn>1</mn> </mrow> </semantics></math> mode.</p>
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<p>Demonstration of the conservation of probability with the simulated system.</p>
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16 pages, 1633 KiB  
Article
Advancing Rice Grain Impurity Segmentation with an Enhanced SegFormer and Multi-Scale Feature Integration
by Xiulin Qiu, Hongzhi Yao, Qinghua Liu, Hongrui Liu, Haozhi Zhang and Mengdi Zhao
Entropy 2025, 27(1), 70; https://doi.org/10.3390/e27010070 - 15 Jan 2025
Viewed by 333
Abstract
During the rice harvesting process, severe occlusion and adhesion exist among multiple targets, such as rice, straw, and leaves, making it difficult to accurately distinguish between rice grains and impurities. To address the current challenges, a lightweight semantic segmentation algorithm for impurities based [...] Read more.
During the rice harvesting process, severe occlusion and adhesion exist among multiple targets, such as rice, straw, and leaves, making it difficult to accurately distinguish between rice grains and impurities. To address the current challenges, a lightweight semantic segmentation algorithm for impurities based on an improved SegFormer network is proposed. To make full use of the extracted features, the decoder was redesigned. First, the Feature Pyramid Network (FPN) was introduced to optimize the structure, selectively fusing the high-level semantic features and low-level texture features generated by the encoder. Secondly, a Part Large Kernel Attention (Part-LKA) module was designed and introduced after feature fusion to help the model focus on key regions, simplifying the model and accelerating computation. Finally, to compensate for the lack of spatial interaction capabilities, Bottleneck Recursive Gated Convolution (B-gnConv) was introduced to achieve effective segmentation of rice grains and impurities. Compared with the original model, the improved model’s pixel accuracy (PA) and F1 score increased by 1.6% and 3.1%, respectively. This provides a valuable algorithmic reference for designing a real-time impurity rate monitoring system for rice combine harvesters. Full article
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<p>Improved model network architecture. Note: H represents the height (number of rows of pixels), W represents the width (number of columns of pixels), C represents the number of channels, MLP stands for Multi-Layer Perceptron, Part-LKA represents the Part Large Kernel Attention module, and B-<math display="inline"><semantics> <msup> <mi mathvariant="normal">g</mi> <mi>n</mi> </msup> </semantics></math>Conv represents the Bottleneck Recursive Gated Convolution.</p>
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<p>Encoder network architecture.</p>
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<p>FPN structure before and after improvement.</p>
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<p>Part-LKA network structure.</p>
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<p>Bottleneck-<math display="inline"><semantics> <msup> <mi mathvariant="normal">g</mi> <mi>n</mi> </msup> </semantics></math>Conv network structure.</p>
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<p>Image annotation results.</p>
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<p>Class Activation Maps of sample images from the original and improved models.</p>
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<p>Visual comparison of segmentation results between the original and improved models.</p>
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26 pages, 348 KiB  
Article
Reporting Standards for Bayesian Network Modelling
by Martine J. Barons, Anca M. Hanea, Steven Mascaro and Owen Woodberry
Entropy 2025, 27(1), 69; https://doi.org/10.3390/e27010069 - 15 Jan 2025
Viewed by 374
Abstract
Reproducibility is a key measure of the veracity of a modelling result or finding. In other research areas, notably in medicine, reproducibility is supported by mandating the inclusion of an agreed set of details into every research publication, facilitating systematic reviews, transparency and [...] Read more.
Reproducibility is a key measure of the veracity of a modelling result or finding. In other research areas, notably in medicine, reproducibility is supported by mandating the inclusion of an agreed set of details into every research publication, facilitating systematic reviews, transparency and reproducibility. Governments and international organisations are increasingly turning to modelling approaches in the development and decision-making for policy and have begun asking questions about accountability in model-based decision making. The ethical issues of relying on modelling that is biased, poorly constructed, constrained by heroic assumptions and not reproducible are multiplied when such models are used to underpin decisions impacting human and planetary well-being. Bayesian Network modelling is used in policy development and decision support across a wide range of domains. In light of the recent trend for governments and other organisations to demand accountability and transparency, we have compiled and tested a reporting checklist for Bayesian Network modelling which will bring the desirable level of transparency and reproducibility to enable models to support decision making and allow the robust comparison and combination of models. The use of this checklist would support the ethical use of Bayesian network modelling for impactful decision making and research. Full article
(This article belongs to the Special Issue Bayesian Network Modelling in Data Sparse Environments)
12 pages, 834 KiB  
Article
A Post-Processing Method for Quantum Random Number Generator Based on Zero-Phase Component Analysis Whitening
by Longju Liu, Jie Yang, Mei Wu, Jinlu Liu, Wei Huang, Yang Li and Bingjie Xu
Entropy 2025, 27(1), 68; https://doi.org/10.3390/e27010068 - 14 Jan 2025
Viewed by 399
Abstract
Quantum Random Number Generators (QRNGs) have been theoretically proven to be able to generate completely unpredictable random sequences, and have important applications in many fields. However, the practical implementation of QRNG is always susceptible to the unwanted classical noise or device imperfections, which [...] Read more.
