Stereocontrolled synthesis of tetrasubstituted olefins

AB Flynn, WW Ogilvie - Chemical reviews, 2007 - ACS Publications
olefins employ different types of alkynyl carbometallation strategies, although another common
technique is the transformation of existing olefins. … form tetrasubstituted olefins have been …

Azidation in the Difunctionalization of Olefins

K Wu, Y Liang, N Jiao - Molecules, 2016 - mdpi.com
Organic azides are key motifs in compounds of relevance to chemical biology, medicinal
chemistry and materials science. In addition, they also serve as useful building blocks due to …

Olefins from biomass intermediates: a review

V Zacharopoulou, AA Lemonidou - Catalysts, 2017 - mdpi.com
… for olefins and their valuable products has prompted research on novel processes and
technologies for their selective production. As olefins are … into the valuable olefins, among other …

Hydromethylation of unactivated olefins

HT Dao, C Li, Q Michaudel, BD Maxwell… - Journal of the …, 2015 - ACS Publications
… The scope of olefins that can be hydromethylated is illustrated in Table 2. Monosubstituted
olefins bearing an aromatic triflate and even a free phenol worked smoothly (1c,d), as did a …

Hydroaminoalkylation of unactivated olefins with dialkylamines

SB Herzon, JF Hartwig - Journal of the American Chemical …, 2008 - ACS Publications
The intermolecular addition of the α-C−H bonds of unactivated dialkylamines to unactivated
olefins in the presence of the chloro amido complex [TaCl 3 (NEt 2 ) 2 ] 2 (2) is described. …

The addition of dichlorocarbene to olefins

W von E. Doering, AK Hoffmann - Journal of the American …, 1954 - ACS Publications
The reaction of chloroform with cyclohexene in the presence of potassium-butoxide gives
an excellent yield of a product, CtHilCL, which contains the bicyclo [4.1. 0] heptane (norcarane) …

Dicarboalkoxylation of olefins and acetylenes

RF Heck - Journal of the American Chemical Society, 1972 - ACS Publications
… Abstract: A convenient procedure is described for converting olefins into
substitutedsuccinate esters and acetylenes into substitutedmaleate esters, by addition of two …

Catalysts for production of lower olefins from synthesis gas: a review

HM Torres Galvis, KP de Jong - ACS catalysis, 2013 - ACS Publications
… in producing lower olefins from alternative feedstocks … olefins from synthesis gas with an
emphasis on a direct or single step process, the so-called FTO or Fischer–Tropsch to olefins

Evaluation and prediction of the stability of bridgehead olefins

WF Maier, PVR Schleyer - Journal of the American Chemical …, 1981 - ACS Publications
Conclusion The stabilities of the C6H5+ system are calculated as shown in Table I. The
lowest activation energy for elimination of C2H2 from 1 is predicted to be 108 kcal/mol. This …

Techno-economic analysis of the coal-to-olefins process in comparison with the oil-to-olefins process

D Xiang, Y Qian, Y Man, S Yang - Applied Energy, 2014 - Elsevier
… This study is concerned with the opportunities and obstacles of coal-to-olefins … -to-olefins
plant with the capacity of 0.7 Mt/a olefins. Comparison is made with a 1.5 Mt/a oil-to-olefins plant …