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KEGG   COMPOUND: C15972
Entry
C15972                      Compound                               
Name
Enzyme N6-(lipoyl)lysine;
Lipoamide-E;
[E2 protein]-N6-lipoyl-L-lysine;
[Lipoyl-carrier protein E2]-N6-lipoyl-L-lysine
Formula
C8H14NOS2R
Structure
Comment
Generic compound in reaction hierarchy
The oxidized lipoyllysine residue in EC 2.3.1.12, dihydrolipoyllysine-residue acetyltransferase ( EC 2.3.1.61, dihydrolipoyllysine-residue succinyltransferase or EC 2.3.1.168, dihydrolipoyllysine-residue (2-methylpropanoyl)transferase ).
Reaction
Pathway
map00010  Glycolysis / Gluconeogenesis
map00020  Citrate cycle (TCA cycle)
map00280  Valine, leucine and isoleucine degradation
map00310  Lysine degradation
map00620  Pyruvate metabolism
map00640  Propanoate metabolism
map00785  Lipoic acid metabolism
map01100  Metabolic pathways
map01240  Biosynthesis of cofactors
Module
M00009  Citrate cycle (TCA cycle, Krebs cycle)
M00011  Citrate cycle, second carbon oxidation, 2-oxoglutarate => oxaloacetate
M00032  Lysine degradation, lysine => saccharopine => acetoacetyl-CoA
M00036  Leucine degradation, leucine => acetoacetate + acetyl-CoA
M00307  Pyruvate oxidation, pyruvate => acetyl-CoA
Network
nt06024  Valine, leucine and isoleucine degradation
nt06031  Citrate cycle and pyruvate metabolism
nt06032  Lipoic acid metabolism
nt06036  Lysine degradation
Enzyme
1.2.4.1         1.2.4.2         1.2.4.4         1.2.4.-         
1.8.1.4         1.11.1.28       2.3.1.200       2.3.1.313       
6.3.1.20
Other DBs
PubChem: 47205285
ChEBI: 80218
KCF data

ATOM        13
            1   S3x S    14.9894  -14.4968
            2   S3x S    13.5885  -14.4968
            3   C1x C    13.1557  -15.8291
            4   C1x C    14.2890  -16.6526
            5   C1y C    15.4223  -15.8291
            6   C1b C    16.6229  -16.5281
            7   C1b C    17.8362  -15.8276
            8   C1b C    19.0493  -16.5281
            9   C1b C    20.2625  -15.8276
            10  C5a C    21.4758  -16.5281
            11  N1b N    22.6890  -15.8276
            12  O5a O    21.4758  -17.9290
            13  R   R    24.0899  -15.8276
BOND        13
            1     1   2 1
            2     2   3 1
            3     3   4 1
            4     4   5 1
            5     1   5 1
            6     5   6 1 #Down
            7     6   7 1
            8     7   8 1
            9     8   9 1
            10    9  10 1
            11   10  11 1
            12   10  12 2
            13   11  13 1

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