Quantum Random Number Generators (QRNGs) have been theoretically proven to be able to generate completely unpredictable random sequences, and have important applications in many fields. However, the practical implementation of QRNG is always susceptible to the unwanted classical noise or device imperfections, which inevitably diminishes the quality of the generated random bits. It is necessary to perform the post-processing to extract the true quantum randomness contained in raw data generated by the entropy source of QRNG. In this work, a novel post-processing method for QRNG based on Zero-phase Component Analysis (ZCA) whitening is proposed and experimentally verified through both time and spectral domain analysis, which can effectively reduce auto-correlations and flatten the spectrum of the raw data, and enhance the random number generation rate of QRNG. Furthermore, the randomness extraction is performed after ZCA whitening, after which the final random bits can pass the NIST test. Full article
(This article belongs to the Special Issue Network Information Theory and Its Applications)
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<p>The typical structure of a QRNG.</p>
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<p>The proposed post-processing scheme for QRNG.</p>
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<p>Data blocks when <math display="inline"><semantics> <mrow> <mi>m</mi> <mo>=</mo> <mn>3</mn> </mrow> </semantics></math>.</p>
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<p>Experimental set up of ASE scheme to acquire the raw data. SLED: superluminescent light emitting diode; PD: photodetector; DSO: digital storage oscilloscope.</p>
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<p>Statistical histogram of raw data for the QRNG based on ASE noise.</p>
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<p>Auto-correlation coefficients before and after ZCA whitening.</p>
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<p>Power spectral density analysis before and after ZCA whitening.</p>
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<p>The results of the NIST-STS test.</p>
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<p>Auto-correlation coefficients of raw data2 and raw data3.</p>
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17 pages, 4366 KiB  
Article
Shannon Entropy Computations in Navier–Stokes Flow Problems Using the Stochastic Finite Volume Method
by Marcin Kamiński and Rafał Leszek Ossowski
Entropy 2025, 27(1), 67; https://doi.org/10.3390/e27010067 - 14 Jan 2025
Viewed by 332
Abstract
The main aim of this study is to achieve the numerical solution for the Navier–Stokes equations for incompressible, non-turbulent, and subsonic fluid flows with some Gaussian physical uncertainties. The higher-order stochastic finite volume method (SFVM), implemented according to the iterative generalized stochastic perturbation [...] Read more.
The main aim of this study is to achieve the numerical solution for the Navier–Stokes equations for incompressible, non-turbulent, and subsonic fluid flows with some Gaussian physical uncertainties. The higher-order stochastic finite volume method (SFVM), implemented according to the iterative generalized stochastic perturbation technique and the Monte Carlo scheme, are engaged for this purpose. It is implemented with the aid of the polynomial bases for the pressure–velocity–temperature (PVT) solutions, for which the weighted least squares method (WLSM) algorithm is applicable. The deterministic problem is solved using the freeware OpenFVM, the computer algebra software MAPLE 2019 is employed for the LSM local fittings, and the resulting probabilistic quantities are computed. The first two probabilistic moments, as well as the Shannon entropy spatial distributions, are determined with this apparatus and visualized in the FEPlot software. This approach is validated using the 2D heat conduction benchmark test and then applied for the probabilistic version of the 3D coupled lid-driven cavity flow analysis. Such an implementation of the SFVM is applied to model the 2D lid-driven cavity flow problem for statistically homogeneous fluid with limited uncertainty in its viscosity and heat conductivity. Further numerical extension of this technique is seen in an application of the artificial neural networks, where polynomial approximation may be replaced automatically by some optimal, and not necessarily polynomial, bases. Full article
(This article belongs to the Section Multidisciplinary Applications)
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<p>3D view of a single finite volume.</p>
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<p>CVs configuration with boundary conditions in the 2D numerical test.</p>
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<p>Expected values (<b>a</b>) and coefficients of variation (<b>b</b>) of the temperatures for Gaussian heat conductivity.</p>
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<p>Shannon entropies of temperatures in the heat flow test for Gaussian heat conductivity.</p>
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<p>Shannon entropies of temperatures T<sub>1</sub> (<b>a</b>) and T<sub>2</sub> (<b>b</b>) in the heat flow test for Gaussian heat conductivity <span class="html-italic">k</span>, according to the random samples in the MCS analysis.</p>
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<p>A comparison of the temperature expectations (T<sub>1</sub> (<b>a</b>) &amp; T<sub>2</sub> (<b>b</b>)) in the given discrete volumes using three concurrent computational techniques.</p>
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<p>A comparison of the temperature coefficients of variation (T<sub>1</sub> (<b>a</b>) &amp; T<sub>2</sub> (<b>b</b>)) in the given discrete volumes using three concurrent computational techniques.</p>
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<p>Common influence of the input uncertainty and the perturbation parameter on (<b>a</b>) expected values and (<b>b</b>) coefficients of variation of the temperature in the finite volume 1.</p>
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<p>Boundary conditions for the lid-driven cavity flow.</p>
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<p>Expected values of the temperature field in the lid-driven cavity flow test for Gaussian viscosity (<b>a</b>) and heat conductivity (<b>b</b>).</p>
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<p>Coefficients of variation of the temperature field in the lid-driven cavity flow test for Gaussian viscosity (<b>a</b>) and heat conductivity (<b>b</b>).</p>
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<p>Shannon entropies for the temperature field in the lid-driven cavity flow test for Gaussian viscosity (<b>a</b>) and heat conductivity (<b>b</b>).</p>
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