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KEGG   REACTION: R13155
Entry
R13155                      Reaction                               
Definition
Quillaic acid 3-O-beta-D-xylosyl-1,3-(beta-D-galactosyl-1,2)-beta-D-glucuronide <=> Quillaic acid 3-O-beta-D-xylosyl-1,3-(beta-D-galactosyl-1,2)-beta-D-glucuronide-28-O-beta-D-fucoside
Equation
C22654 <=> C22656
Comment
glycosyltransferase / dehydrogenase
unclear reaction
Reaction class
RC00523  C22654_C22656
Pathway
rn00999  Biosynthesis of various plant secondary metabolites
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00971  QS-7 biosynthesis, 2,3-epoxysqualene => QS-7
Orthology
K26487  quillaic acid 3-O-Xyl/L-Rha-1,3-(Gal-1,2)-GlcA 28-O-glycosyltransferase
K26488  4-keto-6-deoxyglucose 4-dehydrogenase
Reference
1  [PMID:36952412]
  Authors
Reed J, Orme A, El-Demerdash A, Owen C, Martin LBB, Misra RC, Kikuchi S, Rejzek M, Martin AC, Harkess A, Leebens-Mack J, Louveau T, Stephenson MJ, Osbourn A.
  Title
Elucidation of the pathway for biosynthesis of saponin adjuvants from the soapbark tree.
  Journal
Science 379:1252-1264 (2023)
DOI:10.1126/science.adf3727

  All links  
Pathway (7)   
   KEGG PATHWAY (6)   
   KEGG MODULE (1)   
Chemical substance (2)   
   KEGG COMPOUND (2)   
Chemical reaction (1)   
   KEGG RCLASS (1)   
Gene (29)   
   KEGG ORTHOLOGY (2)   
   KEGG GENES (27)   
All databases (39)   

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