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Maleimide cross-linked bioactive PEG hydrogel exhibits improved reaction kinetics and cross-linking for cell encapsulation and in situ delivery

Adv Mater. 2012 Jan 3;24(1):64-70, 2. doi: 10.1002/adma.201103574. Epub 2011 Dec 16.

Abstract

Engineered polyethylene glycol-maleimide matrices for regenerative medicine exhibit improved reaction efficiency and wider range of Young’s moduli by utilizing maleimide cross-linking chemistry. This hydrogel chemistry is advantageous for cell delivery due to the mild reaction that occurs rapidly enough for in situ delivery, while easily lending itself to “plug-and-play” design variations such as incorporation of enzyme-cleavable cross-links and cell-adhesion peptides.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Animals
  • Cell Line
  • Collagen / metabolism
  • Cross-Linking Reagents / chemistry*
  • Hydrogel, Polyethylene Glycol Dimethacrylate / chemistry*
  • Kinetics
  • Maleimides / chemistry*
  • Mice
  • Oligopeptides / chemistry
  • Oligopeptides / metabolism
  • Polyethylene Glycols / chemistry*
  • Regenerative Medicine
  • Transfection

Substances

  • Cross-Linking Reagents
  • Maleimides
  • Oligopeptides
  • maleimide
  • Hydrogel, Polyethylene Glycol Dimethacrylate
  • Polyethylene Glycols
  • arginyl-glycyl-aspartic acid
  • Collagen